CN106517825B - A kind of preparation method of inflatable boat inside reinforcing material - Google Patents
A kind of preparation method of inflatable boat inside reinforcing material Download PDFInfo
- Publication number
- CN106517825B CN106517825B CN201610945045.5A CN201610945045A CN106517825B CN 106517825 B CN106517825 B CN 106517825B CN 201610945045 A CN201610945045 A CN 201610945045A CN 106517825 B CN106517825 B CN 106517825B
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- CN
- China
- Prior art keywords
- reinforcing material
- inflatable boat
- preparation
- solution
- chromium
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/24—Coatings containing organic materials
- C03C25/26—Macromolecular compounds or prepolymers
- C03C25/28—Macromolecular compounds or prepolymers obtained by reactions involving only carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/12—General methods of coating; Devices therefor
Abstract
The present invention provides a kind of preparation methods of reinforcing material inside inflatable boat; the main component of material are as follows: the alloy coat of glass fibre and load on the glass fibers; chromium, iron, nickel, manganese, cobalt and boron element are formed alloy coat in fiberglass surfacing using laser melting and coating process by the alloy coat; high, wear-resistant, the corrosion resistant alloy coat of the coating hardness; the alloy coat is applied to inflatable dinghy; in use; even if after the worn-off of outer layer PVC film; it can still guarantee that internal PVC film is intact, protective effect is very good.
Description
Technical field
The present invention relates to field of compound material, more particularly to a kind of preparation method of reinforcing material inside inflatable boat.
Background technique
Glass fibre is a kind of inorganic non-metallic material haveing excellent performance, many kinds of, and advantage is good insulating, heat resistance
By force, corrosion resistance is good, high mechanical strength, but the disadvantage is that property is crisp, wearability is poor.It is using glass marble or post-consumer glass as raw material
Through caused by the techniques systems such as high temperature melting, wire drawing, doff, woven fabric, the diameter of monofilament is that several microns are micro- to twenties meters
Rice, is equivalent to the 1/20-1/5 of a hairline, and every bundle fiber precursor is all made of hundreds of even thousands of monofilament.Glass fibers
The reinforcing material being typically used as in composite material is tieed up, electrically insulating material and heat-insulating material, the national economy such as circuit substrate are each
A field.
Inflatable dinghy has been widely used in tourism, drift, sports and competitions, military exploration exploration, fishing, has hunted, and completes
Various water project operations, flood control and sea rescue etc., applying for inflatable dinghy are expanding year by year.In some cases,
It is mandatory using also having, the international convention regulation of marine human life's safety is protected, all sea going ships are all necessary
Equip ready-to-use life raft.
For the durability for improving inflatable dinghy, it is necessary to improve intensity, the wear-resisting and corrosion resistance of inflatable dinghy internal material
Energy.
Summary of the invention
In view of this, the object of the present invention is to provide a kind of preparation methods of reinforcing material inside inflatable boat.
A kind of preparation method of inflatable boat inside reinforcing material, carries out as steps described below:
A, isopropanol chromium, iron chloride, nickel acetate, manganese acetate, cobalt acetate and acetic acid sodium borohydride are added in ethyl alcohol, then plus
Enter acetone, stirs evenly；
B, it is slowly added to the ethanol solution that mass fraction is 50%, adjusting PH is 2-3, stirs 6-8h, obtains solution glue；
C, solution glue is slowly added into the vinyl acetate resin solution that mass fraction is 15%, high-speed stirred 4-6 is small
When；
D, it is loaded on the glass fibers using the above solution as spinning solution using electrostatic spinning process；
E, after 80-100 DEG C of drying, multiple tracks cladding is carried out in carbon dioxide superpower laser, is obtained inside inflatable boat
Reinforcing material.
Preferably, in the step A, chromium, iron, nickel, manganese, cobalt are equimolar mixing, and the amount of the substance of boron element is
The 20-40% of remaining element.
Preferably, in the step E, the weight and bare glass of the inflatable boat inside reinforcing material obtained after cladding are fine
The mass ratio of dimension is (1.05-1.3): 1.
Preferably, in the step E, the condition of laser melting coating are as follows: laser power 800-1000W, scanning speed are
150-200mm/min, with inert gas argon gas shielded when cladding.
