CN106495094A - High effective portable hydrogen generator and its control method - Google Patents

High effective portable hydrogen generator and its control method Download PDF

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Publication number
CN106495094A
CN106495094A CN201610851031.7A CN201610851031A CN106495094A CN 106495094 A CN106495094 A CN 106495094A CN 201610851031 A CN201610851031 A CN 201610851031A CN 106495094 A CN106495094 A CN 106495094A
Authority
CN
China
Prior art keywords
sealing
inner container
hydrogen generator
high effective
tube
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201610851031.7A
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Chinese (zh)
Other versions
CN106495094B (en
Inventor
谢树清
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ruian Poly Technology Co Ltd
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Ruian Poly Technology Co Ltd
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Filing date
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Application filed by Ruian Poly Technology Co Ltd filed Critical Ruian Poly Technology Co Ltd
Priority to CN201610851031.7A priority Critical patent/CN106495094B/en
Publication of CN106495094A publication Critical patent/CN106495094A/en
Application granted granted Critical
Publication of CN106495094B publication Critical patent/CN106495094B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/06Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
    • GPHYSICS
    • G05CONTROLLING; REGULATING
    • G05DSYSTEMS FOR CONTROLLING OR REGULATING NON-ELECTRIC VARIABLES
    • G05D16/00Control of fluid pressure
    • G05D16/20Control of fluid pressure characterised by the use of electric means
    • G05D16/2006Control of fluid pressure characterised by the use of electric means with direct action of electric energy on controlling means
    • G05D16/2013Control of fluid pressure characterised by the use of electric means with direct action of electric energy on controlling means using throttling means as controlling means
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/36Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

Abstract

The invention discloses a kind of high effective portable hydrogen generator, including:Sealing inner container, is provided with solid material, and space is left on top, and sealing inner container is provided with feed tube and escape pipe, and the air inlet of the liquid outlet and escape pipe of feed tube is located at sealing inner container top, and feed tube connects fluid supply;Inner tube, inserts solid material, and the lower port of inner tube is reached outside sealing inner container, and the upper port of inner tube is reached above solid material, offers multiple through holes on the tube wall of inner tube;The outer gallbladder of sealing, with sealing inner container socket sealing and detachable, the lower port of inner tube is located in the cavity that the outer gallbladder of sealing and sealing inner container are formed.The invention also discloses a kind of control method of high effective portable hydrogen generator.There is the present invention pollution-free, easy to carry, efficient, safety, precise control to produce the beneficial effect of hydrogen.

