CN106519626A - Composite material and preparation method thereof - Google Patents
Composite material and preparation method thereof Download PDFInfo
- Publication number
- CN106519626A CN106519626A CN201610981142.XA CN201610981142A CN106519626A CN 106519626 A CN106519626 A CN 106519626A CN 201610981142 A CN201610981142 A CN 201610981142A CN 106519626 A CN106519626 A CN 106519626A
- Authority
- CN
- China
- Prior art keywords
- composite
- parts
- temperature
- mass
- heating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/9258—Velocity
- B29C2948/9259—Angular velocity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/08—Polymer mixtures characterised by other features containing additives to improve the compatibility between two polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/53—Core-shell polymer
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
The invention discloses a composite material and a preparation method thereof. The composite material is prepared from 50 to 80 parts by mass of polycarbonate resin, 10 to 35 parts by mass of ABS resin, 1 to 8 parts by mass of a compatible flexibilizer, 4 to 18 parts by mass of mineral powder, 2 to 8 parts by mass of a flow modifier, 1 to 5 parts by mass of color masterbatch, 0.1 to 1.5 parts by mass of metal powder, 0.1 to 1.5 parts by mass of pearl powder and 0.3 to 1.5 parts by mass of diffusion oil. The composite material is produced by blending raw materials according to a mass part ratio and carrying out melting granulation. Through use of the metal powder and pearl powder, alloy material colorful metal effects satisfy household electrical appliance product appearance and use requirements and the composite material has the advantages of scratch resistance, high hardness and environmental friendliness. The flow modifier can provide material flowability and improve the material injection molding performances. The micro/nano-silicate particles can improve the mechanical properties and gloss of the composite material and improve wear resistance of the composite material so that the composite material meets spray-free and high gloss appearance requirements.
Description
Technical field
The present invention relates to macromolecule engineering plastics modification technology field, more particularly to a kind of composite and its preparation side
Method, more particularly to brilliant metal effect anti-scratch draw high rigidity Merlon/ABS alloy material and preparation method thereof.
Background technology
Polycarbonate plastic (referred to as PC) becomes ability, transparent easy coloring with its excellent impact strength, toughness, heat resistanceheat resistant
The features such as, it is widely used in electronic apparatus, automobile, engineering construction industry, becomes one of most widely used five large-engineering plastics.But
The defects such as Merlon chemical-resistant stability, resistance to scraping property deficiency also limit its application in terms of some products.
Acrylonitrile-butadiene-styrene (ABS) plastics (referred to as ABS resin) are one of most widely used non-universal plastics, tool
There are excellent impact resistance, thermostability, lower temperature resistance, chemical resistance, be easily-synthesized the performances such as processing, by synthesis, modified extensive
It is applied to machinery, automobile, field of electronics.
The synthesis of ABS resin and Merlon can effectively comprehensive respective feature performance benefit, make up respective performance deficiency, make
The high impact-resistant with PC, heat resistanceheat resistant become the excellent chemical stability of ability and ABS, easy processing, low cost etc. simultaneously to obtain complex
Advantage.Through the Merlon/ABS resin alloy material of special formulation and technique, with certain hardness, toughness, glossiness,
Shock resistance, thermostability, and with higher cost performance, it is suitably applied the appearance member and structure of electric equipment products etc.
Part.
Prior art does not have a kind of can not have with reference to the composite of the respective advantage of polycarbonate plastic and ABS resin yet
A kind of preparation method for preparing the composite is provided with, and in existing composite, is also not bound with polycarbonate plastic
With ABS resin bi-material and produce brilliant metal effect nor have anti-scratch draw high rigidity Merlon.
The content of the invention
In place of in view of the shortcomings of the prior art, it is an object of the invention to provide a kind of composite and its preparation side
Method, with Merlon and ABS as base material and by addition it is micro-/receive the function additives such as silicate granules, color masterbatch, and while with metal
Powder, pearl essence are filler, making synthesized it is a kind of draw with high rigidity, anti-scratch, the composite of brilliant metal effect.
The purpose of the present invention is achieved through the following technical solutions：
A kind of composite, the raw material of the composite is according to following mass fraction proportioning：
The composite is fabricated by by blending, melt pelletization according to the raw material of the mass fraction proportioning.
In order to the present invention is better achieved, currently preferred composite proportioning raw materials technical scheme is：It is described compound
The raw material of material is according to following mass fraction proportioning：
The composite is fabricated by by blending, melt pelletization according to the raw material of the mass fraction proportioning.
