CN106519523A - Automobile high-cold-resistance acrylate adhesive and preparation method and application thereof - Google Patents
Automobile high-cold-resistance acrylate adhesive and preparation method and application thereof Download PDFInfo
- Publication number
- CN106519523A CN106519523A CN201611016298.0A CN201611016298A CN106519523A CN 106519523 A CN106519523 A CN 106519523A CN 201611016298 A CN201611016298 A CN 201611016298A CN 106519523 A CN106519523 A CN 106519523A
- Authority
- CN
- China
- Prior art keywords
- parts
- rubber
- automobile
- cold
- sizing material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/18—Applications used for pipes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses an automobile high-cold-resistance acrylate adhesive and a preparation method and application thereof. The acrylate adhesive is composed of the following raw materials including, by weight, 80-88 parts of acrylic ester rubber, 10-16 parts of nitrile butadiene rubber, 2-4 parts of silicone rubber, 18-22 parts of graphene,1.5-1.9 parts of stearic acid, 1.1-1.5 parts of plasticizer TOTM, 1.6-2.1 parts of octyl silane bonded silica gel, 14-17 parts of ultrafine silica powder, 1.0-1.5 pars of anti-aging agents 445, 1.8-2.4 parts of anti-aging agents RDA, 6.5-7.3 parts of N,N'-dicinnamylidene-1,6-hexanediamine, 2.2-2.6 parts of accelerators BG and 0.7-1.0 part of accelerator ZDC. According to the automobile high-cold-resistance acrylate adhesive and the preparation method and application thereof, the nitrile butadiene rubber, the silicone rubber and the acrylic ester rubber are adopted for compound usage, and the requirements for oil resistance, heat resistance, cold resistance and aging resistance of automobile oil return pipes are met.
Description
Technical field
The present invention relates to new material technology field, specifically a kind of automobile high cold-resistant acrylate sizing material and its preparation side
Method and application.
Background technology
The effect of automobile oil return pipe is to make unnecessary oil return to fuel tank, can play the pressure for mediating gasoline, can also subtract
Few oil consumption；In fuel oil oil pump feed to electromotor, after forming certain pressure except normal supply fuel nozzle oil spout, remaining fuel oil
Fuel tank is sent back to by return line, also has certainly the unnecessary gasoline vapor that canister is collected fuel tank to be returned to also by oil return pipe.
Therefore, when selecting the material of automobile oil return pipe, it is necessary to be provided simultaneously with excellent oil resistivity and heat-resisting quantity, in addition, also need
Possess certain lower temperature resistance, resistance to ag(e)ing.
Acrylate rubber (hereinafter referred to as ACM) be with acrylate as main monomer Jing copolymerization obtained by elastomer, its master
Chain is saturated carbon chains, and side base is polar ester groups.Due to special construction give its it is many excellent the characteristics of, such as：Heat-resisting, ageing-resistant,
Oil resistant, resistance to ozone, uvioresistant etc., mechanical property and processing characteristics are better than fluorubber and silicone rubber, its heat-resisting, resistance to ag(e)ing and
Oil resistivity is better than nitrile rubber.ACM is widely used in various high temperature, resistance to oil environment, becomes auto industry in recent years and focuses on
A kind of encapsulant that exploitation is promoted, particularly for the high temperature resistant oil sealing of automobile, bent axle, valve rod, cylinder liner, hydraulic oil pipeline
Deng.However, acrylate rubber also has the disadvantages that：Lower temperature resistance is poor, mechanical performance is poor, moisture resistivity, chemical-resistant resistance
Property is poor.Its poor lower temperature resistance, certainly will limit which in terms of higher automobile oil return pipe is required to temperature tolerance, oil resistivity
Using.
The content of the invention
It is an object of the invention to provide a kind of automobile suitable for automobile oil return pipe with high cold-resistant acrylate sizing material and
Its preparation method and application.
For achieving the above object, the present invention provides following technical scheme：
A kind of automobile in parts by weight, is made up of following raw material with high cold-resistant acrylate sizing material：Acrylate rubber
80～88 parts, 10～16 parts of nitrile rubber, 2～4 parts of silicone rubber, 18～22 parts of Graphene, 1.5～1.9 parts of stearic acid, plasticizer
1.1～1.5 parts of TOTM, 1.6～2.1 parts of octyl silane group silica gel, 14～17 parts of ultrafine silica powder, age resistor 445 1.0
～1.5 parts, 1.8～2.4 parts of anti-aging agent RD A, N, 6.5～7.3 parts of N'- bis- (cinnamylidene -1,6- hexamethylene diamines), accelerant B G
2.2～2.6 parts, 0.7～1.0 part of accelerator ZDC.
