CN106517488A - Solid carbon source supplementary method in sewage treatment system - Google Patents

Solid carbon source supplementary method in sewage treatment system Download PDF

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Publication number
CN106517488A
CN106517488A CN201610941619.1A CN201610941619A CN106517488A CN 106517488 A CN106517488 A CN 106517488A CN 201610941619 A CN201610941619 A CN 201610941619A CN 106517488 A CN106517488 A CN 106517488A
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CN
China
Prior art keywords
carbon source
organic carbon
light
solid organic
wall pipe
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Pending
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CN201610941619.1A
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Chinese (zh)
Inventor
吴为中
宫政
魏才倢
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Peking University
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Peking University
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Priority to CN201610941619.1A priority Critical patent/CN106517488A/en
Publication of CN106517488A publication Critical patent/CN106517488A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/006Regulation methods for biological treatment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/32Biological treatment of water, waste water, or sewage characterised by the animals or plants used, e.g. algae
    • C02F3/327Biological treatment of water, waste water, or sewage characterised by the animals or plants used, e.g. algae characterised by animals and plants
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/34Biological treatment of water, waste water, or sewage characterised by the microorganisms used
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2203/00Apparatus and plants for the biological treatment of water, waste water or sewage
    • C02F2203/004Apparatus and plants for the biological treatment of water, waste water or sewage comprising a selector reactor for promoting floc-forming or other bacteria

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  • Life Sciences & Earth Sciences (AREA)
  • Microbiology (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Botany (AREA)
  • Biotechnology (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Purification Treatments By Anaerobic Or Anaerobic And Aerobic Bacteria Or Animals (AREA)

Abstract

The invention provides a solid carbon source supplementary method in a sewage treatment system. According to the solid carbon source supplementary method, a solid carbon source is packaged with a thin walled tube; one end of the thin walled tube is sealed, the other end is provided with an opening, and micropores are distributed on the wall of the thin walled tube; the thin walled tube is delivered into the sewage treatment system; when the solid carbon source in the thin walled tube is used up, a novel solid carbon source can be delivered into the thin walled tube from the end provided with the opening, and then the thin walled tube is delivered into the sewage treatment system again. The solid carbon source supplementary method is capable of solving problems, that carbon source shortage is caused, and organic carbon source adding method is complex, in low carbon nitrogen ratio sewage treatment, and increasing nitrogen removal efficiency of sewage treatment; operation is simple and convenient; organic carbon source action time is long; dosage is convenient to adjust and control; no secondary pollution is easily caused; and economic value is extremely high.