Description

High effective portable hydrogen generator and its control method
Technical field
The present invention relates to a kind of hydrogen generator, more particularly to portable hydrogen generator, can be used for family, new forms of energy vapour Car.
Background technology
Hydrogen receives much concern as the high energy of a kind of renewable, environmental protection and fuel value, and hydrogen economy is for global energy requirements For, hydrogen fuel is also by substitute fossil fuels.Aluminum-aqueous slkali hydrolytic hydrogen production received much concern in the past more than ten years, but existing Hydrogen generator cannot obtain the hydrogen of easy to carry, efficient, safety, precise control, technically there is no effectively breakthrough.
Content of the invention
The present invention is according to above not enough, there is provided a kind of high effective portable hydrogen generator.
The technical scheme is that:
A kind of high effective portable hydrogen generator, is characterized in that, including:
Sealing inner container, is provided with solid material, and space is left on top, and sealing inner container is provided with feed tube and escape pipe, feed tube Liquid outlet and escape pipe air inlet be located at sealing inner container top, feed tube connect fluid supply;
Inner tube, inserts solid material, and the lower port of inner tube is reached outside sealing inner container, and the upper port of inner tube reaches solid material Top, offers multiple through holes on the tube wall of inner tube;
The outer gallbladder of sealing, with sealing inner container socket sealing and detachable, the lower port of inner tube is located at the outer gallbladder of sealing and sealing inner container shape Into cavity in.
Chemical reaction, hydrogen partial is contacted and is produced with solid material after sealing inner container is flowed into from the liquid of feed tube input Export from escape pipe, part is not reacted after sufficient liquid and solid material mixing from the upper port and/or inner tube of inner tube Through hole continues reaction in the cavity for seal outer gallbladder bottom through interior pipe flow, and the hydrogen of generation is entered from interior infratubal port, then through going out Trachea exports hydrogen, the present solution provides the chance of liquid and solid material chemical reaction twice, so that reaction is filled Point, hydrogen production rate is significantly improved.
It should be noted that liquid can select water or other solution, solid material is then from al-based compound or other energy Produce the material of hydrogen.
For uniform infusion fluid, make chemical reaction more abundant, also include baffle plate, be fixed on the upper of the sealing inner container Portion, baffle plate leave gap with sealing inner container inwall, and the liquid outlet of the feed tube is arranged on the top of baffle center, from liquid outlet The liquid of outflow can be flowed down from gap.
Further, the baffle plate side-looking is tapered.
Canned solid material for convenience, the sealing inner container are sealed to form by upper lid and inner lining, the feed tube and Escape pipe is fixed on lid.
Feed tube and escape pipe can be installed separately, but the scheme being more highly preferred to is, the escape pipe penetrate the baffle plate, Enter feed tube, finally pass from the tube wall of feed tube.Its advantage is to reduce interface, reduces the chance of leakage.
When the material of sealing inner container selects ordinary metallic material, it is possible to chemical reaction occurs with solid material, is understanding Determine the technical problem, plastic layer can be set between the solid material and sealing inner container.
In order to be able to the quantum of output of precise control hydrogen, also include controller, pressure transducer, electromagnetic valve and electromagnetic pump, institute State escape pipe to export through pressure transducer, electromagnetic valve and electromagnetic pump are serially connected in the input of feed tube, pressure transducer, electromagnetic valve Controller is electrically connected with electromagnetic pump.Air relief valve can also be concatenated as conventional usage escape pipe.
Further, sensor and alarm are also included, the sensor is installed in the solid-state for being close to sealing inner container bottom In material, when the height of the surpluses proximity transducer of solid material, sensor output electrical signals, the electrode of sensor is through leading Line is drawn from the sealing inner container, and sensor and alarm electrically connect the controller.When the present invention is used for some equipment for example When automobile is as power source, the surpluses for being known a priori by solid material are needed.
Preferably, the sensor is inductive position sensor, the sensitive surface of inductive position sensor is towards water Square to or upward.When solid material is more, solid material surrounds inductive position sensor, inductive position sensor energy Solid material is detected, when solid material is less, inductive position sensor can also detect solid material around not to be had , so as to export different level signals.
A kind of control method of high effective portable hydrogen generator, including one kind as claimed in claim 7 or 8 efficiently just Formula hydrogen generator is taken, be it is characterized in that, as follows:
A., when the pressure of pressure transducer detection is less than predetermined value, electromagnetic valve and electromagnetic pump are powered, and inject liquid;Predetermined value Can need to be set according to equipment, such as can be lower during domestic, can be with higher on automobile;
B. when the pressure of pressure transducer detection is more than predetermined value, electromagnetic valve and electromagnetic pump power-off, closing liquid;
C., when the height of solid material is less than inductive position sensor, inductive position sensor exports trigger, report Alert device is reported to the police.
Preferably, the predetermined value is 3-5 kPa.
There is the present invention pollution-free, easy to carry, efficient, safety, precise control to produce the beneficial effect of hydrogen.
Description of the drawings
Fig. 1 is the overall structure diagram of the present invention.
Specific embodiment
In conjunction with accompanying drawing, the present invention is further illustrated:
As illustrated, a kind of high effective portable hydrogen generator, including:
Sealing inner container 4, is provided with solid material 7, and space is left on top, and sealing inner container 4 is provided with feed tube 1 and escape pipe 2, enters The air inlet of the liquid outlet of liquid pipe 1 and escape pipe 2 is located at 4 top of sealing inner container, and feed tube 1 connects fluid supply;
Inner tube 6, inserts solid material 7, and the lower port of inner tube 6 is reached outside sealing inner container 4, and the upper port of inner tube 6 is reached admittedly Above state material 7, multiple through holes 61 on the tube wall of inner tube 6, are offered;
The outer gallbladder 5 of sealing, and the socket sealing of sealing inner container 4, the lower port of inner tube 6 are located at the outer gallbladder 5 of sealing and the formation of sealing inner container 4 In cavity 51.
Also include baffle plate 3, be fixed on the top of sealing inner container 4, baffle plate 3 leaves gap 31, feed liquor with 4 inwall of sealing inner container The liquid outlet of pipe 1 is arranged on the top at 3 center of baffle plate, and the liquid flowed out from liquid outlet can be flowed down from gap 31.
Sealing inner container 4 is sealed to form by upper lid and inner lining, and feed tube 1 and escape pipe 2 are fixed on lid.
Escape pipe 2 penetrates baffle plate 3, enters feed tube 1, finally passes from the tube wall of feed tube 1.
3 side-looking of baffle plate is tapered.
Also include that controller, pressure transducer, electromagnetic valve 11 and electromagnetic pump 12, escape pipe 2 are exported through pressure transducer, electricity Magnet valve 11 and electromagnetic pump 12 are serially connected in the input of feed tube 1, the electrical connection control of pressure transducer, electromagnetic valve 11 and electromagnetic pump 12 Device.
Also include that sensor 8 and alarm, sensor 8 are arranged on and are close in the solid material 7 of 4 bottom of sealing inner container, when During the height of the surpluses proximity transducer 8 of solid material 7, sensor 8 exports the signal of telecommunication, the electrode of sensor 8 through wire from Sealing inner container 4 is drawn, and the present embodiment is drawn from the bottom of sealing inner container 4, the top output of finally sealed outer gallbladder 5, sensing Device 8 and alarm electrical connection controller.
Sensor 8 is inductive position sensor, and the sensitive surface of inductive position sensor is towards horizontal direction or upward.
A kind of control method of high effective portable hydrogen generator, including the high effective portable hydrogen generator, by such as Lower step:
A., when the pressure of pressure transducer detection is less than predetermined value, electromagnetic valve 11 and electromagnetic pump 12 are powered, and inject liquid;
B. when the pressure of pressure transducer detection is more than predetermined value, 12 power-off of electromagnetic valve 11 and electromagnetic pump, closing liquid;
C., when the height of solid material 7 is less than inductive position sensor 8, inductive position sensor 8 exports trigger, Alarm equipment alarm.
Predetermined value is 3-5 kPa.
Hydrogen generator of the present invention can be integrated in entirely or essentially parts in one tank body as needed, reserve into Liquid pipe 1 and escape pipe 2, circuit interface etc., are convenient for carrying.

