CN106519918A - Urea-containing automobile leaf spring paint and preparation method thereof - Google Patents
Urea-containing automobile leaf spring paint and preparation method thereof Download PDFInfo
- Publication number
- CN106519918A CN106519918A CN201610905413.3A CN201610905413A CN106519918A CN 106519918 A CN106519918 A CN 106519918A CN 201610905413 A CN201610905413 A CN 201610905413A CN 106519918 A CN106519918 A CN 106519918A
- Authority
- CN
- China
- Prior art keywords
- mentioned
- stirred
- parts
- added
- leaf spring
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
- C09D163/10—Epoxy resins modified by unsaturated compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a urea-containing automobile leaf spring paint, which is composed of the following raw materials by weight: 0.6-2 parts of urea, 6-8 parts of carbon nanotube, 0.7-1 part of diisodecyl phthalate, 7-9 parts of hydroxyethyl methylacrylate, 0.8-1 part of phosphorus pentoxide, 2-3 parts of p-methoxyphenol, 0.6-2 parts of tetrabutylammonium bromide, 17-20 parts of acrylic acid, 6-8 parts of methyl methacrylate, 140-150 parts of epoxy resin E-51, 0.07-0.1 part of ammonium persulfate, 2-3 parts of sodium bicarbonate, 0.6-1 part of sodium dodecyl benzene sulfonate, 0.6-1 part of ammonium ferrous sulfate, 2-3 parts of polytetrahydrofuran glycol, 1-2 parts of potassium zirconium carbonate, 0.3-1 part of diisopropylethanolamine, 0.8-1 part of polybenzimidazole, and 0.1-0.2 part of tributyltin trichloride. The urea-containing automobile leaf spring paint provided by the invention is low in cost, and solves the problems of large "ground amount", environmental unfriendliness and poor anti-rust capability of automobile leaf spring coatings at the present stage.
Description
Technical field
The present invention relates to anticorrosive coating technical field, more particularly to a kind of urea-containing automobile leaf spring coating and its
Preparation method.
Background technology
Acrylic monomerss are often used in the polymerization process of water-borne acrylic resin, due to the hydrophilic carboxylic on acrylic acid
The presence of base so that polymer emulsion stability strengthens, and under conditions of dry film, carboxyl can closely stick to one with ground
Rise, substantially increase the adhesive force for applying interlayer；But in wet environment, due to the carboxylated hydrophilic on acrylic acid, between water
Association it is very strong, hydrone is entered easily by capillary attraction in the interface of coating and metal, causes carboxyl with gold
The active force of category substrate surface is substantially reduced, and dampness adhesive force is performed poor, and resistance to water is reduced, and can consequently also affect film
Antiseptic property.Function phosphate ester monomer is the mixture of phosphate monoester, di-phosphate ester and a small amount of phosphoric acid；Phosphate monoester can be with
Metal base reacts and generates phosphate monoester iron salt, forms fine and close protecting film, and this all phosphate ester is just securely connected
To on base material, so as to improve the adhesive force of film；
In recent years, because special effect of the function phosphate ester in terms of film rustless property and anti-flash rusting is improved so that he is increasingly
It is taken seriously, as increasing R＆D worker begins one's study its application in water soluble acrylic acid anticorrosive paint.By its
The Corrosion Protection improved as additive is obvious, and operating process is simple, convenient, has become water-based anticorrosive paint from now on
One important development direction of research；
However, feature phosphate ester monomer mostly is import, costly, technique prepared by phosphate ester monomer is complex for price,
Domestic fewer to its building-up process systematic research, these unfavorable factors have limited to phosphate ester in water soluble acrylic acid anticorrosive paint
In application development.But more excellent, the less expensive phosphate ester of volatility is made slow progress, so, simplify the preparation technology of phosphate ester
