CN106519995A - Toughened alpha-cyanoacrylate adhesive - Google Patents
Toughened alpha-cyanoacrylate adhesive Download PDFInfo
- Publication number
- CN106519995A CN106519995A CN201610947856.9A CN201610947856A CN106519995A CN 106519995 A CN106519995 A CN 106519995A CN 201610947856 A CN201610947856 A CN 201610947856A CN 106519995 A CN106519995 A CN 106519995A
- Authority
- CN
- China
- Prior art keywords
- alpha
- cyanoacrylate
- core
- polymerization inhibitor
- toughening type
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
Abstract
The invention relates to the field of adhesives, especially to a toughened alpha-cyanoacrylate adhesive. The adhesive comprises the following components by weight percentage: 85-99% of an alpha-cyanoacrylate monomer; 0.001-10% of an anionic polymerization inhibitor; 0.01-4% of a free radical polymerization inhibitor; and 0.01-5% of micro-nano size core-shell particles. According to the invention, micro-nano size core-shell particles are introduced into the alpha-cyanoacrylate adhesive to enhance the toughness and impact resistance of the alpha-cyanoacrylate adhesive. The alpha-cyanoacrylate adhesive prepared according to the invention not only has good toughness, but also has high viscosity, is conducive to bonding porous materials and is suitable for wide-gap scenes.
Description
Technical field
The present invention relates to adhesive area, more particularly to a kind of alpha-cyanacrylate adhesive of toughness reinforcing.
Background technology
Alpha-cyanacrylate adhesive can be polymerized rapidly and solidifies in the case where trace water is helped, can bonding remove poly- second
Nearly all material beyond the inert materials such as alkene, curing rate are fast, thus are widely used；But a-cyanoacrylate is gluing
Agent is enbrittled the poor problem of big and moisture resistance.
The method for toughening of alpha-cyanacrylate adhesive, mainly has following several：（1) add mutual with cyanoacrylate
The good plasticizer of dissolubility, this method have the shortcomings that to reduce adhesive strength and curing rate；（2）Addition can be with alpha-cyano propylene
The good comonomer of the plasticity of acid ester monomer, such as cyano group 1,3-propanedicarboxylic acid alkene ester, alpha-cyanoacrylate alkoxy alkyl etc., it is this this kind of
Monomer has that price is higher, is usually used in preparing extraordinary adhesive；（3）Increase the ester group molecule of a-cyanoacrylate
Amount, the toughness for for example adding alpha-cyanoacrylate monooctyl ester are just better than Mecrilate and ethyl α-cyanoacrylate, but
The price of this kind of monomer is higher, therefore is usually used in the special dimensions such as medical adhesive；（4）Add rubber elastomer, such as butyronitrile rubber
Glue, neoprene, ASA rubber（The copolymer of acrylonitrile styrene acrylic ester rubber）Deng, but these contain rubber
The shortcomings of there is weatherability difference and be difficult to dispersed in the cyanacrylate adhesive of elastomer.
The content of the invention
The purpose of the present invention is to overcome problem of the prior art, improves alpha-cyanacrylate adhesive toughness, there is provided Yi Zhongzeng
Tough type alpha-cyanacrylate adhesive.
For achieving the above object, the technical scheme for being adopted is the present invention：A kind of toughening type a-cyanoacrylate is gluing
Agent, it is characterised in that：The toughening type alpha-cyanacrylate adhesive is by weight percentage, composed of the following components：
Ethyl α-cyanoacrylate monomer 85-99%；
Anionic polymerisation polymerization inhibitor 0.001-10%；
Radical polymerization polymerization inhibitor 0.01-4%；
Micro-or nano size core-shell particles 0.01-5%.
