CN106519319A - High-performance rainshoe outsole prepared from short glass fibers - Google Patents
High-performance rainshoe outsole prepared from short glass fibers Download PDFInfo
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- CN106519319A CN106519319A CN201610908138.0A CN201610908138A CN106519319A CN 106519319 A CN106519319 A CN 106519319A CN 201610908138 A CN201610908138 A CN 201610908138A CN 106519319 A CN106519319 A CN 106519319A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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Abstract
The invention discloses a high-performance rainshoe outsole prepared from short glass fibers. The high-performance rainshoe outsole is characterized by being prepared from, by weight, 20-40 parts of short glass fibers, 30-60 parts of natural rubber, 1-1.2 parts of dimethyl silicone oil, 0.5-1 part of an antioxidant, 5-10 parts of metallocene polyethylene, 8-15 parts of polylactic acid, 1-5 parts of a synergist, 0.5-1 part of a nucleating agent, 3-8 parts of modified kaolin, 0.5-1 part of a surfactant, 1-3 parts of a chain extender, 0.5-1 part of dry oxhide gelatin powder, 2-3 parts of fumed silica, 0.5-1 part of nano-aluminum powder and 0.01-0.02 part of graphene microsheets. According to the high-performance rainshoe outsole prepared from the short glass fibers, raw material preparation of a traditional rainshoe outsole is changed, the rigidity, the abrasive resistance and the processability of the material are improved through cooperation of a processing technology, therefore, the outsole can be prevented from being pierced by a hard object, it is guaranteed that the outsole cannot be broken, and harm cannot be caused to feet.
Description
Technical field
The present invention relates to rain boots technical field, and in particular to the big bottom of high-performance rain boots prepared by a kind of utilization short glass fiber.
Background technology
Existing waterproof footwear, such as rain boots, galosh, are by vamp or leg of a boot face and sole or the sole of rubber or rubber and plastic mostly
Become an entirety along bar bonding, the vamp or leg of a boot face itself of its rubber or rubber and plastic just has good water proofing property, so as to just may be used
To prevent rainwater from entering in footwear well, and in order to prevent the sole of skidding rain boots from can also arrange non-slipping block.However, existing
Waterproof rain boots simply have single water-proof function mostly, to some special environment and do not have effect well, and its function is opened up
Exhibition is poor, and sole is easily broken off, and is easily punctured by hard thing.
The content of the invention
The technical problem to be solved is that a kind of performance of offer is good, prepared by lower-cost utilization short glass fiber
The big bottom of high-performance rain boots.
The technical problem to be solved employs the following technical solutions to realize：
The big bottom of high-performance rain boots prepared by a kind of utilization short glass fiber, is made up of the component of following parts by weight：Short glass fiber 20-
40th, natural rubber 30-60, dimethicone 1-1.2, antioxidant 0.5-1, metallocene PE 5-10, PLA 8-15, synergistic
Agent 1-5, nucleator 0.5-1, modified kaolin 3-8, surfactant 0.5-1, chain extender 1-3, dry cow glue powder 0.5-1, gas
Phase white carbon 2-3, nanometer aluminium powder 0.5-1, graphene microchip 0.01-0.02.
Described antioxidant selects irgasfos 168/1098.
Described synergist selects quaternary alkylphosphonium salt intercalation modifying montmorillonite.
Described nucleator is from poly- 3- methyl butenes -1, polyvinyl cyclosilane, polyvinyl cycloalkanes, poly- propane
The mixture of one or more.Nucleator is the New function auxiliary agent for promoting polymer crystallization and improving its grainiess, can make to gather
Compound heterogeneous nucleation, improves rigidity, wearability and the processing characteristics of material, so as to improve the firm of blend to a certain extent
Property, wearability and electric durability energy, improve fluidity of molten, it is easy to extrude, injection mo(u)lding processing.
The surfactant selects KH-550 surfactants, i.e. γ-aminopropyl triethoxysilane.
Described chain extender selects SAG-008 chain extenders.
The graphene microchip is to generate graphite carbon crystal so that three-dimensional cellular fashion length is brilliant, graphite carbon crystal profit after generation
With the nano-milled mode of wet type, ground with single direction, generation thickness is nanosizing, and area is micronized graphene microchip；
The graphene microchip minimizing thickness is 5nm, and graphene microchip enhancing infrared radiation wavelength, its wavelength peak-peak exist
7.5～9.5 μm.Graphene microchip is the New function auxiliary agent for promoting polymer crystallization and improving its grainiess, can make polymer
Heterogeneous nucleation, improves rigidity, wearability and the processing characteristics of material, and its mechanical property is more excellent.