As further scheme of the invention：In parts by weight, it is made up of following raw material：Acrylate rubber 84～86
Part, 12～14 parts of nitrile rubber, 2～3 parts of silicone rubber, 19～21 parts of Graphene, 1.7～1.9 parts of stearic acid, plasticizer TOTM
1.2～1.4 parts, 1.8～2.0 parts of octyl silane group silica gel, 15～16 parts of ultrafine silica powder, age resistor 445 1.2～1.3
Part, 2.0～2.2 parts of anti-aging agent RD A, N, 6.7～7.0 parts of N'- bis- (cinnamylidene -1,6- hexamethylene diamines), accelerant B G 2.3～
2.5 parts, 0.8～0.9 part of accelerator ZDC.
As further scheme of the invention：In parts by weight, it is made up of following raw material：85 parts of acrylate rubber,
13 parts of nitrile rubber, 2.5 parts of silicone rubber, 20 parts of Graphene, 1.8 parts of stearic acid, 1.3 parts of plasticizer TOTM, octane base silane key
Close 1.9 parts of silica gel, 15 parts of ultrafine silica powder, 445 1.2 parts of age resistor, 2.1 parts of anti-aging agent RD A, N, N'- bis- (cinnamylidene-
1,6- hexamethylene diamines) 6.8 parts, 2.4 parts of accelerant B G, 0.85 part of accelerator ZDC.
The described automobile preparation method of high cold-resistant acrylate sizing material, comprises the following steps：
(1) Graphene, octyl silane group silica gel, ultrafine silica powder are preheated to into 150～158 DEG C, by stearic acid, are increased
Modeling agent TOTM, age resistor 445, anti-aging agent RD A are preheated to 155～162 DEG C, standby；
(2) in proportion by acrylate rubber, nitrile rubber, silicone rubber mixing, it is 450～500W, micro- in microwave power
Wave frequency obtains first compound to carry out 2～3min of microwave heating under conditions of 6～8GHz；
(3) then in proportion the raw material of preheating in step (1) is poured in the first compound of step (2), is kneaded,
Obtain elastomeric compound；
(4) N, N'- bis- (cinnamylidene -1,6- hexamethylene diamines), accelerator are added in proportion toward the elastomeric compound of step (3)
BG, accelerator ZDC, temperature be 158～165 DEG C, pressure be 18～20MPa under conditions of carry out 3～5min of sulfuration, it is naturally cold
But, described automobile is obtained with high cold-resistant acrylate sizing material.
Application of the described automobile with high cold-resistant acrylate sizing material in terms of automobile oil return pipe is prepared.
Compared with prior art, the invention has the beneficial effects as follows：The present invention selects nitrile rubber, silicone rubber and acrylate
Rubber compounding use, using octyl silane group silica gel and the mixed filler of ultrafine silica powder, using age resistor 445
With the mixture of anti-aging agent RD A as age resistor, in the base for not changing the heat-resisting of acrylate rubber, oil resistant, ageing-resistant performance
On plinth, its low temperature cold tolerance is improved.Compared with traditional acrylate rubber, tolerance to cold is significantly improved,
Brittleness temperature may be up to -59 DEG C without fracture and oil resistant, and ageing-resistant performance is still good, compensate for acrylate rubber in use
Deficiency, and the performance such as the oil resistant of rubber, oil resistant, ageing-resistant substantially do not change, and meets automobile oil return pipe oil resistant, resistance to
The requirement of hot, cold-resistant, ageing-resistant performance.
Specific embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described,
Obviously, described embodiment is only a part of embodiment of the invention, rather than the embodiment of whole.Based in the present invention
Embodiment, the every other embodiment obtained under the premise of creative work is not made by those of ordinary skill in the art, all
Belong to the scope of protection of the invention.
Embodiment 1
In the embodiment of the present invention, a kind of automobile cold-resistant acrylate sizing material of height, in parts by weight, by following raw material group
Into：80 parts of acrylate rubber, 16 parts of nitrile rubber, 2 parts of silicone rubber, 22 parts of Graphene, 1.5 parts of stearic acid, plasticizer TOTM
1.5 parts, 1.6 parts of octyl silane group silica gel, 17 parts of ultrafine silica powder, 445 1.0 parts of age resistor, 2.4 parts of anti-aging agent RD A,
6.5 parts of N, N'- bis- (cinnamylidene -1,6- hexamethylene diamines), 2.6 parts of accelerant B G, 0.7 part of accelerator ZDC.
