CN106519557A - High-temperature-resistant molded plastic and preparation method thereof - Google Patents

High-temperature-resistant molded plastic and preparation method thereof Download PDF

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Publication number
CN106519557A
CN106519557A CN201610990486.7A CN201610990486A CN106519557A CN 106519557 A CN106519557 A CN 106519557A CN 201610990486 A CN201610990486 A CN 201610990486A CN 106519557 A CN106519557 A CN 106519557A
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Prior art keywords
temperature
molded plastic
raw material
aluminum phosphate
beryllium oxide
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CN201610990486.7A
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CN106519557B (en
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叶晨希
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ANJI WANHANG FURNITURE Co Ltd
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Individual
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L61/00Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
    • C08L61/04Condensation polymers of aldehydes or ketones with phenols only
    • C08L61/06Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a high-temperature-resistant molded plastic and a preparation method thereof and relates to the technical field of plastics. The high-temperature-resistant molded plastic is mainly prepared from linear phenolic resin, poly phenoxy resin, abandoned toughened glass powder, nano barium carbonate, calcium hydroxide, carbon fiber, stearic acid, triallyl cyanurate, tert-butyl peroxybenzoate, aluminum phosphate, beryllium oxide, magnesium molybdate, basalt fiber, petroleum sulfonic acid and the like. The molded plastic adopts the linear phenolic resin and the poly phenoxy resin as main raw materials, the phenolic resin has excellent high-temperature-resistant performance and is conductive to strengthening of the high-temperature-resistant performance of the molded plastic, and the poly phenoxy resin is low in price, is conductive to reduction of production cost, can also improve the water resistance, leakage resistance and strength of the molded plastic and meanwhile is matched with the aluminum phosphate, the beryllium oxide, the magnesium molybdate, the basalt fiber and other ingredients so that the high-temperature-resistant performance of the material can be improved. The molded plastic produced by adopting the method is high in strength, good in high temperature resistance, excellent in leakage and water resistance and long in service life.

