CN106496911A - A kind of artificial grass filaments wear-resisting functions master batch, its preparation method and application - Google Patents
A kind of artificial grass filaments wear-resisting functions master batch, its preparation method and application Download PDFInfo
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- CN106496911A CN106496911A CN201611122446.7A CN201611122446A CN106496911A CN 106496911 A CN106496911 A CN 106496911A CN 201611122446 A CN201611122446 A CN 201611122446A CN 106496911 A CN106496911 A CN 106496911A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/44—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
- D01F6/46—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polyolefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Textile Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
The invention belongs to new material technology field, and in particular to a kind of artificial grass filaments wear-resisting functions master batch and preparation method thereof, master batch of the present invention are made up of grafted material and catalyst material two parts, and grafted material includes following components in parts by mass：70 99 parts of polyvinyl resin, 0.01 10 parts of initiator initiator, 1 10 parts of silane coupler, 0.01 10 parts of antioxidant, catalyst material includes following components in parts by mass：80 99 parts of polyvinyl resin, 0.1 10 parts of catalyst, 0.1 10 parts of antioxidant.Using two step method, grafted material and catalyst material is first prepared, then by grafted material material and catalyst material by a certain percentage through screw extruder pelletize, soak certain time in uniform temperature water-bath, be drying to obtain wear-resisting functions master batch.Wear-resisting functions master batch prepared by the present invention, is added in careless silk matrix, can significantly increase the anti-wear performance of grass fiber, intensity, tear resistance, fatigue performance etc..
Description
Technical field
The present invention relates to new material technology field, and in particular to a kind of artificial grass filaments functional agglomerate, and it is related to the master batch
Preparation method and application.
Background technology
Artificial turf fiber is the core material on artificial motion lawn, its performance determine motion lawn mechanical property,
Sports safety performance and motion comfort property.At present, artificial turf fiber main material be polymer, with desirable physical,
While chemical property, have that case hardness is low, bearing capacity is low, under the conditions of high-strength frequency usage, easy to wear, there is grass
The phenomenons such as silk jag, tear, easily cause danger, are unfavorable for the development of blue-ribbon event.Therefore, abrasion resistance properties have become appraiser
An of paramount importance index of turf quality is made, before it is safety and the quality stability for ensureing artificial motion lawn
Carry.
Based on the research of artificial grass filaments abrasion resistance properties, focus primarily upon that careless silk raw material is modified and careless silk shape changes
Become, as patent application CN101476174A and patent application CN102493011A improves careless silk by adding inorganic rigid particle
Intensity, but inorganic particulate agglomeration is serious, cause to disperse in matrix resin uneven, so as to cause on the wear rate of careless silk
Rise, greatly reduce the polishing machine and stability on motion lawn.And patent application CN105019333A passes through to prepare careless silk
Into S-shaped, contact area increases, and plays a part of to a certain extent to buffer dispersive pressure, but as contact area is big, careless silk table
Face causes coefficient of friction little compared with smooth, and athlete easily slips in motor process, therefore, is unfavorable for the development that moves, reduces grass
The security performance on level ground.
Content of the invention
Therefore, above-mentioned artificial grass filaments shortcoming easy to wear, the technical problem to be solved in the present invention are, there is provided a kind of artificial
Careless silk wear-resisting functions master batch, the artificial grass filaments with the master batch manufacture are wear-resisting and anti-skidding.Simultaneously, there is provided the preparation method of the master batch,
In addition, additionally providing the application of the master batch.
The technical scheme is that, a kind of artificial grass filaments wear-resisting functions master batch, the master batch includes grafted material 80-99 weights
Amount part and catalyst material 1-20 weight portion；
The grafted material includes following components in parts by mass：
Polyvinyl resin：70-99 parts
Initiator：0.01-10 parts
Silane coupler：1-10 parts
Antioxidant：0.01-10 parts；
The catalyst material includes following components in parts by mass：
Polyvinyl resin：80-99 parts
Catalyst：0.1-10 parts
Antioxidant：0.1-10 parts.
