CN106525951A - Device and method for detecting methane content in gas - Google Patents

Device and method for detecting methane content in gas Download PDF

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Publication number
CN106525951A
CN106525951A CN201610875084.2A CN201610875084A CN106525951A CN 106525951 A CN106525951 A CN 106525951A CN 201610875084 A CN201610875084 A CN 201610875084A CN 106525951 A CN106525951 A CN 106525951A
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connector
quantitative loop
gas
quantitative
way valve
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CN201610875084.2A
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余超
李新颖
姜知明
宋新
郑梦甜
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Suzhou Fir Precision Instrument Co Ltd
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Suzhou Fir Precision Instrument Co Ltd
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Priority to CN201610875084.2A priority Critical patent/CN106525951A/en
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
    • G01N27/62Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating the ionisation of gases, e.g. aerosols; by investigating electric discharges, e.g. emission of cathode
    • G01N27/626Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating the ionisation of gases, e.g. aerosols; by investigating electric discharges, e.g. emission of cathode using heat to ionise a gas
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N1/00Sampling; Preparing specimens for investigation
    • G01N1/02Devices for withdrawing samples
    • G01N1/22Devices for withdrawing samples in the gaseous state
    • G01N1/2273Atmospheric sampling
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
    • G01N27/62Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating the ionisation of gases, e.g. aerosols; by investigating electric discharges, e.g. emission of cathode
    • G01N27/64Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating the ionisation of gases, e.g. aerosols; by investigating electric discharges, e.g. emission of cathode using wave or particle radiation to ionise a gas, e.g. in an ionisation chamber

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  • Health & Medical Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Pathology (AREA)
  • General Physics & Mathematics (AREA)
  • Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Analytical Chemistry (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Electrochemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Toxicology (AREA)
  • Engineering & Computer Science (AREA)
  • Biomedical Technology (AREA)
  • Molecular Biology (AREA)
  • Other Investigation Or Analysis Of Materials By Electrical Means (AREA)

Abstract

The invention relates to the field of gas component detection, in particular to the field of gas methane content detection and provides a device for detecting methane content in gas and a methane content detecting method applying the detecting device. The methane content detecting device comprises a multi-way valve, quantitative rings, a gas sampling system, a gas carrying and delivery system, a gas control system and a detector, wherein the quantitative rings include the first quantitative ring and the second quantitative ring, and the detector comprises a flame ionization detector and a light ionization detector. By the adoption of the technical scheme, rapid detection of the methane content in gas can be achieved without a chromatographic column, and the online gas component detecting efficiency is greatly improved.

