CN106521309A - Heat resisting cast iron boiler furnace bar and preparation method thereof - Google Patents

Heat resisting cast iron boiler furnace bar and preparation method thereof Download PDF

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Publication number
CN106521309A
CN106521309A CN201611164629.5A CN201611164629A CN106521309A CN 106521309 A CN106521309 A CN 106521309A CN 201611164629 A CN201611164629 A CN 201611164629A CN 106521309 A CN106521309 A CN 106521309A
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iron
cast iron
heat
analysis
resisting cast
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CN201611164629.5A
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Chinese (zh)
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张鲁云
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Guangxi University
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Guangxi University
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Priority to CN201611164629.5A priority Critical patent/CN106521309A/en
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C37/00Cast-iron alloys
    • C22C37/10Cast-iron alloys containing aluminium or silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C33/00Making ferrous alloys
    • C22C33/08Making cast-iron alloys
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C37/00Cast-iron alloys
    • C22C37/06Cast-iron alloys containing chromium

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Refinement Of Pig-Iron, Manufacture Of Cast Iron, And Steel Manufacture Other Than In Revolving Furnaces (AREA)
  • Investigating, Analyzing Materials By Fluorescence Or Luminescence (AREA)

Abstract

The invention discloses a heat resisting cast iron boiler furnace bar and a preparation method thereof. The heat resisting cast iron boiler furnace bar comprises the following components in percentage by weight: 2.2-2.6% of C, 5-6% of Si, 0.7-0.9% of Mn, 0.6-1.0% of Cr, P not more than 0.2%, S not more than 0.12%, and the balance of Fe. The preparation method comprises batching, preheating, smelting, quick analysis in front of a furnace, final deoxidation, inoculation and casting. The method is simple in casting process, prevents cast iron oxidation and low-temperature growth through controlling adding quantities of carbon, silicon and chromium in cast iron, casts heat resisting cast iron, and in particular, is suitable for the boiler furnace bar of a boiler.