Description

The compensation process of solid-phase carbon source in a kind of sewage disposal system
Technical field
The invention belongs to sewage treatment area, adds the technology of carbon source, more particularly to low-carbon (LC) in being related to sewage disposal process For a kind of not enough solid organic carbon source for adopting of carbon source and carbon source compensation process in nitrogen ratio (C/N) sewage disposal.
Background technology
Often there is the not enough situation of carbon source during low ratio of carbon to ammonium (C/N) sewage is processed, cause nitrogen phosphorus ligands effect It is poor.Existing solution is mainly supplements powdery or liquid organic carbon source in processing system, by processing system The Organic substance that methanol, ethanol, glucose or Fructose etc. are readily biodegradable is added in water inlet, the carbon-nitrogen ratio of water inlet is improved, is promoted Denitrification denitrogenation, improves denitrification effect.Also method directly conveys untreated raw water by the middle-end in handling process, to reach To the effect for supplementing organic carbon.As these organic carbon biochemical reaction speed are fast, in order to keep higher denitrification effect, need not Disconnected ground supplementary carbon source, so as to increased the difficulty of the operating cost and follow-up management of sewage disposal system.In order to reduce running into This, prior art is by attempting municipal sewage or the Industry Waste containing higher organic concentration are added in the water inlet of processing system Water, but, due to the water-quality constituents complexity of these waste water, it is easy to introduce other polluters so that sewage disposal system goes out The water quality deterioration of water, and system operation is unstable, inefficiency.At present, also it is no it is cheap and easy to get, be easy to add and supplement and long-term Effectively, organic carbon source more preferably suitable for low ratio of carbon to ammonium (C/N) sewage disposal.
The content of the invention
In order to overcome the above-mentioned deficiencies of the prior art, the present invention provides a kind of solid organic carbon source and carbon source compensation process, The problems such as to solve not enough carbon source during low carbon-nitrogen ratio sewage is processed and complicated organic carbon source adding method, improve sewage disposal Nitric efficiency.
The present invention provide technical scheme be:
A kind of solid organic carbon source, the solid organic carbon source are the mixture of one or more degradable polymer.Wherein, Degradable polymer is poly butylene succinate (PBS), poly butyric valeric acid copolyesters (PHBV) or polycaprolactone (PCL) In one or more of mixture.Degradable polymer can have various shapes, including strip or graininess etc..
A kind of solid organic carbon source compensation process, above-mentioned solid phase organic carbon source is added in sewage disposal system, is supplemented System organic carbon, so as to improve the nitric efficiency of sewage disposal, the compensation process includes:Solid organic carbon source is seated on wall It is covered with the light-wall pipe of micropore;Again above-mentioned light-wall pipe is positioned in sewage disposal system.
In above-mentioned solid phase organic carbon source compensation process, on wall, it is covered with light-wall pipe one end sealing of micropore, another end opening.Will Light-wall pipe is positioned in sewage disposal system, and specifically light-wall pipe vertically can be inserted in sewage disposal system, light-wall pipe Upwards, the opening can expose the surface of sewage disposal system to opening, or the table of sewage disposal system is placed in Jing after blocking Below face.When the solid organic carbon source loaded in light-wall pipe exhausts, new solid phase can be added from the opening of light-wall pipe Organic carbon source is in light-wall pipe, then is placed in sewage disposal system.
In above-mentioned solid phase organic carbon source compensation process, multiple light-wall pipes for being filled with solid organic carbon source can be placed in sewage In processing system.In embodiments of the present invention, processing system is artificial wet land system, the solid organic carbon provided by the present invention Source compensation process adds solid organic carbon source in artificial wet land system, and the dosage in solid organic carbon source accounts for wet land filler volume 2~10%.
The material of light-wall pipe does not have particular/special requirement, can be rigid plastics, polyvinyl chloride (PVC), polypropylene type (PP), General purpose polystyrene (GPPS), impact resistant polystyrene (HIPS), poly- carbonic acid tree cruel (PC), polyacetals tree extremely (POM) or its Its material.
Compared with prior art, the invention has the beneficial effects as follows:
The invention provides solid organic carbon source is added to sewage disposal system by a kind of solid organic carbon source compensation process In, to reach replenishment system organic carbon, the purpose of the nitric efficiency of sewage disposal is improved, specifically, first by solid organic carbon source It is seated in light-wall pipe;Light-wall pipe one end sealing, another end opening are covered with micropore on the wall of the light-wall pipe;Again by institute State light-wall pipe to be positioned in sewage disposal system;When the solid organic carbon source loaded in light-wall pipe exhausts, opening from light-wall pipe Add new solid organic carbon source at mouth end in light-wall pipe, then light-wall pipe is placed in sewage disposal system.The present invention has Advantages below:
First, the present invention provides a kind of solid organic carbon source, and the solid organic carbon source is one or more degradable polymer Mixture, compare liquid carbon source, the solid organic carbon source that the present invention is provided has long action time, is easy to regulate and control dosage, The advantages of being less prone to secondary pollution;
2nd, the invention provides the compensation process in solid organic carbon source, the method, can be from dress after solid-phase carbon source exhausts The light-wall pipe for filling out solid-phase carbon source exposes the new solid-phase carbon source of addition at the upper end open of system surfaces, easy to operation;
3rd, the present invention is provided solid-phase carbon source economy, it is easy to get, and can degrades under field conditions (factors), discharge biological The organic carbon source for utilizing, it is ensured that the effectiveness of processing system denitrogenation, and the denitrogenation of processing system is had remarkably promote effect, have There is very high economic worth.
Description of the drawings
Fig. 1 is the light-wall pipe structure chart for loading solid organic carbon source;
Fig. 2 is the schematic diagram of the light-wall pipe that multiple filling solid organic carbon sources are placed with artificial wet land system;
Wherein, 1 hygrophyte;2 water distributors;3 fillers;4 strip solid-phase carbon sources;5 perforation pvc pipes;6 wear Hole pvc pipe opening;7 perforation pvc pipe blind ends.
Specific embodiment
Below in conjunction with the accompanying drawings, the present invention is further described by embodiment, but limits the model of the present invention never in any form Enclose.
Fig. 1 is the thin-walled tubular construction for loading solid organic carbon source, wherein PHBV of the solid organic carbon source loaded for strip Degradable polymer.Solid organic carbon source (4) can be loaded in light-wall pipe by opening (6) place of light-wall pipe.Thin-walled The material of pipe be PVC (5), pipe range 80cm, diameter 2cm;The punched areas for being covered with micropore are located at the blind end (7) of pipe, long 50cm.
Fig. 2 is the artificial wet land system of the light-wall pipe for being placed with multiple filling solid organic carbon sources, as shown in Fig. 2 manually Wetland pond is length × width × height=0.4m × 0.3m × 1m.Certain river sewage is taken from the water inlet of artificial wet land system, in the sewage, CODCrFor 43.05~173.86mg/L, total nitrogen is 1.87~39.4mg/L, and total phosphorus is 0.23~3.44mg/L.Artificial swamp system System hydraulic surface loading is 0.1-0.5m3/m2·d.Artificial swamp surface kind has plant (1), based on hygrophyte.Manual moist Ground water distributor (2) water distribution uniformity.Artificial swamp unit cells fill centimetre stone, heavy haydite (3) from bottom to top respectively, and filling is high Degree is respectively the high 20cm of centimetre rock layers, heavy haydite floor height 70cm, and many perforation pvc pipes of Φ 10mm are inserted in centimetre rock layers (5), the lower end of pipe is sealed (7), upper end open (6), fills strip PHBV solid-phase carbon sources (4) in perforation pvc pipe.Solid-phase carbon source Dosage accounts for the 2.5% of wet land filler volume.
Above-mentioned artificial wet land system by the present invention provide solid organic carbon source and solid organic carbon source compensation process to Add solid organic carbon source in artificial wet land system, artificial swamp is good in run duration wastewater treatment efficiency, and in the winter time 0~ When 8 DEG C, treatment effect is still very stable.The average removal efficiency of total nitrogen of the artificial swamp is up to 85% or so.
It should be noted that the purpose for publicizing and implementing example is help further understands the present invention, but the skill of this area Art personnel be appreciated that:In without departing from the present invention and spirit and scope of the appended claims, various substitutions and modifications are all It is possible.Therefore, the present invention should not be limited to embodiment disclosure of that, and the scope of protection of present invention is with claim The scope that book is defined is defined.

