CN106498749A - A kind of water solublity thermal-reactive polyurethane hydrophilic, fire-retardant, antibacterial finishing agent and its application - Google Patents
A kind of water solublity thermal-reactive polyurethane hydrophilic, fire-retardant, antibacterial finishing agent and its application Download PDFInfo
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- CN106498749A CN106498749A CN201610944526.4A CN201610944526A CN106498749A CN 106498749 A CN106498749 A CN 106498749A CN 201610944526 A CN201610944526 A CN 201610944526A CN 106498749 A CN106498749 A CN 106498749A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
- D06M15/568—Reaction products of isocyanates with polyethers
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
- D06M13/148—Polyalcohols, e.g. glycerol or glucose
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
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- D—TEXTILES; PAPER
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- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
- D06M2101/12—Keratin fibres or silk
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
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- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/20—Treatment influencing the crease behaviour, the wrinkle resistance, the crease recovery or the ironing ease
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/30—Flame or heat resistance, fire retardancy properties
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Abstract
The present invention relates to technical field of textile auxiliary agent, discloses a kind of water solublity thermal-reactive polyurethane hydrophilic, fire-retardant, antibacterial finishing agent, including the component of following parts by weight：Water solublity thermal-reactive polyurethane, 15 20 parts；Aceglutamide, 0.1 10 parts；Glycerol, 2 12 parts.The present invention add aceglutamide as finishing agent in additive, it is capable of the carrying out of catalytic reaction and significantly improves polyurethane and synthetic fibers crosslinking degree, low concentration polyurethane just can give synthetic fibers and wool fiber lasting hydrophilic, reactivity and flexibility are significantly increased simultaneously, persistency is high, fabric after arrangement not only has good hydrophilic, but also there is anti-flammability and antibiotic property.
Description
Technical field：
A kind of the present invention relates to technical field of textile auxiliary agent, more particularly to water solublity thermal-reactive polyurethane finishing agent.
Background technology：
Thermal-reactive soluble polyurethane is early 1970s, by Japanese first industrial pharmaceutical company and Germany
Auxiliary agent in a series of techniques for after-finishing of textile products that Bayer companies have passed through the research and development of more than 10 years and succeed.Cause
The series of products do not contain formaldehyde, not APEO, without solvent, after putting goods on the market from the end of the eighties in last century, American-European, Japanese etc.
Extensively apply in the textile processing of west.
Heat answer type soluble polyurethane main usess be Pilus Caprae seu Oviss, wrinkle resistant, the shrink-resistant finish of silk fabric, cotton, linen
Wrinkle resistant, shrinkproof, the lasting water suction antistatic finish of the synthetic fibers such as terylene, with various auxiliary agents and with the property for making fabric after process
There can be persistency (patience).Thermal-reactive soluble polyurethane can make fabric thicken sense, richness, elasticity good, have one
Fixed hanging degree, is suitable for dimensionally stable, machine washable, the processing of the functional clothing fabric such as non-ironing.
But as the technology preparation concentration of its hydrophilic finishing agent is big, need during improve Financial cost, and use
Catalyst to be added and other auxiliary addition agents, produce industry a large amount of waste liquids and environment are caused to bear.
Content of the invention：
The present invention is directed to the deficiencies in the prior art, there is provided a kind of new water solublity thermal-reactive polyurethane finishing agent, adds
Plus aceglutamide and glycerol are used as finishing auxiliarieses, the arrangement efficiency of polyurethane is significantly improved, reduce the usage amount of polyurethane；Whole
Fabric after reason not only has good hydrophilic, but also there is anti-flammability and antibiotic property.
In order to achieve the above object, the application provides technical scheme below：
A kind of water solublity thermal-reactive polyurethane hydrophilic, fire-retardant, antibacterial finishing agent, are grouped by the group of following parts by weight
Into：
Water solublity thermal-reactive polyurethane：15-20 parts；
Aceglutamide：0.1-10 parts；Glycerol：2-12 parts.
Preferably, it is grouped into by the group of following parts by weight：
Water solublity thermal-reactive polyurethane：15-18 parts；
Aceglutamide：0.5-1.2 parts；Glycerol：4.0-9.0 part.
Preferably, the water solublity thermal-reactive polyurethane is with isophorone diisocyanate, N methyldiethanol amine, poly-
Propylene Glycol -2000 is primary raw material, is synthesized with methyl ethyl ketoxime as end-capping reagent.