The preparation method of reinforcing material, has the advantages that inside a kind of inflatable boat provided by the present invention
1, various metals substance is loaded on the glass fibers using electrostatic spinning process, not only load effect is good, and
Load Balanced；
2, handled using metal of the laser melting and coating process to fiberglass surfacing, available hardness is high, it is wear-resistant,
Corrosion resistant alloy coat, the alloy coat are applied to inflatable dinghy, in use, even if after the worn-off of outer layer PVC film, it still can be with
PVC film inside guaranteeing is intact, and protective effect is very good；
3, boron element is added on the basis of conventional chromium, iron, nickel, manganese, cobalt alloy coating, the hardness of coating significantly improves.
Specific embodiment
Embodiment 1
A kind of preparation method of inflatable boat inside reinforcing material, carries out as steps described below:
A, isopropanol chromium, iron chloride, nickel acetate, manganese acetate, cobalt acetate and acetic acid sodium borohydride are added in ethyl alcohol, then plus
Enter acetone, stirs evenly；
B, it is slowly added to the ethanol solution that mass fraction is 50%, adjusting PH is 2.5, stirs 7h, obtains solution glue；
C, solution glue is slowly added into the vinyl acetate resin solution that mass fraction is 15%, high-speed stirred 5 hours；
D, it is loaded on the glass fibers using the above solution as spinning solution using electrostatic spinning process；
E, after 95 DEG C of drying, multiple tracks cladding is carried out in carbon dioxide superpower laser, obtains enhancing inside inflatable boat
Material.
In the step A, chromium, iron, nickel, manganese, cobalt are equimolar mixing, and the amount of the substance of boron element is remaining element
30%.
In the step E, the inflatable boat inside weight of reinforcing material and the matter of virgin glass fibre that are obtained after cladding
Amount is than being 1.2:1.
In the step E, the condition of laser melting coating are as follows: laser power 900W, scanning speed 180mm/min melt
With inert gas argon gas shielded when covering.
Embodiment 2
A kind of preparation method of inflatable boat inside reinforcing material, carries out as steps described below:
A, isopropanol chromium, iron chloride, nickel acetate, manganese acetate, cobalt acetate and acetic acid sodium borohydride are added in ethyl alcohol, then plus
Enter acetone, stirs evenly；
B, it is slowly added to the ethanol solution that mass fraction is 50%, adjusting PH is 3, stirs 6h, obtains solution glue；
C, solution glue is slowly added into the vinyl acetate resin solution that mass fraction is 15%, high-speed stirred 6 hours；
D, it is loaded on the glass fibers using the above solution as spinning solution using electrostatic spinning process；
E, after 80 DEG C of drying, multiple tracks cladding is carried out in carbon dioxide superpower laser, obtains enhancing inside inflatable boat
Material.
In the step A, chromium, iron, nickel, manganese, cobalt are equimolar mixing, and the amount of the substance of boron element is remaining element
40%.
In the step E, the inflatable boat inside weight of reinforcing material and the matter of virgin glass fibre that are obtained after cladding
Amount is than being 1.05:1.
In the step E, the condition of laser melting coating are as follows: laser power 1000W, scanning speed 150mm/min melt
With inert gas argon gas shielded when covering.
Embodiment 3
A kind of preparation method of inflatable boat inside reinforcing material, carries out as steps described below:
A, isopropanol chromium, iron chloride, nickel acetate, manganese acetate, cobalt acetate and acetic acid sodium borohydride are added in ethyl alcohol, then plus
Enter acetone, stirs evenly；
B, it is slowly added to the ethanol solution that mass fraction is 50%, adjusting PH is 2, stirs 8h, obtains solution glue；
C, solution glue is slowly added into the vinyl acetate resin solution that mass fraction is 15%, high-speed stirred 4 hours；
D, it is loaded on the glass fibers using the above solution as spinning solution using electrostatic spinning process；
E, after 100 DEG C of drying, multiple tracks cladding is carried out in carbon dioxide superpower laser, obtains enhancing inside inflatable boat
Material.
In the step A, chromium, iron, nickel, manganese, cobalt are equimolar mixing, and the amount of the substance of boron element is remaining element
20%.
In the step E, the inflatable boat inside weight of reinforcing material and the matter of virgin glass fibre that are obtained after cladding
Amount is than being 1.3:1.
In the step E, the condition of laser melting coating are as follows: laser power 800W, scanning speed 200mm/min melt
With inert gas argon gas shielded when covering.
Comparative example 1
By the boron element removal in embodiment 1, remaining preparation condition is constant.
To reinforcing material inside the inflatable boat of embodiment 1-3 and comparative example 1 carry out detection and with it is untreated
Glass fibre compare, obtain following test data.