Description

A kind of high temperature resistant moulding compound and preparation method thereof
Technical field
The present invention relates to plastics arts, more specifically a kind of high temperature resistant moulding compound and preparation method thereof.
Background technology
, compared with common thermoplastic, moulding compound is with higher physical dimension stability, more resistant to extreme for moulding compound The features such as high heat and humidity complex environment, chemicals-resistant burn into high mechanical properties.Apply to space flight and aviation, naval ship and civilian The industry such as ship, firearms, electronics and electrical component, power equipment component.
The content of the invention
The invention aims to provide a kind of high temperature resistant moulding compound and preparation method thereof.
The purpose of the present invention is achieved through the following technical solutions:
A kind of high temperature resistant moulding compound, is made up of following raw material:Linear phenol-aldehyde resin 50-60, focus ratio 20-30, Discarded safety glass powder 3-5, nano barium carbonate 4-6, calcium hydroxide 3-5, carbon fiber 2-4, stearic acid 3-5, cyanuric acid triolefin Propyl ester 1-3, peroxidized t-butyl perbenzoate 2-4, aluminum phosphate 1-3, beryllium oxide 3-5, magnesium molybdate 1-3, basalt fibre 2-4, stone Oily sulfonic acid 3-5, cumyl peroxide 1-3, dicyanodiamine 1-2.
A kind of preparation method of high temperature resistant moulding compound, comprises the following steps:
(1)Each raw material is weighed by weight;
(2)By stearic acid, triallyl cyanurate, peroxidized t-butyl perbenzoate, magnesium molybdate, mahogany acid, peroxidating two Isopropylbenzene, dicyanodiamine are added equipped with linear phenol-aldehyde resin, in the stirred tank of focus ratio, are stirred to being uniformly dispersed;
(3)Nano barium carbonate, calcium hydroxide, aluminum phosphate, basalt fibre are added, is stirred with the speed strength of 500-600r/min Mix;
(4)Ultrasonic strength emulsification instrument is opened, adds beryllium oxide, Jing strong stirrings to obtain disperseing homogeneous pasty state raw material;
(5)It is barrier film with polyethylene film, the discarded safety glass powder of 25mm, carbon is impregnated on laminar film plastic units for sheet material fine Dimension, Jing after roll-in winding, thickening storage.
It is an advantage of the current invention that:
The moulding compound of the present invention adopts linear phenol-aldehyde resin, focus ratio for primary raw material, and phenolic resin has excellent resistance to High-temperature behavior, contributes to strengthening the heat-resisting quantity of moulding compound, and focus ratio is not only cheap, contributes to reduction and produces into This, moreover it is possible to strengthen resistance to water, leakage resistance and the intensity of moulding compound, while with aluminum phosphate, beryllium oxide, magnesium molybdate, basalt The compositions such as fiber are used cooperatively, and can improve the resistance to elevated temperatures of material.Moulding compound intensity that the present invention is produced is high, heat-resisting quantity Good, leakage resistance and excellent water resistance, long service life.
Specific embodiment
Embodiment 1, a kind of high temperature resistant moulding compound, by following weight portion(kg)Raw material is made:Linear phenol-aldehyde resin 50, poly- phenol Oxygen tree fat 20, discarded safety glass powder 3, nano barium carbonate 4, calcium hydroxide 3, carbon fiber 2, stearic acid 3, three allyl of cyanuric acid Ester 1, peroxidized t-butyl perbenzoate 2, aluminum phosphate 1, beryllium oxide 3, magnesium molybdate 1, basalt fibre 2, mahogany acid 3, peroxidating Diisopropylbenzene (DIPB) 1, dicyanodiamine 1.
A kind of preparation method of high temperature resistant moulding compound, comprises the following steps:
(1)Each raw material is weighed by weight;
(2)By stearic acid, triallyl cyanurate, peroxidized t-butyl perbenzoate, magnesium molybdate, mahogany acid, peroxidating two Isopropylbenzene, dicyanodiamine are added equipped with linear phenol-aldehyde resin, in the stirred tank of focus ratio, are stirred to being uniformly dispersed;
(3)Nano barium carbonate, calcium hydroxide, aluminum phosphate, basalt fibre are added, with the speed strong stirring of 500r/min;
(4)Ultrasonic strength emulsification instrument is opened, adds beryllium oxide, Jing strong stirrings to obtain disperseing homogeneous pasty state raw material;
(5)It is barrier film with polyethylene film, the discarded safety glass powder of 25mm, carbon fiber is impregnated on laminar film plastic units for sheet material Deng raw material, Jing after roll-in winding, thickening storage.
Embodiment 2, a kind of high temperature resistant moulding compound, by following weight portion(kg)Raw material is made:Linear phenol-aldehyde resin 55, poly- phenol Oxygen tree fat 25, discarded safety glass powder 4, nano barium carbonate 5, calcium hydroxide 4, carbon fiber 3, stearic acid 4, three allyl of cyanuric acid Ester 2, peroxidized t-butyl perbenzoate 3, aluminum phosphate 2, beryllium oxide 4, magnesium molybdate 2, basalt fibre 3, mahogany acid 4, peroxidating Diisopropylbenzene (DIPB) 2, dicyanodiamine 1.
A kind of preparation method of high temperature resistant moulding compound, comprises the following steps:
(1)Each raw material is weighed by weight;
(2)By stearic acid, triallyl cyanurate, peroxidized t-butyl perbenzoate, magnesium molybdate, mahogany acid, peroxidating two Isopropylbenzene, dicyanodiamine are added equipped with linear phenol-aldehyde resin, in the stirred tank of focus ratio, are stirred to being uniformly dispersed;
(3)Nano barium carbonate, calcium hydroxide, aluminum phosphate, basalt fibre are added, with the speed strong stirring of 550r/min;
(4)Ultrasonic strength emulsification instrument is opened, adds beryllium oxide, Jing strong stirrings to obtain disperseing homogeneous pasty state raw material;
(5)It is barrier film with polyethylene film, the discarded safety glass powder of 25mm, carbon fiber is impregnated on laminar film plastic units for sheet material Deng raw material, Jing after roll-in winding, thickening storage.
Embodiment 3, a kind of high temperature resistant moulding compound, by following weight portion(kg)Raw material is made:Linear phenol-aldehyde resin 60, poly- phenol Oxygen tree fat 30, discarded safety glass powder 5, nano barium carbonate 6, calcium hydroxide 5, carbon fiber 4, stearic acid 5, three allyl of cyanuric acid Ester 3, peroxidized t-butyl perbenzoate 4, aluminum phosphate 3, beryllium oxide 5, magnesium molybdate 3, basalt fibre 4, mahogany acid 5, peroxidating Diisopropylbenzene (DIPB) 3, dicyanodiamine 2.
A kind of preparation method of high temperature resistant moulding compound, comprises the following steps:
(1)Each raw material is weighed by weight;
(2)By stearic acid, triallyl cyanurate, peroxidized t-butyl perbenzoate, magnesium molybdate, mahogany acid, peroxidating two Isopropylbenzene, dicyanodiamine are added equipped with linear phenol-aldehyde resin, in the stirred tank of focus ratio, are stirred to being uniformly dispersed;
(3)Nano barium carbonate, calcium hydroxide, aluminum phosphate, basalt fibre are added, with the speed strong stirring of 600r/min;
(4)Ultrasonic strength emulsification instrument is opened, adds beryllium oxide, Jing strong stirrings to obtain disperseing homogeneous pasty state raw material;
(5)It is barrier film with polyethylene film, the discarded safety glass powder of 25mm, carbon fiber is impregnated on laminar film plastic units for sheet material Deng raw material, Jing after roll-in winding, thickening storage.
The main performance testing result of moulding compound obtained in above-described embodiment 1-3 is as shown in the table:
The main performance testing result of moulding compound obtained in 1 embodiment 1-3 of table
Embodiment 1 Embodiment 2 Embodiment 3
Bending strength(MPa) 85.6 88.4 89.1
Impact strength(MPa) 3.7 4.1 4.2
Mould shrinks(%) 0.51 0.46 0.53
After-contraction(%) 0.39 0.37 0.41
Apparent and coloring It is excellent It is excellent It is excellent
Maximum operating temperature(℃) 220 250 235

