CN106513637A - Preparing method of foamed aluminum sandwich plate - Google Patents

Preparing method of foamed aluminum sandwich plate Download PDF

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Publication number
CN106513637A
CN106513637A CN201610908524.XA CN201610908524A CN106513637A CN 106513637 A CN106513637 A CN 106513637A CN 201610908524 A CN201610908524 A CN 201610908524A CN 106513637 A CN106513637 A CN 106513637A
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aluminum
aluminium
temperature
plate
alloy
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CN106513637B (en
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左孝青
郑翰
蒋玉圆
周芸
陆建生
罗晓旭
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Kunming University of Science and Technology
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Kunming University of Science and Technology
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D19/00Casting in, on, or around objects which form part of the product

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Laminated Bodies (AREA)
  • Refrigerator Housings (AREA)

Abstract

The invention provides a preparing method of a foamed aluminum sandwich plate and belongs to the field of porous metal materials. Core aluminum alloy (material A) is fused, preserved and tackified at a temperature T1, and a foaming agent TiH2 treated by pre-oxidation is added into the tackified core aluminum alloy melt (material A), stirred and dispersed; a foaming die is preheated to the temperature T1, an aluminum or aluminum alloy plate (material B) is preheated to a temperature T2 which is 10-15 DEG C lower than the solidus temperature of the aluminum or aluminum alloy plate (material B), and the difference between T1 and T2 is 10-20 DEG C; the preheated aluminum or aluminum alloy plate (material B) is padded at the bottom of the die, the tackified core aluminum alloy melt (the material A) containing the TiH2 is poured into the die, and the temperature of the die is controlled at the T1 to carry out heat preservation and foaming; and after the foaming process is finished and cooling is carried out, the foamed aluminum sandwich plate of which the surface layer and a foamed aluminum core are metallurgically combined is obtained, and the thickness of the surface layer of the sandwich plate is controlled through the thickness of a panel.

