CN106519341A - Automobile clean air pipe rubber product formula - Google Patents

Automobile clean air pipe rubber product formula Download PDF

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Publication number
CN106519341A
CN106519341A CN201610756800.5A CN201610756800A CN106519341A CN 106519341 A CN106519341 A CN 106519341A CN 201610756800 A CN201610756800 A CN 201610756800A CN 106519341 A CN106519341 A CN 106519341A
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CN
China
Prior art keywords
parts
account
rubber
accounts
virgin rubber
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610756800.5A
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Chinese (zh)
Inventor
麻学刚
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Aboveground Rubber And Plastic Co Ltd In Suzhou
Original Assignee
Aboveground Rubber And Plastic Co Ltd In Suzhou
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Aboveground Rubber And Plastic Co Ltd In Suzhou filed Critical Aboveground Rubber And Plastic Co Ltd In Suzhou
Priority to CN201610756800.5A priority Critical patent/CN106519341A/en
Publication of CN106519341A publication Critical patent/CN106519341A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/02Copolymers with acrylonitrile
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/18Applications used for pipes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Tires In General (AREA)

Abstract

The invention discloses an automobile clean air pipe rubber product formula. The formula includes: virgin rubber 1203W, virgin rubber DN2850, virgin rubber DN101L, carbon black N550, MC, a plasticizer W-260, aluminum hydroxide L-40, stearic acid, an anti-aging agent 6PPD, an anti-aging agent 224, an accelerator CBS-80, an accelerator TT-75E, an accelerator TETD-75F and a curing agent S-80. By the way, the automobile clean air pipe rubber product formula provided by the invention can make the product acquire +/-25 hardness change properties under a room temperature 15min fuel oil placement condition and acquire the performance of a maximum hardness variation of 15 under a 23DEG C 48h fuel oil placement condition with no harmful substance. The product can fully meet the requirements of environmental protection, and has broad market prospects.

