CN106495648A - Anion infrared-emitting materials and its manufacture method and application - Google Patents
Anion infrared-emitting materials and its manufacture method and application Download PDFInfo
- Publication number
- CN106495648A CN106495648A CN201610977465.1A CN201610977465A CN106495648A CN 106495648 A CN106495648 A CN 106495648A CN 201610977465 A CN201610977465 A CN 201610977465A CN 106495648 A CN106495648 A CN 106495648A
- Authority
- CN
- China
- Prior art keywords
- emitting materials
- infrared
- anion
- anion infrared
- present
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B30/00—Compositions for artificial stone, not containing binders
Abstract
The invention discloses a kind of anion infrared-emitting materials and its manufacture method and application.Anion infrared-emitting materials of the present invention include that the composition of following mass percent has：Aluminum oxide 34 36%, silica 33 35%, diboron trioxide 10 12%, magnesia 4 6%, di-iron trioxide 7 9%, sodium oxide molybdena 0.5 1.5%, potassium oxide 0.01 0.08%, calcium oxide 0.3 0.5%, phosphorus pentoxide 0.1 0.4%, titanium dioxide 0.4 0.7%, ferrous oxide 1 2%, zinc oxide 1.5 3%, yittrium oxide 0.3 0.5%, zirconium dioxide 0.1 0.3%.Anion infrared-emitting materials of the present invention have launches strong anion and infrared characteristic at small temperature and pressure change.
Description
Technical field
The invention belongs to inorganic functional material technical field, and in particular to a kind of anion infrared-emitting materials and its manufacture
Methods and applications.
Background technology
Medically, after negative oxygen ion enters blood, cytoactive can be strengthened, the biography of the electrolyte such as Na, K and waste
Frequency that is defeated, exchanging can also be accelerated, and make internal ion keep balance, so as to improve vis medicatrix naturae and the immunity of human body, while
Activation parasympathetic nerve, makes one ataraxia, drop in blood pressure, mood and is loosened.Appropriate negative oxygen ion is sucked daily to strong
Health is of great advantage.Negative aeroion is a kind of negatively charged gas ion in air.Various gas componants in air are not complete
It is exist with molecular path entirely, a portion is present with the free state of ion.Wherein electronegative molecule or particulate (custom
Claim anion) human body synthesis and vitamin storage can be facilitated, strengthen the physiological activity with human activin, to human body and other biological
Vital movement have highly important impact, therefore it is otherwise known as " air vitamin ", with depositing dust, sterilizing and physiology
The functions such as health care.
Infrared ray is a kind of electromagnetic wave between visible ray and microwave, and wavelength is between 0.76～1000 micron.Its
Medium wavelength is the most beneficial to human body in the far infrared of 4～15 micron wavebands.Energy after the far infrared of absorption of human body this wave band
Thermogenetic effect is produced in subcutaneous 3～5 centimetres of depths, is activated the hydrone in cell tissue, in upper state, is contributed to
The synthesis of biology enzyme, therefore can strengthen body's immunity and power of regeneration, expand capillary, improve microcirculation, promote new
Old metabolism and blood flow.
At present, people also possess some special knowledge to anion infrared-emitting materials, summarize existing anion infrared-emitting materials,
But due to the functional component species and content proportioning of existing anion infrared-emitting materials, science does not cause its generally existing remote
Infrared and negative-ion energy is weak.
Content of the invention
It is an object of the invention to overcoming the shortcomings of that above-mentioned prior art is present, there is provided a kind of anion infrared-emitting materials
And its prepare, to solve existing anion infrared-emitting materials due to its composition species and content not science and caused far infrared
The technical problem weak with negative-ion energy.
In order to realize foregoing invention purpose, one aspect of the present invention, there is provided a kind of anion infrared-emitting materials.Described negative
Ion infrared-emitting materials include the composition of following mass percent：
A kind of another aspect of the present invention, there is provided preparation method of anion infrared-emitting materials.The preparation method bag
Include following steps：
Each component materials are weighed respectively in proportion according to the composition contained by anion infrared-emitting materials of the present invention；
Carry out after mixing treatment, carrying out ultra-fine grinding process by each component materials for weighing.
The another aspect of the embodiment of the present invention, there is provided the range of application of the invention described above anion infrared-emitting materials.This
Invention anion infrared-emitting materials environmental protection, cigarette, coating, weaving, cosmetics, purify water, purify air, anti-electromagnetism spoke
Penetrate, the application in health products.