Preferably, the water solublity thermal-reactive polyurethane is that polyethers obtains base polyurethane prepolymer for use as with isocyanates reaction,
Synthesized with prepolymer reaction using sodium sulfite as sealer again.
Preferably, the water solublity thermal-reactive polyurethane is F-2840E.
A kind of water solublity thermal-reactive polyurethane hydrophilic described above, fire-retardant, antibacterial finishing agent are applied to synthesis fine
Dimensional fabric or hydrophilic, fire-retardant, the antibiotic finish process of wool fabric, are also claimed content.
Preferably, the hydrophilic, fire-retardant of the synthetic fabrics, the arrangement formula of liquid of antibiotic finish are：
Water solublity thermal-reactive polyurethane hydrophilic, fire-retardant, antibacterial finishing agent 10-20g, water 1000g；Bath raio is 1:30；
The hydrophilic, fire-retardant of the synthetic fibers, the finishing technique of antibiotic finish are：
Pad, dry, baking, padding, baking, hot water wash, drying；
The hydrophilic, fire-retardant of the wool fabric, the arrangement formula of liquid of antibiotic finish are：
Water solublity thermal-reactive polyurethane hydrophilic, fire-retardant, antibacterial finishing agent 20-50g, water 1000g；Bath raio is 1:30；
The hydrophilic, fire-retardant of the wool fabric, the finishing technique of antibiotic finish are：
Pad, dry, baking, hot water wash, drying.
The invention has the advantages that：
(1) catalyst and additive during, the present invention adds aceglutamide as finishing agent, can significantly improve poly- ammonia
Ester and synthetic fibers crosslinking degree, low concentration just can give synthetic fibers and wool fiber lasting hydrophilic.
(2), due to containing more Hydrophilicrto polyether segment in molecule, synthetic fibers are given and wool fiber molecule is good
Hydrophilic, while significantly increasing reactivity and flexibility, persistency is high.
(3) during, finishing agent of the present invention is to wool fiber arrangement, in neutral conditions just can be with wool fiber molecule
On carboxyl there is complexation reaction, and in the form of complex absorption in wool surface, persistency is high.
(4) thin film with flame retardant effect is formed after being crosslinked with fiber during, the present invention is arranged to synthetic fibers
Absorption reaches more excellent flame retardant effect on synthetic fibers surface.
(5), finishing agent of the present invention can also give fabric certain antibacterial effect after arranging, the effect be by with fabric table
Face forms thin film class material and prevents microorganism from permeating to fabric as barrier, reaches antibacterial purpose, while can also enter
One step suppresses the growth of microbial bacterial further to prevent which from breeding.
(6), thermal-reactive soluble polyurethane finishing agent of the present invention apply as Pilus Caprae seu Oviss, silk fabric wrinkle resistant, anti-
Contracting processing；Wrinkle resistant, the shrink-resistant finish of cotton, linen can be used as；The lasting water suction as synthetic fibers such as terylene is applied to resist
Electrostatic is arranged, and there is persistency (patience) with various auxiliary agents and with the performance for making fabric after process.
(7), thermal-reactive soluble polyurethane finishing agent of the present invention can make fabric thicken sense, richness, elastic good, tool
There is certain hanging degree, be suitable for dimensionally stable, machine washable, the processing of the functional clothing fabric such as non-ironing.
Specific embodiment：
In order to be better understood from the present invention, below by embodiment, the present invention is further described, and embodiment is served only for solving
The present invention is released, any restriction will not be constituted to the present invention.
Embodiment 1
A kind of water solublity thermal-reactive polyurethane hydrophilic, fire-retardant, antibacterial finishing agent, are grouped by the group of following parts by weight
Into：
Water solublity thermal-reactive polyurethane：15 parts；
Aceglutamide：0.1 part；Glycerol：2 parts.
The water solublity thermal-reactive polyurethane with isophorone diisocyanate, N methyldiethanol amine, polypropylene glycol-
2000 is primary raw material, is synthesized with methyl ethyl ketoxime as end-capping reagent.
The hydrophilic, fire-retardant of the synthetic fabrics, the arrangement formula of liquid of antibiotic finish are：
Embodiment 2
A kind of water solublity thermal-reactive polyurethane hydrophilic, fire-retardant, antibacterial finishing agent, are grouped by the group of following parts by weight
Into：
Water solublity thermal-reactive polyurethane：20 parts；
Aceglutamide：10 parts；Glycerol：12 parts.
The water solublity thermal-reactive polyurethane with isophorone diisocyanate, N methyldiethanol amine, polypropylene glycol-
2000 is primary raw material, is synthesized with methyl ethyl ketoxime as end-capping reagent.