The method of modifying of the modified kaolin is：First by the weight waters such as the kaolin addition of 10-15 weight portions, disperse
30min is stood after uniform, adds the silane coupler of the polyacrylamide and 0.5-1 part weight portions of 2-3 weight portions, it is fully mixed
15s is processed using Surface Treatment with Plasma machine after conjunction, recycles microwave reactor to process 3min, it is dry that gained mixture sends into freezing
Dry machine, the grind into powder Jing after being fully dried.Kaolin can improve the fusion between various materials through modification
Property, increase the agglomeration between material, improve the wearability of product.
A kind of technique for preparing the big bottom of above-mentioned rain boots, step are as follows：
(1) short glass fiber, dry cow glue powder, gas-phase silica, nanometer aluminium powder and graphene microchip are added to into mixing first
In machine, mixer temperature setting is 85 DEG C～95 DEG C, mixes 25～40 minutes, then puts into double screw extruder extruding pelletization,
Obtain master batch material；Raw material is made to fuse into one by granulation, beneficial to following process process；
(2) master batch material is put in mixer, add natural rubber, dimethicone, antioxidant, metallocene PE,
PLA, synergist, nucleator, modified kaolin, surfactant and chain extender, mixer temperature setting are 110 DEG C, mixed
Mix 5-10 minutes in conjunction machine；
(3) mixed material in step (2) is sent into into extruder, extruder is provided with 7 extrusion operation temperature areas, each temperature
The extrusion temperature in area is respectively 190-195 DEG C, 195-205 DEG C, 205-210 DEG C, 210-215 DEG C, 215-218 DEG C, 218-220
DEG C, 220-225 DEG C, extruding pelletization obtains particulate material；
(4) particulate material feeding degausser is carried out into demagnetization process, through three road demagnetizations, removes the magnetic of master batch material, then unite
One collects and carries out dried process；
Degausser carries out demagnetization using strong magnetic roller degausser, particulate material was descended from strong magnetic roller, by demagnetization
Process, mainly make reworked material not produce electrostatic, be easy to the application of product；
(5) particulate material after demagnetization sends into extruder, clamp-ons mould, cools down after shaping.
The invention has the beneficial effects as follows：The present invention changes traditional rain sole raw material and prepares, and coordinates processing technology, improves material
The rigidity of material, wearability and processing characteristics, are prevented from hard thing and pierce through sole, it is ensured that sole does not rupture, and will not cause wound to pin
Evil.
Specific embodiment
In order that technological means, creation characteristic, reached purpose and effect that the present invention is realized are easy to understand, tie below
Specific embodiment is closed, the present invention is expanded on further.
Embodiment 1
The big bottom of high-performance rain boots prepared by a kind of utilization short glass fiber, is made up of the component of following parts by weight：Short glass fiber 40,
Natural rubber 60, dimethicone 1.2, irgasfos 168 1, metallocene PE 10, PLA 15, quaternary alkylphosphonium salt intercalation modifying are covered
De- soil 5, polyvinyl cyclosilane 1, modified kaolin 8, γ-aminopropyl triethoxysilane 1, chain extender 3, dry cow glue powder
1st, gas-phase silica 3, nanometer aluminium powder 1, graphene microchip 0.02.
Nucleator is to promote polymer crystallization and improve the New function auxiliary agent of its grainiess, can make polymer out-phase into
Core, improves the rigidity of material, wearability and processing characteristics, so as to improve to a certain extent the rigid of blend, wearability and
Electric durability energy, improves fluidity of molten, it is easy to extrude, injection mo(u)lding is processed.Chain extender selects SAG-008 chain extenders, Graphene
Microplate is to generate graphite carbon crystal so that three-dimensional cellular fashion length is brilliant, and after generation, graphite carbon crystal utilizes the nano-milled side of wet type
Formula, is ground with single direction, and generation thickness is nanosizing, and area is micronized graphene microchip；The graphene microchip is thick
Degree is minimised as 5nm, and graphene microchip strengthens infrared radiation wavelength, and its wavelength peak-peak is at 7.5～9.5 μm.Graphene
Microplate is the New function auxiliary agent for promoting polymer crystallization and improving its grainiess, can make polymer heterogeneous nucleation, improves material
Rigidity, wearability and processing characteristics, its mechanical property is more excellent.