Description

Methane content testing equipment and detection method in a kind of gas
Technical field
The present invention relates to field of gas detection, more particularly, it relates to methane content testing equipment and inspection in a kind of gas Survey method.
Background technology
Methane is a kind of greenhouse gases, and for unit formula number, the greenhouse effect of methane is bigger than carbon dioxide 25 times. Although methane is substantially nontoxic to people, during excessive concentration, in making air, oxygen content is substantially reduced, and makes one asphyxia, when in air When methane reaches 25%-30%, can cause headache, it is dizzy, weak, absent minded, situations such as breathe and palpitate quickly.If too late When away from death by suffocation can be caused.
In view of in air methane a variety of harm, to the polluter that produces methane, to carry out on-line monitoring just very necessary.
The content of the invention
The present invention is in order to solve above-mentioned technical problem, there is provided methane content testing equipment in a kind of gas, can solve the problem that The problem that methane content detection is present in existing gas.
Corresponding to this, another technical problem to be solved of the invention is to provide a kind of using methane content inspection in the gas The detection method of measurement equipment.
For methane content testing equipment in gas, the testing equipment for solving the technical problem of the invention includes many Port valve, quantitative loop, gas sampling system, carrier gas induction system, gas control system and detector;Characterized in that, described Quantitative loop includes the first quantitative loop and the second quantitative loop, and the detector includes flame ionization detector and photoionization inspection Survey device;
There is the multiple-way valve gas sampling system connector, first the first connector of quantitative loop, the first quantitative loop second to connect Mouth, second the first connector of quantitative loop, second the second connector of quantitative loop, the first connector of carrier gas induction system, carrier gas conveying The second connector of device, flame ionization detector connector, photoionization detector connector and air pump connector;Institute State first the first connector of quantitative loop, the first quantitative loop, first the second connector of quantitative loop to be sequentially connected;Second quantitative loop First connector, the second quantitative loop, second the second connector of quantitative loop are sequentially connected;
The multiple-way valve has load condition position and sample introduction mode bit, and when multiple-way valve is located at load condition position, the gas is adopted Sample system connector, first the first connector of quantitative loop, the first quantitative loop, first the second connector of quantitative loop, the second quantitative loop First connector, the second quantitative loop, second the second connector of quantitative loop, air pump connector are sequentially communicated, it is ensured that sample gas is gathered To the first quantitative loop and the second quantitative loop;When the multiple-way valve is located at sample introduction mode bit, the first connector of carrier gas induction system, First the first connector of quantitative loop, the first quantitative loop, first the second connector of quantitative loop, flame ionization detector connector according to Secondary connection, the second connector of carrier gas induction system, second the first connector of quantitative loop, the second quantitative loop, the second quantitative loop second Connector, photoionization detector connector are sequentially communicated.
Used as the improvement of the present invention, gas sampling system includes air pump, two-position three-way valve and manograph.
Used as the improvement of the present invention, multiple-way valve is to adopt ten-way valve, it would however also be possible to employ two groups of six-way valves.
Used as the improvement of the present invention, gas control system includes electronic pressure controller, void column and vapour lock.
Used as the improvement of the present invention, carrier gas induction system includes a three way cock.
As photoionization detector does not have any response to methane, so optical ionic detector can quickly measure gas NMHC content in body.
For methane content detection method in gas, the present invention solves the method for above-mentioned technical problem includes following step Suddenly:
(1)The multiple-way valve is set to into load condition position, under test gas enter multiple-way valve by gas sampling system, pass sequentially through Gas sampling system connector, first the first connector of quantitative loop, the first quantitative loop, first the second connector of quantitative loop, second The first connector of quantitative loop, the second quantitative loop, second the second connector of quantitative loop, it is ensured that under test gas are gathered to the first quantitative loop With the second quantitative loop;
(2)The multiple-way valve is set to into sample introduction mode bit, under test gas are loaded into detector by carrier gas, specially:Carrier gas passes through Carrier gas induction system enters multiple-way valve, and first via carrier gas passes sequentially through the first connector of carrier gas induction system, the first quantitative loop One connector, the first quantitative loop, first the second connector of quantitative loop, flame ionization detector connector enter flame ion Detector;Second road-load gas passes sequentially through the second connector of carrier gas induction system, second the first connector of quantitative loop, second quantitative Ring, second the second connector of quantitative loop, photoionization detector connector enter photoionization detector;