The present invention obtains a kind of alpha-cyanoacrylate ester gum of good toughness as toughener using micro-or nano size core-shell particles
Stick.Micro-or nano size core-shell particles generally have the core surrounded by shell, and core is by the polymerization with elastomer or rubber like performance
Material is constituted, and shell is made up of the polymeric material of inelastic body.For example, core can be made up of following material, for example, diene homopolymerization
Thing or copolymer, and shell can be by the polymer of the appropriate one or more high monomer of glass transition temperature or copolymer structure
Into monomer such as (methyl) acrylate, vi-ny l aromatic monomers (for example, styrene), vinyl cyanide (for example, propylene
Nitrile), unsaturated acids and acid anhydride (for example, acrylic acid) etc..Typically, core can account for the about 50-95wt% of particle, and shell can include
The about 5-50wt% of particle.
A kind of typical micro-nano core-shell particles are the particles of dry powder form, the trade name of such as NipponZeon sale
The Core-shell rubber particles of F351.In addition to this it is possible to be with the particle-stabilised dispersion masterbatch in the epoxy that is separated, example
Such as the trade name MX154 of Kaneka sale, the core-shell particles of MX257, these core-shell particles are by (methyl) acrylate-fourth two
Alkene-cinnamic copolymer is core, and wherein butadiene is the main component of the copolymer in the core.
Typically, adhesive can contain the elastomer particle with nucleocapsid structure of about 5-25wt%.Except being used alone
It is mentioned above to wait micro-and nano-particles, can also be using mixed systems such as various core-shell particles.
The invention has the beneficial effects as follows：A large amount of cyano group in a-cyanoacrylate molecule cause intermolecular force very
By force, intermolecular slip is limited, and a-cyanoacrylate molecule is smaller in addition so that the physical crosslinking point between cyano group is close
Degree is high, and this is the crisp main cause of instant drying adhesive.Therefore the active force for effectively increasing molecular length and weakening between molecule can
To realize toughening effect.The present invention adds core-shell particles and produces phase separation effect, so as to reduce the active force between cyano group, together
When compared to common liquid rubber additive, core shell rubbers will not aggregate and precipitate, the phase separation in formulation is actually base
This is uniform.Instant drying adhesive after toughness reinforcing of the present invention will not lose curing rate and glue-joint strength.
By micro-or nano size core-shell particles be incorporated into a-cyanoacrylate it is gluing in, using micro-or nano size core-shell particles
Strengthen the gluing toughness of a-cyanoacrylate and shock resistance.A-cyanoacrylate using present invention manufacture is gluing
Agent, not only with good toughness, and with higher viscosity, is conducive to bonding porous material and is applied to wide slot field
Scape.
Specific embodiment
To make the object, technical solutions and advantages of the present invention become more apparent, below in conjunction with specific embodiment, to this
Bright further description.
A kind of toughening type alpha-cyanacrylate adhesive, it is by weight percentage, composed of the following components：
Ethyl α-cyanoacrylate monomer 85-99%；
Anionic polymerisation polymerization inhibitor 0.001-10%；
Radical polymerization polymerization inhibitor 0.01-4%；
Micro-or nano size core-shell particles 0.01-5%.
Cyanoacrylate monomer selects 2- methyl 2-cyanoacrylates, 2- cyanacrylates, 2- alpha-cyanoacrylates third
Ester, 2- Tisuacryls, 2- alpha-cyanoacrylate methoxy acrylates, 2- alpha-cyanoacrylate ethoxy ethyl esters, 2- cyanoacrylates
One or more in sour methoxyl group propyl ester.
Anionic polymerisation polymerization inhibitor selects the one kind in sulfur dioxide, boron trifluoride complex, p-methyl benzenesulfonic acid, methanesulfonic acid
Or it is several.
Radical polymerization polymerization inhibitor is quinone, hydroquinone, one or more in p methoxy phenol.
Micro-or nano size core-shell particles, its particle size range are 10 nanometers -200 microns.
Micro-or nano size core-shell particles are the trade name F351 Core-shell rubber particles of Japanese NipponZeon sale or day
The core-shell particles of the trade name MX154 or MX257 of this Kaneka sale.