The method of modifying of modified kaolin is：First by the weight waters such as the kaolin addition of 10-15 weight portions, it is uniformly dispersed
After stand 30min, add the silane coupler of the polyacrylamide and 0.5-1 part weight portions of 2-3 weight portions, after being sufficiently mixed
15s is processed using Surface Treatment with Plasma machine, recycles microwave reactor to process 3min, gained mixture sends into freeze-drying
Machine, the grind into powder Jing after being fully dried.Kaolin can improve the fusion between various materials through modification
Property, increase the agglomeration between material, improve the wearability of product.
A kind of technique for preparing the big bottom of above-mentioned rain boots, step are as follows：
(1) short glass fiber, dry cow glue powder, gas-phase silica, nanometer aluminium powder and graphene microchip are added to into mixing first
In machine, mixer temperature setting is 85 DEG C～95 DEG C, mixes 25～40 minutes, then puts into double screw extruder extruding pelletization,
Obtain master batch material；Raw material is made to fuse into one by granulation, beneficial to following process process；
(2) master batch material is put in mixer, add natural rubber, dimethicone, antioxidant, metallocene PE,
PLA, synergist, nucleator, modified kaolin, surfactant and chain extender, mixer temperature setting are 110 DEG C, mixed
Mix 5-10 minutes in conjunction machine；
(3) mixed material in step (2) is sent into into extruder, extruder is provided with 7 extrusion operation temperature areas, each temperature
The extrusion temperature in area is respectively 190-195 DEG C, 195-205 DEG C, 205-210 DEG C, 210-215 DEG C, 215-218 DEG C, 218-220
DEG C, 220-225 DEG C, extruding pelletization obtains particulate material；
(4) particulate material feeding degausser is carried out into demagnetization process, through three road demagnetizations, removes the magnetic of master batch material, then unite
One collects and carries out dried process；
Degausser carries out demagnetization using strong magnetic roller degausser, particulate material was descended from strong magnetic roller, by demagnetization
Process, mainly make reworked material not produce electrostatic, be easy to the application of product；
(5) particulate material after demagnetization sends into extruder, clamp-ons mould, cools down after shaping.
Embodiment 2
The big bottom of high-performance rain boots prepared by a kind of utilization short glass fiber, is made up of the component of following parts by weight：Short glass fiber 20,
Natural rubber 30, dimethicone 1, irgasfos 168 0.5, metallocene PE 5, PLA 8, quaternary alkylphosphonium salt intercalation modifying cover de-
It is soil 1, polyvinyl cyclosilane 0.5, modified kaolin 3, γ-aminopropyl triethoxysilane 0.5, SAG-008 chain extenders 1, dry
Cow glue powder 0.5, gas-phase silica 2, nanometer aluminium powder 0.5, graphene microchip 0.01.
Nucleator is to promote polymer crystallization and improve the New function auxiliary agent of its grainiess, can make polymer out-phase into
Core, improves the rigidity of material, wearability and processing characteristics, so as to improve to a certain extent the rigid of blend, wearability and
Electric durability energy, improves fluidity of molten, it is easy to extrude, injection mo(u)lding is processed.
Graphene microchip is to generate graphite carbon crystal so that three-dimensional cellular fashion length is brilliant, and after generation, graphite carbon crystal is using wet
The nano-milled mode of formula, is ground with single direction, and generation thickness is nanosizing, and area is micronized graphene microchip；Graphite
Alkene microplate minimizing thickness be 5nm, graphene microchip strengthen infrared radiation wavelength, its wavelength peak-peak is in 7.5～9.5 μ
m.Graphene microchip is the New function auxiliary agent for promoting polymer crystallization and improving its grainiess, can make polymer heterogeneous nucleation,
Rigidity, wearability and the processing characteristics of material is improved, its mechanical property is more excellent.
The method of modifying of modified kaolin is：First by the weight waters such as the kaolin addition of 10-15 weight portions, it is uniformly dispersed
After stand 30min, add the silane coupler of the polyacrylamide and 0.5-1 part weight portions of 2-3 weight portions, after being sufficiently mixed
15s is processed using Surface Treatment with Plasma machine, recycles microwave reactor to process 3min, gained mixture sends into freeze-drying
Machine, the grind into powder Jing after being fully dried.Kaolin can improve the fusion between various materials through modification
Property, increase the agglomeration between material, improve the wearability of product.