(3)Total hydrocarbon content of the flame ionization detector measurement into the under test gas of flame ionization detector, photoionization Detectors measure enters the NMHC content of the under test gas of photoionization detector;
(4)Total hydrocarbon content under test gas is deducted into NMHC content under test gas, methane contains in obtaining under test gas Amount.
NMHC testing equipment in the present invention can be realized in the case where chromatographic column is not used, be realized to gas The quick detection of middle methane content, substantially increases the efficiency of on-line checking.
Description of the drawings
Fig. 1 is the schematic diagram of the first embodiment of methane content testing equipment in gas of the present invention;
Fig. 2 is ten-way valve connector schematic diagram in the first embodiment of methane content testing equipment in gas of the present invention;
Fig. 3 is the schematic diagram of methane content second embodiment of testing equipment in gas of the present invention;
Fig. 4 is two groups of six-way valve connector schematic diagrams in second embodiment of methane content testing equipment in gas of the present invention.
Specific embodiment
In order that those skilled in the art more fully understands technical scheme, it is below in conjunction with the accompanying drawings and concrete real The present invention is described in further detail to apply example.
Fig. 1 and Fig. 2 illustrate the structure of the first embodiment of methane content testing equipment in gas of the present invention.Such as Fig. 1 And shown in Fig. 2, in gas, methane content testing equipment includes ten-way valve 3, quantitative loop, gas sampling system 1, carrier gas induction system 14th, gas control system and detector, the quantitative loop include the first quantitative loop 2 and the second quantitative loop 8, the detector bag Include flame ionization detector 6 and photoionization detector 7.
Ten-way valve has gas sampling system connector 001, first quantitative loop the first connector 002, the first quantitative loop Two connectors 005, second quantitative loop the first connector 006, second the second connector of quantitative loop 009, carrier gas induction system first Connector 003, the second connector of carrier gas conveyer device 007, flame ionization detector connector 004, photoionization detector Connector 008 and air pump connector 010;First quantitative loop, first connector 002, the first quantitative loop 2, first are quantitative The second connector of ring 005 is sequentially connected;Second quantitative loop, first connector 006, the second quantitative loop 8, the second quantitative loop Two connectors 009 are sequentially connected;
The ten-way valve has load condition position and sample introduction mode bit, and when multiple-way valve is located at load condition position, the gas is adopted Sample system connector 001, first quantitative loop the first connector 002, the first quantitative loop 2, first the second connector of quantitative loop 005, Second quantitative loop the first connector 006, the second quantitative loop 8, second the second connector of quantitative loop 009, air pump connector 010 according to Secondary connection, it is ensured that sample gas is gathered to the first quantitative loop 2 and the second quantitative loop 8;When the ten-way valve is located at sample introduction mode bit, carry Gas induction system the first connector 001, first quantitative loop the first connector 002, the first quantitative loop 2, the first quantitative loop second connect Interface 005, flame ionization detector connector 004 are sequentially communicated, and the second connector of carrier gas induction system 007, second is quantitative Ring the first connector 006, the second quantitative loop 8, second the second connector of quantitative loop 009, photoionization detector connector 008 according to Secondary connection.
Gas sampling system 1 also includes air pump 9, two-position three-way valve 10 and manograph 11.Gas control system Including electronic pressure controller 12, void column 4 and vapour lock 5.Carrier gas induction system 14 includes a three way cock 13.
Method using the testing equipment detection methane content described in embodiment one is as follows:
(1)The ten-way valve is set to into load condition position, under test gas enter ten-way valve by gas sampling system, pass sequentially through Gas sampling system connector, first the first connector of quantitative loop, the first quantitative loop, first the second connector of quantitative loop, second The first connector of quantitative loop, the second quantitative loop, second the second connector of quantitative loop, it is ensured that under test gas are gathered to the first quantitative loop With the second quantitative loop;
(2)The ten-way valve is set to into sample introduction mode bit, under test gas are loaded into detector by carrier gas, specially:Carrier gas passes through Carrier gas induction system enters ten-way valve, and first via carrier gas passes sequentially through the first connector of carrier gas induction system, the first quantitative loop One connector, the first quantitative loop, first the second connector of quantitative loop, flame ionization detector connector enter flame ion Detector;Second road-load gas passes sequentially through the second connector of carrier gas induction system, second the first connector of quantitative loop, second quantitative Ring, second the second connector of quantitative loop, photoionization detector connector enter photoionization detector;