And the utilization rate of raising function phosphate ester monomer becomes current practicable method as far as possible；Epoxy resin is to acrylic resin
Modified hardness and resistance to water to paint film increase significantly；
The modified rustless property that can efficiently improve paint film of the phosphate ester function monomer to acrylic resin, and operate letter
Just.As current fluorine-containing emulsifier and fluorine monomer are expensive, grafting efficiency is low.The present invention considers automobile leaf spring application
Particular/special requirement, adopt phosphate ester monomer and the monomer modified acrylic resin of epoxy acrylic for matrix resin；
The coating process of automobile leaf spring is：Leaf spring carries out application one by one, and then assembly is locked together is carried out again
Application.If applying thickness, during locking together, the coating between two spring leafs will be squeezed out, or even destruction is applied
Layer.If coating is too thin, general coating rustless property is poor, is not enough to protect automobile leaf spring piece, and this is accomplished by obtained
Possess rustless property as high as possible in the case that coating material coating is relatively thin.At present both at home and abroad the coating of automobile leaf spring compared with
Thickness, the destruction of too thick extruding during more or less presence coating assembly, can further become corrosion point, sternly at these destructions
The quality of the impact automobile leaf spring coating of weight, the rust-preventing characteristic for improving unit thickness coating as far as possible are increasingly becoming urgent need solution
A difficult problem certainly.Then, the present invention is modified to it using acrylic resin as matrix resin with epoxy resin, and this just makes
Antiseptic property, adhesive force that coating material had both had epoxy resin excellent is obtained, and with the excellent chemical-resistant of acrylic resin
And pliability, greatly improve the rustless property of unit thickness coating.
The content of the invention
The object of the invention is exactly for the defect for making up prior art, there is provided a kind of urea-containing automobile leaf spring coating
And preparation method thereof.
The present invention is achieved by the following technical solutions：
A kind of urea-containing automobile leaf spring coating, it is made up of the raw material of following weight parts：
Carbamide 0.6-2, CNT 6-8, diisooctyl phthalate 0.7-1, hydroxyethyl methylacrylate 7-9, five oxidations
Two phosphorus 0.8-1, p methoxy phenol 2-3, tetrabutyl ammonium bromide 0.6-2, acrylic acid 17-20, methyl methacrylate 6-8, ring
Oxygen tree fat E-51140-150, Ammonium persulfate. 0.07-0.1, sodium bicarbonate 2-3, dodecylbenzene sodium sulfonate 0.6-1, ferrous sulfate
Ammonium 0.6-1, PTMG 2-3, potassium zirconium carbonate 1-2, diisopropyl ethanolamine 0.3-1, polybenzimidazoles 0.8-1,
Tributyl tin trichloride 0.1-0.2.
A kind of preparation method of described urea-containing automobile leaf spring coating, comprises the following steps：
（1）Above-mentioned polybenzimidazoles is added in the dehydrated alcohol of its weight 7-10 times, is stirred, liter high-temperature is 54-
60 DEG C, insulated and stirred 10-14 minute, above-mentioned Ferrous ammonium sulfate, the 65-70% of above-mentioned p methoxy phenol weight is added, continue to protect
Temperature stirring 20-30 minutes, tributyl tin trichloride is added, is stirred to room temperature, is obtained alcohol dispersion liquid；
（2）Above-mentioned alcohol dispersion liquid, hydroxyethyl methylacrylate are mixed, warming temperature is 30-35 DEG C, under 1000-1200 rev/min
Insulated and stirred 10-13 minute, above-mentioned phosphorus pentoxide is added, it is 70-75 DEG C to rise high-temperature, insulated and stirred 100-120 minute, plus
Enter the water of mixed system weight 4-6%, send in 87-90 DEG C of water bath with thermostatic control, insulated and stirred 2.7-3 hour, discharging cooling is obtained
Hydroxyl phosphate；
（3）Above-mentioned tetrabutyl ammonium bromide, remaining p methoxy phenol are mixed, are added in aforesaid propylene acid, are stirred,