Description

A kind of automobile cleaned air pipe rubber formula
Technical field
A kind of the present invention relates to rubber materials, more particularly to automobile cleaned air pipe rubber formula.
Background technology
The just growing big important component part become in auto industry of automobile rubber pipe industry.With Chinese vapour work The continuous development of industry, automobile rubber pipe industry must also be constantly brought forth new ideas, and actively using new material, new technology, new equipment, not turn off The rubber seal product for sending out new is meeting the demand of different user.
The content of the invention
The invention mainly solves the technical problem of providing a kind of automobile cleaned air pipe rubber formula, product is made to exist Room temperature 15min fuel oil obtains ± 25 firmness change performance under the conditions of placing, and obtains under the conditions of 23 DEG C of 48h fuel oils are placed The performance of highest hardness variable quantity 15 and there is no harmful substance, can fully meet environmental requirement, with extensive market prospects.
For solving above-mentioned technical problem, one aspect of the present invention is:A kind of automobile cleaned air pipe is provided Rubber is filled a prescription, including:Virgin rubber 1203W, virgin rubber DN2850, virgin rubber DN101L, carbon black N550, MC, plasticizer W-260, hydrogen Aluminum oxide L-40, stearic acid, age resistor 6PPD, age resistor 224, accelerator CBS -80, accelerator TT-75E, acceterator TE TD- 75F and vulcanizing agent S-80, the automobile cleaned air pipe rubber formula are calculated according to mass percent, including following weight Part:Virgin rubber 1203W accounts for 40-60 parts, virgin rubber DN2850 and accounts for 0-40 parts, virgin rubber DN101L and account for 0-60 parts, carbon black N550 and accounts for 40 parts, MC Account for 30 parts, plasticizer W-260 account for 10-12 parts, aluminium hydroxide L-40 account for 5 parts, stearic acid account for 1 part, age resistor 6PPD account for 2 parts, it is anti- Old agent 224 account for 2 parts, accelerator CBS -80 account for 1.88 parts, accelerator TT-75E account for 0.93 part, acceterator TE TD-75F account for 1.31 parts 0.63 part is accounted for vulcanizing agent S-80.
In a preferred embodiment of the present invention, the automobile cleaned air pipe rubber is filled a prescription according to mass percent Calculate, including following weight portion:Virgin rubber 1203W account for 60 parts, virgin rubber DN2850 account for 40 parts, carbon black N550 account for 40 parts, MC account for 30 parts, Plasticizer W-260 account for 12 parts, aluminium hydroxide L-40 account for 5 parts, stearic acid account for 1 part, age resistor 6PPD account for 2 parts, age resistor 224 account for 2 Part, accelerator CBS -80 account for 1.88 parts, accelerator TT-75E account for 0.93 part, acceterator TE TD-75F account for 1.31 parts and vulcanizing agent S- 80 account for 0.63 part.
The invention has the beneficial effects as follows:A kind of automobile cleaned air pipe rubber formula that the present invention is provided, makes product ± 25 firmness change performance is obtained under the conditions of room temperature 15min fuel oil is placed, and is obtained under the conditions of 23 DEG C of 48h fuel oils are placed Obtain the performance of highest hardness variable quantity 15 and there is no harmful substance, can fully meet environmental requirement, before extensive market Scape.
Specific embodiment
Technical scheme in the embodiment of the present invention will be clearly and completely described below, it is clear that described enforcement Example is only a part of embodiment of the present invention, rather than the embodiment of whole.Based on the embodiment in the present invention, this area is common All other embodiment that technical staff is obtained under the premise of creative work is not made, belongs to the model of present invention protection Enclose.
The embodiment of the present invention includes:
A kind of automobile cleaned air pipe rubber formula, including:Virgin rubber 1203W, virgin rubber DN2850, virgin rubber DN101L, carbon black N550, MC, plasticizer W-260, aluminium hydroxide L-40, stearic acid, age resistor 6PPD, age resistor 224, accelerator CBS -80, rush Enter agent TT-75E, acceterator TE TD-75F and vulcanizing agent S-80, the automobile cleaned air pipe rubber is filled a prescription according to quality Percentage is calculated, including following weight portion:Virgin rubber 1203W accounts for 40-60 parts, virgin rubber DN2850 and accounts for 0-40 parts, virgin rubber DN101L and accounts for 0-60 parts, carbon black N550 account for 40 parts, MC accounts for 30 parts, plasticizer W-260 accounts for 10-12 parts, aluminium hydroxide L-40 and account for 5 parts, stearic acid Account for 1 part, age resistor 6PPD account for 2 parts, age resistor 224 account for 2 parts, accelerator CBS -80 account for 1.88 parts, accelerator TT-75E account for 0.93 Part, acceterator TE TD-75F account for 1.31 parts and vulcanizing agent S-80 and account for 0.63 part.
Wherein, the hardness range of product is 70 ± 5, and more than tensile strength 10MPA, elongation is more than 250%.
Wherein, under conditions of using 125 DEG C of temperature, after product 168h, firmness change is less than+25, and tensile strength change is little In 25, elongation change is less than 30%.
Wherein, under conditions of using 100 DEG C of temperature, after product 24h, Compression Set is less than 50.
Wherein, after under room temperature condition, fuel oil places 15min, firmness change scope is ± 25;Under the conditions of 23 DEG C, fuel oil is placed Hardness change maximum 15 after 48h.
Wherein, raw material MSDS unharmful substances addition.
Specific embodiment one:
The automobile cleaned air pipe rubber formula is calculated according to mass percent, including following weight portion:Virgin rubber 1203W Account for 60 parts, virgin rubber DN2850 account for 40 parts, carbon black N550 account for 40 parts, MC account for 30 parts, plasticizer W-260 account for 12 parts, aluminium hydroxide L- 40 account for 5 parts, stearic acid account for 1 part, age resistor 6PPD account for 2 parts, age resistor 224 account for 2 parts, accelerator CBS -80 account for 1.88 parts, promote Agent TT-75E accounts for 0.93 part, acceterator TE TD-75F accounts for 1.31 parts and vulcanizing agent S-80 and account for 0.63 part.
Wherein, the hardness change of product is by virgin rubber 1203W, virgin rubber DN2850, virgin rubber DN101L and plasticizer W- What 260 consumption was adjusted.In experimentation, in order to realize goal of the invention, by adjusting above-mentioned material number, phase is determined The hardness change of product under experiment condition is answered, so that it is determined that meeting the product formula of goal of the invention.
According to above-mentioned rubber compounding, experiment detection is carried out, obtain virgin rubber 1203W, virgin rubber DN2850, virgin rubber DN101L and increasing Agent W-260 is to elastomeric material performance and the impact of processing for modeling, as shown in table 1.
Table 1
It can be seen from Table 1 that, with matching somebody with somebody for virgin rubber 1203W, virgin rubber DN2850, virgin rubber DN101L and plasticizer W-260 consumptions Than change, rubber hardness variable quantity changes therewith, and wherein under room temperature * 15min experiment conditions, hardness change is -26 side Case cannot meet the object of the invention, and under 23 DEG C of * 48h experiment conditions, hardness change is that+16 scheme cannot meet this Improving eyesight.
According to above-mentioned experimental result, in order to reach the purpose of the present invention, a kind of automobile that can obtain the present invention is totally empty The each component of tracheae rubber formula and content, i.e.,:
Virgin rubber 1203W account for 60 parts, virgin rubber DN2850 account for 40 parts, carbon black N550 account for 40 parts, MC account for 30 parts, plasticizer W-260 account for 12 Part, aluminium hydroxide L-40 account for 5 parts, stearic acid account for 1 part, age resistor 6PPD account for 2 parts, age resistor 224 account for 2 parts, accelerator CBS -80 Account for 1.88 parts, accelerator TT-75E accounts for 0.93 part, acceterator TE TD-75F accounts for 1.31 parts and vulcanizing agent S-80 and account for 0.63 part.
In sum, the invention provides a kind of automobile cleaned air pipe rubber formula, makes product in room temperature 15min Fuel oil obtains ± 25 firmness change performance under the conditions of placing, and under the conditions of 23 DEG C of 48h fuel oils are placed obtains highest hardness The performance of variable quantity 15 and there is no harmful substance, can fully meet environmental requirement, with extensive market prospects.
Embodiments of the invention are the foregoing is only, the scope of the claims of the present invention is not thereby limited, it is every using this Equivalent structure or equivalent flow conversion that bright description is made, or directly or indirectly it is used in other related technology necks Domain, is included within the scope of the present invention.