According to a kind of artificial grass filaments wear-resisting functions master batch of the present invention, it is preferred that the polyvinyl resin is high density
One or more in polyethylene, Low Density Polyethylene, linear low density polyethylene (LLDPE), polyethylene melt index are 0.3-30；
The initiator is the double tert-butyl peroxy base diisopropylbenzene (DIPB)s of α-α, di-tert-butyl peroxide, cumyl peroxide,
One or more in benzoyl peroxide；
It is vinyltrimethoxy silane, vinyl triethoxyl silicon that the silane coupler is the silane coupler
One kind in alkane, vinyl dimethylethoxysilane, four dimethyl ethenyl Siloxysilanes, dimethyl divinyl silane
Or it is multiple；
The antioxidant is one or more in Hinered phenols, phosphorous acid esters and thio-2 acid dibasic acid esters.
According to a kind of artificial grass filaments wear-resisting functions master batch of the present invention, it is preferred that the catalyst includes dibutyl two
Tin laurate, carboxylic acid stannum, moon silicic acid dibutyitin maleate, tin dilaurate di-n-octyl, organic acid and nonhygroscopic metal oxygen
One or more in the condensation catalyst of compound, esters peroxide and nonhygroscopic metal-oxide composition.
Further, the one kind of the organic acid in stearic acid, ethanedioic acid；The nonhygroscopic metal-oxide choosing
One kind in autoxidation zinc, Tin monoxide；The esters peroxide is selected from the own ester of tert-butyl hydroperoxide 3,5,5- trimethyls, mistake
One kind in the acetic oxide tert-butyl ester；The one kind of the nonhygroscopic metal-oxide in zinc oxide, Tin monoxide.
Present invention also offers the preparation method of above-mentioned artificial grass filaments wear-resisting functions master batch, comprises the following steps：
(1) polyvinyl resin, initiator, silane coupler, antioxidant are placed in high-speed mixer and are mixed at room temperature
Uniformly, by the material of mix homogeneously through screw extruder pelletize, dry；
(2) polyvinyl resin, catalyst, antioxidant are placed in high-speed mixer mix homogeneously at room temperature, will mixing
Uniform material is dried through screw extruder pelletize；
(3) by grafted material 80-99 weight portions and catalyst material 1-20 weight portion mix homogeneously, through screw extruder pelletize,
1-60h is soaked in 28-98 DEG C of water-bath, be drying to obtain artificial grass filaments wear-resisting functions master batch.
According to the preparation method of artificial grass filaments wear-resisting functions master batch of the present invention, it is preferred that in step (3), water-bath
Temperature is 30-90 DEG C；The soak time is 2-48h.
According to the preparation method of artificial grass filaments wear-resisting functions master batch of the present invention, it is preferred that in step (1), (2) and (3),
The baking temperature is 50-100 DEG C.
According to the preparation method of artificial grass filaments wear-resisting functions master batch of the present invention, it is preferred that in step (1), (2) and (3),
The drying time is 2-24h.
According to the preparation method of artificial grass filaments wear-resisting functions master batch of the present invention, it is preferred that in step (1), (2), described
The mixed at room temperature time is 3-30min；The screw machine is double screw extruder.
Further, the twin screw is in 140-220 DEG C of melting extrusion pelletize.
Present invention also offers application of the above-mentioned artificial grass filaments master batch in artificial grass filaments field.
Wear-resisting functions master batch prepared by the present invention is mainly used in artificial grass filaments, is added in careless silk formula by a certain percentage.
As organosilane crosslinked polyethylene causes Hi-fax to be cross-linked into effective tridimensional network in master batch, become the motion of strand
Difficult, so as to improve the abrasion resistance properties of material, mechanical property, ageing resistace.