Embodiment 3
A kind of water solublity thermal-reactive polyurethane hydrophilic, fire-retardant, antibacterial finishing agent, are grouped by the group of following parts by weight
Into：
Water solublity thermal-reactive polyurethane：15 parts；
Aceglutamide：0.5 part；Glycerol：4.0 part.
The water solublity thermal-reactive polyurethane is that polyethers obtains base polyurethane prepolymer for use as with isocyanates reaction, then with sulfurous
Sour hydrogen sodium is synthesized with prepolymer reaction as sealer.
The hydrophilic, fire-retardant of the synthetic fabrics, the arrangement formula of liquid of antibiotic finish are：
Embodiment 4
A kind of water solublity thermal-reactive polyurethane hydrophilic, fire-retardant, antibacterial finishing agent, are grouped by the group of following parts by weight
Into：
Water solublity thermal-reactive polyurethane：18 parts；
Aceglutamide：1.2 part；Glycerol：9.0 part.
The water solublity thermal-reactive polyurethane is that polyethers obtains base polyurethane prepolymer for use as with isocyanates reaction, then with sulfurous
Sour hydrogen sodium is synthesized with prepolymer reaction as sealer.
Embodiment 5
A kind of water solublity thermal-reactive polyurethane hydrophilic, fire-retardant, antibacterial finishing agent, are grouped by the group of following parts by weight
Into：
Water solublity thermal-reactive polyurethane：15 parts；
Aceglutamide：1.2 part；Glycerol：4.0 part.
The water solublity thermal-reactive polyurethane is F-2840E.
Embodiment 6
A kind of water solublity thermal-reactive polyurethane hydrophilic, fire-retardant, antibacterial finishing agent, are grouped by the group of following parts by weight
Into：
Water solublity thermal-reactive polyurethane：18 parts；
Aceglutamide：0.5 part；Glycerol：9.0 part.
The water solublity thermal-reactive polyurethane is F-2840E.
Embodiment 7
A kind of water solublity thermal-reactive polyurethane hydrophilic, fire-retardant, antibacterial finishing agent, are grouped by the group of following parts by weight
Into：
Water solublity thermal-reactive polyurethane：17 parts；
Aceglutamide：0.8 part；Glycerol：7.0 part.
The water solublity thermal-reactive polyurethane with isophorone diisocyanate, N methyldiethanol amine, polypropylene glycol-
2000 is primary raw material, is synthesized with methyl ethyl ketoxime as end-capping reagent.
Comparative example 1
Conventional urethane class hydrophilic finishing agent
Water solublity thermal-reactive polyurethane：16 parts；
Catalyst：0.5 part；NaHCO3(1% solution)：3.2 part.
The water solublity thermal-reactive polyurethane with isophorone diisocyanate, N methyldiethanol amine, polypropylene glycol-
2000 is primary raw material, is synthesized with methyl ethyl ketoxime as end-capping reagent.
Comparative example 2
Polyurethaness hydrophilic finishing agent
Water solublity thermal-reactive polyurethane：17 parts；Glycerol：7.0 part.
The water solublity thermal-reactive polyurethane with isophorone diisocyanate, N methyldiethanol amine, polypropylene glycol-
2000 is primary raw material, is synthesized with methyl ethyl ketoxime as end-capping reagent.
Comparative example 3
Polyurethaness hydrophilic finishing agent
Water solublity thermal-reactive polyurethane：17 parts；Aceglutamide：0.8 part.
The water solublity thermal-reactive polyurethane with isophorone diisocyanate, N methyldiethanol amine, polypropylene glycol-
2000 is primary raw material, is synthesized with methyl ethyl ketoxime as end-capping reagent.
During above-mentioned hydrophilic finishing agent is applied to the arrangement of synthetic fibers or wool fabric.
Application one：The hydrophilic finiss of synthetic fibers：
Arranging formula of liquid is：
Embodiment and comparative example finishing agent 10g, water 1000g；Bath raio is 1:30；
Finishing technique is：
Pad, dry, baking, padding, baking, hot water wash, drying.
Application two：The hydrophilic finiss of wool fabric
Arranging formula of liquid is：
Embodiment and comparative example finishing agent 20g, water 1000g；Bath raio is 1:30；
Finishing technique is：
Pad, dry, baking, hot water wash, drying.