Claims (6)

1. a kind of solid organic carbon source compensation process, solid organic carbon source is added in sewage disposal system, to reach supplement System organic carbon, improves the purpose of the nitric efficiency of sewage disposal, and the carbon source compensation process includes:
1) solid organic carbon source is seated in light-wall pipe;Light-wall pipe one end sealing, another end opening, the light-wall pipe It is covered with micropore on wall;
2) light-wall pipe is positioned in sewage disposal system;
3) when the solid organic carbon source loaded in light-wall pipe exhausts, add new solid organic carbon from the opening of light-wall pipe Source is in light-wall pipe, then light-wall pipe is placed in sewage disposal system.
2. solid organic carbon source as claimed in claim 1 compensation process, is characterized in that, the solid organic carbon source is a kind of or many Plant the mixture of degradable polymer;The degradable polymer is poly butylene succinate, poly butyric valeric acid copolymerization The mixture of one or more in ester or polycaprolactone;The shape of the degradable polymer includes strip or graininess.
3. solid organic carbon source as claimed in claim 1 compensation process, is characterized in that, light-wall pipe is vertically inserted into sewage disposal In system, upwards, the opening exposes the surface of sewage disposal system or sewage is placed in Jing after blocking the opening of light-wall pipe Below the surface of processing system.
4. solid organic carbon source as claimed in claim 1 compensation process, is characterized in that, by multiple solid organic carbon sources of being filled with Light-wall pipe is placed in sewage disposal system.
5. solid organic carbon source as claimed in claim 1 compensation process, is characterized in that, the sewage disposal system is artificial swamp System, the dosage that solid organic carbon source is added in the artificial wet land system account for the 2~10% of wet land filler volume.
6. solid organic carbon source as claimed in claim 1 compensation process, is characterized in that, the material of light-wall pipe include rigid plastics, Polyvinyl chloride, polypropylene type, general purpose polystyrene, impact resistant polystyrene, poly- carbonic acid tree are cruel, the cruel material of polyacetals tree.
CN201610941619.1A 2016-11-01 2016-11-01 Solid carbon source supplementary method in sewage treatment system Pending CN106517488A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610941619.1A CN106517488A (en) 2016-11-01 2016-11-01 Solid carbon source supplementary method in sewage treatment system

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CN201610941619.1A CN106517488A (en) 2016-11-01 2016-11-01 Solid carbon source supplementary method in sewage treatment system

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CN106517488A true CN106517488A (en) 2017-03-22

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110683639A (en) * 2019-09-12 2020-01-14 天津大学 Solid carbon source for promoting low-temperature denitrification and preparation method and application thereof

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103253772A (en) * 2013-05-23 2013-08-21 中国环境科学研究院 Solid carbon source enhanced nitrogen removal system of horizontal subsurface flow constructed wetland

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103253772A (en) * 2013-05-23 2013-08-21 中国环境科学研究院 Solid carbon source enhanced nitrogen removal system of horizontal subsurface flow constructed wetland

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
常军军等: "花卉秸秆为碳源的潜流人工湿地对硝氮的去除及其负效应", 《环境工程学报》 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110683639A (en) * 2019-09-12 2020-01-14 天津大学 Solid carbon source for promoting low-temperature denitrification and preparation method and application thereof

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Application publication date: 20170322

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