Description

A kind of preparation method of aluminium foam sandwich plate
Technical field
The present invention relates to a kind of preparation method of aluminium foam sandwich plate, belongs to porous metal material field.
Background technology
Aluminium foam sandwich plate is that a kind of surface is aluminum or aluminum alloy solid layer, and sandwich of the core for foamed aluminium, with list Pure foamed aluminium is compared, with higher specific strength and energy absorption capability, in building, motor vehicles, aircraft, ship, decoration etc. Field has wide practical use.
At present, the main flow preparation method of aluminium foam sandwich plate be mull technique, powder metallurgy foaming method and.Mull technique is adopted to be had Machine glue is by foamed aluminium and aluminum(Or aluminium alloy)Panel is bonded together, and obtains aluminium foam sandwich plate;Powder metallurgy foaming rule is Pass through powder metallurgy route first(Mixed powder, pressure processing), expandable precursor is obtained, then by expandable precursor and aluminum (Or aluminium alloy)Panel carries out composite rolling, obtains aluminium foam sandwich plate finally by foamable.The weak point of mull technique Be that panel is low with the bond strength of foam core, and 200 DEG C are usually no more than using temperature;Although powder metallurgy foaming method is obtained Panel and the high intensity aluminium foam sandwich plate that foam core is metallurgical binding, but limited by powder metallurgy process itself, in product Exist in cost, yield and size clearly disadvantageous.
For obtaining panel and foam core for the controllable high strength sandwich panel of metallurgical binding and surface layer thickness, this patent proposition A kind of aluminium foam sandwich plate preparation method, obtains the expandable precursor for including foaming agent from melt approach, with reference to TiH2Pretreatment, cladding the process such as aluminum or aluminum alloy plate and thermal insulation foaming, prepare between panel and foam core be metallurgical binding The controllable aluminium foam sandwich plate of interface and surface thickness, overcomes powder metallurgy foaming method in goods cost, yield and size Deficiency, overcome deficiency of the mull technique aluminium foam sandwich plate in plate-core bond strength.
The content of the invention
By aluminium alloy(Materials A)In the temperature melting insulations of T1, thickening, Jing pre-oxidation is added in the core aluminum alloy melt of thickening The foaming agent TiH of process2It is stirred dispersion;Foaming mould is preheated to into T1 temperature, aluminum or aluminum alloy plate(Material B)It is preheated to 10 ~ 15 DEG C lower than its solidus temperature of T2 temperature;One block of preheated aluminum or aluminum alloy plate is encased inside into mold bottom, and will be contained TiH2The core aluminum alloy melt of thickening pour in mould, subsequently in one piece of preheated aluminum or aluminum alloy of bath surface lid Plate, finally covers mould upper cover plate;The temperature for controlling mould carries out thermal insulation foaming for T1, and in foaming process, core aluminum alloy melts Body foaming becomes the foamed aluminum-core of sandwich plate, and panel melts and forms the solid object surface layer up and down of sandwich plate;Foaming process terminates And after cooling down, obtaining surface layer and the aluminium foam sandwich plate that foamed aluminum-core is metallurgical binding, sandwich plate surface layer thickness passes through face Plate thickness is controlled.Concrete steps include:
(1)Aluminium alloy melt melting and heat preservation:By aluminium alloy(Materials A)At temperature T1 higher than 20 ~ 30 DEG C of its liquidus temperature After fusing, insulation obtains core aluminum alloy melt in 30 ~ 60 minutes;
(2)Aluminium alloy melt is viscosified:In step(1)Viscosifier metal Ca is added in the core aluminum alloy melt of acquisition, with 1000 ~ The mixing speed of 2000rpm is stirred 10 ~ 15 minutes, obtains the aluminium alloy melt of thickening;Wherein, the addition of Ca is molten for aluminium alloy 1 ~ 3%wt of weight;
(3)Add foaming agent:In step(2)The foaming agent of Jing pre-oxidation treatments is added in the aluminium alloy melt of the thickening for obtaining TiH2, 40 ~ 100s is stirred with the mixing speed of 1000 ~ 3000rpm, expandable melt is obtained;
(4)Mould and aluminium sheet preheating:By the aluminum or aluminum alloy plate that thickness is 1 ~ 2mm(Material B)It is preheated to than its liquidus temperature Temperature T2 that low 10 ~ 15 DEG C of T3, mould are preheated to temperature T1, and preheated aluminum or aluminum alloy plate is encased inside step below mould (3)The expandable melt for obtaining pours mould into, in one layer of aluminum or aluminum alloy plate of bath surface lid and covers mould upper cover plate;
(5)Thermal insulation foaming:By step(4)The mould for including melt and aluminum or aluminum alloy plate for obtaining thermal insulation foaming at temperature T1 5 ~ 7 minutes, after foaming body air cooling, obtain aluminium foam sandwich plate.
Step of the present invention(1)Described in aluminium alloy be that binary that aluminum and Si, Cu, Mg, Zn, Mn element are constituted or polybasic aluminum are closed Gold;Step(4)Described in aluminum or aluminum alloy plate be commercial pure Al sheet or all kinds of aluminium alloy plates.