(3)Total hydrocarbon content of the flame ionization detector measurement into the under test gas of flame ionization detector, photoionization Detectors measure enters the NMHC content of the under test gas of photoionization detector;
(4)Total hydrocarbon content under test gas is deducted into NMHC content under test gas, methane contains in obtaining under test gas Amount.
Fig. 3 and Fig. 4 illustrate the structure of methane content second embodiment of testing equipment in gas of the present invention.Such as Fig. 3 And shown in Fig. 4, NMHC testing equipment includes two six-way valves(15、16), quantitative loop, gas sampling system 1, carrier gas it is defeated System 14, gas control system and detector, the quantitative loop is sent to include the first quantitative loop 2 and the second quantitative loop 8, the inspection Surveying device includes flame ionization detector 6 and photoionization detector 7.
Six-way valve 15 has gas sampling system connector 101, first quantitative loop the first connector 102, the first quantitative loop Second connector 105, the first connector of carrier gas induction system 103, flame ionization detector connector 104.
Six-way valve 16 has second the first connector of quantitative loop 202, the second connector of carrier gas conveyer device 204, second fixed Amount ring the second connector 205, photoionization detector connector 203 and air pump connector 206.
First quantitative loop, first connector 102, the first quantitative loop 2, first the second connector of quantitative loop 105 connect successively Connect;Second quantitative loop, first connector 202, the second quantitative loop 8, second the second connector of quantitative loop 204 are sequentially connected.
The six-way valve has load condition position and sample introduction mode bit, when multiple-way valve is located at load condition position, the gas Sampler body system connector 101, first quantitative loop the first connector 102, the first quantitative loop 2, first the second connector of quantitative loop 105th, second quantitative loop the first connector 202, the second quantitative loop 8, second the second connector of quantitative loop 204, air pump connector 206 are sequentially communicated, it is ensured that sample gas is gathered to the first quantitative loop 2 and the second quantitative loop 8;When the six-way valve is located at sample introduction mode bit When, carrier gas induction system first connect 103 mouthfuls, first quantitative loop the first connector 102, the first quantitative loop 2, the first quantitative loop the Two connectors 105, flame ionization detector connector 104 are sequentially communicated, the second connector of carrier gas induction system 204, second Quantitative loop the first connector 202, the second quantitative loop 8, second the second connector of quantitative loop 204, photoionization detector connector 203 are sequentially communicated.
Gas sampling system 1 also includes air pump 9, two-position three-way valve 10 and manograph 11.Gas control system Including electronic pressure controller 12, void column 4 and vapour lock 5.Carrier gas induction system 14 includes a three way cock 13.
Method using the testing equipment detection methane content described in embodiment two is as follows:
(1)The six-way valve is set to into load condition position, under test gas enter six-way valve by gas sampling system, pass sequentially through Gas sampling system connector, first the first connector of quantitative loop, the first quantitative loop, first the second connector of quantitative loop, second The first connector of quantitative loop, the second quantitative loop, second the second connector of quantitative loop, it is ensured that under test gas are gathered to the first quantitative loop With the second quantitative loop;
(2)The six-way valve is set to into sample introduction mode bit, under test gas are loaded into detector by carrier gas, specially:Carrier gas passes through Carrier gas induction system enters six-way valve, and first via carrier gas passes sequentially through the first connector of carrier gas induction system, the first quantitative loop One connector, the first quantitative loop, first the second connector of quantitative loop, flame ionization detector connector enter flame ion Detector;Second road-load gas passes sequentially through the second connector of carrier gas induction system, second the first connector of quantitative loop, second quantitative Ring, second the second connector of quantitative loop, photoionization detector connector enter photoionization detector;
(3)Total hydrocarbon content of the flame ionization detector measurement into the under test gas of flame ionization detector, photoionization Detectors measure enters the NMHC content of the under test gas of photoionization detector;
(4)Total hydrocarbon content under test gas is deducted into NMHC content under test gas, methane contains in obtaining under test gas Amount.
Both examples above is only the preferred embodiment of the present invention, it is noted that above-mentioned preferred implementation Limitation of the present invention is not construed as, protection scope of the present invention should be defined by claim limited range.For this For the those of ordinary skill of technical field, without departing from the spirit and scope of the present invention, can also make it is some improvement and Retouching, these improvements and modifications also should be regarded as protection scope of the present invention.