Artificial grass filaments matrix formulation of the present invention includes following components in parts by mass：
LLDPE resins：50-95 parts
Masterbatch：2-15 parts
Processing aid：0.1-10 parts
Wear-resisting functions master batch：1-30 parts
The abrasion-resistant polishing machine of artificial grass filaments is caused in concrete artificial grass filaments formula due to adding wear-resisting functions master batch
Strengthen, because wear-resistant masterbatch is crosslinked with silicane LLDPE, good with the artificial grass filaments matrix resin LLDPE compatibilitys, due to wear-resisting mother
Grain is partial cross-linked three-dimensional network stereochemical structure, is favorably improved the intensity of careless silk, the opposing modeling that high load capacity friction is produced repeatedly
Property deformation, therefore, the addition of wear-resisting functions master batch improves the performance of artificial grass filaments, particularly friction and wear behavior.
The artificial grass filaments wear-resistant masterbatch of the present invention, its anti-wear performance are characterized by coefficient of friction and abrasion loss,
Coefficient of friction 0.62-0.80, abrasion loss scope 0.1-10, from abrasion loss can direct judgement material anti-wear performance quality, rub
Coefficient increase is wiped, illustrates that frictional force increases, non-skid property is improved.
Polyethylene molecule is long-chain linear structure or branched structure, has good processing fluidity, but hardness is not enough, resist compacted
Degeneration is poor.Therefore, artificial turf fiber, preferably, surface is more smooth for compliance.But artificial turf fiber case hardness is low, holds
Loading capability is poor, in heavy duty repeatedly friction process is susceptible to plastic deformation, easily produces adhesive wear.Therefore, material wear-resistant
Poor-performing.
As crosslinked with silicane defines new-Si-O- chemical bonds, the shape of three-dimensional network stereochemical structure between polyethylene molecule
Into the ability that improve polyethylene opposing deformation and plow, in friction process occur due to local friction's heat accumulation material
Soften adherent phenomenon to mitigate, anti-wear performance is improved, on the one hand as polyethylene is partial cross-linked so that material surface hardness is improved,
Surface roughness is improved, and coefficient of friction increases, and plays anti-skidding effect well to a certain extent.
Artificial grass filaments wear-resisting functions master batch prepared by the present invention, based on polyvinyl resin, with artificial grass filaments matrix tree
The fat linear low density polyethylene (LLDPE) compatibility is good, hence it is evident that improve the abrasion resistance properties and physical and mechanical property of careless silk.
The master batch passes through to introduce-Si-O- groups in polyethylene, forms it into tridimensional network under certain condition,
The sliding of strand is limited, the not enough shortcoming of creep is overcome, is added in careless silk matrix formulation, drastically increases artificial
The abrasion resistance properties and physical and mechanical property of careless silk, and environmentally safe, long service life.
Specific embodiment
With reference to specific embodiment, the present invention is described in further detail, and embodiment is served only for explaining this
Bright, any restriction is not constituted to the present invention.
Embodiment 1
A kind of artificial grass filaments wear-resisting functions master batch and preparation method thereof, comprises the following steps：
The preparation of artificial grass filaments wear-resisting functions master batch grafted material, comprises the following steps：
(1) in parts by mass
97 parts of linear low density polyethylene (LLDPE)
0.2 part of cumyl peroxide
3 parts of vinylethoxysilane
0.05 part of antioxidant；
(2) linear low density polyethylene (LLDPE), cumyl peroxide, vinylethoxysilane are added high-speed mixer
In, room temperature mixing 5min；The material of above-mentioned mix homogeneously is added in double screw extruder, melt pelletization, each section of temperature of extruder
Degree is respectively：150 DEG C, 165 DEG C, 170 DEG C, 175 DEG C, rotating speed 30r/min, 100 DEG C dry 6h, and grafted material is obtained；
The preparation of artificial grass filaments wear-resisting functions masterbatch catalyst material, comprises the following steps：
(1) in parts by mass
99 parts of linear low density polyethylene (LLDPE)
1 part of dibutyl tin dilaurate
0.2 part of antioxidant；
(2) linear low density polyethylene (LLDPE), dibutyl tin dilaurate, antioxidant are placed in high-speed mixer, room temperature is mixed
Close 5min；The material of above-mentioned mix homogeneously is added in double screw extruder, melt pelletization, each section of temperature of extruder are respectively：
150 DEG C, 165 DEG C, 170 DEG C, 175 DEG C, rotating speed 30r/min, 100 DEG C dry 6h, and catalyst material is obtained；
Artificial grass filaments wear-resisting functions master batch and preparation method thereof, including in parts by mass, 95 parts of grafted material, catalyst material 5
Part, melting mixing pelletize；Above-mentioned pellet being placed in 12h in the water-bath that temperature is 80 DEG C, being taken out and 6h is dried at 100 DEG C, people is obtained
Make careless silk wear-resisting functions master batch.