The present invention is using 2- cyanacrylates as the preferred monomers for preparing toughening type alpha-cyanacrylate adhesive；
The preferred sulfur dioxide of anionic polymerisation polymerization inhibitor；The preferred hydroquinone of radical polymerization polymerization inhibitor.
The micro-nano Toughened With Core-Shell Particles type alpha-cyanacrylate adhesive of utilization that the present invention is provided, can also include which
His auxiliary agent, other auxiliary agents are viscosifier, heat-resistant agent, reinforcing agent, coupling agent, spice etc..
Embodiment 1：
In the ethyl cyanoacrylate monomer that weight content is 93.95% addition 5% anionic polymerisation polymerization inhibitor sulfur dioxide,
1% radical polymerization hydroquinone of polymerization retarder, 0.05% F351, with mixing and stirring in glue kettle, are obtained glue.
Tensile shear strength（Manganese steel）For 15.9MPa, peel strength（No. 10 steel）For 13.6N/25mm.
Embodiment 2：
The anionic polymerisation polymerization inhibitor titanium dioxide of addition 0.05% in the ethyl cyanoacrylate monomer that weight content is 98.35%
Sulfur, 1.5% radical polymerization hydroquinone of polymerization retarder, 0.1% F351, with mixing and stirring in glue kettle, are obtained glue.
Tensile shear strength（Manganese steel）For 32.1MPa, peel strength（No. 10 steel）For 26.7N/25mm.
Embodiment 3：
The anionic polymerisation polymerization inhibitor titanium dioxide of addition 0.05% in the ethyl cyanoacrylate monomer that weight content is 98.45%
Sulfur, 1% radical polymerization hydroquinone of polymerization retarder, 0.5% F351, with mixing and stirring in glue kettle, are obtained glue.
Tensile shear strength（Manganese steel）For 22.1MPa, peel strength（No. 10 steel）For 20.7N/25mm.
Embodiment 4：
The anionic polymerisation polymerization inhibitor titanium dioxide of addition 0.5% in the ethyl cyanoacrylate monomer that weight content is 98.9%
Sulfur, 0.5% radical polymerization hydroquinone of polymerization retarder, 0.1% MX154, with mixing and stirring in glue kettle, are obtained glue
Liquid.
Tensile shear strength（Manganese steel）For 18.1MPa, peel strength（No. 10 steel）For 19.7N/25mm.
Embodiment 5：
The anionic polymerisation polymerization inhibitor titanium dioxide of addition 0.05% in the ethyl cyanoacrylate monomer that weight content is 96.45%
Sulfur, 3% radical polymerization hydroquinone of polymerization retarder, 0.5% MX154, with mixing and stirring in glue kettle, are obtained glue.
Tensile shear strength（Manganese steel）For 35.2MPa, peel strength（No. 10 steel）For 24.3N/25mm.
Embodiment 6：
The anionic polymerisation polymerization inhibitor titanium dioxide of addition 0.05% in the ethyl cyanoacrylate monomer that weight content is 98.9%
Sulfur, 0.05% radical polymerization hydroquinone of polymerization retarder, 1.0% MX154, with mixing and stirring in glue kettle, are obtained glue
Liquid.
Tensile shear strength（Manganese steel）For 26.1MPa, peel strength（No. 10 steel）For 20.7N/25mm.
Embodiment 7：
The anionic polymerisation polymerization inhibitor titanium dioxide of addition 0.05% in the ethyl cyanoacrylate monomer that weight content is 93.95%
Sulfur, 1.0% radical polymerization hydroquinone of polymerization retarder, 5.0% MX154, with mixing and stirring in glue kettle, are obtained glue
Liquid.
Tensile shear strength（Manganese steel）For 32.9MPa, peel strength（No. 10 steel）For 24.1N/25mm.
Embodiment 8:
The anionic polymerisation polymerization inhibitor titanium dioxide of addition 5.0% in the ethyl cyanoacrylate monomer that weight content is 86.0%
Sulfur, 4.0% radical polymerization hydroquinone of polymerization retarder, 5.0% MX154, with mixing and stirring in glue kettle, are obtained glue
Liquid.