The described automobile preparation method of high cold-resistant acrylate sizing material, comprises the following steps：
(1) Graphene, octyl silane group silica gel, ultrafine silica powder are preheated to into 150 DEG C, by stearic acid, plasticizer
TOTM, age resistor 445, anti-aging agent RD A are preheated to 155 DEG C, standby；
(2) in proportion by acrylate rubber, nitrile rubber, silicone rubber mixing, it is 450W, microwave frequency in microwave power
For microwave heating 3min is carried out under conditions of 6GHz, first compound is obtained；
(3) then in proportion the raw material of preheating in step (1) is poured in the first compound of step (2), is kneaded,
Obtain elastomeric compound；
(4) N, N'- bis- (cinnamylidene -1,6- hexamethylene diamines), accelerator are added in proportion toward the elastomeric compound of step (3)
BG, accelerator ZDC, temperature be 158 DEG C, pressure be 18MPa under conditions of carry out sulfuration 5min, natural cooling is obtained described
Automobile with high cold-resistant acrylate sizing material.
Embodiment 2
In the embodiment of the present invention, a kind of automobile cold-resistant acrylate sizing material of height, in parts by weight, by following raw material group
Into：88 parts of acrylate rubber, 10 parts of nitrile rubber, 4 parts of silicone rubber, 18 parts of Graphene, 1.9 parts of stearic acid, plasticizer TOTM
1.1 parts, 2.1 parts of octyl silane group silica gel, 14 parts of ultrafine silica powder, 445 1.5 parts of age resistor, 1.8 parts of anti-aging agent RD A,
7.3 parts of N, N'- bis- (cinnamylidene -1,6- hexamethylene diamines), 2.2 parts of accelerant B G, 1.0 parts of accelerator ZDC.
The described automobile preparation method of high cold-resistant acrylate sizing material, comprises the following steps：
(1) Graphene, octyl silane group silica gel, ultrafine silica powder are preheated to into 158 DEG C, by stearic acid, plasticizer
TOTM, age resistor 445, anti-aging agent RD A are preheated to 155 DEG C, standby；
(2) in proportion by acrylate rubber, nitrile rubber, silicone rubber mixing, it is 500W, microwave frequency in microwave power
For microwave heating 2min is carried out under conditions of 8GHz, first compound is obtained；
(3) then in proportion the raw material of preheating in step (1) is poured in the first compound of step (2), is kneaded,
Obtain elastomeric compound；
(4) N, N'- bis- (cinnamylidene -1,6- hexamethylene diamines), accelerator are added in proportion toward the elastomeric compound of step (3)
BG, accelerator ZDC, temperature be 165 DEG C, pressure be 20MPa under conditions of carry out sulfuration 3min, natural cooling is obtained described
Automobile with high cold-resistant acrylate sizing material.
Embodiment 3
In the embodiment of the present invention, a kind of automobile cold-resistant acrylate sizing material of height, in parts by weight, by following raw material group
Into：84 parts of acrylate rubber, 14 parts of nitrile rubber, 2 parts of silicone rubber, 21 parts of Graphene, 1.7 parts of stearic acid, plasticizer TOTM
1.4 parts, 1.8 parts of octyl silane group silica gel, 16 parts of ultrafine silica powder, 445 1.2 parts of age resistor, 2.2 parts of anti-aging agent RD A,
6.7 parts of N, N'- bis- (cinnamylidene -1,6- hexamethylene diamines), 2.5 parts of accelerant B G, 0.8 part of accelerator ZDC.
Preparation method of the described automobile with high cold-resistant acrylate sizing material, it is same as Example 1.
Embodiment 4
In the embodiment of the present invention, a kind of automobile cold-resistant acrylate sizing material of height, in parts by weight, by following raw material group
Into：86 parts of acrylate rubber, 12 parts of nitrile rubber, 3 parts of silicone rubber, 19 parts of Graphene, 1.9 parts of stearic acid, plasticizer TOTM
1.2 parts, 2.0 parts of octyl silane group silica gel, 15 parts of ultrafine silica powder, 445 1.3 parts of age resistor, 2.0 parts of anti-aging agent RD A,
7.0 parts of N, N'- bis- (cinnamylidene -1,6- hexamethylene diamines), 2.3 parts of accelerant B G, 0.9 part of accelerator ZDC.