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 1 | Comparative example | |
| Tensile strength MPa | 825 | 812 | 822 | 680 | 635 |
| Stretch modulus GPa | 48 | 47 | 47 | 42 | 35 |
| Compression strength MPa | 1025 | 982 | 989 | 632 | 587 |
| Compression modulus GPa | 52 | 51 | 51 | 45 | 38 |
By the above test data it is recognised that the intensity of reinforcing material is very good inside inflatable boat prepared by the present invention.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto,
Anyone skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (4)
1. the preparation method of reinforcing material inside a kind of inflatable boat, which is characterized in that carry out as steps described below:
A, isopropanol chromium, iron chloride, nickel acetate, manganese acetate, cobalt acetate and acetic acid sodium borohydride are added in ethyl alcohol, add third
Ketone stirs evenly；
B, it is slowly added to the ethanol solution that mass fraction is 50%, adjusting pH is 2-3, stirs 6-8h, obtains solution glue；
C, solution glue is slowly added into the vinyl acetate resin solution that mass fraction is 15%, high-speed stirred 4-6 hours；
D, it is loaded on the glass fibers using the above solution as spinning solution using electrostatic spinning process；
E, after 80-100 DEG C of drying, multiple tracks cladding is carried out in carbon dioxide superpower laser, obtains enhancing inside inflatable boat
Material.
2. the preparation method of reinforcing material inside inflatable boat as described in claim 1, which is characterized in that the step A
In, chromium, iron, nickel, manganese, cobalt are equimolar mixing, and the amount of the substance of boron element is chromium, either element object in iron, nickel, manganese, cobalt
The 20-40% of the amount of matter.
3. the preparation method of reinforcing material inside inflatable boat as described in claim 1, which is characterized in that the step E
In, the weight of inflatable boat inside reinforcing material and the mass ratio of virgin glass fibre obtained after cladding is (1.05-1.3): 1.
4. the preparation method of reinforcing material inside inflatable boat as described in claim 1, which is characterized in that the step E
In, the condition of laser melting coating are as follows: laser power 800-1000W, scanning speed 150-200mm/min, inertia when cladding
Gases argon protection.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610945045.5A CN106517825B (en) | 2016-11-02 | 2016-11-02 | A kind of preparation method of inflatable boat inside reinforcing material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610945045.5A CN106517825B (en) | 2016-11-02 | 2016-11-02 | A kind of preparation method of inflatable boat inside reinforcing material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106517825A CN106517825A (en) | 2017-03-22 |
| CN106517825B true CN106517825B (en) | 2019-03-01 |
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Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6103003A (en) * | 1998-03-28 | 2000-08-15 | Ledbetter; C. Burgess | Textured coating and method of applying same |
| CN100475882C (en) * | 1999-07-30 | 2009-04-08 | 匹兹堡玻璃板工业俄亥俄股份有限公司 | Impregnated glass fiber strands and products including the same |
| FR2827856B1 (en) * | 2001-07-25 | 2004-06-04 | Saint Gobain Quartz | MINERAL FIBER PROVIDED WITH A MICROPOROUS OR MESOPOROUS COATING |
| KR101349161B1 (en) * | 2012-02-07 | 2014-01-10 | 현대자동차주식회사 | Polymer nanocomposites containing glass fiber coated with metal-carbonnanotube and graphite and a fabrication process thereof |
| CN103287031B (en) * | 2013-06-05 | 2015-01-07 | 天津工业大学 | Method for preparing synchronous reinforced and toughened glass fiber resin-base composite material |
| CN104028047B (en) * | 2014-06-11 | 2016-04-06 | 东华大学 | A kind of high abrasion antistripping electrostatic spinning nano fiber composite filter material and spinning process thereof |
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2016
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| Date | Code | Title | Description |
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| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20190123 Address after: 264204 Wangjiahe Village, Yangting Town, Huancui District, Weihai City, Shandong Province Applicant after: WEIHAI CHAOYANG BOAT DEVELOPMENT Co.,Ltd. Address before: 313000 Southwest Village, Hongxing bridge, Changxing County, Huzhou, Zhejiang Applicant before: CHANGXING YONGQIANG PLASTIC CO.,LTD. |
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| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A preparation method of internal reinforcing material for inflatable ships Effective date of registration: 20230213 Granted publication date: 20190301 Pledgee: Weihai Commercial Bank Co.,Ltd. Tashan sub branch Pledgor: WEIHAI CHAOYANG BOAT DEVELOPMENT Co.,Ltd. Registration number: Y2023980032479 |