Currently preferred Merlon, ABS resin difference technical scheme it is as follows：The thermal deformation temperature of the Merlon
Spend for 110～150 DEG C, the heat distortion temperature of the ABS resin is 70～90 DEG C.
Currently preferred metal powder technical scheme is as follows：The geometry of the metal powder be cornflake, metal powder
Size be 10～50 μm.
The technical scheme of currently preferred pearl essence is as follows：The size of the pearl essence is 50～110 μm.
Currently preferred compatilizer is as follows with toughener technical scheme：The compatible toughening agents are methyl methacrylate
Ester-butadiene-styrene terpolymer；The weight portion of the MBS terpolymer
Number content is as follows：The parts by weight of methyl methacrylate are 25～45 parts, and the parts by weight of butadiene are 20～40 parts, benzene second
The parts by weight of alkene are 15～55 parts.
Currently preferred flow ability modifying agent technical scheme is as follows：The flow ability modifying agent is synthetic thermoplastic acrylonitrile benzene
Ethene polymerss, the wherein weight percent content of AS resins (also known as SAN) are 70～90%.
Currently preferred mineral powder technical scheme is as follows：The mineral powder for it is micro-/receive silicate granules Jing Tissuemat Es
Surface-active-treatment is formed, and the particle diameter of mineral powder is in 2000～3000 mesh.
A kind of preparation method of composite, its preparation method are as follows：
Merlon and ABS resin in A, the material component of the composite is required to dried, and which is dried temperature
Spend for 80～100 DEG C, 3～6 hours drying times；
B, all raw materials of composite will be prepared high-speed mixer is added to (in high-speed mixer according to component proportioning
Blade rotating speed is 35～44r/s) high speed mixes 2～5 minutes, and the heating-up temperature of high-speed mixer is 190～260 DEG C, is passed through
High-speed mixer is mixed evenly to prepare composite mixture material；
C, the composite mixture material for obtaining step B can be answered Jing after the melt pelletization of melting granulator is processed
Condensation material finished granule, control melting granulator main-machine screw rotating speed be 35～44r/s, and control feed rotating speed be 25～
35r/s, through five heating-up temperature sections in melting granulator, its temperature conditionss difference is as follows for composite mixture material：
First paragraph heating-up temperature is 190 DEG C, and second segment heating-up temperature is 220 DEG C, and the 3rd section of heating-up temperature is 240 DEG C, the
Four sections of heating-up temperatures are 240 DEG C, and the 5th section of heating-up temperature is 240 DEG C.
The present invention compared with the prior art, with advantages below and beneficial effect：
The present invention reasonably have adjusted the physical property of Merlon and ABS composite material, the metal powder of addition, pearl essence
The brilliant metal effect of alloy material can be made to reach household appliances outward appearance use requirement, it is good with anti-scratch stroke, high rigidity, the feature of environmental protection
The advantages of.The present invention is additionally added flow ability modifying agent, can provide material flowability, improves material injection performance；The micro-nano of addition
Silicate granules can improve the mechanical property of composite, glossiness, also can reinforcing material anti-wear performance, make brilliant metal
Effect anti-scratch is drawn high rigidity Merlon and disclosure satisfy that product exempts from spraying, high glaze outward appearance demand with ABS resin composite.
Specific embodiment
The present invention is described in further detail with reference to embodiment：
Embodiment
A kind of composite and preparation method thereof, the raw material of the composite is according to following mass fraction proportioning：
The composite is fabricated by by blending, melt pelletization according to the raw material of the mass fraction proportioning.
In order to the present invention is better achieved, currently preferred composite proportioning raw materials technical scheme is：It is described compound
The raw material of material is according to following mass fraction proportioning：
The composite is fabricated by by blending, melt pelletization according to the raw material of the mass fraction proportioning.
The heat distortion temperature of the Merlon is 110～150 DEG C, and the heat distortion temperature of the ABS resin is 70～90
℃。
The geometry of the metal powder is cornflake, and the size of metal powder is 10～50 μm.
The size of the pearl essence is 50～110 μm.
The compatible toughening agents are MBS terpolymer；The methacrylic acid
The parts by weight content of methyl ester-butadiene-styrene terpolymer is as follows：The parts by weight of methyl methacrylate be 25～
45 parts, the parts by weight of butadiene are 20～40 parts, and cinnamic parts by weight are 15～55 parts.
The flow ability modifying agent is synthetic thermoplastic acrylonitrile styrene polymer, and wherein AS resins are (also known as styrene-the third
Alkene lonitrile copolymer) weight percent content be 70～90%.