Preparation method of the described automobile with high cold-resistant acrylate sizing material, it is same as Example 2.
Embodiment 5
In the embodiment of the present invention, a kind of automobile cold-resistant acrylate sizing material of height, in parts by weight, by following raw material group
Into：85 parts of acrylate rubber, 13 parts of nitrile rubber, 2.5 parts of silicone rubber, 20 parts of Graphene, 1.8 parts of stearic acid, plasticizer
1.3 parts of TOTM, 1.9 parts of octyl silane group silica gel, 15 parts of ultrafine silica powder, 445 1.2 parts of age resistor, anti-aging agent RD A
2.1 parts, N, 6.8 parts of N'- bis- (cinnamylidene -1,6- hexamethylene diamines), 2.4 parts of accelerant B G, accelerator ZDC0.85 parts.
The described automobile preparation method of high cold-resistant acrylate sizing material, comprises the following steps：
(1) Graphene, octyl silane group silica gel, ultrafine silica powder are preheated to into 155 DEG C, by stearic acid, plasticizer
TOTM, age resistor 445, anti-aging agent RD A are preheated to 158 DEG C, standby；
(2) in proportion by acrylate rubber, nitrile rubber, silicone rubber mixing, it is 480W, microwave frequency in microwave power
For microwave heating 2.5min is carried out under conditions of 7GHz, first compound is obtained；
(3) then in proportion the raw material of preheating in step (1) is poured in the first compound of step (2), is kneaded,
Obtain elastomeric compound；
(4) N, N'- bis- (cinnamylidene -1,6- hexamethylene diamines), accelerator are added in proportion toward the elastomeric compound of step (3)
BG, accelerator ZDC, temperature be 162 DEG C, pressure be 19MPa under conditions of carry out sulfuration 4min, natural cooling is obtained described
Automobile with high cold-resistant acrylate sizing material.
Comparative example 1
On the basis of the formula of embodiment 5, octyl silane group silica gel is replaced with into ultrafine silica powder, remaining and enforcement
Example 5 is identical.
Comparative example 2
On the basis of the formula of embodiment 5, age resistor ZDC is replaced with into age resistor BG, remaining and 5 complete phase of embodiment
Together.
Comparative example 3
On the basis of the formula of embodiment 5, nitrile rubber is replaced with into silicone rubber, remaining is identical with embodiment 5.
Comparative example 4
On the basis of the formula of embodiment 5, silicone rubber is replaced with into nitrile rubber, remaining is identical with embodiment 5.
Test the mechanical performance of sizing material obtained in each example, thermostability, tolerance to cold, resistance to machine oil, oil resistant (IRM 903) property and
Ozone resistance.Test result is as shown in table 1～4.
The mechanical performance of sizing material obtained in 1 each example of table
The thermostability and tolerance to cold of sizing material obtained in 2 each example of table
The resistance to machine oil of sizing material obtained in 3 each example of table
The oil resistivity and ozone resistance of sizing material obtained in 4 each example of table
From table 1～4：Compared with matched group, sizing material obtained in embodiment 1～5 has preferable mechanical performance, heat-resisting
Property, tolerance to cold, resistance to machine oil, oil resistivity and ozone resistance；Wherein table 1 illustrates the present invention from nitrile rubber, silicone rubber and third
Olefin(e) acid ester rubber compounding use, and using octyl silane group silica gel and the mixed filler of ultrafine silica powder so that
Sizing material has preferable mechanical performance, and table 2, table 3 and table 4 illustrate the present invention from nitrile rubber, silicone rubber and acrylate rubber
Glue compounding use, with preferable thermostability, tolerance to cold and oil resistivity, additionally, can show that the present invention adopts age resistor by table 4
445 with the mixture of anti-aging agent RD A as age resistor, with preferable ozone resistance.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, Er Qie
In the case of spirit or essential attributes without departing substantially from the present invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, embodiment all should be regarded as exemplary, and be nonrestrictive, the scope of the present invention is by appended power
Profit is required rather than described above is limited, it is intended that all in the implication and scope of the equivalency of claim by falling
Change is included in the present invention.
Moreover, it will be appreciated that although this specification is been described by according to embodiment, not each embodiment is only wrapped
Containing an independent technical scheme, this narrating mode of description is only that those skilled in the art should for clarity
Using description as an entirety, the technical scheme in each embodiment can also Jing it is appropriately combined, form those skilled in the art
Understandable other embodiment.