Description

A kind of heat-resisting cast iron boiler grate bar and preparation method thereof
Technical field
The present invention relates to the production technical field of ferrous metal, especially a kind of heat-resisting cast iron boiler grate bar and its preparation side Method.
Background technology
In the industrial production, some parts are worked under the high temperature conditions, and such as boiler fitting, petrochemical industry, metallurgy set Standby part etc., as they are acted on by high temperature, than more fragile at normal temperatures, it requires that part has and supports at high temperature The performance of collapse resistance.
The content of the invention
It is an object of the present invention to be directed to the problems referred to above, a kind of heat-resisting cast iron boiler grate bar and preparation method thereof is proposed, led to Control carbon in cast iron, silicon, the addition of chromium are crossed, heat-resisting cast iron boiler grate bar is cast out.
The technical solution adopted for the present invention to solve the technical problems is:The percentage by weight of its composition is:C2.2~ 2.6%th, Si5~6%, Mn0.7~0.9%, Cr0.6~1.0%, P≤0.2%, S≤0.12%, balance of Fe.
A kind of method for preparing heat-resisting cast iron boiler grate bar, including following several steps:
The first step:Dispensing:By steel scrap, foundry returns, the pig iron, ferrosilicon, ferromanganese, ferrochrome press C2.2~2.6%, Si5~6%, Mn0.7~ 0.9%th, Cr0.6~1.0%, P≤0.2%, S≤0.12%, the mode of balance of Fe percentage by weights carry out dispensing;
Second step:Preheating:By optimization calculate steel scrap, foundry returns, the pig iron input intermediate frequency furnace in preheated;
3rd step:Melting:After by the steel scrap in intermediate frequency furnace, foundry returns, pig iron fusing, put into its quantity for furnace charge 15~ 25%, composition carries out pre-deoxidation for the deoxidier of lime 60%+ fluorites 40%, then puts into ferrosilicon, ferromanganese and ferrochrome that baking processes and obtain To iron liquid, when bonded hard ferrite magnet is warming up to 1490~1640 DEG C, add 0.1% deslagging agent once to remove the gred, be then covered by heat preserving agent wait Sample analysis;
4th step:Both analysis:Take iron liquid stokehold spectrometer analysis quickly to be analyzed with reference to carbon silicon heat analysis, according to Analysis result adjusts chemical composition;
5th step:Final deoxidizing:Bonded hard ferrite magnet is warming up to into 1490~1640 DEG C, the aluminium that its quantity is iron liquid 0.1~0.3% is put into Carry out final deoxidizing;
6th step:Inoculation:Iron liquid carries out inoculation when flowing to casting ladle from intermediate frequency furnace, adds its quantity to be iron liquid amount 0.3~0.5% inovulant, the granularity of inovulant is 2~6mm, and inovulant is 75 ferrosilicon;
7th step:Cast:When bonded hard ferrite magnet is down to 1470~1540 DEG C, poured into a mould, obtained the casting of heat-resisting cast iron boiler grate bar Part.
The invention has the beneficial effects as follows:Casting technique is simple, by the addition for controlling carbon in cast iron, silicon, chromium, prevents casting Iron is aoxidized and low-temperature epitaxy, is cast out heat-resisting cast iron, is particularly suitable for the boiler grate bar of boiler.
Specific embodiment
Embodiment 1:
A kind of method for preparing heat-resisting cast iron boiler grate bar of this example, including following several steps:
The first step:Dispensing:Steel scrap, foundry returns, the pig iron, ferrosilicon, ferromanganese, ferrochrome are pressed into C2.2%, Si5%, Mn0.7%, Cr0.6%, P ≤ 0.2%, S≤0.12%, the mode of balance of Fe percentage by weights carry out dispensing;
Second step:Preheating:By optimization calculate steel scrap, foundry returns, the pig iron input intermediate frequency furnace in preheated;
3rd step:Melting:After by the steel scrap in intermediate frequency furnace, foundry returns, pig iron fusing, it is furnace charge 15% to put into its quantity, into The deoxidier for being divided into lime 60%+ fluorites 40% carries out pre-deoxidation, then puts into ferrosilicon, ferromanganese and ferrochrome that baking processes and obtain iron Liquid, when bonded hard ferrite magnet is warming up to 1490 DEG C, adds 0.1% deslagging agent once to remove the gred, is then covered by heat preserving agent and waits sample analysis;
4th step:Both analysis:Take iron liquid stokehold spectrometer analysis quickly to be analyzed with reference to carbon silicon heat analysis, according to Analysis result adjusts chemical composition;
5th step:Final deoxidizing:Bonded hard ferrite magnet is warming up to into 1490 DEG C, putting into the aluminium that its quantity is iron liquid 0.1% carries out final deoxidizing;
6th step:Inoculation:Iron liquid carries out inoculation when flowing to casting ladle from intermediate frequency furnace, adds its quantity to be iron liquid amount 0.3% inovulant, the granularity of inovulant is 2mm, and inovulant is 75 ferrosilicon;
7th step:Cast:When bonded hard ferrite magnet is down to 1470 DEG C, poured into a mould, obtained heat-resisting cast iron boiler grate bar foundry goods.
Embodiment 2:
A kind of method for preparing heat-resisting cast iron boiler grate bar of this example, including following several steps:
The first step:Dispensing:By steel scrap, foundry returns, the pig iron, ferrosilicon, ferromanganese, ferrochrome press C2.4%, Si5.5%, Mn0.8%, Cr0.8%, P≤0.2%, S≤0.12%, the mode of balance of Fe percentage by weights carry out dispensing;
Second step:Preheating:By optimization calculate steel scrap, foundry returns, the pig iron input intermediate frequency furnace in preheated;
3rd step:Melting:After by the steel scrap in intermediate frequency furnace, foundry returns, pig iron fusing, it is furnace charge 20% to put into its quantity, into The deoxidier for being divided into lime 60%+ fluorites 40% carries out pre-deoxidation, then puts into ferrosilicon, ferromanganese and ferrochrome that baking processes and obtain iron Liquid, when bonded hard ferrite magnet is warming up to 1515 DEG C, adds 0.1% deslagging agent once to remove the gred, is then covered by heat preserving agent and waits sample analysis;
4th step:Both analysis:Take iron liquid stokehold spectrometer analysis quickly to be analyzed with reference to carbon silicon heat analysis, according to Analysis result adjusts chemical composition;
5th step:Final deoxidizing:Bonded hard ferrite magnet is warming up to into 1515 DEG C, putting into the aluminium that its quantity is iron liquid 0.2% carries out final deoxidizing;
6th step:Inoculation:Iron liquid carries out inoculation when flowing to casting ladle from intermediate frequency furnace, adds its quantity to be iron liquid amount 0.4% inovulant, the granularity of inovulant is 4mm, and inovulant is 75 ferrosilicon;
7th step:Cast:When bonded hard ferrite magnet is down to 1505 DEG C, poured into a mould, obtained heat-resisting cast iron boiler grate bar foundry goods.
Embodiment 3:
A kind of method for preparing heat-resisting cast iron boiler grate bar of this example, including following several steps:
The first step:Dispensing:Steel scrap, foundry returns, the pig iron, ferrosilicon, ferromanganese, ferrochrome are pressed into C2.6%, Si6%, Mn0.9%, Cr1.0%, P ≤ 0.2%, S≤0.12%, the mode of balance of Fe percentage by weights carry out dispensing;
Second step:Preheating:By optimization calculate steel scrap, foundry returns, the pig iron input intermediate frequency furnace in preheated;
3rd step:Melting:After by the steel scrap in intermediate frequency furnace, foundry returns, pig iron fusing, it is furnace charge 25% to put into its quantity, into The deoxidier for being divided into lime 60%+ fluorites 40% carries out pre-deoxidation, then puts into ferrosilicon, ferromanganese and ferrochrome that baking processes and obtain iron Liquid, when bonded hard ferrite magnet is warming up to 1640 DEG C, adds 0.1% deslagging agent once to remove the gred, is then covered by heat preserving agent and waits sample analysis;
4th step:Both analysis:Take iron liquid stokehold spectrometer analysis quickly to be analyzed with reference to carbon silicon heat analysis, according to Analysis result adjusts chemical composition;
5th step:Final deoxidizing:Bonded hard ferrite magnet is warming up to into 1640 DEG C, putting into the aluminium that its quantity is iron liquid 0.3% carries out final deoxidizing;
6th step:Inoculation:Iron liquid carries out inoculation when flowing to casting ladle from intermediate frequency furnace, adds its quantity to be iron liquid amount 0.5% inovulant, the granularity of inovulant is 6mm, and inovulant is 75 ferrosilicon;
7th step:Cast:When bonded hard ferrite magnet is down to 1540 DEG C, poured into a mould, obtained heat-resisting cast iron boiler grate bar foundry goods.
Above the specific embodiment of the present invention is described, but these explanations can not be considered as limiting the present invention Scope, protection scope of the present invention limited by appended claims, where appointing on the basis of the claims in the present invention What modification, equivalent and improvement etc., each fall within protection scope of the present invention it.