Table one：The hydrophilic (synthetic fibers) of fabric after arrangement
Table two：The hydrophilic (wool fiber) of fabric after arrangement
Table three：Flame retardant effect after finishing agent application
Table four：To escherichia coli and the suppression ratio of staphylococcus aureuses after finishing agent application
Synthetic fibers and wool fabric after finishing agent described in the embodiment of the present invention is arranged are respectively provided with good
Hydrophilic, compared with comparative example one (conventional urethane hydrophilic finishing agent), with anti-flammability and biocidal property, with comparative example two and right
Ratio three is compared, with extremely excellent hydrophilicity.
Claims (7)
1. a kind of water solublity thermal-reactive polyurethane hydrophilic, fire-retardant, antibacterial finishing agent, it is characterised in that by following parts by weight
Group be grouped into：
Water solublity thermal-reactive polyurethane：15-20 parts；
Aceglutamide：0.1-10 parts；Glycerol：2-12 parts.
2. a kind of water solublity thermal-reactive polyurethane hydrophilic according to claim 1, fire-retardant, antibacterial finishing agent, its feature
It is, is grouped into by the group of following parts by weight：
Water solublity thermal-reactive polyurethane：15-18 parts；
Aceglutamide：0.5-1.2 parts；Glycerol：4.0-9.0 part.
3. a kind of water solublity thermal-reactive polyurethane hydrophilic according to claim 1 and 2, fire-retardant, antibacterial finishing agent, its are special
Levy and be：The water solublity thermal-reactive polyurethane with isophorone diisocyanate, N methyldiethanol amine, polypropylene glycol-
2000 is primary raw material, is synthesized with methyl ethyl ketoxime as end-capping reagent.
4. a kind of water solublity thermal-reactive polyurethane hydrophilic according to claim 1 and 2, fire-retardant, antibacterial finishing agent, its are special
Levy and be：The water solublity thermal-reactive polyurethane is that polyethers obtains base polyurethane prepolymer for use as with isocyanates reaction, then with sulfurous
Sour hydrogen sodium is synthesized with prepolymer reaction as sealer.
5. a kind of water solublity thermal-reactive polyurethane hydrophilic according to claim 1 and 2, fire-retardant, antibacterial finishing agent, its are special
Levy and be：The water solublity thermal-reactive polyurethane is F-2840E.
6. a kind of water solublity thermal-reactive polyurethane hydrophilic described in claim 1 or 2, fire-retardant, antibacterial finishing agent are applied to close
Into fabric or hydrophilic, fire-retardant, the antibiotic finish process of wool fabric.
7. a kind of water solublity thermal-reactive polyurethane hydrophilic, the application of fire-retardant, antibacterial finishing agent according to claim 6, its
It is characterised by：
The hydrophilic, fire-retardant of the synthetic fabrics, the arrangement formula of liquid of antibiotic finish are：
Water solublity thermal-reactive polyurethane hydrophilic, fire-retardant, antibacterial finishing agent 10-20g, water 1000g；Bath raio is 1:30；
The hydrophilic, fire-retardant of the synthetic fibers, the finishing technique of antibiotic finish are：
Pad, dry, baking, padding, baking, hot water wash, drying；
The hydrophilic, fire-retardant of the wool fabric, the arrangement formula of liquid of antibiotic finish are：
Water solublity thermal-reactive polyurethane hydrophilic, fire-retardant, antibacterial finishing agent 20-50g, water 1000g；Bath raio is 1:30；
The hydrophilic, fire-retardant of the wool fabric, the finishing technique of antibiotic finish are：
Pad, dry, baking, hot water wash, drying.
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| CN201610944526.4A CN106498749A (en) | 2016-11-02 | 2016-11-02 | A kind of water solublity thermal-reactive polyurethane hydrophilic, fire-retardant, antibacterial finishing agent and its application |
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Cited By (1)
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| CN108424502A (en) * | 2018-02-27 | 2018-08-21 | 合肥微晶材料科技有限公司 | A kind of multifunctional monomer and the low square resistance flexible transparent conducting film based on it |
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| CN105113255A (en) * | 2015-09-07 | 2015-12-02 | 杭州美高华颐化工有限公司 | Organosilicone modification polyurethane color fixing agent and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108424502A (en) * | 2018-02-27 | 2018-08-21 | 合肥微晶材料科技有限公司 | A kind of multifunctional monomer and the low square resistance flexible transparent conducting film based on it |
| CN108424502B (en) * | 2018-02-27 | 2020-06-16 | 合肥微晶材料科技有限公司 | Multifunctional monomer and low-sheet-resistance flexible transparent conductive film based on same |
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