Claims (2)

1. a kind of automobile cleaned air pipe rubber is filled a prescription, it is characterised in that include:Virgin rubber 1203W, virgin rubber DN2850, original Glue DN101L, carbon black N550, MC, plasticizer W-260, aluminium hydroxide L-40, stearic acid, age resistor 6PPD, age resistor 224, rush Enter agent CBS-80, accelerator TT-75E, acceterator TE TD-75F and vulcanizing agent S-80, the automobile cleaned air pipe rubber Formula is calculated according to mass percent, including following weight portion:Virgin rubber 1203W account for 40-60 parts, virgin rubber DN2850 account for 0-40 parts, Virgin rubber DN101L account for 0-60 parts, carbon black N550 account for 40 parts, MC account for 30 parts, plasticizer W-260 account for 10-12 parts, aluminium hydroxide L-40 Account for 5 parts, stearic acid account for 1 part, age resistor 6PPD account for 2 parts, age resistor 224 account for 2 parts, accelerator CBS -80 account for 1.88 parts, accelerator TT-75E accounts for 0.93 part, acceterator TE TD-75F accounts for 1.31 parts and vulcanizing agent S-80 and account for 0.63 part.
2. a kind of automobile cleaned air pipe rubber according to claim 1 is filled a prescription, it is characterised in that the automobile is done Headroom tracheae rubber formula is calculated according to mass percent, including following weight portion:Virgin rubber 1203W accounts for 60 parts, virgin rubber DN2850 account for 40 parts, carbon black N550 account for 40 parts, MC account for 30 parts, plasticizer W-260 account for 12 parts, aluminium hydroxide L-40 account for 5 parts, it is stearic Acid accounts for 1 part, age resistor 6PPD accounts for 2 parts, age resistor 224 accounts for 2 parts, accelerator CBS -80 accounts for 1.88 parts, accelerator TT-75E accounts for 0.93 part, acceterator TE TD-75F accounts for 1.31 parts and vulcanizing agent S-80 and accounts for 0.63 part.
CN201610756800.5A 2016-08-30 2016-08-30 Automobile clean air pipe rubber product formula Pending CN106519341A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610756800.5A CN106519341A (en) 2016-08-30 2016-08-30 Automobile clean air pipe rubber product formula

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610756800.5A CN106519341A (en) 2016-08-30 2016-08-30 Automobile clean air pipe rubber product formula

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CN106519341A true CN106519341A (en) 2017-03-22

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Country Status (1)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1048453A2 (en) * 1999-04-26 2000-11-02 THE GOODYEAR TIRE & RUBBER COMPANY Hose construction containing fluoroplastic terpolymers
CN102766295A (en) * 2012-07-12 2012-11-07 安徽中鼎密封件股份有限公司 Clean air tube and preparation method thereof
CN105602042A (en) * 2016-01-29 2016-05-25 漯河市邦威橡胶有限公司 High-pressure braided-hose inner-layer rubber

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1048453A2 (en) * 1999-04-26 2000-11-02 THE GOODYEAR TIRE & RUBBER COMPANY Hose construction containing fluoroplastic terpolymers
CN102766295A (en) * 2012-07-12 2012-11-07 安徽中鼎密封件股份有限公司 Clean air tube and preparation method thereof
CN105602042A (en) * 2016-01-29 2016-05-25 漯河市邦威橡胶有限公司 High-pressure braided-hose inner-layer rubber

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
巩瑞: ""耐油高压钢丝胶管内胶硫化体系的探究"", 《特种橡胶制品》 *

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Application publication date: 20170322

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