A kind of technique for preparing the big bottom of above-mentioned rain boots, step are as follows：
(1) short glass fiber, dry cow glue powder, gas-phase silica, nanometer aluminium powder and graphene microchip are added to into mixing first
In machine, mixer temperature setting is 85 DEG C～95 DEG C, mixes 25～40 minutes, then puts into double screw extruder extruding pelletization,
Obtain master batch material；Raw material is made to fuse into one by granulation, beneficial to following process process；
(2) master batch material is put in mixer, add natural rubber, dimethicone, antioxidant, metallocene PE,
PLA, synergist, nucleator, modified kaolin, surfactant and chain extender, mixer temperature setting are 110 DEG C, mixed
Mix 5-10 minutes in conjunction machine；
(3) mixed material in step (2) is sent into into extruder, extruder is provided with 7 extrusion operation temperature areas, each temperature
The extrusion temperature in area is respectively 190-195 DEG C, 195-205 DEG C, 205-210 DEG C, 210-215 DEG C, 215-218 DEG C, 218-220
DEG C, 220-225 DEG C, extruding pelletization obtains particulate material；
(4) particulate material feeding degausser is carried out into demagnetization process, through three road demagnetizations, removes the magnetic of master batch material, then unite
One collects and carries out dried process；
Degausser carries out demagnetization using strong magnetic roller degausser, particulate material was descended from strong magnetic roller, by demagnetization
Process, mainly make reworked material not produce electrostatic, be easy to the application of product；
(5) particulate material after demagnetization sends into extruder, clamp-ons mould, cools down after shaping.
Embodiment 3
The big bottom of high-performance rain boots prepared by a kind of utilization short glass fiber, is made up of the component of following parts by weight：Short glass fiber 40,
Natural rubber 30, dimethicone 1.2, irgasfos 168 0.5, metallocene PE 10, PLA 8, quaternary alkylphosphonium salt intercalation modifying are covered
De- soil 5, polyvinyl cyclosilane 0.5, modified kaolin 8, γ-aminopropyl triethoxysilane 0.5, chain extender 3, dry ox-hide
Rubber powder 0.5, gas-phase silica 3, nanometer aluminium powder 0.5, graphene microchip 0.02.
Nucleator is to promote polymer crystallization and improve the New function auxiliary agent of its grainiess, can make polymer out-phase into
Core, improves the rigidity of material, wearability and processing characteristics, so as to improve to a certain extent the rigid of blend, wearability and
Electric durability energy, improves fluidity of molten, it is easy to extrude, injection mo(u)lding is processed.
Graphene microchip is to generate graphite carbon crystal so that three-dimensional cellular fashion length is brilliant, and after generation, graphite carbon crystal is using wet
The nano-milled mode of formula, is ground with single direction, and generation thickness is nanosizing, and area is micronized graphene microchip；It is described
Graphene microchip minimizing thickness is 5nm, and graphene microchip strengthens infrared radiation wavelength, its wavelength peak-peak 7.5～
9.5μm.Graphene microchip is to promote polymer crystallization and improve the New function auxiliary agent of its grainiess, can make polymer out-phase into
Core, improves rigidity, wearability and the processing characteristics of material, and its mechanical property is more excellent.
The method of modifying of modified kaolin is：First by the weight waters such as the kaolin addition of 10-15 weight portions, it is uniformly dispersed
After stand 30min, add the silane coupler of the polyacrylamide and 0.5-1 part weight portions of 2-3 weight portions, after being sufficiently mixed
15s is processed using Surface Treatment with Plasma machine, recycles microwave reactor to process 3min, gained mixture sends into freeze-drying
Machine, the grind into powder Jing after being fully dried.Kaolin can improve the fusion between various materials through modification
Property, increase the agglomeration between material, improve the wearability of product.
A kind of technique for preparing the big bottom of above-mentioned rain boots, step are as follows：
(1) short glass fiber, dry cow glue powder, gas-phase silica, nanometer aluminium powder and graphene microchip are added to into mixing first
In machine, mixer temperature setting is 85 DEG C～95 DEG C, mixes 25～40 minutes, then puts into double screw extruder extruding pelletization,
Obtain master batch material；Raw material is made to fuse into one by granulation, beneficial to following process process；
(2) master batch material is put in mixer, add natural rubber, dimethicone, antioxidant, metallocene PE,
PLA, synergist, nucleator, modified kaolin, surfactant and chain extender, mixer temperature setting are 110 DEG C, mixed
Mix 5-10 minutes in conjunction machine；
(3) mixed material in step (2) is sent into into extruder, extruder is provided with 7 extrusion operation temperature areas, each temperature
The extrusion temperature in area is respectively 190-195 DEG C, 195-205 DEG C, 205-210 DEG C, 210-215 DEG C, 215-218 DEG C, 218-220
DEG C, 220-225 DEG C, extruding pelletization obtains particulate material；
(4) particulate material feeding degausser is carried out into demagnetization process, through three road demagnetizations, removes the magnetic of master batch material, then unite
One collects and carries out dried process；
Degausser carries out demagnetization using strong magnetic roller degausser, particulate material was descended from strong magnetic roller, by demagnetization
Process, mainly make reworked material not produce electrostatic, be easy to the application of product；
(5) particulate material after demagnetization sends into extruder, clamp-ons mould, cools down after shaping.