Embodiment 2
A kind of artificial grass filaments wear-resisting functions master batch and preparation method thereof, including the preparation of grafted material and catalyst material, prepares
Step is as described above, including in parts by mass, above-mentioned pellet is put by 90 parts of grafted material, 10 parts of catalyst material, melting mixing pelletize
9h in the water-bath that temperature is 70 DEG C, takes out and dries 6h at 100 DEG C, and artificial grass filaments wear-resisting functions master batch is obtained.
Embodiment 3
A kind of artificial grass filaments wear-resisting functions master batch and preparation method thereof, comprises the following steps：
The preparation of artificial grass filaments wear-resisting functions master batch grafted material, comprises the following steps：
(1) in parts by mass
95 parts of linear low density polyethylene (LLDPE)
0.2 part of cumyl peroxide
5 parts of vinylethoxysilane
0.05 part of antioxidant；
(2) linear low density polyethylene (LLDPE), cumyl peroxide, vinylethoxysilane are added high-speed mixer
In, room temperature mixing 5min；The material of above-mentioned mix homogeneously is added in double screw extruder, melt pelletization, each section of temperature of extruder
Degree is respectively：150 DEG C, 165 DEG C, 170 DEG C, 175 DEG C, rotating speed 30r/min, 100 DEG C dry 6h, and grafted material is obtained；
The preparation of artificial grass filaments wear-resisting functions masterbatch catalyst material, comprises the following steps：
(1) in parts by mass
98 parts of linear low density polyethylene (LLDPE)
2 parts of dibutyl tin dilaurate
0.2 part of antioxidant；
(2) linear low density polyethylene (LLDPE), dibutyl tin dilaurate, antioxidant are placed in high-speed mixer, room temperature is mixed
Close 5min；The material of above-mentioned mix homogeneously is added in double screw extruder, melt pelletization, each section of temperature of extruder are respectively：
150 DEG C, 165 DEG C, 170 DEG C, 175 DEG C, rotating speed 30r/min, 100 DEG C dry 6h, and catalyst material is obtained；
Artificial grass filaments wear-resisting functions master batch and preparation method thereof, including in parts by mass, 95 parts of grafted material, catalyst material 5
Part, melting mixing pelletize；Above-mentioned pellet being placed in 12h in the water-bath that temperature is 80 DEG C, being taken out and 6h is dried at 100 DEG C, people is obtained
Make careless silk wear-resisting functions master batch.
Embodiment 4
A kind of artificial grass filaments wear-resisting functions master batch and preparation method thereof, including the preparation of grafted material and catalyst material, prepares
Step is as described above, including in parts by mass, above-mentioned pellet is put by 90 parts of grafted material, 10 parts of catalyst material, melting mixing pelletize
9h in the water-bath that temperature is 70 DEG C, takes out and dries 6h at 100 DEG C, and artificial grass filaments wear-resisting functions master batch is obtained.
Above-mentioned obtained wear-resistant masterbatch vulcanizing press 15MPa molding 10min are prepared sample, resistance to for use in doing
Mill performance detection.Method of testing is：The sample that master batch is made 22 × 14 × 2mm, then tests through the abrasion examination of high-speed loop block
Test machine under certain loads, emery wheel rotates the coefficient of friction after 2000 times and abrasion loss (mass decrement before and after abrasion) to represent,
Unit g/kg.