Tensile shear strength（Manganese steel）For 30.9MPa, peel strength（No. 10 steel）For 20.5N/25mm.
As can be seen from the above embodiments：Micro-nano core-shell particles（F351 and MX154）Cyanoacrylate can be strengthened
Adhesive shear strength and T-shaped peel strength, that is, improve toughness；When F351 is 0.1%, toughening effect is optimum, and content is excessive or mistake
It is few all to reduce toughening effect.When MX154 is 0.5%, toughening effect is optimum, and content is excessive or very few can all reduce toughening effect.
Claims (6)
1. a kind of toughening type alpha-cyanacrylate adhesive, it is characterised in that：The toughening type a-cyanoacrylate is gluing
Agent is by weight percentage, composed of the following components：
Ethyl α-cyanoacrylate monomer 85-99%；
Anionic polymerisation polymerization inhibitor 0.001-10%；
Radical polymerization polymerization inhibitor 0.01-4%；
Micro-or nano size core-shell particles 0.01-5%.
2. a kind of toughening type alpha-cyanacrylate adhesive according to claim 1, it is characterised in that：The cyano group third
Olefin(e) acid ester monomer selects 2- methyl 2-cyanoacrylates, 2- cyanacrylates, 2- cyanoacrylate propyl propionates, 2- alpha-cyanoacrylates
In butyl ester, 2- alpha-cyanoacrylate methoxy acrylates, 2- alpha-cyanoacrylate ethoxy ethyl esters, 2- alpha-cyanoacrylate methoxyl group propyl ester
One or more.
3. a kind of toughening type alpha-cyanacrylate adhesive according to claim 1, it is characterised in that：The anion
One or more in polymerization inhibitor selection sulfur dioxide, boron trifluoride complex, p-methyl benzenesulfonic acid, methanesulfonic acid.
4. a kind of toughening type alpha-cyanacrylate adhesive according to claim 1, it is characterised in that：The free radical
Polymerization inhibitor is quinone, hydroquinone, one or more in p methoxy phenol.
5. a kind of toughening type alpha-cyanacrylate adhesive according to claim 1, it is characterised in that：It is described micro-nano
Sized core-shell particle, its particle size range are 10 nanometers -200 microns.
6. a kind of toughening type alpha-cyanacrylate adhesive according to claim 1, it is characterised in that：It is described micro-nano
Sized core-shell particle is the trade name F351 Core-shell rubber particles of Japanese Nippon Zeon sale or Japan Kaneka sale
The core-shell particles of trade name MX154 or MX257.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610947856.9A CN106519995A (en) | 2016-10-26 | 2016-10-26 | Toughened alpha-cyanoacrylate adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610947856.9A CN106519995A (en) | 2016-10-26 | 2016-10-26 | Toughened alpha-cyanoacrylate adhesive |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106519995A true CN106519995A (en) | 2017-03-22 |
Family
ID=58293345
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610947856.9A Pending CN106519995A (en) | 2016-10-26 | 2016-10-26 | Toughened alpha-cyanoacrylate adhesive |
Country Status (1)
| Country | Link |
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| CN (1) | CN106519995A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107442381A (en) * | 2017-09-01 | 2017-12-08 | 山东华成中德传动设备有限公司 | A kind of wood mold coupled surface treatment method |
| CN109021843A (en) * | 2018-06-07 | 2018-12-18 | 得力集团有限公司 | Low albefaction instant glue of a kind of impact resistance and preparation method thereof |