Main performance is tested：The product that embodiment 1-3 is produced carries out every test, its performance test results following table institute
Show.
| Test event | Embodiment 1 | Embodiment 2 | Embodiment 3 |
| Density (g/cm3) | 3.16 | 2.86 | 2.72 |
| Tensile strength (MPa) | 254 | 243 | 206 |
| Elongation at break (%) | 4.7 | 3.6 | 3.9 |
| Bending strength (MPa) | 120 | 150 | 160 |
| Bending modulus (MPa) | 2610 | 3500 | 3250 |
| Coefficient of friction | 0.25 | 0.20 | 0.19 |
As can be seen from the above table, the sole density that prepared by the present invention is high, and wearability is good, not easy fracture, is adapted to various severe
Environment wears.
The general principle and principal character and advantages of the present invention of the present invention has been shown and described above.The technology of the industry
Personnel it should be appreciated that the present invention is not restricted to the described embodiments, the simply explanation described in above-described embodiment and specification this
The principle of invention, without departing from the spirit and scope of the present invention, the present invention also has various changes and modifications, these changes
Change and improvement is both fallen within scope of the claimed invention.The claimed scope of the invention by appending claims and its
Equivalent thereof.
Claims (8)
1. the big bottom of high-performance rain boots that prepared by a kind of utilization short glass fiber, it is characterised in that be made up of the component of following parts by weight：
Short glass fiber 20-40, natural rubber 30-60, dimethicone 1-1.2, antioxidant 0.5-1, metallocene PE 5-10, PLA
8-15, synergist 1-5, nucleator 0.5-1, modified kaolin 3-8, surfactant 0.5-1, chain extender 1-3, dry cow glue powder
0.5-1, gas-phase silica 2-3, nanometer aluminium powder 0.5-1, graphene microchip 0.01-0.02；
The preparation technology at the big bottom of above-mentioned rain boots is as follows：
(1) first short glass fiber, dry cow glue powder, gas-phase silica, nanometer aluminium powder and graphene microchip are added in mixer,
Mixer temperature setting is 85 DEG C～95 DEG C, mixes 25～40 minutes, then puts into double screw extruder extruding pelletization, obtain mother
Pellet；
(2) master batch material is put in mixer, adds natural rubber, dimethicone, antioxidant, metallocene PE, poly- breast
Acid, synergist, nucleator, modified kaolin, surfactant and chain extender, mixer temperature setting are 110 DEG C, in mixer
Middle mixing 5-10 minutes；
(3) mixed material in step (2) is sent into into extruder, extruder is provided with 7 extrusion operation temperature areas, each warm area
Extrusion temperature be respectively 190-195 DEG C, 195-205 DEG C, 205-210 DEG C, 210-215 DEG C, 215-218 DEG C, 218-220 DEG C,
220-225 DEG C, extruding pelletization obtains particulate material；
(4) particulate material feeding degausser is carried out into demagnetization process, through three road demagnetizations, removes the magnetic of master batch material, then unified receipts
Collect and carry out dried process；
(5) particulate material after demagnetization sends into extruder, clamp-ons mould, cools down after shaping.
2. the big bottom of high-performance rain boots that prepared by a kind of utilization short glass fiber according to claim 1, it is characterised in that described
Antioxidant selects irgasfos 168/1098.
3. the big bottom of high-performance rain boots that prepared by a kind of utilization short glass fiber according to claim 1, it is characterised in that described
Synergist selects quaternary alkylphosphonium salt intercalation modifying montmorillonite.
4. the big bottom of high-performance rain boots that prepared by a kind of utilization short glass fiber according to claim 1, it is characterised in that described
Nucleator is from the mixed of one or more in poly- 3- methyl butenes -1, polyvinyl cyclosilane, polyvinyl cycloalkanes, poly- propane
Compound.