Comparative example
Type low density polyethylene resin is prepared sample according to the method described above, its coefficient of friction and abrasion loss is tested.
Testing result is as follows
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Comparative example | |
| Coefficient of friction | 0.68 | 0.70 | 0.71 | 0.71 | 0.62 |
| Abrasion loss | 3.26 | 0.51 | 0.32 | 0.48 | 25.29 |
Thus, it will be seen that the present invention substantially reduces compared with comparative example in abrasion loss, anti-wear performance is greatly enhanced, friction system
Number has increased compared with comparative example, contributes to anti-skidding.
Above-described embodiment, simply section Example of the invention, is not used for limiting the scope of the present invention, therefore all with this
Equivalence changes or modification that the feature and principle of invention claim is done, all should be included within the scope of the invention as claimed.
Claims (10)
1. a kind of artificial grass filaments wear-resisting functions master batch, it is characterised in that：The master batch includes grafted material 80-99 weight portions and catalysis
Agent material 1-20 weight portions；
The grafted material includes following components in parts by mass：
Polyvinyl resin：70-99 parts
Initiator：0.01-10 parts
Silane coupler：1-10 parts
Antioxidant：0.01-10 parts；
The catalyst material includes following components in parts by mass：
Polyvinyl resin：80-99 parts
Catalyst：0.1-10 parts
Antioxidant：0.1-10 parts.
2. a kind of artificial grass filaments wear-resisting functions master batch according to claim 1, it is characterised in that：The polyvinyl resin is
One or more in high density polyethylene (HDPE), Low Density Polyethylene, linear low density polyethylene (LLDPE), polyethylene melt index are 0.3-
30；
The initiator is the double tert-butyl peroxy base diisopropylbenzene (DIPB)s of α-α, di-tert-butyl peroxide, cumyl peroxide, peroxide
Change one or more in benzoyl；
It is vinyltrimethoxy silane, VTES, second that the silane coupler is the silane coupler
One kind or many in thiazolinyl dimethylethoxysilane, four dimethyl ethenyl Siloxysilanes, dimethyl divinyl silane
Kind；
The antioxidant is one or more in Hinered phenols, phosphorous acid esters and thio-2 acid dibasic acid esters.
3. a kind of artificial grass filaments wear-resisting functions master batch according to claim 1, it is characterised in that：The catalyst includes two
Butyl tin dilaurate stannum, carboxylic acid stannum, moon silicic acid dibutyitin maleate, tin dilaurate di-n-octyl, organic acid and nonhygroscopic
One or more in the condensation catalyst of metal-oxide, esters peroxide and nonhygroscopic metal-oxide composition.
4. a kind of artificial grass filaments wear-resisting functions master batch according to claim 3, it is characterised in that：The organic acid is selected from hard
One kind in fat acid, ethanedioic acid；The one kind of the nonhygroscopic metal-oxide in zinc oxide, Tin monoxide；The ester
The one kind of class peroxide in the own ester of tert-butyl hydroperoxide 3,5,5- trimethyls, peroxide acetic acid butyl ester；Described do not inhale
The one kind of wet metal-oxide in zinc oxide, Tin monoxide.
5. the preparation method of a kind of artificial grass filaments wear-resisting functions master batch described in claim 1, it is characterised in that：Including following step
Suddenly：
(1) polyvinyl resin, initiator, silane coupler, antioxidant are placed in high-speed mixer mix homogeneously at room temperature,
By the material of mix homogeneously through screw extruder pelletize, dry；
(2) polyvinyl resin, catalyst, antioxidant are placed in high-speed mixer mix homogeneously at room temperature, by mix homogeneously
Material through screw extruder pelletize, dry；
(3) by grafted material 80-99 weight portions and catalyst material 1-20 weight portion mix homogeneously, through screw extruder pelletize, in 28-
1-60h is soaked in 98 DEG C of water-baths, be drying to obtain artificial grass filaments wear-resisting functions master batch.
