CN1065080A - The high-temperature corrosion-resistant coating of ferrous materials - Google Patents

The high-temperature corrosion-resistant coating of ferrous materials Download PDF

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Publication number
CN1065080A
CN1065080A CN 92107534 CN92107534A CN1065080A CN 1065080 A CN1065080 A CN 1065080A CN 92107534 CN92107534 CN 92107534 CN 92107534 A CN92107534 A CN 92107534A CN 1065080 A CN1065080 A CN 1065080A
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Prior art keywords
ferrous materials
resistant coating
corrosion
coating
aluminum
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CN 92107534
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CN1038941C (en
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蒋建清
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Southeast University
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Southeast University
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Publication of CN1038941C publication Critical patent/CN1038941C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Abstract

A kind of high-temperature corrosion-resistant coating of ferrous materials is made up of the mixture of aluminium oxide powder, alumina fiber and zinc white.With itself and water glass furnishing suspension solution, be sprayed on the surface of ferrous materials, and then the workpiece that will be sprayed is dried under 200 ℃-300 ℃ temperature, steel material surface promptly forms one deck corrosion-resistant coating, iron and steel parts with this corrosion-resistant coating, in pyritous aluminum or aluminum alloy liquation, have superior corrosion resistance, the life-span of the iron and steel parts that need work in the aluminum or aluminum alloy liquation is greatly improved.

Description

The high-temperature corrosion-resistant coating of ferrous materials
The present invention is a kind of under hot environment, and the corrosion-resistant coating material of ferrous materials in the aluminum or aluminum alloy liquation belongs to the technical field of the protection against corrosion coating of ferrous materials.
At present, in 600~1000 ℃ molten aluminium alloy, the etching problem of ferrous materials is very serious, even stainless steel also can be snapped erosion when working soon in high temperature aluminum liquid, or generates iron-aluminium frangible compounds and damages; In addition, traditional coating zinc white (ZnO) method although corrosion stability is made moderate progress, but still is difficult in the medium-term and long-term use of high temperature aluminium alloys liquation.For this reason, it is very necessary seeking a kind of more efficiently high-temperature anticorrosive coating.
Purpose of the present invention just provides a kind of under hot environment, and ferrous materials has the ferrous materials corrosion-resistant coating of good corrosion resistance in the aluminum or aluminum alloy liquation.
Corrosion-resistant coating prescription of the present invention and complete processing are as follows:
To cross the aluminium sesquioxide (Al of 320 mesh sieves 2O 3) powder is main, the percentage composition of its weight adds 7%~5% alumina fiber and 45% following zinc white (ZnO) again in 50%~95% scope, mix mix well after, with water glass (nNa 2Omsio 2) with this powder mix furnishing suspension, at room temperature, with air compressor with this liquid spray on the workpiece that cleans up, in 200~300 ℃ big stove, toasted 3~4 hours then.Take out air cooling, the surface of iron and steel parts promptly forms-50~100 μ m thick even, densification, anti-corrosion, and firm white coating.The content of zinc white is few more, and the etch resistant properties of coating is just good more.The diameter of alumina fiber is about 5 microns, and its length is 1~2 millimeter.
The invention has the advantages that this coating has superior erosion resistance, after surface of steel workpiece coated this coating, this workpiece can long term operation in the aluminum or aluminum alloy liquation and be not corroded, and has prolonged the work-ing life of this workpiece effectively, and has reduced production cost.In addition, owing in coated material, added alumina fiber, make the peeling resistance of this coating greatly improve.In coated material, also added zinc white, therefore made the cost of this coated material reduce greatly,, can also regulate the add-on of zinc white according to the job requirement of reality.So that cost and coating quality have a suitable preferred value.
Embodiment of the present invention are as follows:
With soft steel is example, at first, removes the rusty stain of workpiece surface, and cleans up, to be dried after, will cross the Al of 320 mesh sieve 2O 3Powder (85%wt) alumina fiber 5%wt and zinc white (10%wt) mix, and add an amount of water glass (account for gross weight 50%) then, and furnishing thin liquid shape in the spray gun of packing into, is opened the compressor of calming the anger.Make air pressure reach 2~4 kgfs/cm 2Between the time, open spray gun, workpiece surface is sprayed equably, and gauge control is about 60~100 μ m, then, close spray gun, workpiece moved in 300 ℃ the air furnace baking 3 hours, and took out the back air cooling, the surface of steel promptly forms a densification, anti-corrosion coating, test shows: the soft steel with this coating can life-time service in 880 ℃ molten aluminium alloy, and unlikely surface corrosion phenomenon.
In order to lower the cost of coating, generally in aluminium oxide powder and fiber, add an amount of zinc white, the add-on of zinc white is decided according to the specific requirement of workpiece, and the add-on of zinc white is low more, and its coating quality is good more, but cost is also high more; Otherwise the cost of the slightly inferior coating of coating quality then can lower many, but the add-on of zinc white generally is no more than the amount of aluminium sesquioxide.Just can realize the present invention according to the above.