Compared with prior art, anion infrared-emitting materials of the present invention by contained with pyroelectricity and piezoelectricity
Composition proportion so that interact between each functional component crystal, therefore, in the environment of small temperature and pressure change,
The electrical potential difference between composition crystal can be caused, so that air occurs ionization and distributes far infrared and negative aeroion, produced
The strong negative oxygen ion of life.In addition, anion infrared-emitting materials of the present invention contain with the oxygen-containing sodium iron being characterized, magnalium silicon boron ring
The silicate material of shape structure, isomorph are developed, tool pyroelectricity and voltage endurance, polar ion is vibrated in equilbrium position and is drawn
Play dipole moment change and produce far infrared.Therefore, anion infrared-emitting materials of the present invention have and become in small temperature and pressure
Change the strong anion of lower transmitting and infrared characteristic.
Anion infrared-emitting materials preparation method of the present invention passes through for contained component materials proportionally to add mixing,
Each component materials can be dispersed in compound, so as to ensure the anion infrared-emitting materials stable performance for preparing, tool
Have in the environment of small temperature and pressure change, the electrical potential difference between composition crystal can be caused, and have pyroelectricity and electricity
Pressure property dynamic characteristic, so that launch strong far infrared and negative oxygen ion.
Just because of anion infrared-emitting materials of the present invention have can launch as described above strong far infrared and negative oxygen from
Son, therefore, extends the range of application of anion infrared-emitting materials of the present invention and in environmental protection, cigarette, coating, weaving, cosmetic
Product, purify water, purify air, deodorizing sterilizing, anti-electromagnetic radiation, the effect that applies in the field such as health care.
Description of the drawings
Below in conjunction with drawings and Examples, the invention will be further described, in accompanying drawing：
Relative radiation power spectrums of the Fig. 1 for 1 material of the embodiment of the present invention.
Specific embodiment
In order that the objects, technical solutions and advantages of the present invention become more apparent, with reference to embodiments, to the present invention
It is further elaborated.It should be appreciated that specific embodiment described herein is not used to only in order to explain the present invention
Limit the present invention.
The quality of embodiment of the present invention Related Component noted in the disclosure not only may refer to the concrete of each component
Content, it is also possible to represent the proportionate relationship of quality or weight between each component, therefore, as long as according to embodiment of the present invention specification
The content of related component is scaled up or is reduced within embodiment of the present invention specification scope of disclosure.Specifically, originally
Quality described in inventive embodiments specification can be mass unit known to the chemical fields such as μ g, mg, g, kg.
On the one hand, the embodiment of the present invention provides a kind of anion infrared emission that can launch strong far infrared and anion
Material.The anion infrared-emitting materials include the composition of following mass percent：
So, contain mentioned component uniform crystal dispersion shape just because of embodiment of the present invention anion infrared-emitting materials
Into stable mixture, and the composition of the proportioning has pyroelectricity and piezoelectricity, therefore, in small temperature and pressure change
In environment, the electrical potential difference between composition crystal can be caused so that air occur ionization distribute far infrared and air bear from
Sonization, produces strong negative oxygen ion.In addition, anion infrared-emitting materials of the present invention contain with the oxygen-containing sodium iron being characterized, magnesium
The silicate material of aluminium silicon boron circulus, isomorph are developed, tool pyroelectricity and voltage endurance, make polar ion in equilbrium position
Vibrate and cause dipole moment change to produce far infrared.
In one embodiment, the component content contained by above-mentioned anion infrared-emitting materials is as follows：
By adjusting the content ratio of above-mentioned anion infrared-emitting materials ingredient, so that composition crystal percentage
Adjustment with further improve anion infrared-emitting materials have at small temperature and pressure change transmitting anion and
The ability of infrared characteristic, and improve transmitting anion and infrared intensity.
In as one embodiment of the invention, the anion infrared-emitting materials in above-described embodiment are graininess, and one is real
Apply in example, the granular anion infrared-emitting materials particle diameter is 1500-4000 mesh, be specifically 1500 mesh, 3000 mesh,
4000 mesh.It is, of course, also possible to according to the needs of actual application, carry out actual adjustment to its form and particle diameter etc..In addition, warp
Detection, the anion-generating capacity of the present embodiment ion infrared-emitting materials can reach 20000-60000ions/cm3.
On the other hand, one kind side of preparation of anion infrared-emitting materials in above-described embodiment is embodiments provided
Method.In one embodiment, the anion infrared-emitting materials preparation method comprises the steps：
Composition contained by step S01. embodiment of the present invention anion infrared-emitting materials as described above is pressed respectively
Ratio weighs each component materials；
The each component materials for weighing are carried out carrying out ultra-fine grinding process after mixing treatment by step S02..