Claims (2)

1. a kind of high temperature resistant moulding compound, it is characterised in that:It is made up of following raw material:Linear phenol-aldehyde resin 50-60, poly- phenol Oxygen tree fat 20-30, discarded safety glass powder 3-5, nano barium carbonate 4-6, calcium hydroxide 3-5, carbon fiber 2-4, stearic acid 3-5, Triallyl cyanurate 1-3, peroxidized t-butyl perbenzoate 2-4, aluminum phosphate 1-3, beryllium oxide 3-5, magnesium molybdate 1-3, the Black Warrior Rock fiber 2-4, mahogany acid 3-5, cumyl peroxide 1-3, dicyanodiamine 1-2.
2. the preparation method of a kind of high temperature resistant moulding compound according to claim 1, it is characterised in that:Comprise the following steps:
(1)Each raw material is weighed by weight;
(2)By stearic acid, triallyl cyanurate, peroxidized t-butyl perbenzoate, magnesium molybdate, mahogany acid, peroxidating two Isopropylbenzene, dicyanodiamine are added equipped with linear phenol-aldehyde resin, in the stirred tank of focus ratio, are stirred to being uniformly dispersed;
(3)Nano barium carbonate, calcium hydroxide, aluminum phosphate, basalt fibre are added, is stirred with the speed strength of 500-600r/min Mix;
(4)Ultrasonic strength emulsification instrument is opened, adds beryllium oxide, Jing strong stirrings to obtain disperseing homogeneous pasty state raw material;
(5)It is barrier film with polyethylene film, the discarded safety glass powder of 25mm, carbon fiber is impregnated on laminar film plastic units for sheet material Deng raw material, Jing after roll-in winding, thickening storage.
CN201610990486.7A 2016-11-10 2016-11-10 A kind of high temperature resistant moulding compound and preparation method thereof Active CN106519557B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112280206A (en) * 2019-07-25 2021-01-29 张炜 High-temperature-resistant fireproof plastic and preparation method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101585963A (en) * 2009-06-10 2009-11-25 惠州市沃特新材料有限公司 Colorful conductive high temperature resistance molding compound and prepartion method thereof
CN101665613A (en) * 2009-09-24 2010-03-10 上海欧亚合成材料有限公司 High-temperature baking resistant phenolic molding compound and preparation method thereof
CN103183908A (en) * 2011-12-27 2013-07-03 常熟市亚美模特儿衣架有限公司 High-temperature-resistant phenolic moulding compound
CN103183907A (en) * 2011-12-27 2013-07-03 常熟市亚美模特儿衣架有限公司 High-temperature-resistant phenolic glass fibre reinforced plastic material
CN105017653A (en) * 2015-08-19 2015-11-04 苏州凯欧曼新材料科技有限公司 Impact resistant engineering plastic for electrical equipment and preparation method thereof
CN105924895A (en) * 2016-06-30 2016-09-07 禹州市远大塑料电器有限责任公司 High-temperature-resistant phenolic moulding plastic

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101585963A (en) * 2009-06-10 2009-11-25 惠州市沃特新材料有限公司 Colorful conductive high temperature resistance molding compound and prepartion method thereof
CN101665613A (en) * 2009-09-24 2010-03-10 上海欧亚合成材料有限公司 High-temperature baking resistant phenolic molding compound and preparation method thereof
CN103183908A (en) * 2011-12-27 2013-07-03 常熟市亚美模特儿衣架有限公司 High-temperature-resistant phenolic moulding compound
CN103183907A (en) * 2011-12-27 2013-07-03 常熟市亚美模特儿衣架有限公司 High-temperature-resistant phenolic glass fibre reinforced plastic material
CN105017653A (en) * 2015-08-19 2015-11-04 苏州凯欧曼新材料科技有限公司 Impact resistant engineering plastic for electrical equipment and preparation method thereof
CN105924895A (en) * 2016-06-30 2016-09-07 禹州市远大塑料电器有限责任公司 High-temperature-resistant phenolic moulding plastic

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112280206A (en) * 2019-07-25 2021-01-29 张炜 High-temperature-resistant fireproof plastic and preparation method thereof

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Effective date of registration: 20191128

Address after: 313300 baishuiwan Industrial Park, Tianhuangping Town, Anji County, Huzhou City, Zhejiang Province

Patentee after: Anji Wanhang Furniture Co., Ltd.

Address before: 325200 Wenzhou City, Ruian, Anyang Street Qing Qing District, building 1, room 7, unit 601, room

Patentee before: Ye Chenxi

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Denomination of invention: The invention relates to a high temperature resistant molding compound and a preparation method thereof

Effective date of registration: 20210721

Granted publication date: 20180925

Pledgee: Zhejiang Anji Rural Commercial Bank Co.,Ltd. baishuiwan sub branch

Pledgor: ANJI WANHANG FURNITURE Co.,Ltd.

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