Claims (4)

1, a kind of in the aluminum or aluminum alloy liquation corrosion-resistant coating of ferrous materials, the material that it is characterized in that this coating is by 50%~95% aluminium oxide powder (Al 2O 3) and 7%~5% alumina fiber add that the zinc white (ZnO) below 45% mixes.
2, the high-temperature corrosion-resistant coating of ferrous materials according to claim 1 is characterized in that its coating process is: the mixture of aluminium oxide powder, alumina fiber and zinc white is added water glass (nNa 2Omsio 2), furnishing suspension is sprayed on the surface of ferrous materials, places it in then under 200 ℃~300 ℃ the condition to toast 3~4 hours.
3, the high-temperature corrosion-resistant coating of ferrous materials according to claim 1 and 2, the thickness that it is characterized in that coating are 50~100 μ m.
4, the high-temperature corrosion-resistant coating of ferrous materials according to claim 1 and 2 is characterized in that described alumina fiber, and its diameter is about 5 microns, and its length is 1~2 millimeter.
CN92107534A 1992-04-29 1992-04-29 High-temp. corrosion-resisting coating for iron and steel materials Expired - Fee Related CN1038941C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN92107534A CN1038941C (en) 1992-04-29 1992-04-29 High-temp. corrosion-resisting coating for iron and steel materials

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN92107534A CN1038941C (en) 1992-04-29 1992-04-29 High-temp. corrosion-resisting coating for iron and steel materials

Publications (2)

Publication Number Publication Date
CN1065080A true CN1065080A (en) 1992-10-07
CN1038941C CN1038941C (en) 1998-07-01

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CN92107534A Expired - Fee Related CN1038941C (en) 1992-04-29 1992-04-29 High-temp. corrosion-resisting coating for iron and steel materials

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CN (1) CN1038941C (en)

Cited By (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1059689C (en) * 1998-04-13 2000-12-20 冶金工业部钢铁研究总院 High-temperature paint
CN1109722C (en) * 1999-12-23 2003-05-28 重庆钢铁(集团)有限责任公司 High-temp antioxidizing paint
CN102795843A (en) * 2012-09-07 2012-11-28 厚波 High-strength anti-stripping wear-resistant ceramic paint and preparation method thereof
CN106193952A (en) * 2016-08-31 2016-12-07 南通苏通人防防护设备有限公司 A kind of closed guard gate
CN106320920A (en) * 2016-08-31 2017-01-11 南通苏通人防防护设备有限公司 High strength civil air-defense door
CN106320901A (en) * 2016-08-31 2017-01-11 南通苏通人防防护设备有限公司 Method for manufacturing steel disguising door and steel plate used for human preventing door
CN106319377A (en) * 2016-08-31 2017-01-11 南通苏通人防防护设备有限公司 High-strength camouflage door used in cooperation with civil air defense door and manufacturing method for manufacturing camouflage door steel plate
CN106319384A (en) * 2016-08-31 2017-01-11 南通苏通人防防护设备有限公司 Disguised door used in cooperation with civil air defense door
CN106401408A (en) * 2016-08-31 2017-02-15 南通苏通人防防护设备有限公司 High-strength civil defense door made of steel plate and steel plate manufacturing method
CN106401407A (en) * 2016-08-31 2017-02-15 南通苏通人防防护设备有限公司 Civil air defense door and manufacturing method of steel plate for manufacturing civil air defense door
CN106401410A (en) * 2016-08-31 2017-02-15 南通苏通人防防护设备有限公司 High-strength-performance civil air defense door
CN106401412A (en) * 2016-08-31 2017-02-15 南通苏通人防防护设备有限公司 Civil air defense door and manufacturing method for steel plate used for making civil air defense door leaf
CN106401409A (en) * 2016-08-31 2017-02-15 南通苏通人防防护设备有限公司 Steel civil air defense door
CN106401411A (en) * 2016-08-31 2017-02-15 南通苏通人防防护设备有限公司 High-strength camouflage door used in fit with civil air defense door
CN106437450A (en) * 2016-08-31 2017-02-22 南通苏通人防防护设备有限公司 Civil air defense door with disguise door
CN106433255A (en) * 2016-08-31 2017-02-22 南通苏通人防防护设备有限公司 High-strength civil-air-defence door
CN109704577A (en) * 2019-01-03 2019-05-03 桂林理工大学 A kind of high temperature resistant molten aluminum etching ground and preparation method thereof
CN110252627A (en) * 2019-06-10 2019-09-20 辽宁工程技术大学 A kind of preparation method of resistance to molten aluminum corrosion steel surface oxide coating
CN112608659A (en) * 2020-12-23 2021-04-06 江苏金洋机械有限公司 High-temperature corrosion-resistant coating of steel material for railway track base plate tool