Specifically, in above-mentioned steps S01, composition and each component content contained by anion infrared-emitting materials are as above
Literary described, in order to save length, will not be described here.Wherein, the raw material of each composition can be directly commercial, in order to improve the present invention
The infrared and anion intensity of embodiment anion infrared-emitting materials transmitting, each component materials can be with Analysis about Selection pure raw material.
In above-mentioned steps S02, mixing treatment can be mixed using batch mixer, it would however also be possible to employ grinder or ball milling
Machine carries out mixing treatment so that each raw material is well mixed, and processes in order to follow-up ultra-fine grinding.Therefore, as long as can make
The mode that each component materials are well mixed is obtained, in scope disclosed by the invention.
It is in order that each component materials particle diameter reaches nanoscale that ultra-fine smashing is processed, and the particle diameter of ultra-fine grinding is put down
50-80nm is distributed in, each component materials is sufficiently mixed uniformly, is on the other hand improved each component materials nanometer
Synergistic effect between grain, so that anion infrared-emitting materials can be in the environment of small temperature and pressure change
The strong anion of transmitting and infrared characteristic.The ultra-fine condition for processing that smashes can be entered according to conventional ultra-fine smashing treatment conditions
Row is arranged.
Another aspect, based on anion infrared-emitting materials mentioned above and preparation method thereof, due to present invention enforcement
As described above, its crystalchecked, with the ring in small temperature and pressure change for example anion infrared-emitting materials
In border, the electrical potential difference between composition crystal can be caused, and have pyroelectricity and voltage endurance, so as to launch strong far infrared and negative oxygen
Ion.Therefore, embodiment of the present invention anion infrared-emitting materials have wider range of application, such as in a particular embodiment,
Embodiment of the present invention anion infrared-emitting materials can in environmental protection, cigarette, coating, weaving, cosmetics, purify water, purify
Apply in the fields such as air, deodorizing sterilizing, anti-electromagnetic radiation, health care, and play in small temperature and pressure change
Launch strong far infrared and negative oxygen ion in environment, so as to realize corresponding function.In every field, application is referred to existing
The application of the infrared or anion material having, such as which can be through various nonmetal mediums and act on liquid and solid, strengthen
Its activity, alcoholic degree, make mouthfeel more continuous soft, or will be direct for the chip containing embodiment of the present invention anion infrared-emitting materials
Contact body pain spot and problem areas, the effect that can be eased and improve.
Above-mentioned anion infrared-emitting materials and preparation method thereof are described in detail below in conjunction with specific embodiment.
Embodiment 1：
Present embodiments provide a kind of anion infrared-emitting materials and preparation method thereof.Wherein, the anion is infrared
Emissive material includes the component of following portions by weight：
The preparation method of the anion infrared-emitting materials is as follows：
S11. each component materials are weighed respectively in proportion according to the composition contained by the present embodiment anion infrared-emitting materials；
S12. carry out after mixing treatment, carrying out ultra-fine grinding process by each component materials for weighing so that the grain of ultra-fine grinding
Footpath is evenly distributed in 50-80nm.
Embodiment 2
Present embodiments provide a kind of anion infrared-emitting materials and preparation method thereof.Wherein, the anion is infrared
Emissive material includes the component of following portions by weight：
The preparation method of the anion infrared-emitting materials is carried out with reference to preparation method in embodiment 1.
Embodiment 3
Present embodiments provide a kind of anion infrared-emitting materials and preparation method thereof.Wherein, the anion is infrared
Emissive material includes the component of following portions by weight：
The preparation method of the anion infrared-emitting materials is carried out with reference to preparation method in embodiment 1.
Comparative example
Existing anionic particle material, including：Alundum (Al2O3) 30%, organic germanium powder 0.4%, sapphire powder 2%, dioxy
SiClx 26%, magnesia 5%, boron trioxide 10%, di-iron trioxide 8%, sodium oxide molybdena 1%, phosphorus pentoxide 0.2%, dioxy
Change titanium 0.4%, iron oxide 8%, calcium oxide 2%, periclase 2%, activated carbon 5%.
The test of respective performances
It is existing that the anion infrared-emitting materials that above-described embodiment 1 to embodiment 3 is provided and comparative example provide
Anionic particle material carries out negative ion concentration measure and infrared analysis respectively.