Claims (2)

1. a kind of heat-resisting cast iron boiler grate bar, it is characterised in that:The percentage by weight of its composition is:C2.2~2.6%, Si5~ 6%th, Mn0.7~0.9%, Cr0.6~1.0%, P≤0.2%, S≤0.12%, balance of Fe.
2. a kind of method of the heat-resisting cast iron boiler grate bar prepared described in claim 1, it is characterised in that:Including following several steps Suddenly:
The first step:Dispensing:Steel scrap, foundry returns, the pig iron, ferrosilicon, ferromanganese and ferrochrome are pressed into C2.2~2.6%, Si5~6%, Mn0.7 ~0.9%, Cr0.6~1.0%, P≤0.2%, S≤0.12%, the mode of balance of Fe percentage by weights carry out dispensing;
Second step:Preheating:By optimization calculate steel scrap, foundry returns, the pig iron input intermediate frequency furnace in preheated;
3rd step:Melting:After by the steel scrap in intermediate frequency furnace, foundry returns, pig iron fusing, put into its quantity for furnace charge 15~ 25%, composition carries out pre-deoxidation for the deoxidier of lime 60%+ fluorites 40%, then puts into ferrosilicon, ferromanganese and ferrochrome that baking processes and obtain To iron liquid, when bonded hard ferrite magnet is warming up to 1490~1640 DEG C, add 0.1% deslagging agent once to remove the gred, be then covered by heat preserving agent wait Sample analysis;
4th step:Both analysis:Take iron liquid stokehold spectrometer analysis quickly to be analyzed with reference to carbon silicon heat analysis, according to Analysis result adjusts chemical composition;
5th step:Final deoxidizing:Bonded hard ferrite magnet is warming up to into 1490~1640 DEG C, the aluminium that its quantity is iron liquid 0.1~0.3% is put into Carry out final deoxidizing;
6th step:Inoculation:Iron liquid carries out inoculation when flowing to casting ladle from intermediate frequency furnace, adds its quantity to be iron liquid amount 0.3~0.5% inovulant, the granularity of inovulant is 2~6mm, and inovulant is 75 ferrosilicon;
7th step:Cast:When bonded hard ferrite magnet is down to 1470~1540 DEG C, poured into a mould, obtained the casting of heat-resisting cast iron boiler grate bar Part.
CN201611164629.5A 2016-12-16 2016-12-16 Heat resisting cast iron boiler furnace bar and preparation method thereof Pending CN106521309A (en)