The mineral powder is formed for micro-/silicate granules Jing Tissuemat E surface-active-treatment of receiving, and the particle diameter of mineral powder exists
2000～3000 mesh.
A kind of preparation method of composite, its preparation method are as follows：
Merlon and ABS resin in A, the material component of the composite is required to dried, and which is dried temperature
Spend for 80～100 DEG C, 3～6 hours drying times；
B, all raw materials of composite will be prepared high-speed mixer is added to (in high-speed mixer according to component proportioning
Blade rotating speed is 35～44r/s) high speed mixes 2～5 minutes, and the heating-up temperature of high-speed mixer is 190～260 DEG C, is passed through
High-speed mixer is mixed evenly to prepare composite mixture material；
C, the composite mixture material for obtaining step B can be answered Jing after the melt pelletization of melting granulator is processed
Condensation material finished granule, control melting granulator main-machine screw rotating speed be 35～44r/s, and control feed rotating speed be 25～
35r/s, through five heating-up temperature sections in melting granulator, its temperature conditionss difference is as follows for composite mixture material：
First paragraph heating-up temperature is 190 DEG C, and second segment heating-up temperature is 220 DEG C, and the 3rd section of heating-up temperature is 240 DEG C, the
Four sections of heating-up temperatures are 240 DEG C, and the 5th section of heating-up temperature is 240 DEG C.
Embodiment 1
A kind of preparation method of composite, the raw material of composite weigh various raw materials according to 1 composition of raw materials of table, wherein
Polycarbonate resin (under conditions of 300 DEG C/1.2Kg ISO1133 (ASTM D-1238), its melt index in 19g/10min,
Rockwell hardness (ISO2039-2ASTM D-785) is R120 (M75)).(under conditions of 200 DEG C/5Kg, its melting refers to ABS resin
In 8.5g/10min, 1.57) index of refraction is to number.Compatible toughening agents are MBS ternary altogether
Polymers, MBS terpolymer are nucleocapsid structure, and core is the butadiene-styrene of crosslinking
Copolymer (Tg<- 70 DEG C), shell be grafting polymethyl methacrylate (duricrust), methyl methacrylate-butadiene-benzene
Ethylene-dien terpolymer is 40% for the weight percent content of the acrylic acid methyl ester. of nucleocapsid structure, and butadiene percentage by weight contains
Measure as 35%, styrene weight percent content is for 25%).(micro-/silicate granules of receiving are simultaneously at Jing PE wax surface activitys for mineral powder
Reason, 3000 mesh of particle diameter).Flow ability modifying agent is synthetic thermoplastic acrylonitrile styrene polymer, and wherein AS resins are (also known as benzene second
Alkene-acrylonitrile copolymer) weight percent content be 80%；Using front polycarbonate resin, ABS resin under the conditions of 90 DEG C
It is dried 4 hours；Polycarbonate resin, ABS, micro-nano silicate granules, compatible toughening agents, color masterbatch are sequentially added, expansion is subsequently adding
Oil is dissipated, adds high-speed mixer high speed to mix 2 minutes；After metal powder, pearl essence, flow ability modifying agent are sequentially added again at a high speed
Stirring 3～5 minutes, then switches to stirring at low speed 2 minutes, then low speed discharging.Material Jing fusing and pelletings after mixing are obtained
Brilliant metal effect anti-scratch draws the composite of high rigidity Merlon/ABS, and product property detection data is shown in Table 2.Melting
Granulation conditions are：Main-machine screw rotating speed 42.5r/s, feed rotating speed 33r/s；Five heating-up temperature sections of melt pelletization are as follows：The
One section of heating-up temperature is 215 DEG C, and second segment heating-up temperature is 225 DEG C, and the 3rd section of heating-up temperature is 230 DEG C, the 4th section of heating temperature
Spend for 240 DEG C, the 5th section of heating-up temperature is 240 DEG C, the head temperature of melting granulator is 200 DEG C, the melt of melting granulator
Temperature is 240 DEG C.
Embodiment 2
A kind of preparation method of composite, the composite material and preparation method thereof of embodiment 2 are same as Example 1, concrete former
Material proportioning is shown in Table 1；The composite products of embodiment 2 are tested according to GB, and properties of product data are as shown in table 2
Embodiment 3
A kind of preparation method of composite, the composite material and preparation method thereof of embodiment 3 are same as Example 1, concrete former
Material proportioning is shown in Table 1；The composite products of embodiment 3 are tested according to GB, and properties of product data are as shown in table 2
Table 1：The raw material and proportioning of composite
Unit：Kilogram
| Component | Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative example 1 | Comparative example 2 |
| Merlon | 50 | 80 | 65 | 50 | 80 |
| ABS resin | 10 | 35 | 22.5 | 10 | 35 |
| Compatible toughening agents | 1 | 8 | 4.5 | 1 | 8 |
| Mineral powder | 4 | 18 | 11 | 0 | 18 |
| Flow ability modifying agent | 2 | 8 | 5 | 0 | 0 |
| Color masterbatch | 1 | 5 | 3 | 0 | 0 |
| Metal powder | 0.1 | 1.5 | 0.8 | 0 | 0 |
| Pearl essence | 0.1 | 1.5 | 0.8 | 0 | 0 |
| Diffusing oil | 0.3 | 1.5 | 0.9 | 0 | 0 |
Table 2：By the composite property prepared by composite material and preparation method thereof
In the present invention, tensile strength is tested according to GB GB/T1040.2-2006；Bending strength, bending moduluses are pressed
Tested according to GB GB/T9341-2000；Izod notched impact strength is tested according to GB GB/T1843-2008；
Heat distortion temperature is tested according to GB GB/T1634.2-2004；Melt flow rate (MFR) is entered according to GB GB/T3682-2000
Row test；
From Table 2, it can be seen that the ratio and composition by each component in rationally control formula, adds metal powder, pearly-lustre
A kind of Merlon of brilliant metal effect/ABS composite woods can be obtained in the case of powder filler, mineral powder and flow ability modifying agent
Material, so as to relatively low cost by the method for blending and modifying realize environmental protection exempt to paint, with high rigidity, anti-scratch stroke, colorful
The preparation of metal effect composite, the method are simple to operate, and required raw material is easy to get.But, the scope of the present invention is not only
It is limited to this, in being additionally included in the composite of brilliant metal effect, adds the metal powder of any different-grain diameter, pearl essence and not
The implementations such as the coloring agent with color, should all contain in the scope of the present invention.
Presently preferred embodiments of the present invention is the foregoing is only, not to limit the present invention, all essences in the present invention
Any modification, equivalent and improvement made within god and principle etc., should be included within the scope of the present invention.
Claims (9)
1. a kind of composite, it is characterised in that：The raw material of the composite is according to following mass fraction proportioning：
The composite is fabricated by by blending, melt pelletization according to the raw material of the mass fraction proportioning.
2. according to a kind of composite described in claim 1, it is characterised in that：The raw material of the composite is according to following matter
Amount number proportioning：
The composite is fabricated by by blending, melt pelletization according to the raw material of the mass fraction proportioning.
3. according to a kind of composite described in claim 1 or 2, it is characterised in that：The heat distortion temperature of the Merlon
For 110～150 DEG C, the heat distortion temperature of the ABS resin is 70～90 DEG C.
4. according to a kind of composite described in claim 1 or 2, it is characterised in that：The geometry of the metal powder is jade
Rice lamellar, the size of metal powder is 10～50 μm.
5. according to a kind of composite described in claim 1 or 2, it is characterised in that：The size of the pearl essence is 50
～110 μm.
6. according to a kind of composite described in claim 1 or 2, it is characterised in that：The compatible toughening agents are metering system
Sour methyl ester-butadiene-styrene terpolymer；The weight of the MBS terpolymer
Amount number content is as follows：The parts by weight of methyl methacrylate are 25～45 parts, and the parts by weight of butadiene are 20～40 parts,
Cinnamic parts by weight are 15～55 parts.
7. according to a kind of composite described in claim 1 or 2, it is characterised in that：The flow ability modifying agent is synthesis thermoplastic
Property acrylonitrile styrene polymer, wherein the weight percent content of AS resins be 70～90%.
8. according to a kind of composite described in claim 1 or 2, it is characterised in that：The mineral powder for it is micro-/receive silicate
Grain Jing Tissuemat E surface-active-treatment is formed, and the particle diameter of mineral powder is in 2000～3000 mesh.
9. a kind of preparation method for preparing the composite described in any one of claim 1～8, it is characterised in that：Its preparation side
Method is as follows：
Merlon and ABS resin in A, the material component of the composite is required to dried, and its baking temperature is
80～100 DEG C, 3～6 hours drying times；
B, all raw materials of composite will be prepared high-speed mixer high speed is added to according to component proportioning and mix 2～5 minutes,
The heating-up temperature of high-speed mixer is 190～260 DEG C, is mixed evenly to prepare composite mixture material through high-speed mixer；
C, the composite mixture material for obtaining step B are obtained composite wood Jing after the melt pelletization of melting granulator is processed
Material finished granule, the main-machine screw rotating speed for controlling melting granulator is 35～44r/s, and controls to feed rotating speed for 25～35r/s,
, through five heating-up temperature sections in melting granulator, its temperature conditionss difference is as follows for composite mixture material：
First paragraph heating-up temperature is 190 DEG C, and second segment heating-up temperature is 220 DEG C, and the 3rd section of heating-up temperature is 240 DEG C, the 4th section
Heating-up temperature is 240 DEG C, and the 5th section of heating-up temperature is 240 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610981142.XA CN106519626A (en) | 2016-11-08 | 2016-11-08 | Composite material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610981142.XA CN106519626A (en) | 2016-11-08 | 2016-11-08 | Composite material and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106519626A true CN106519626A (en) | 2017-03-22 |
Family
ID=58349867
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610981142.XA Pending CN106519626A (en) | 2016-11-08 | 2016-11-08 | Composite material and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106519626A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107163542A (en) * | 2017-07-17 | 2017-09-15 | 四川长虹智能制造技术有限公司 | A kind of PC/AS/ acrylic resins alloy material and preparation method thereof |
| CN107189398A (en) * | 2017-07-19 | 2017-09-22 | 深圳金福创新科技有限公司 | Nanometer exempts from spraying high-modulus scratch-resistant engineering plastic materials and preparation method, application |
| CN107629435A (en) * | 2017-11-06 | 2018-01-26 | 宝天高科（广东）有限公司 | Bloom exempts from spray on polymer alloy material and its manufacture method |
| CN108192312A (en) * | 2018-01-12 | 2018-06-22 | 中山长虹电器有限公司 | The highlighted of metal/pearly-lustre illusion-colour texture with exquisiteness exempts to spray polycarbonate composite material and preparation method thereof |
| CN110511554A (en) * | 2019-09-17 | 2019-11-29 | 四川长虹电器股份有限公司 | Halogen-free flameproof nitrogen phosphorus Si modification graphene/polycarbonate/ABS alloy material and preparation method thereof |
| CN113045883A (en) * | 2019-12-27 | 2021-06-29 | 惠州视维新技术有限公司 | Imitation metal material, television middle frame and preparation method thereof |
| CN113292836A (en) * | 2021-05-22 | 2021-08-24 | 宁波市威宏明实汽车零部件有限公司 | ABS (acrylonitrile butadiene styrene) and PC (polycarbonate) composite material as well as preparation method and application thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101787192A (en) * | 2009-10-15 | 2010-07-28 | 上海锦湖日丽塑料有限公司 | Low-gloss polycarbonate styreneresin composite and preparation method thereof |
| CN101974218A (en) * | 2010-11-12 | 2011-02-16 | 大河宝利材料科技(苏州)有限公司 | Special plastic/acrylonitrile butadiene styrene (PC/ABS) alloy for notebook computer shell |
| CN102464857A (en) * | 2010-11-15 | 2012-05-23 | 上海锦湖日丽塑料有限公司 | Extrusion grade aesthetical resin possessing metal color effect and its preparation method |
| CN103342886A (en) * | 2013-07-19 | 2013-10-09 | 上海锦湖日丽塑料有限公司 | PC (Poly Carbonate)/ABS (Acylonitrile Butadiene Styrene) coated alloy material and preparation method thereof |
-
2016
- 2016-11-08 CN CN201610981142.XA patent/CN106519626A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101787192A (en) * | 2009-10-15 | 2010-07-28 | 上海锦湖日丽塑料有限公司 | Low-gloss polycarbonate styreneresin composite and preparation method thereof |
| CN101974218A (en) * | 2010-11-12 | 2011-02-16 | 大河宝利材料科技(苏州)有限公司 | Special plastic/acrylonitrile butadiene styrene (PC/ABS) alloy for notebook computer shell |
| CN102464857A (en) * | 2010-11-15 | 2012-05-23 | 上海锦湖日丽塑料有限公司 | Extrusion grade aesthetical resin possessing metal color effect and its preparation method |
| CN103342886A (en) * | 2013-07-19 | 2013-10-09 | 上海锦湖日丽塑料有限公司 | PC (Poly Carbonate)/ABS (Acylonitrile Butadiene Styrene) coated alloy material and preparation method thereof |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107163542A (en) * | 2017-07-17 | 2017-09-15 | 四川长虹智能制造技术有限公司 | A kind of PC/AS/ acrylic resins alloy material and preparation method thereof |
| CN107189398A (en) * | 2017-07-19 | 2017-09-22 | 深圳金福创新科技有限公司 | Nanometer exempts from spraying high-modulus scratch-resistant engineering plastic materials and preparation method, application |
| CN107629435A (en) * | 2017-11-06 | 2018-01-26 | 宝天高科（广东）有限公司 | Bloom exempts from spray on polymer alloy material and its manufacture method |
| CN108192312A (en) * | 2018-01-12 | 2018-06-22 | 中山长虹电器有限公司 | The highlighted of metal/pearly-lustre illusion-colour texture with exquisiteness exempts to spray polycarbonate composite material and preparation method thereof |
| CN110511554A (en) * | 2019-09-17 | 2019-11-29 | 四川长虹电器股份有限公司 | Halogen-free flameproof nitrogen phosphorus Si modification graphene/polycarbonate/ABS alloy material and preparation method thereof |
| CN113045883A (en) * | 2019-12-27 | 2021-06-29 | 惠州视维新技术有限公司 | Imitation metal material, television middle frame and preparation method thereof |
| CN113292836A (en) * | 2021-05-22 | 2021-08-24 | 宁波市威宏明实汽车零部件有限公司 | ABS (acrylonitrile butadiene styrene) and PC (polycarbonate) composite material as well as preparation method and application thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106519626A (en) | Composite material and preparation method thereof | |
| CN107973976B (en) | High-impact-resistance high-gloss spray-free PP/PETG alloy material and preparation method thereof | |
| CN105419205B (en) | A kind of high glaze exempts from the PMMA/ASA alloy resin composition and preparation method thereof of spraying | |
| CN101649102B (en) | High-gloss composite material and preparation method thereof | |
| CN106519530B (en) | A kind of composite material and preparation method | |
| CN107286469B (en) | Spraying-free scratch-resistant PP alloy material and preparation method thereof | |
| CN100549087C (en) | PC terpolymer resin/polybutylene terephthalate alloy material | |
| CN103044910B (en) | Glass fiber reinforced nylon 6 composite material with superhigh content and preparation method thereof | |
| CN104098884B (en) | A kind of automotive trim low gloss PC/ABS alloy | |
| CN101875753B (en) | ABS (Acrylonitrile Butadiene Styrene) modified material with high heat resistance, high gloss and flame retardance and preparation method thereof | |
| CN103289288A (en) | Flame-retardant heat-resisting high-strength ABS (Acrylonitrile Butadiene Styrene) modified material and preparation method | |
| CN107083030A (en) | A kind of low warpage high-strength glass fiber enhanced PBT/ASA alloy materials and preparation method thereof | |
| CN102443256A (en) | High-heat-resistance polycarbonate (PC)/acrylonitrile styrene acrylate copolymer (ASA) alloy material and preparation method thereof | |
| CN102775720A (en) | High-impact and high-heat-resistance ABS alloy and its preparation technology | |
| CN104403258A (en) | Antiflaming reinforcing ABS composite material and preparation method thereof | |
| CN103756240A (en) | Stress whitening resistance ABS (Acrylonitrile Butadiene Styrene) composite material as well as preparation method and application thereof | |
| CN108192312A (en) | The highlighted of metal/pearly-lustre illusion-colour texture with exquisiteness exempts to spray polycarbonate composite material and preparation method thereof | |
| CN101469107B (en) | Glass fiber reinforced PBT / ABS composite material with excellent surface and high fluidity | |
| CN107082960A (en) | A kind of flame retardant type high-gloss polypropylene composite and preparation method thereof | |
| CN107523001A (en) | A kind of ABS/PC 3D consumptive material PP Pipe Compounds and preparation method thereof | |
| CN109836757A (en) | Low gloss low-density HI high impact high heat resistance PC/ABS alloy material and preparation method thereof | |
| CN109467901A (en) | A kind of high glaze, permanent anti-static and the good glass fiber reinforced PC/ABS alloy of dimensional stability and preparation method thereof | |
| CN107118531A (en) | A kind of polycarbonate compositions of excellent chemical resistance and preparation method thereof | |
| CN102181121B (en) | High-fatigue-resistance ABS (Acrylonitrile Butadiene Styrene) resin composition and preparation method thereof | |
| CN108285629B (en) | PC/ABS/PA6 composition and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170322 |