Claims (7)

1. methane content testing equipment in a kind of gas, it is characterised in that including multiple-way valve, quantitative loop, gas sampling system, load Gas induction system, gas control system and detector;Characterized in that, the quantitative loop includes that the first quantitative loop and second is determined Amount ring, the detector include flame ionization detector and photoionization detector;
There is the multiple-way valve gas sampling system connector, first the first connector of quantitative loop, the first quantitative loop second to connect Mouth, second the first connector of quantitative loop, second the second connector of quantitative loop, the first connector of carrier gas induction system, carrier gas conveying The second connector of system, flame ionization detector connector, photoionization detector connector and air pump connector;Institute State first the first connector of quantitative loop, the first quantitative loop, first the second connector of quantitative loop to be sequentially connected;Second quantitative loop First connector, the second quantitative loop, second the second connector of quantitative loop are sequentially connected;
The multiple-way valve has load condition position and sample introduction mode bit, and when multiple-way valve is located at load condition position, the gas is adopted Sample system connector, first the first connector of quantitative loop, the first quantitative loop, first the second connector of quantitative loop, the second quantitative loop First connector, the second quantitative loop, second the second connector of quantitative loop, air pump connector are sequentially communicated, it is ensured that sample gas is gathered To the first quantitative loop and the second quantitative loop;When the multiple-way valve is located at sample introduction mode bit, the first connector of carrier gas induction system, First the first connector of quantitative loop, the first quantitative loop, first the second connector of quantitative loop, flame ionization detector connector according to Secondary connection, the second connector of carrier gas induction system, second the first connector of quantitative loop, the second quantitative loop, the second quantitative loop second Connector, photoionization detector connector are sequentially communicated.
2. testing equipment according to claim 1, it is characterised in that the gas sampling system include air pump, two Three-way valve and manograph.
3. testing equipment according to claim 1, it is characterised in that the gas control system includes electron pressure control Device, void column and vapour lock.
4. testing equipment according to claim 1, it is characterised in that the multiple-way valve is ten-way valve.
5. testing equipment according to claim 1, it is characterised in that the multiple-way valve is two groups of six-way valves.
6. testing equipment according to claim 1, it is characterised in that the carrier gas induction system includes that three connects Head.
7. the methane content detection method of the testing equipment described in a kind of any one of application claim 1 to 6, it is characterised in that Comprise the following steps:
(1)The multiple-way valve is set to into load condition position, under test gas enter multiple-way valve by gas sampling system, pass sequentially through Gas sampling system connector, first the first connector of quantitative loop, the first quantitative loop, first the second connector of quantitative loop, second The first connector of quantitative loop, the second quantitative loop, second the second connector of quantitative loop, it is ensured that under test gas are gathered to the first quantitative loop With the second quantitative loop;
(2)The multiple-way valve is set to into sample introduction mode bit, under test gas are loaded into detector by carrier gas, specially:Carrier gas passes through Carrier gas induction system enters multiple-way valve, and first via carrier gas passes sequentially through the first connector of carrier gas induction system, the first quantitative loop One connector, the first quantitative loop, first the second connector of quantitative loop, flame ionization detector connector enter flame ion Detector;Second road-load gas passes sequentially through the second connector of carrier gas induction system, second the first connector of quantitative loop, second quantitative Ring, second the second connector of quantitative loop, photoionization detector connector enter photoionization detector;
(3)Total hydrocarbon content of the flame ionization detector measurement into the under test gas of flame ionization detector, photoionization Detectors measure enters the NMHC content of the under test gas of photoionization detector;
(4)Total hydrocarbon content under test gas is deducted into NMHC content under test gas, methane contains in obtaining under test gas Amount.
CN201610875084.2A 2016-10-08 2016-10-08 Device and method for detecting methane content in gas Pending CN106525951A (en)

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CN201610875084.2A CN106525951A (en) 2016-10-08 2016-10-08 Device and method for detecting methane content in gas

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CN104678062A (en) * 2015-03-03 2015-06-03 重庆创图环境检测有限公司 VOC (volatile organic compound) gas and non-methane total hydrocarbon gas sampling and detecting system
CN105510478A (en) * 2015-12-30 2016-04-20 聚光科技(杭州)股份有限公司 Online detection device and method of non-methane total hydrocarbon
CN105717065A (en) * 2016-04-07 2016-06-29 南京波腾科技工程有限公司 Continuous monitoring device for non-methane total hydrocarbon and working method of continuous monitoring device

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104678062A (en) * 2015-03-03 2015-06-03 重庆创图环境检测有限公司 VOC (volatile organic compound) gas and non-methane total hydrocarbon gas sampling and detecting system
CN105510478A (en) * 2015-12-30 2016-04-20 聚光科技(杭州)股份有限公司 Online detection device and method of non-methane total hydrocarbon
CN105717065A (en) * 2016-04-07 2016-06-29 南京波腾科技工程有限公司 Continuous monitoring device for non-methane total hydrocarbon and working method of continuous monitoring device

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