Obtain acrylic dispersions；
（4）Above-mentioned potassium zirconium carbonate is added in the deionized water of its weight 10-13 times, is stirred, add diisopropyl second
Hydramine, the insulated and stirred 4-9 minute at 60-67 DEG C, adds above-mentioned CNT, stirs to room temperature, and Deca concentration is 70-76%
Sulfuric acid solution, regulation pH be 2-3, stirring reaction 16-20 minute, filter, will precipitation washing 3-4 time, the vacuum at 50-60 DEG C
1-2 hours are dried, modified precipitation is obtained；
（5）Above-mentioned epoxy resin E-51 is taken, is sent in 100-110 DEG C of oil bath, Deca aforesaid propylene acid dispersion liquid, insulation are stirred
3-4 hours are mixed, discharging cooling obtains epoxy acrylic ester monomer；
（6）By above-mentioned diisooctyl phthalate, epoxy acrylic ester monomer, methyl methacrylate, detergent alkylate sulphur
Sour sodium mixing, is added in the deionized water of compound weight 6-9 times, stirs, obtain pre-emulsion；
（7）Above-mentioned sodium bicarbonate is added in the deionized water of its weight 18-20 times, is stirred at 70-75 DEG C, added
Above-mentioned Ammonium persulfate., modified precipitation, it is 80-85 DEG C to rise high-temperature, and Deca above-mentioned pre-emulsion adds above-mentioned hydroxyl after completion of dropping
Phosphate ester, continuation insulated and stirred 50-60 minute, it is 60-65 DEG C to reduce temperature, is incubated 30-40 minutes, and regulation pH is 6-7, is ground
50 μm are less than to fineness, are obtained final product.
It is an advantage of the invention that：Using method：Using the front coating by the present invention and its weight 20-30%
2771 firming agent of Anquamine mixes, and stirs, you can carry out application；
The epoxy radicals of epoxy acrylate are fixed on the stratum nucleare of nucleocapsid structure by the method for core-shell emulsion polymerization by the present invention,
Methacrylic acid is poly- in emulsion as the hydrophilic crosslinked dose of outer layer for being fixed on core-shell latex particles, the wherein carboxyl on methacrylic acid
First with organic amine and closing during conjunction so that the initial ring that emulsion will not be too early during polymerization and storage
The reaction of epoxide and carboxyl, with moisture evaporation, emulsion particle particle contact, piles up, deforms, subsiding, and polymer macromolecule is obtained
Sufficiently mix, and with the volatilization of organic amine, increasing carboxyl is unsealed, the epoxy radicals in different layers are distributed across
Meet with carboxyl and there occurs cross-linking reaction, constitute the cross-linking system of the self-crossing emulsion of the present invention, the degree of cross linking of paint film and cause
Close property is greatly improved；
The phosphate ester monomer that complex can be formed with metallic surface containing a large amount of phosphorus hydroxyls is incorporated into acrylic acid by the present invention
In ester emulsion, in phosphate ester monomer, phosphorus hydroxyl has stronger chelation with metal surface, can act on being formed with polyvalent metal
Phosphate complex, and polymer is strongly attached on metal base in the form of covalent bond, wet adhesion is significantly improved,
Substantial amounts of phosphorus hydroxyl is distributed in the shell of core-shell emulsion, and the phosphorus hydroxyl of shell can be contacted with metal surface, be prevented the very first time
The appearance of " dodging erosion " phenomenon so that emulsion has the function of similar phosphorization, both eliminates phosphorus for automobile leaf spring coating
Change and process this procedure, etching waste liquor will not be produced again and pollute environment, reduce cost, solve automobile leaf spring coating
At this stage " landing amount " it is big, not environmentally, the problem of antirust ability difference；The coating of the present invention can form uniform steady in substrate surface
Fixed film, coating waterproofing are good, and weatherability is strong, and service life is long.