Claims (5)
1. a kind of automobile is with high cold-resistant acrylate sizing material, it is characterised in that in parts by weight, be made up of following raw material：Third
80～88 parts of olefin(e) acid ester rubber, 10～16 parts of nitrile rubber, 2～4 parts of silicone rubber, 18～22 parts of Graphene, stearic acid 1.5～
1.9 parts, 1.1～1.5 parts of plasticizer TOTM, 1.6～2.1 parts of octyl silane group silica gel, 14～17 parts of ultrafine silica powder,
445 1.0～1.5 parts of age resistor, 1.8～2.4 parts of anti-aging agent RD A, N, N'- bis- (cinnamylidene -1,6- hexamethylene diamines) 6.5～
7.3 parts, 2.2～2.6 parts of accelerant B G, 0.7～1.0 part of accelerator ZDC.
2. automobile according to claim 1 is with high cold-resistant acrylate sizing material, it is characterised in that in parts by weight, by
Following raw material composition：84～86 parts of acrylate rubber, 12～14 parts of nitrile rubber, 2～3 parts of silicone rubber, Graphene 19～21
Part, 1.7～1.9 parts of stearic acid, 1.2～1.4 parts of plasticizer TOTM, 1.8～2.0 parts of octyl silane group silica gel, silicon oxide
15～16 parts of micropowder, 445 1.2～1.3 parts of age resistor, 2.0～2.2 parts of anti-aging agent RD A, N, bis- (cinnamylidene -1,6- of N'-
Hexamethylene diamine) 6.7～7.0 parts, 2.3～2.5 parts of accelerant B G, 0.8～0.9 part of accelerator ZDC.
3. automobile according to claim 2 is with high cold-resistant acrylate sizing material, it is characterised in that in parts by weight, by
Following raw material composition：85 parts of acrylate rubber, 13 parts of nitrile rubber, 2.5 parts of silicone rubber, 20 parts of Graphene, stearic acid 1.8
It is part, 1.3 parts of plasticizer TOTM, 1.9 parts of octyl silane group silica gel, 15 parts of ultrafine silica powder, 445 1.2 parts of age resistor, anti-
2.1 parts of old agent RDA, N, 6.8 parts of N'- bis- (cinnamylidene -1,6- hexamethylene diamines), 2.4 parts of accelerant B G, accelerator ZDC 0.85
Part.
4. used the preparation method of high cold-resistant acrylate sizing material, its feature to exist according to the arbitrary described automobile of claims 1 to 3
In comprising the following steps：
(1) Graphene, octyl silane group silica gel, ultrafine silica powder are preheated to into 150～158 DEG C, by stearic acid, plasticizer
TOTM, age resistor 445, anti-aging agent RD A are preheated to 155～162 DEG C, standby；
(2) in proportion by acrylate rubber, nitrile rubber, silicone rubber mixing, it is 450～500W, Microwave Frequency in microwave power
Rate obtains first compound to carry out 2～3min of microwave heating under conditions of 6～8GHz；
(3) then in proportion the raw material of preheating in step (1) is poured in the first compound of step (2), is kneaded, obtained
Elastomeric compound；
(4) add N in proportion toward the elastomeric compound of step (3), N'- bis- (cinnamylidene -1,6- hexamethylene diamines), accelerant B G, promote
Enter agent ZDC, temperature be 158～165 DEG C, pressure be 18～20MPa under conditions of carry out 3～5min of sulfuration, natural cooling, system
Described automobile is obtained with high cold-resistant acrylate sizing material.