5. the big bottom of high-performance rain boots that prepared by a kind of utilization short glass fiber according to claim 1, it is characterised in that the table
Face activating agent selects KH-550 surfactants, i.e. γ-aminopropyl triethoxysilane.
6. the big bottom of high-performance rain boots that prepared by a kind of utilization short glass fiber according to claim 1, it is characterised in that described
Chain extender selects SAG-008 chain extenders.
7. the big bottom of high-performance rain boots that prepared by a kind of utilization short glass fiber according to claim 1, it is characterised in that the stone
Black alkene microplate is to generate graphite carbon crystal so that three-dimensional cellular fashion length is brilliant, and after generation, graphite carbon crystal is nano-milled using wet type
Mode, is ground with single direction, and generation thickness is nanosizing, and area is micronized graphene microchip；The graphene microchip
Minimizing thickness is 5nm, and graphene microchip strengthens infrared radiation wavelength, and its wavelength peak-peak is at 7.5～9.5 μm.
8. the big bottom of high-performance rain boots that prepared by a kind of utilization short glass fiber according to claim 1, it is characterised in that described to change
Property improvement of kaolin is：First by the weight waters such as the kaolin addition of 10-15 weight portions, stand after being uniformly dispersed
30min, adds the silane coupler of the polyacrylamide and 0.5-1 part weight portions of 2-3 weight portions, utilizes after being sufficiently mixed
Ion surface processor processes 15s, recycles microwave reactor to process 3min, and gained mixture sends into freeze drier, and Jing fills
Divide grind into powder after being dried.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610908138.0A CN106519319A (en) | 2016-10-18 | 2016-10-18 | High-performance rainshoe outsole prepared from short glass fibers |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610908138.0A CN106519319A (en) | 2016-10-18 | 2016-10-18 | High-performance rainshoe outsole prepared from short glass fibers |
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| CN106519319A true CN106519319A (en) | 2017-03-22 |
Family
ID=58332324
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| Application Number | Title | Priority Date | Filing Date |
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| CN201610908138.0A Pending CN106519319A (en) | 2016-10-18 | 2016-10-18 | High-performance rainshoe outsole prepared from short glass fibers |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110066427A (en) * | 2019-05-23 | 2019-07-30 | 福建五持恒科技发展有限公司 | Graphene reclaimed rubber foamed shoe-pad and preparation method thereof |
| CN110564026A (en) * | 2019-10-18 | 2019-12-13 | 福州大学 | preparation method of high-wear-resistance rain shoes |
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| CN104004237A (en) * | 2014-05-26 | 2014-08-27 | 芜湖风雪橡胶有限公司 | Rubber material composition for soles and method for preparing rubber material for soles |
| CN104152035A (en) * | 2014-08-12 | 2014-11-19 | 安徽碳索材料科技有限公司 | Oil-based radiation heat-loss paint and preparation method thereof |
| CN105400017A (en) * | 2015-12-08 | 2016-03-16 | 黄涌芮 | Abrasion resistant rubber and preparation method thereof |
| CN105602015A (en) * | 2015-11-14 | 2016-05-25 | 胡运冲 | Lightweight wear-resistant antiskiding rubber shoe sole material and preparation method thereof |
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2016
- 2016-10-18 CN CN201610908138.0A patent/CN106519319A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104004237A (en) * | 2014-05-26 | 2014-08-27 | 芜湖风雪橡胶有限公司 | Rubber material composition for soles and method for preparing rubber material for soles |
| CN104152035A (en) * | 2014-08-12 | 2014-11-19 | 安徽碳索材料科技有限公司 | Oil-based radiation heat-loss paint and preparation method thereof |
| CN105602015A (en) * | 2015-11-14 | 2016-05-25 | 胡运冲 | Lightweight wear-resistant antiskiding rubber shoe sole material and preparation method thereof |
| CN105400017A (en) * | 2015-12-08 | 2016-03-16 | 黄涌芮 | Abrasion resistant rubber and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110066427A (en) * | 2019-05-23 | 2019-07-30 | 福建五持恒科技发展有限公司 | Graphene reclaimed rubber foamed shoe-pad and preparation method thereof |
| CN110564026A (en) * | 2019-10-18 | 2019-12-13 | 福州大学 | preparation method of high-wear-resistance rain shoes |
| CN110564026B (en) * | 2019-10-18 | 2021-08-31 | 福州大学 | Preparation method of high-wear-resistance rain shoes |
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