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1051573A (en) * 1989-11-10 1991-05-22 西安航空发动机公司 A kind of fire resistant anticorrosive paint

Cited By (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1059689C (en) * 1998-04-13 2000-12-20 冶金工业部钢铁研究总院 High-temperature paint
CN1109722C (en) * 1999-12-23 2003-05-28 重庆钢铁(集团)有限责任公司 High-temp antioxidizing paint
CN102795843A (en) * 2012-09-07 2012-11-28 厚波 High-strength anti-stripping wear-resistant ceramic paint and preparation method thereof
CN102795843B (en) * 2012-09-07 2014-11-05 厚波 High-strength anti-stripping wear-resistant ceramic paint and preparation method thereof
CN106401407A (en) * 2016-08-31 2017-02-15 南通苏通人防防护设备有限公司 Civil air defense door and manufacturing method of steel plate for manufacturing civil air defense door
CN106401409A (en) * 2016-08-31 2017-02-15 南通苏通人防防护设备有限公司 Steel civil air defense door
CN106320901A (en) * 2016-08-31 2017-01-11 南通苏通人防防护设备有限公司 Method for manufacturing steel disguising door and steel plate used for human preventing door
CN106319377A (en) * 2016-08-31 2017-01-11 南通苏通人防防护设备有限公司 High-strength camouflage door used in cooperation with civil air defense door and manufacturing method for manufacturing camouflage door steel plate
CN106319384A (en) * 2016-08-31 2017-01-11 南通苏通人防防护设备有限公司 Disguised door used in cooperation with civil air defense door
CN106401408A (en) * 2016-08-31 2017-02-15 南通苏通人防防护设备有限公司 High-strength civil defense door made of steel plate and steel plate manufacturing method
CN106193952A (en) * 2016-08-31 2016-12-07 南通苏通人防防护设备有限公司 A kind of closed guard gate
CN106401410A (en) * 2016-08-31 2017-02-15 南通苏通人防防护设备有限公司 High-strength-performance civil air defense door
CN106401412A (en) * 2016-08-31 2017-02-15 南通苏通人防防护设备有限公司 Civil air defense door and manufacturing method for steel plate used for making civil air defense door leaf
CN106320920A (en) * 2016-08-31 2017-01-11 南通苏通人防防护设备有限公司 High strength civil air-defense door
CN106401411A (en) * 2016-08-31 2017-02-15 南通苏通人防防护设备有限公司 High-strength camouflage door used in fit with civil air defense door
CN106437450A (en) * 2016-08-31 2017-02-22 南通苏通人防防护设备有限公司 Civil air defense door with disguise door
CN106433255A (en) * 2016-08-31 2017-02-22 南通苏通人防防护设备有限公司 High-strength civil-air-defence door
CN109704577A (en) * 2019-01-03 2019-05-03 桂林理工大学 A kind of high temperature resistant molten aluminum etching ground and preparation method thereof
CN110252627A (en) * 2019-06-10 2019-09-20 辽宁工程技术大学 A kind of preparation method of resistance to molten aluminum corrosion steel surface oxide coating
CN110252627B (en) * 2019-06-10 2021-06-01 辽宁工程技术大学 Preparation method of aluminum liquid corrosion resistant steel surface oxide coating
CN112608659A (en) * 2020-12-23 2021-04-06 江苏金洋机械有限公司 High-temperature corrosion-resistant coating of steel material for railway track base plate tool

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