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Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106929749A (en) * 2017-04-21 2017-07-07 龙邹 A kind of cast iron gear and preparation method thereof
CN106987762A (en) * 2017-04-21 2017-07-28 龙邹 A kind of cast-iron crankshaft and preparation method thereof
CN107012387A (en) * 2017-04-20 2017-08-04 龙邹 A kind of cast iron automobile shift fork and preparation method thereof
CN107090564A (en) * 2017-04-21 2017-08-25 龙邹 A kind of cast iron cam shaft and preparation method thereof
CN107090563A (en) * 2017-04-20 2017-08-25 龙邹 A kind of cast iron sprocket wheel and preparation method thereof
CN107090562A (en) * 2017-04-20 2017-08-25 龙邹 A kind of cast iron automobile axle and preparation method thereof
CN107557651A (en) * 2017-09-07 2018-01-09 太湖县众瑞精密铸造有限公司 A kind of agricultural colter
CN107557649A (en) * 2017-09-07 2018-01-09 太湖县众瑞精密铸造有限公司 Agriculture apparatus
CN107557650A (en) * 2017-09-07 2018-01-09 太湖县众瑞精密铸造有限公司 Agriculture apparatus and its production method
CN107557687A (en) * 2017-09-07 2018-01-09 太湖县众瑞精密铸造有限公司 A kind of agricultural colter and its production method
CN107630170A (en) * 2017-09-07 2018-01-26 太湖县众瑞精密铸造有限公司 A kind of axe and its production method with service life length

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CN102796940A (en) * 2012-08-31 2012-11-28 丹阳市锦雄机械制造有限公司 Preparation method of high-silicon heat-resistant ductile iron
CN103060662A (en) * 2012-12-26 2013-04-24 宁波市瑞通新材料科技有限公司 Preparation process of alloy cast iron grinding ball
CN106011360A (en) * 2016-07-01 2016-10-12 宁国市开源电力耐磨材料有限公司 Smelting technology of high-strength low-stress gray pig iron

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CN102796940A (en) * 2012-08-31 2012-11-28 丹阳市锦雄机械制造有限公司 Preparation method of high-silicon heat-resistant ductile iron
CN103060662A (en) * 2012-12-26 2013-04-24 宁波市瑞通新材料科技有限公司 Preparation process of alloy cast iron grinding ball
CN106011360A (en) * 2016-07-01 2016-10-12 宁国市开源电力耐磨材料有限公司 Smelting technology of high-strength low-stress gray pig iron

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Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107012387A (en) * 2017-04-20 2017-08-04 龙邹 A kind of cast iron automobile shift fork and preparation method thereof
CN107090563A (en) * 2017-04-20 2017-08-25 龙邹 A kind of cast iron sprocket wheel and preparation method thereof
CN107090562A (en) * 2017-04-20 2017-08-25 龙邹 A kind of cast iron automobile axle and preparation method thereof
CN106929749A (en) * 2017-04-21 2017-07-07 龙邹 A kind of cast iron gear and preparation method thereof
CN106987762A (en) * 2017-04-21 2017-07-28 龙邹 A kind of cast-iron crankshaft and preparation method thereof
CN107090564A (en) * 2017-04-21 2017-08-25 龙邹 A kind of cast iron cam shaft and preparation method thereof
CN107557651A (en) * 2017-09-07 2018-01-09 太湖县众瑞精密铸造有限公司 A kind of agricultural colter
CN107557649A (en) * 2017-09-07 2018-01-09 太湖县众瑞精密铸造有限公司 Agriculture apparatus
CN107557650A (en) * 2017-09-07 2018-01-09 太湖县众瑞精密铸造有限公司 Agriculture apparatus and its production method
CN107557687A (en) * 2017-09-07 2018-01-09 太湖县众瑞精密铸造有限公司 A kind of agricultural colter and its production method
CN107630170A (en) * 2017-09-07 2018-01-26 太湖县众瑞精密铸造有限公司 A kind of axe and its production method with service life length

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Application publication date: 20170322