Specific embodiment
A kind of urea-containing automobile leaf spring coating, it is made up of the raw material of following weight parts：
Carbamide 0.6, CNT 6, diisooctyl phthalate 0.7, hydroxyethyl methylacrylate 7, phosphorus pentoxide 0.8,
P methoxy phenol 2, tetrabutyl ammonium bromide 0.6, acrylic acid 17, methyl methacrylate 6, epoxy resin E-51 146, over cure
Sour ammonium 0.07, sodium bicarbonate 2, dodecylbenzene sodium sulfonate 0.6, Ferrous ammonium sulfate 0.6, PTMG 2, zirconium carbonate
Potassium 1, diisopropyl ethanolamine 0.3, polybenzimidazoles 0.8, tributyl tin trichloride 0.1.
A kind of preparation method of described urea-containing automobile leaf spring coating, comprises the following steps：
（1）Above-mentioned polybenzimidazoles is added in the dehydrated alcohol of 7 times of its weight, is stirred, it is 54 DEG C to rise high-temperature, is protected
Temperature stirring 10 minutes, add above-mentioned Ferrous ammonium sulfate, the 65% of above-mentioned p methoxy phenol weight, continue insulated and stirred 20 minutes,
Tributyl tin trichloride is added, is stirred to room temperature, is obtained alcohol dispersion liquid；
（2）Above-mentioned alcohol dispersion liquid, hydroxyethyl methylacrylate are mixed, warming temperature is 30 DEG C, 1000 revs/min of lower insulated and stirred
10 minutes, above-mentioned phosphorus pentoxide is added, it is 70 DEG C to rise high-temperature, and insulated and stirred 100 minutes adds mixed system weight 4%
Water, sends in 87 DEG C of water bath with thermostatic control, insulated and stirred 2.7 hours, and discharging cooling obtains hydroxyl phosphate；
（3）Above-mentioned tetrabutyl ammonium bromide, remaining p methoxy phenol are mixed, are added in aforesaid propylene acid, are stirred,
Obtain acrylic dispersions；
（4）Above-mentioned potassium zirconium carbonate is added in the deionized water of 10 times of its weight, is stirred, add diisopropyl ethanol
Amine, insulated and stirred 4 minutes at 60 DEG C add above-mentioned CNT, stir to room temperature, and Deca concentration is 70% sulfuric acid solution,
It is 2 to adjust pH, and stirring reaction 16 minutes is filtered, and by precipitation washing 3 times, is vacuum dried 1 hour, obtains modified precipitation at 50 DEG C；
（5）Above-mentioned epoxy resin E is taken, is sent in 100 DEG C of oil bath, Deca aforesaid propylene acid dispersion liquid, insulated and stirred 3 are little
When, discharging cooling obtains epoxy acrylic ester monomer；
（6）By above-mentioned diisooctyl phthalate, epoxy acrylic ester monomer, methyl methacrylate, detergent alkylate sulphur
Sour sodium mixing, is added in the deionized water of 6 times of compound weight, stirs, obtain pre-emulsion；
（7）Above-mentioned sodium bicarbonate is added in the deionized water of 18 times of its weight, is stirred at 70 DEG C, add above-mentioned mistake
Ammonium sulfate, modified precipitation, it is 80 DEG C to rise high-temperature, and Deca above-mentioned pre-emulsion adds above-mentioned hydroxyl phosphate after completion of dropping, after
Continuous insulated and stirred 50 minutes, it is 60 DEG C to reduce temperature, is incubated 30 minutes, and it is 6 to adjust pH, is ground to fineness less than 50 μm, obtains final product.
Performance test：
Resistance to 3% saline 700h is unchanged；
1 grade of adhesive force, without " flash rusting "；
Impact resistance：≥50kg/cm；
Acid resistance：（25% sulphuric acid, 25 DEG C）：30d is unchanged；
Alkali resistance：（25% sodium hydroxide, 25 DEG C）：30d is unchanged.