1. negative ion concentration is determined：
Negative ion concentration assay method：Take anion infrared-emitting materials and contrast in 500 grams of embodiments 1-3 respectively to implement
Anionic particle material in example, and the material in each embodiment is uniformly spread out, closed 24 hours, public with U.S. Alphalab
The AIC-1000 anionic textiles instrument of department's production once, takes 20 data every time, tries to achieve the average of each data every detection in 1 hour
Value is used as final detection result
Negative ion concentration measurement result：Test data is shown in Table 1：
2. the measure of infrared wavelength is launched：
Infrared wavelength assay method：Respectively in Example 1-3 in anion infrared-emitting materials and comparative example
Anionic particle material is according to GB/T 7287-2008《Infrared radiation heater test method》It is measured.
Infrared wavelength measurement result：Embodiment 1-3 material infra red energy density is respectively 5.33 × 102W/m2、5.19
×102W/m2(37℃)、4.92×102W/m2(37 DEG C), and the infra red energy density of comparative example's material is respectively
4.51×102W/m2.Wherein, 1 relative radiation power spectrum of embodiment (infrared radiation wavelength scope) is as shown in Figure 1.
Presently preferred embodiments of the present invention is the foregoing is only, not in order to limit the present invention, all in essence of the invention
Any modification, equivalent and improvement that is made within god and principle etc., should be included within the scope of the present invention.
Claims (8)
1. a kind of anion infrared-emitting materials, it is characterised in that including the composition of following mass percent：
2. anion infrared-emitting materials according to claim 1, it is characterised in that including following mass percent into
Point：
3. anion infrared-emitting materials according to claim 1 and 2, it is characterised in that：The anion infrared emission
Material is graininess, and the grain diameter is 1500-4000 mesh.
4. anion infrared-emitting materials according to claim 1 and 2, it is characterised in that：The anion infrared emission
The anion-generating capacity of material is 20000-60000ions/cm3.
5. a kind of preparation method of anion infrared-emitting materials, comprises the steps：
Each composition is weighed respectively in proportion according to the composition contained by the arbitrary described anion infrared-emitting materials of claim 1-2
Raw material；
Carry out after mixing treatment, carrying out ultra-fine grinding process by each component materials for weighing.
6. method according to claim 5, it is characterised in that：Compound after the ultra-fine grinding is processed crosses 1500-
4000 mesh sieve.
7. the method according to claim 5 or 6, it is characterised in that：The anion infrared-emitting materials for preparing negative
Ion generating capacity is 20000-60000ions/cm3.
8. according to claim 1-4 arbitrary described anion infrared-emitting materials or arbitrary described according to claim 5-7
Anion infrared-emitting materials prepared by method environmental protection, cigarette, coating, weaving, cosmetics, purify water, purify air, anti-
Application in electromagnetic radiation, health products.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610977465.1A CN106495648B (en) | 2016-10-28 | 2016-10-28 | Anion infrared-emitting materials and its manufacturing method and application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610977465.1A CN106495648B (en) | 2016-10-28 | 2016-10-28 | Anion infrared-emitting materials and its manufacturing method and application |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106495648A true CN106495648A (en) | 2017-03-15 |
| CN106495648B CN106495648B (en) | 2018-12-18 |
Family
ID=58323280
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610977465.1A Active CN106495648B (en) | 2016-10-28 | 2016-10-28 | Anion infrared-emitting materials and its manufacturing method and application |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106495648B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110372208A (en) * | 2019-07-02 | 2019-10-25 | 浙江开尔新材料股份有限公司 | The method for discharging the enamel glaze slip of anion and preparing anion enamel plate using it |
| CN114455948A (en) * | 2020-11-10 | 2022-05-10 | 李昭林 | Calcined synthetic material and preparation method thereof, and negative oxygen ion ceramic and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0023587B1 (en) * | 1979-08-06 | 1982-05-12 | Degussa Aktiengesellschaft | Temperature-stabilized pyrogenic oxide mixture of silica oxide, process for its production and its use |
| CN1250038A (en) * | 1999-09-20 | 2000-04-12 | 天津市硅酸盐研究所 | Anion generating and far infrared emitting material and its preparation |