Foaming agent TiH of the present invention2The particle size range of granule is 37 ~ 74 μm;Foaming agent TiH2Preprocess method for adopting With 400 DEG C of 6h+(470~520)The technique of DEG C 1h carries out oxidation processes in atmospheric environment.
Temperature T1 of the present invention>T3>T2, T1-T2=10 ~ 20 DEG C.
The aluminium foam sandwich plate that the method for the invention is prepared, solid layer, core of the surface for 1.0 ~ 2.0mm of thickness For 3 ~ 6mm of average pore size, the aluminium foam sandwich plate of porosity 75 ~ 90%.
Inventive principle:
1st, the matching principle of blowing temperature, preheating temperature and upper and lower aluminum or aluminum alloy plate liquidus temperature
Prepare aluminium foam sandwich plate and need to determine 3 key temperatures, blowing temperature T1, upper and lower aluminum or aluminum alloy plate preheating temperature T2, Upper and lower aluminum or aluminum alloy plate liquidus temperature T3, triadic relation is T1>T3>T2, experimental studies results show there is following relation:
(1)Blowing temperature, core aluminum alloy melting and heat preservation temperature, mold preheating temperature are T1
(2)Upper and lower aluminum or aluminum alloy plate preheating temperature T2, T1-T2=10 ~ 20 DEG C
(3)Upper and lower aluminum or aluminum alloy plate liquidus temperature T3, T3-T2=10 ~ 15 DEG C
Mould is different from the preheating temperature of upper and lower aluminum or aluminum alloy plate, separately preheats, and T1>T2;Aluminum or aluminum alloy plate exists up and down Preheating(Preheating temperature T2)When be solid-state, and foaming when be liquid(Blowing temperature T1).
The starting point of Temperature Matching is core aluminum alloy (materials A)Liquidus temperature, thus release thermal insulation foaming temperature T1, determines upper and lower aluminum or aluminum alloy plate according to T1(Material B)Preheating temperature and liquidus temperature T2, subsequently select aluminum and aluminium alloy Plate(Material B)I.e.:The liquidus temperature of materials A → thermal insulation foaming temperature T1 →(Material B)Preheating temperature and liquidus temperature → Determine material B.
2nd, the porosity control law of foamed aluminium
Relation between blowing temperature, foamed time and porosity is:
In formula,:The porosity of foamed aluminium board(%, 0<<100%)
t:Foamed time(min)
T 2 :Blowing temperature(600~670℃)
3rd, the relation of foaming agent pretreatment and foam process
To foaming agent TiH2Surface oxidation treatment is carried out, oxide layer can be generated in its surface in situ, disperseed in high temperature aluminum melt The low decomposition platform area of Shi Youyi sections(Ith areas of Fig. 2 Zhong), the TiH within the period2Do not decompose or decompose on a small quantity, be conducive to foaming agent It is dispersed, and which can be made to keep enough activity in foaming process(II, III area in Fig. 2), obtain enough Gas production is realizing effective foaming process.
The dispersed with stirring time(That is time period in Ith areas of Tu2Zhong)It is mutual between blowing temperature, foaming agent pretreating process Relation is:
In formula, S:TiH2In the dispersed with stirring time of temperature(S,>0)
T 1 :TiH2The maximum temperature of oxidation processes(470~520℃)
T 2 :Blowing temperature(600~670℃)
Beneficial effects of the present invention:The expandable precursor for including foaming agent is obtained from melt approach, with reference to TiH2It is pre- Process, coat the process such as aluminum or aluminum alloy plate and thermal insulation foaming, prepare between panel and foam core as metallurgical bonding interface and table The controllable aluminium foam sandwich plate of face thickness, overcomes deficiency of the powder metallurgy foaming method in goods cost, yield and size, gram Deficiency of the mull technique aluminium foam sandwich plate in plate-core bond strength is taken, technical process is simple, controllable, be capable of achieving industrialization Production.
Description of the drawings
Fig. 1 is aluminium foam sandwich plate preparation technology flow chart;
Fig. 2 is oxidation pre-treatment TiH2In the Isothermal Decomposition curve synoptic diagram of blowing temperature.
Specific embodiment
The present invention is described in further detail with specific embodiment below in conjunction with the accompanying drawings, but protection scope of the present invention is simultaneously It is not limited to the content.
Embodiment 1
(1)Alloy melting and heat preservation:AlSi12 alloys are melted in 600 DEG C, 30 minutes are incubated;
(2)Thickening:To step(1)Add in the AlSi12 alloy melts of acquisition and with AlSi12 alloy melt mass percents be The Ca of 1.5%wt, is stirred 15 minutes with the mixing speed of 1000rpm, obtains the AlSi12 alloy melts of thickening;
(3)Add foaming agent:To step(2)Add and AlSi12 alloy melt quality in the thickening AlSi12 alloy melts of acquisition Foaming agent TiH of the percentage ratio for 400 DEG C of 6h+470 DEG C of 1h pre-oxidation treatments of 1.0%wt, Jing2, foaming agent TiH2The granularity model of granule Enclose for 37 ~ 74 μm, it is 70s that the mixing speed of foaming agent dispersed with stirring is 3000rpm, mixing time, obtains foamable melt;