Claims (2)
1. a kind of urea-containing automobile leaf spring coating, it is characterised in that it is made up of the raw material of following weight parts：
Carbamide 0.6-2, CNT 6-8, diisooctyl phthalate 0.7-1, hydroxyethyl methylacrylate 7-9, five oxidations
Two phosphorus 0.8-1, p methoxy phenol 2-3, tetrabutyl ammonium bromide 0.6-2, acrylic acid 17-20, methyl methacrylate 6-8, ring
Oxygen tree fat E-51140-150, Ammonium persulfate. 0.07-0.1, sodium bicarbonate 2-3, dodecylbenzene sodium sulfonate 0.6-1, ferrous sulfate
Ammonium 0.6-1, PTMG 2-3, potassium zirconium carbonate 1-2, diisopropyl ethanolamine 0.3-1, polybenzimidazoles 0.8-1,
Tributyl tin trichloride 0.1-0.2.
2. a kind of preparation method of urea-containing automobile leaf spring coating as claimed in claim 1, it is characterised in that include
Following steps：
（1）Above-mentioned polybenzimidazoles is added in the dehydrated alcohol of its weight 7-10 times, is stirred, liter high-temperature is 54-
60 DEG C, insulated and stirred 10-14 minute, above-mentioned Ferrous ammonium sulfate, the 65-70% of above-mentioned p methoxy phenol weight is added, continue to protect
Temperature stirring 20-30 minutes, tributyl tin trichloride is added, is stirred to room temperature, is obtained alcohol dispersion liquid；
（2）Above-mentioned alcohol dispersion liquid, hydroxyethyl methylacrylate are mixed, warming temperature is 30-35 DEG C, under 1000-1200 rev/min
Insulated and stirred 10-13 minute, above-mentioned phosphorus pentoxide is added, it is 70-75 DEG C to rise high-temperature, insulated and stirred 100-120 minute, plus
Enter the water of mixed system weight 4-6%, send in 87-90 DEG C of water bath with thermostatic control, insulated and stirred 2.7-3 hour, discharging cooling is obtained
Hydroxyl phosphate；
（3）Above-mentioned tetrabutyl ammonium bromide, remaining p methoxy phenol are mixed, are added in aforesaid propylene acid, are stirred,
Obtain acrylic dispersions；
（4）Above-mentioned potassium zirconium carbonate is added in the deionized water of its weight 10-13 times, is stirred, add diisopropyl second
Hydramine, the insulated and stirred 4-9 minute at 60-67 DEG C, adds above-mentioned CNT, stirs to room temperature, and Deca concentration is 70-76%
Sulfuric acid solution, regulation pH be 2-3, stirring reaction 16-20 minute, filter, will precipitation washing 3-4 time, the vacuum at 50-60 DEG C
1-2 hours are dried, modified precipitation is obtained；
（5）Above-mentioned epoxy resin E-51 is taken, is sent in 100-110 DEG C of oil bath, Deca aforesaid propylene acid dispersion liquid, insulation are stirred
3-4 hours are mixed, discharging cooling obtains epoxy acrylic ester monomer；
（6）By above-mentioned diisooctyl phthalate, epoxy acrylic ester monomer, methyl methacrylate, detergent alkylate sulphur
Sour sodium mixing, is added in the deionized water of compound weight 6-9 times, stirs, obtain pre-emulsion；
（7）Above-mentioned sodium bicarbonate is added in the deionized water of its weight 18-20 times, is stirred at 70-75 DEG C, added
Above-mentioned Ammonium persulfate., modified precipitation, it is 80-85 DEG C to rise high-temperature, and Deca above-mentioned pre-emulsion adds above-mentioned hydroxyl after completion of dropping
Phosphate ester, continuation insulated and stirred 50-60 minute, it is 60-65 DEG C to reduce temperature, is incubated 30-40 minutes, and regulation pH is 6-7, is ground
50 μm are less than to fineness, are obtained final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610905413.3A CN106519918A (en) | 2016-10-17 | 2016-10-17 | Urea-containing automobile leaf spring paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610905413.3A CN106519918A (en) | 2016-10-17 | 2016-10-17 | Urea-containing automobile leaf spring paint and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106519918A true CN106519918A (en) | 2017-03-22 |
Family
ID=58332245