| CN1392115A (en) * | 2002-08-13 | 2003-01-22 | 河北工业大学 | Multifunctinoal health ceramic material and its preparing method and use |
| CN1557886A (en) * | 2004-01-15 | 2004-12-29 | 陈民全 | Environmental protection building paint additives having odour-removing, antiseptic and oxygen-adding function |
| CN104291794A (en) * | 2014-09-17 | 2015-01-21 | 李忠 | Negative ion granular material capable of producing microcurrent |
-
2016
- 2016-10-28 CN CN201610977465.1A patent/CN106495648B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0023587B1 (en) * | 1979-08-06 | 1982-05-12 | Degussa Aktiengesellschaft | Temperature-stabilized pyrogenic oxide mixture of silica oxide, process for its production and its use |
| CN1250038A (en) * | 1999-09-20 | 2000-04-12 | 天津市硅酸盐研究所 | Anion generating and far infrared emitting material and its preparation |
| CN1392115A (en) * | 2002-08-13 | 2003-01-22 | 河北工业大学 | Multifunctinoal health ceramic material and its preparing method and use |
| CN1557886A (en) * | 2004-01-15 | 2004-12-29 | 陈民全 | Environmental protection building paint additives having odour-removing, antiseptic and oxygen-adding function |
| CN104291794A (en) * | 2014-09-17 | 2015-01-21 | 李忠 | Negative ion granular material capable of producing microcurrent |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110372208A (en) * | 2019-07-02 | 2019-10-25 | 浙江开尔新材料股份有限公司 | The method for discharging the enamel glaze slip of anion and preparing anion enamel plate using it |
| CN110372208B (en) * | 2019-07-02 | 2021-12-31 | 浙江开尔新材料股份有限公司 | Enamel glaze slip capable of releasing negative ions and method for preparing negative ion enamel plate by using enamel glaze slip |
| CN114455948A (en) * | 2020-11-10 | 2022-05-10 | 李昭林 | Calcined synthetic material and preparation method thereof, and negative oxygen ion ceramic and preparation method thereof |
| CN114455948B (en) * | 2020-11-10 | 2024-02-02 | 李昭林 | Calcining synthetic material and preparation method thereof, negative oxygen ion ceramic and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106495648B (en) | 2018-12-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102569749B (en) | Graphene/hydroxyapatite nano composite and preparation method thereof | |
| CN106726628A (en) | Negative ion far-infrared multifunctional nano material | |
| KR101971940B1 (en) | Manufacturing method for emitter having far-infrared radiation thermal effect and an anion generating function and the emitter made therefrom | |
| CN106495648A (en) | Anion infrared-emitting materials and its manufacture method and application | |
| Liu et al. | Synthesis-temperature-regulated multi-enzyme-mimicking activities of ceria nanozymes | |
| HUP0004821A2 (en) | Soft-pellet drug and process for the preparation thereof | |
| JP2022009122A (en) | Agricultural material and method for growing plant | |
| Roychoudhury et al. | Diatom-based biosynthesis of gold-silica nanocomposite and their DNA binding affinity | |
| US7063801B2 (en) | Composite material and method for preparing the same, and raw composite material used for preparing the same | |
| CN106698380B (en) | A kind of hydroxyapatite and preparation method thereof using shell preparation | |
| CN108354897B (en) | A kind of silica/the polypyrrole can be used for medicament slow release/poly- (acrylamide and acrylic acid) carries the preparation of medicine plural gel | |
| CN105413628A (en) | Healthcare type negative ion far infrared particles as well as preparation raw materials, preparation method and application thereof | |
| KR100460526B1 (en) | High functional composition having action on minus ion and far infrared ray | |
| CN112646438A (en) | Negative ion antibacterial coating and preparation method thereof | |
| Carmody et al. | A spectroscopic study of mechanochemically activated kaolinite with the aid of chemometrics | |
| Ponta et al. | Synthesis and characterisation of nanostructured silica-powellite-HAP composites | |
| US20020139963A1 (en) | Composition emitting far infrared rays and method for preparation thereof | |
| Tămăşan et al. | Spectroscopic characterisation and in vitro behaviour of kaolinite polyvinyl alcohol nanocomposite | |
| CN103146758A (en) | Method for preparing nano silver particles through microbial surface reduction | |
| CN109399638A (en) | A kind of preparation method of dendroid silicon nanoparticle | |
| CN105754401A (en) | Hexacyclic stone-containing negative air ion powder and preparation method thereof | |
| KR20180111233A (en) | Antibacterial soap emitting far infrared rays emitted at room temperature or above room temperature | |
| CN108295999B (en) | A kind of Khotan jade superfine powder and preparation method thereof | |
| CN101919798A (en) | Dense silicon dioxide coated pearl powder | |
| KR20150129520A (en) | Method for manufacturing cosmetic material that includes Au-zinc zeolite |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |