A kind of high temperature resistant moulding compound and preparation method thereof
Technical field
The present invention relates to plastics arts, more specifically a kind of high temperature resistant moulding compound and preparation method thereof.
Background technology
, compared with common thermoplastic, moulding compound is with higher physical dimension stability, more resistant to extreme for moulding compound
The features such as high heat and humidity complex environment, chemicals-resistant burn into high mechanical properties.Apply to space flight and aviation, naval ship and civilian
The industry such as ship, firearms, electronics and electrical component, power equipment component.
The content of the invention
The invention aims to provide a kind of high temperature resistant moulding compound and preparation method thereof.
The purpose of the present invention is achieved through the following technical solutions:
A kind of high temperature resistant moulding compound, is made up of following raw material:Linear phenol-aldehyde resin 50-60, focus ratio 20-30,
Discarded safety glass powder 3-5, nano barium carbonate 4-6, calcium hydroxide 3-5, carbon fiber 2-4, stearic acid 3-5, cyanuric acid triolefin
Propyl ester 1-3, peroxidized t-butyl perbenzoate 2-4, aluminum phosphate 1-3, beryllium oxide 3-5, magnesium molybdate 1-3, basalt fibre 2-4, stone
Oily sulfonic acid 3-5, cumyl peroxide 1-3, dicyanodiamine 1-2.
A kind of preparation method of high temperature resistant moulding compound, comprises the following steps:
(1)Each raw material is weighed by weight;
(2)By stearic acid, triallyl cyanurate, peroxidized t-butyl perbenzoate, magnesium molybdate, mahogany acid, peroxidating two
Isopropylbenzene, dicyanodiamine are added equipped with linear phenol-aldehyde resin, in the stirred tank of focus ratio, are stirred to being uniformly dispersed;
(3)Nano barium carbonate, calcium hydroxide, aluminum phosphate, basalt fibre are added, is stirred with the speed strength of 500-600r/min
Mix;
(4)Ultrasonic strength emulsification instrument is opened, adds beryllium oxide, Jing strong stirrings to obtain disperseing homogeneous pasty state raw material;
(5)It is barrier film with polyethylene film, the discarded safety glass powder of 25mm, carbon is impregnated on laminar film plastic units for sheet material fine
Dimension, Jing after roll-in winding, thickening storage.
It is an advantage of the current invention that:
The moulding compound of the present invention adopts linear phenol-aldehyde resin, focus ratio for primary raw material, and phenolic resin has excellent resistance to
High-temperature behavior, contributes to strengthening the heat-resisting quantity of moulding compound, and focus ratio is not only cheap, contributes to reduction and produces into
This, moreover it is possible to strengthen resistance to water, leakage resistance and the intensity of moulding compound, while with aluminum phosphate, beryllium oxide, magnesium molybdate, basalt
The compositions such as fiber are used cooperatively, and can improve the resistance to elevated temperatures of material.Moulding compound intensity that the present invention is produced is high, heat-resisting quantity
Good, leakage resistance and excellent water resistance, long service life.
Specific embodiment
Embodiment 1, a kind of high temperature resistant moulding compound, by following weight portion(kg)Raw material is made:Linear phenol-aldehyde resin 50, poly- phenol
Oxygen tree fat 20, discarded safety glass powder 3, nano barium carbonate 4, calcium hydroxide 3, carbon fiber 2, stearic acid 3, three allyl of cyanuric acid
Ester 1, peroxidized t-butyl perbenzoate 2, aluminum phosphate 1, beryllium oxide 3, magnesium molybdate 1, basalt fibre 2, mahogany acid 3, peroxidating
Diisopropylbenzene (DIPB) 1, dicyanodiamine 1.
A kind of preparation method of high temperature resistant moulding compound, comprises the following steps:
(1)Each raw material is weighed by weight;
(2)By stearic acid, triallyl cyanurate, peroxidized t-butyl perbenzoate, magnesium molybdate, mahogany acid, peroxidating two
Isopropylbenzene, dicyanodiamine are added equipped with linear phenol-aldehyde resin, in the stirred tank of focus ratio, are stirred to being uniformly dispersed;
(3)Nano barium carbonate, calcium hydroxide, aluminum phosphate, basalt fibre are added, with the speed strong stirring of 500r/min;
(4)Ultrasonic strength emulsification instrument is opened, adds beryllium oxide, Jing strong stirrings to obtain disperseing homogeneous pasty state raw material;
(5)It is barrier film with polyethylene film, the discarded safety glass powder of 25mm, carbon fiber is impregnated on laminar film plastic units for sheet material
Deng raw material, Jing after roll-in winding, thickening storage.
Embodiment 2, a kind of high temperature resistant moulding compound, by following weight portion(kg)Raw material is made:Linear phenol-aldehyde resin 55, poly- phenol
Oxygen tree fat 25, discarded safety glass powder 4, nano barium carbonate 5, calcium hydroxide 4, carbon fiber 3, stearic acid 4, three allyl of cyanuric acid
Ester 2, peroxidized t-butyl perbenzoate 3, aluminum phosphate 2, beryllium oxide 4, magnesium molybdate 2, basalt fibre 3, mahogany acid 4, peroxidating
Diisopropylbenzene (DIPB) 2, dicyanodiamine 1.
A kind of preparation method of high temperature resistant moulding compound, comprises the following steps:
(1)Each raw material is weighed by weight;
(2)By stearic acid, triallyl cyanurate, peroxidized t-butyl perbenzoate, magnesium molybdate, mahogany acid, peroxidating two
Isopropylbenzene, dicyanodiamine are added equipped with linear phenol-aldehyde resin, in the stirred tank of focus ratio, are stirred to being uniformly dispersed;
(3)Nano barium carbonate, calcium hydroxide, aluminum phosphate, basalt fibre are added, with the speed strong stirring of 550r/min;
(4)Ultrasonic strength emulsification instrument is opened, adds beryllium oxide, Jing strong stirrings to obtain disperseing homogeneous pasty state raw material;
(5)It is barrier film with polyethylene film, the discarded safety glass powder of 25mm, carbon fiber is impregnated on laminar film plastic units for sheet material
Deng raw material, Jing after roll-in winding, thickening storage.
Embodiment 3, a kind of high temperature resistant moulding compound, by following weight portion(kg)Raw material is made:Linear phenol-aldehyde resin 60, poly- phenol
Oxygen tree fat 30, discarded safety glass powder 5, nano barium carbonate 6, calcium hydroxide 5, carbon fiber 4, stearic acid 5, three allyl of cyanuric acid
Ester 3, peroxidized t-butyl perbenzoate 4, aluminum phosphate 3, beryllium oxide 5, magnesium molybdate 3, basalt fibre 4, mahogany acid 5, peroxidating
Diisopropylbenzene (DIPB) 3, dicyanodiamine 2.
A kind of preparation method of high temperature resistant moulding compound, comprises the following steps:
(1)Each raw material is weighed by weight;
(2)By stearic acid, triallyl cyanurate, peroxidized t-butyl perbenzoate, magnesium molybdate, mahogany acid, peroxidating two
Isopropylbenzene, dicyanodiamine are added equipped with linear phenol-aldehyde resin, in the stirred tank of focus ratio, are stirred to being uniformly dispersed;
(3)Nano barium carbonate, calcium hydroxide, aluminum phosphate, basalt fibre are added, with the speed strong stirring of 600r/min;
(4)Ultrasonic strength emulsification instrument is opened, adds beryllium oxide, Jing strong stirrings to obtain disperseing homogeneous pasty state raw material;
(5)It is barrier film with polyethylene film, the discarded safety glass powder of 25mm, carbon fiber is impregnated on laminar film plastic units for sheet material
Deng raw material, Jing after roll-in winding, thickening storage.
The main performance testing result of moulding compound obtained in above-described embodiment 1-3 is as shown in the table:
The main performance testing result of moulding compound obtained in 1 embodiment 1-3 of table
|
Embodiment 1 |
Embodiment 2 |
Embodiment 3 |
Bending strength(MPa) |
85.6 |
88.4 |
89.1 |
Impact strength(MPa) |
3.7 |
4.1 |
4.2 |
Mould shrinks(%) |
0.51 |
0.46 |
0.53 |
After-contraction(%) |
0.39 |
0.37 |
0.41 |
Apparent and coloring |
It is excellent |
It is excellent |
It is excellent |
Maximum operating temperature(℃) |
220 |
250 |
235 |