6. the preparation method of a kind of artificial grass filaments wear-resisting functions master batch according to claim 5, it is characterised in that：The step
Suddenly, in (3), bath temperature is 30-90 DEG C；It is 2-48h the times that the soak time is.
7. the preparation method of a kind of artificial grass filaments wear-resisting functions master batch according to claim 5, it is characterised in that：Step
(1), in (2) and (3), the baking temperature is 50-100 DEG C；In step (1), (2) and (3), the drying time is 2-24h.
8. the preparation method of a kind of artificial grass filaments wear-resisting functions master batch according to claim 5, it is characterised in that：Step
(1), in (2), the mixed at room temperature time is 3-30min；The screw machine is double screw extruder.
9. the preparation method of a kind of artificial grass filaments wear-resisting functions master batch according to claim 8, it is characterised in that：Described double
Screw rod is in 140-220 DEG C of melting extrusion pelletize.
10. application of the artificial grass filaments master batch in artificial grass filaments field described in claim 1.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201611122446.7A CN106496911B (en) | 2016-12-08 | 2016-12-08 | Artificial grass wear-resistant functional master batch, and preparation method and application thereof |
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| CN201611122446.7A CN106496911B (en) | 2016-12-08 | 2016-12-08 | Artificial grass wear-resistant functional master batch, and preparation method and application thereof |
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| CN106496911B CN106496911B (en) | 2020-03-24 |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108976689A (en) * | 2018-07-30 | 2018-12-11 | 界首市鑫龙机械设备购销有限公司 | A kind of preparation method of the crosslinked with silicane wear-resistant masterbatch of treated basalt fiber-whisker reinforcement |
| CN108977916A (en) * | 2018-08-07 | 2018-12-11 | 江苏联创人造草坪股份有限公司 | A kind of high temperature resistant chinampa and preparation method thereof |
| CN110628124A (en) * | 2019-10-15 | 2019-12-31 | 江苏联创人造草坪股份有限公司 | Weather-resistant flame-retardant artificial grass filament and preparation method thereof |
| CN114133654A (en) * | 2021-12-17 | 2022-03-04 | 广州爱奇实业有限公司 | Polyethylene composition, preparation method and application thereof |
| CN117431661A (en) * | 2023-11-02 | 2024-01-23 | 河北赛恩塑业有限公司 | Suspension type spliced lawn |
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| GB1346588A (en) * | 1970-10-14 | 1974-02-13 | Dow Corning Ltd | Cross linked polyolefin sheets and films and the preparation thereof |
| CN102493011A (en) * | 2011-11-14 | 2012-06-13 | 泰山体育产业集团有限公司 | Wear-resistant artificial turf fiber |
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2016
- 2016-12-08 CN CN201611122446.7A patent/CN106496911B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1346588A (en) * | 1970-10-14 | 1974-02-13 | Dow Corning Ltd | Cross linked polyolefin sheets and films and the preparation thereof |
| CN102493011A (en) * | 2011-11-14 | 2012-06-13 | 泰山体育产业集团有限公司 | Wear-resistant artificial turf fiber |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108976689A (en) * | 2018-07-30 | 2018-12-11 | 界首市鑫龙机械设备购销有限公司 | A kind of preparation method of the crosslinked with silicane wear-resistant masterbatch of treated basalt fiber-whisker reinforcement |
| CN108977916A (en) * | 2018-08-07 | 2018-12-11 | 江苏联创人造草坪股份有限公司 | A kind of high temperature resistant chinampa and preparation method thereof |
| CN110628124A (en) * | 2019-10-15 | 2019-12-31 | 江苏联创人造草坪股份有限公司 | Weather-resistant flame-retardant artificial grass filament and preparation method thereof |
| CN114133654A (en) * | 2021-12-17 | 2022-03-04 | 广州爱奇实业有限公司 | Polyethylene composition, preparation method and application thereof |
| CN117431661A (en) * | 2023-11-02 | 2024-01-23 | 河北赛恩塑业有限公司 | Suspension type spliced lawn |
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| Publication number | Publication date |
|---|---|
| CN106496911B (en) | 2020-03-24 |
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