(4)Mould and aluminium sheet preheating:AlSi9 alloy sheets of the thickness for 1mm are preheated to into 590 DEG C, mould is preheated to 600 DEG C, mould Tool lower section be encased inside preheated AlSi9 alloy sheets, by step 3 obtain containing TiH2Thickening aluminium alloy melt pour mould into, One layer of AlSi9 alloy sheets of bath surface lid simultaneously cover mould upper cover plate;
(5)Thermal insulation foaming:Mold temperature of the step 4 containing melt and AlSi9 alloy sheets is maintained at into 7 points of 600 DEG C of thermal insulation foamings Clock, it is average pore size 3mm, porosity 75% to obtain surface after foaming body air cooling for the solid AlSi9 alloy-layers of thickness 1mm, core AlSi12 alloy foam sandwich plates.
Embodiment 2
(1)Aluminium alloy melt melting and heat preservation:ZL111 alloys are melted in 620 DEG C, 50 minutes are incubated;
(2)Thickening:To step(1)In the ZL111 alloy melts of acquisition, addition is 2%wt with ZL111 alloy melts mass percent Ca, stirred 12 minutes with the mixing speed of 1500rpm, obtain the ZL111 alloy melts of thickening;
(3)Add foaming agent:To step(2)Add and ZL111 alloy melts quality hundred in the thickening ZL111 alloy melts of acquisition Divide than the foaming agent TiH for 400 DEG C of 6h+490 DEG C of 1h pre-oxidation treatments of 1.5%wt, Jing2, foaming agent TiH2The particle size range of granule For 37 ~ 74 μm, the mixing speed of foaming agent dispersed with stirring is 2000rpm, and mixing time is 40s, obtains foamable aluminium alloy Melt is stand-by;
(4)Mould and aluminium sheet preheating:AlSi7 alloy sheets of the thickness for 1mm are preheated to into 600 DEG C, mould is preheated to 620 DEG C, mould Tool lower section is encased inside preheated AlSi7 alloy sheets, by step(3)Obtain containing TiH2Thickening aluminium alloy melt pour mould into, In one layer of AlSi7 alloy sheets of bath surface lid and cover mould upper cover plate;
(5)Thermal insulation foaming:By step(4)The mold temperature containing melt and AlSi7 alloy sheets for obtaining is maintained at 620 DEG C to be carried out Thermal insulation foaming 6 minutes, it is average pore size to obtain surface after foaming body air cooling for the solid AlSi7 alloy-layers of thickness 1m, core The ZL111 alloy foam sandwich plates of 4mm, porosity 80%.
Embodiment 3
(1)Aluminium alloy melt melting and heat preservation:7075 alloys are melted in 670 DEG C, 50 minutes are incubated;
(2)Thickening:To step(1)In 7075 alloy melts for obtaining, addition is 3%wt's with 7075 alloy melt mass percents Ca, is stirred 12 minutes with the mixing speed of 1800rpm, obtains 7075 alloy melts of thickening;
(3)Add foaming agent:To step(2)Add and 7075 alloy melt quality percentages in 7075 alloy melt of thickening of acquisition Than the foaming agent TiH for 400 DEG C of 6h+520 DEG C of 1h pre-oxidation treatments of 2%wt, Jing2, foaming agent TiH2The particle size range of granule be 37 ~ 74 μm, the mixing speed of foaming agent dispersed with stirring is 1000rpm, and mixing time is 100s, obtains foamable aluminium alloy melt It is stand-by;
(4)Mould and aluminium sheet preheating:Pure aluminum plate of the thickness for 2mm is preheated to into 650 DEG C, mould is preheated to 670 DEG C, below mould Preheated pure aluminum plate is encased inside, by step(3)Obtain containing TiH2Thickening aluminium alloy melt pour mould into, in bath surface lid One layer of pure aluminum plate simultaneously covers mould upper cover plate;
(5)Thermal insulation foaming:By step(4)The mold temperature containing melt and pure aluminum plate for obtaining is maintained at 670 DEG C and is incubated Foaming 5 minutes, it is average pore size 5mm, porosity to obtain surface after foaming body air cooling for the solid aluminum layer of thickness 2mm, core 85% 7075 alloy foam sandwich plates.
Embodiment 4
(1)Aluminium alloy melt melting and heat preservation:AlMg10 alloys are melted at 640 DEG C, 60 minutes are incubated;
(2)Aluminium alloy melt is viscosified:To step(1)Addition and AlMg10 alloy melt quality in the AlMg10 alloy melts of acquisition Ca of the percentage ratio for 2.0%wt, is stirred 10 minutes with the mixing speed of 2000rpm, obtains the AlMg10 alloy melts of thickening;
(3)Add foaming agent:To step(2)Add and AlMg10 alloy melt quality in the thickening AlMg10 alloy melts of acquisition Foaming agent TiH of the percentage ratio for 400 DEG C of 6h+510 DEG C of 1h pre-oxidation treatments of 1.7%wt, Jing2, the stirring speed of foaming agent dispersed with stirring Spend for 2000rpm, mixing time is 45s;
(4)Mould and aluminium sheet preheating:AlSi4 alloy sheets of the thickness for 1.5mm are preheated to into 620 DEG C, mould is preheated to 640 DEG C, Preheated AlSi4 alloy sheets are encased inside below mould, by step(3)Obtain containing TiH2Thickening aluminium alloy melt pour mould into Tool, in one layer of AlSi4 alloy sheets of bath surface lid and covers mould upper cover plate;
(5)Thermal insulation foaming:By step(4)The mold temperature containing melt and AlSi4 alloy sheets for obtaining is maintained at 640 DEG C to be carried out Thermal insulation foaming 7 minutes, it is average pore size to obtain surface after foaming body air cooling for the solid AlSi4 alloy-layers of thickness 1.5mm, core The AlMg10 alloy foam sandwich plates of 6mm, porosity 90%.