5. the high cold-resistant acrylate sizing material of the automobile according to claims 1 to 3 is arbitrary is in terms of automobile oil return pipe is prepared
Application.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611016298.0A CN106519523A (en) | 2016-11-18 | 2016-11-18 | Automobile high-cold-resistance acrylate adhesive and preparation method and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611016298.0A CN106519523A (en) | 2016-11-18 | 2016-11-18 | Automobile high-cold-resistance acrylate adhesive and preparation method and application thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106519523A true CN106519523A (en) | 2017-03-22 |
Family
ID=58352679
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611016298.0A Pending CN106519523A (en) | 2016-11-18 | 2016-11-18 | Automobile high-cold-resistance acrylate adhesive and preparation method and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106519523A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109161140A (en) * | 2018-07-10 | 2019-01-08 | 刘勇 | A kind of heat-resisting cold-resistant acrylic rubber material |
| CN113789076A (en) * | 2021-09-07 | 2021-12-14 | 中国人民解放军陆军装甲兵学院 | Graphene oxide slurry and preparation method and application thereof |
| CN115746420A (en) * | 2022-12-01 | 2023-03-07 | 枣庄市天一实业有限公司 | High-wear-resistance hydraulic rubber pipe and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102977532A (en) * | 2012-11-27 | 2013-03-20 | 天津鹏翎胶管股份有限公司 | Acrylate rubber composition |
| CN105400015A (en) * | 2015-12-08 | 2016-03-16 | 黄涌芮 | High temperature resistance rubber and preparation method thereof |
-
2016
- 2016-11-18 CN CN201611016298.0A patent/CN106519523A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102977532A (en) * | 2012-11-27 | 2013-03-20 | 天津鹏翎胶管股份有限公司 | Acrylate rubber composition |
| CN105400015A (en) * | 2015-12-08 | 2016-03-16 | 黄涌芮 | High temperature resistance rubber and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 翁国文 等: "《橡胶技术问答》", 31 July 2010, 化学工业出版社 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109161140A (en) * | 2018-07-10 | 2019-01-08 | 刘勇 | A kind of heat-resisting cold-resistant acrylic rubber material |
| CN113789076A (en) * | 2021-09-07 | 2021-12-14 | 中国人民解放军陆军装甲兵学院 | Graphene oxide slurry and preparation method and application thereof |
| CN113789076B (en) * | 2021-09-07 | 2022-04-29 | 中国人民解放军陆军装甲兵学院 | Graphene oxide slurry and preparation method and application thereof |
| CN115746420A (en) * | 2022-12-01 | 2023-03-07 | 枣庄市天一实业有限公司 | High-wear-resistance hydraulic rubber pipe and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106519523A (en) | Automobile high-cold-resistance acrylate adhesive and preparation method and application thereof | |
| CN102585514B (en) | Resistance oil silicone rubber | |
| CN101168620B (en) | Heat-conducting anti-flaming liquid silicon rubber and preparation method thereof | |
| CN103772859B (en) | Fluororubber compounded rubber of a kind of modification and preparation method thereof | |
| CN101982491B (en) | Heat-resistant ethylene propylene diene monomer filled with mineral reinforcing agent | |
| CN106117823A (en) | A kind of high temperature resistant oil resistant and the EPT rubber composition of low abnormal smells from the patient | |
| CN104086830B (en) | A kind of high-strength cold and oil resistant rubber material | |
| CN106674634A (en) | High cold-resistant acrylate adhesive, preparation method thereof and application | |
| CN106117651A (en) | Oil resistant, wear-resisting dual density footwear rubber sole and preparation method thereof | |
| CN107446195A (en) | A kind of oil hose NBR elastomeric compounds and preparation method thereof | |
| CN103804827A (en) | Formula of inner glue for automotive fuel oil rubber pipe | |
| CN101402798B (en) | Heat conduction flame-proof liquid silicon rubber for electron and method of producing the same | |
| CN104788964A (en) | Preparation process for silicone rubber cable sheath used for ship | |
| CN106674846A (en) | High-cold-resistance acrylate rubber material for automobiles, and preparation method and application thereof | |
| CN105622943A (en) | Synthesis method of high molecular weight polysiloxane containing nitrile group and vinyl at the same time and preparation method of addition type heat vulcanized nitrile silicone rubber | |
| CN108250643A (en) | A kind of automobile height resists cold acrylate sizing material | |
| JP7169191B2 (en) | acrylic rubber composition | |
| CN103709472A (en) | High temperature resistant and aging resistant chloroprene rubber composition | |
| CN106519524A (en) | High cold-resistant acrylate rubber material and preparation method and application thereof | |
| CN105778105A (en) | Synthesis of siloxane containing nitrile group and vinyl group at same time and preparation method of room-temperature addition type nitrile silicone rubber | |
| CN106751298A (en) | A kind of method prepared by automobile high-strength acrylate sizing material | |
| CN103724891A (en) | Fluororubber composition with high tearing property for turbocharging pipe | |
| CN105504416B (en) | A kind of high temperature resistant oil resistant neoprene preparation raw material | |
| CN106751294A (en) | A kind of high strength acrylic acid esters sizing material and preparation method and application | |
| CN109517235A (en) | A kind of effective NBR rubber compound of engine charge and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20170322 |
|
| WD01 | Invention patent application deemed withdrawn after publication |