| CN116731666A (en) * | 2023-08-15 | 2023-09-12 | 山东凯恩新材料科技有限公司 | Waterproof quick-drying adhesive and preparation method thereof |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4560723A (en) * | 1983-11-14 | 1985-12-24 | Minnesota Mining And Manufacturing Company | Cyanoacrylate adhesive composition having sustained toughness |
| CN1138614A (en) * | 1995-03-23 | 1996-12-25 | 株式会社三键 | Cyanoacrylate adhesive composition |
| CN1487983A (en) * | 2001-01-08 | 2004-04-07 | ���̩��(R&D)����˾ | Cyanoacrylate compositions curable to flexible polymeric materials |
| CN101663338A (en) * | 2007-03-09 | 2010-03-03 | 汉高公司 | cyanoacrylate compositions incorporating graphite platelets |
| CN101679709A (en) * | 2006-12-19 | 2010-03-24 | 汉高公司 | Cyanoacrylate compositions containing dispersions of core shell rubbers in (meth)acrylates |
| CN101967354A (en) * | 2010-09-15 | 2011-02-09 | 北京天山新材料技术股份有限公司 | Low whitening alpha-cyanoacrylate adhesive |
| CN102504708A (en) * | 2011-11-07 | 2012-06-20 | 北京天山新材料技术股份有限公司 | Toughened alpha-cyanoacrylate adhesive and preparation method thereof |
| CN104520396A (en) * | 2012-01-23 | 2015-04-15 | 汉高知识产权控股有限责任公司 | Two-part, cyanoacrylate/free radically curable adhesive systems |
| CN105143375A (en) * | 2013-03-15 | 2015-12-09 | 汉高知识产权控股有限责任公司 | Two-part, cyanoacrylate/cationically curable adhesive systems |
-
2016
- 2016-10-26 CN CN201610947856.9A patent/CN106519995A/en active Pending
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4560723A (en) * | 1983-11-14 | 1985-12-24 | Minnesota Mining And Manufacturing Company | Cyanoacrylate adhesive composition having sustained toughness |
| CN1138614A (en) * | 1995-03-23 | 1996-12-25 | 株式会社三键 | Cyanoacrylate adhesive composition |
| CN1487983A (en) * | 2001-01-08 | 2004-04-07 | ���̩��(R&D)����˾ | Cyanoacrylate compositions curable to flexible polymeric materials |
| CN101679709A (en) * | 2006-12-19 | 2010-03-24 | 汉高公司 | Cyanoacrylate compositions containing dispersions of core shell rubbers in (meth)acrylates |
| CN101663338A (en) * | 2007-03-09 | 2010-03-03 | 汉高公司 | cyanoacrylate compositions incorporating graphite platelets |
| CN101967354A (en) * | 2010-09-15 | 2011-02-09 | 北京天山新材料技术股份有限公司 | Low whitening alpha-cyanoacrylate adhesive |
| CN102504708A (en) * | 2011-11-07 | 2012-06-20 | 北京天山新材料技术股份有限公司 | Toughened alpha-cyanoacrylate adhesive and preparation method thereof |
| CN104520396A (en) * | 2012-01-23 | 2015-04-15 | 汉高知识产权控股有限责任公司 | Two-part, cyanoacrylate/free radically curable adhesive systems |
| CN105143375A (en) * | 2013-03-15 | 2015-12-09 | 汉高知识产权控股有限责任公司 | Two-part, cyanoacrylate/cationically curable adhesive systems |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107442381A (en) * | 2017-09-01 | 2017-12-08 | 山东华成中德传动设备有限公司 | A kind of wood mold coupled surface treatment method |
| CN109021843A (en) * | 2018-06-07 | 2018-12-18 | 得力集团有限公司 | Low albefaction instant glue of a kind of impact resistance and preparation method thereof |
| CN109021843B (en) * | 2018-06-07 | 2021-08-06 | 得力集团有限公司 | Impact-resistant low-whitening instant adhesive and preparation method thereof |
| CN116731666A (en) * | 2023-08-15 | 2023-09-12 | 山东凯恩新材料科技有限公司 | Waterproof quick-drying adhesive and preparation method thereof |
| CN116731666B (en) * | 2023-08-15 | 2023-10-20 | 山东凯恩新材料科技有限公司 | Waterproof quick-drying adhesive and preparation method thereof |
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