Claims (4)

1. a kind of preparation method of aluminium foam sandwich plate, it is characterised in that specifically include following steps:
(1)Aluminium alloy melt melting and heat preservation:Protect after aluminium alloy is melted at temperature T1 higher than 20 ~ 30 DEG C of its liquidus temperature Temperature obtains core aluminum alloy melt in 30 ~ 60 minutes;
(2)Aluminium alloy melt is viscosified:In step(1)Viscosifier metal Ca is added in the core aluminum alloy melt of acquisition, with 1000 ~ The mixing speed of 2000rpm is stirred 10 ~ 15 minutes, obtains the aluminium alloy melt of thickening;Wherein, the addition of Ca is molten for aluminium alloy 1 ~ 3%wt of weight;
(3)Add foaming agent:In step(2)The foaming agent of Jing pre-oxidation treatments is added in the aluminium alloy melt of the thickening for obtaining TiH2, 40 ~ 100s is stirred with the mixing speed of 1000 ~ 3000rpm, expandable melt is obtained;
(4)Mould and aluminium sheet preheating:By thickness for 1 ~ 2mm aluminum or aluminum alloy plate be preheated to it is lower by 10 than its liquidus temperature T3 ~ 15 DEG C of temperature T2, mould are preheated to temperature T1, and preheated aluminum or aluminum alloy plate is encased inside step below mould(3)Obtain Expandable melt pours mould into, in one layer of aluminum or aluminum alloy plate of bath surface lid and covers mould upper cover plate;
(5)Thermal insulation foaming:By step(4)The mould for including melt and aluminum or aluminum alloy plate for obtaining thermal insulation foaming at temperature T1 5 ~ 7 minutes, after foaming body air cooling, obtain aluminium foam sandwich plate.
2. the preparation method of aluminium foam sandwich plate according to claim 1, it is characterised in that:Step(1)Described in aluminium alloy The binary constituted with Si, Cu, Mg, Zn, Mn element for aluminum or polynary aluminium alloy;Step(4)Described in aluminum or aluminum alloy plate be work Industry pure aluminum plate or all kinds of aluminium alloy plates.
3. the preparation method of aluminium foam sandwich plate according to claim 1, it is characterised in that:Foaming agent TiH2The granularity of granule Scope is 37 ~ 74 μm;Foaming agent TiH2Preprocess method be using 400 DEG C of 6h+(470~520)The technique of DEG C 1h is in big compression ring Oxidation processes are carried out in border.
4. the preparation method of aluminium foam sandwich plate according to claim 1, it is characterised in that:T1>T3>T2, T1-T2=10 ~ 20 ℃。
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CN107069598A (en) * 2017-04-25 2017-08-18 扬中市众成管路配件有限公司 A kind of high-strength cable bus bar installation casing
CN107069599A (en) * 2017-04-25 2017-08-18 扬中市众成管路配件有限公司 A kind of mini cable remittance wire casing and preparation method thereof
CN107604189A (en) * 2017-09-29 2018-01-19 重庆理工大学 A kind of foam aluminum sandwich and its Semi-Solid Thixoforming Seepage Foundry method
CN107695318A (en) * 2017-09-29 2018-02-16 重庆理工大学 A kind of foam magnesium sandwich plate and its Semi-Solid Thixoforming Seepage Foundry method
CN109128105A (en) * 2018-08-21 2019-01-04 安徽省鸣新材料科技有限公司 Production method based on foam melt method batch micro operations foamed aluminium filling member
CN109530658A (en) * 2019-01-24 2019-03-29 安徽省新方尊自动化科技有限公司 A kind of foamed fiber aluminium and preparation method thereof
CN111299549A (en) * 2020-03-10 2020-06-19 中信戴卡股份有限公司 Preparation method of foamed aluminum filled aluminum alloy cavity casting
CN111394605A (en) * 2020-03-20 2020-07-10 江苏大学 TiB2Preparation method of particle reinforced foamed aluminum/aluminum alloy
CN112108652A (en) * 2019-12-27 2020-12-22 航天特种材料及工艺技术研究所 Integrated preparation method of light foamed aluminum sandwich board and light foamed aluminum sandwich board
CN113102775A (en) * 2021-04-15 2021-07-13 广东华研智能科技有限公司 Method for preparing foamed aluminum component through electric arc additive manufacturing
CN114147067A (en) * 2021-12-17 2022-03-08 东北大学 Method for preparing foam metal sandwich board by combined casting and rolling
KR102615541B1 (en) * 2022-10-05 2023-12-19 주식회사 디알액시온 A method of casting and bonding a composite aluminum material and an Al-Si-Mg-based aluminum material