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610905413.3A Withdrawn CN106519918A (en) | 2016-10-17 | 2016-10-17 | Urea-containing automobile leaf spring paint and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106519918A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107201002A (en) * | 2017-06-29 | 2017-09-26 | 倪群 | A kind of carbon nano-tube hybridization grafting flame retardant epoxy material and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102127271A (en) * | 2010-12-24 | 2011-07-20 | 大连工业大学 | Water-based epoxy modified phosphorus-containing styrene-acrylic antirust emulsion and synthesis method thereof |
| CN102924667A (en) * | 2012-10-26 | 2013-02-13 | 武汉海源九天新材料有限公司 | Single-component self-phosphatizing antirust acrylic emulsion, and preparation method and application thereof |
-
2016
- 2016-10-17 CN CN201610905413.3A patent/CN106519918A/en not_active Withdrawn
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102127271A (en) * | 2010-12-24 | 2011-07-20 | 大连工业大学 | Water-based epoxy modified phosphorus-containing styrene-acrylic antirust emulsion and synthesis method thereof |
| CN102924667A (en) * | 2012-10-26 | 2013-02-13 | 武汉海源九天新材料有限公司 | Single-component self-phosphatizing antirust acrylic emulsion, and preparation method and application thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107201002A (en) * | 2017-06-29 | 2017-09-26 | 倪群 | A kind of carbon nano-tube hybridization grafting flame retardant epoxy material and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107163815B (en) | Anticorrosion, fireproof steel structure special coating and preparation method thereof | |
| CN107236437B (en) | A kind of water-based anticorrosive paint and preparation method thereof | |
| CN105859936A (en) | Acrylate copolymer emulsion, and aqueous industrial anticorrosive paint adopting acrylate copolymer emulsion as film forming substance | |
| CN110229594A (en) | A kind of preparation method of the super-hydrophobic composite anticorrosion coating of terpolymer doped polyaniline | |
| CN103602193A (en) | Priming paint for water-borne heavy anti-corrosion coating and preparation method thereof | |
| CN108047839A (en) | A kind of aqueous inorganic environmental protection coating material and preparation method thereof | |
| CN108913013A (en) | A kind of high bond strength ocean concrete anti-corrosion material and its preparation process | |
| CN103627286A (en) | Water-based finishing coat for heavy-duty coating and preparation method of water-based finishing coat | |
| CN106497300A (en) | A kind of automobile leaf spring anti-flaming dope and preparation method thereof | |
| CN106957579A (en) | One-component acrylate paint with anti-corrosion, anti-wear performance | |
| CN106519918A (en) | Urea-containing automobile leaf spring paint and preparation method thereof | |
| CN104845484A (en) | High-mechanical-performance water-proof engineering machinery paint | |
| CN108314946A (en) | A kind of composite aqueous paint | |
| CN111909587B (en) | Water-based primer and preparation method and application thereof | |
| CN106543843A (en) | Modified automobile leaf spring coating of a kind of graphene oxide and preparation method thereof | |
| CN106519878A (en) | Titanate-modified automobile leaf spring coating and preparation method thereof | |
| CN106543854A (en) | A kind of epoxy automobile leaf spring coating and preparation method thereof | |
| CN106566362A (en) | Hard and saponified automobile leaf spring coating and preparation method thereof | |
| CN106543856A (en) | A kind of automobile leaf spring nano paint and preparation method thereof | |
| CN106519917A (en) | Flash-rust preventing automobile steel plate spring paint and preparation method thereof | |
| CN106543845A (en) | It is a kind of to be combined silane-modified automobile leaf spring coating and preparation method thereof | |
| CN106566360A (en) | Self-cleaning automotive steel plate spring coating and preparation method thereof | |
| CN106519875A (en) | Anti-oxidization automobile steel plate spring paint and preparation method thereof | |
| CN107033723A (en) | One kind is without deposition automobile leaf spring coating and preparation method thereof | |
| CN100509979C (en) | Polymer composition and monomeric composition preparied using the same |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20170322 |