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CN107069599A (en) * 2017-04-25 2017-08-18 扬中市众成管路配件有限公司 A kind of mini cable remittance wire casing and preparation method thereof
CN107069598A (en) * 2017-04-25 2017-08-18 扬中市众成管路配件有限公司 A kind of high-strength cable bus bar installation casing
CN107604189A (en) * 2017-09-29 2018-01-19 重庆理工大学 A kind of foam aluminum sandwich and its Semi-Solid Thixoforming Seepage Foundry method
CN107695318A (en) * 2017-09-29 2018-02-16 重庆理工大学 A kind of foam magnesium sandwich plate and its Semi-Solid Thixoforming Seepage Foundry method
CN109128105A (en) * 2018-08-21 2019-01-04 安徽省鸣新材料科技有限公司 Production method based on foam melt method batch micro operations foamed aluminium filling member
CN109530658A (en) * 2019-01-24 2019-03-29 安徽省新方尊自动化科技有限公司 A kind of foamed fiber aluminium and preparation method thereof
CN112108652A (en) * 2019-12-27 2020-12-22 航天特种材料及工艺技术研究所 Integrated preparation method of light foamed aluminum sandwich board and light foamed aluminum sandwich board
CN111299549A (en) * 2020-03-10 2020-06-19 中信戴卡股份有限公司 Preparation method of foamed aluminum filled aluminum alloy cavity casting
WO2021179607A1 (en) * 2020-03-10 2021-09-16 中信戴卡股份有限公司 Preparation method for aluminum foam-filled hollow aluminum alloy casting
CN111394605A (en) * 2020-03-20 2020-07-10 江苏大学 TiB2Preparation method of particle reinforced foamed aluminum/aluminum alloy
CN113102775A (en) * 2021-04-15 2021-07-13 广东华研智能科技有限公司 Method for preparing foamed aluminum component through electric arc additive manufacturing
CN114147067A (en) * 2021-12-17 2022-03-08 东北大学 Method for preparing foam metal sandwich board by combined casting and rolling
CN114147067B (en) * 2021-12-17 2022-09-09 东北大学 Method for preparing foam metal sandwich board by combined casting and rolling
KR102615541B1 (en) * 2022-10-05 2023-12-19 주식회사 디알액시온 A method of casting and bonding a composite aluminum material and an Al-Si-Mg-based aluminum material

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