Claims (10)

1. a kind of high effective portable hydrogen generator, is characterized in that, including:
Sealing inner container(4), solid material is installed(7), space, sealing inner container are left in top(4)It is provided with feed tube(1)With go out Trachea(2), feed tube(1)Liquid outlet and escape pipe(2)Air inlet be located at sealing inner container(4)Top, feed tube(1)Connection Fluid supply;
Inner tube(6), insert solid material(7), inner tube(6)Lower port reach sealing inner container(4)Outward, inner tube(6)Upper end Mouth reaches solid material(7)Top, inner tube(6)Tube wall on offer multiple through holes(61);
The outer gallbladder of sealing(5), with sealing inner container(4)Socket sealing, inner tube(6)Lower port be located at the outer gallbladder of sealing(5)In sealing Gallbladder(4)The cavity of formation(51)Interior.
2. a kind of high effective portable hydrogen generator as claimed in claim 1, is characterized in that, also include baffle plate(3), it is fixed on The sealing inner container(4)Top, baffle plate(3)With sealing inner container(4)Inwall leaves gap(31), the feed tube(1)Go out Liquid mouth is arranged on baffle plate(3)The top at center, the liquid flowed out from liquid outlet can be from gap(31)Flow down.
3. a kind of high effective portable hydrogen generator as claimed in claim 2, is characterized in that, the sealing inner container(4)By upper Lid and inner lining are sealed to form, the feed tube(1)And escape pipe(2)It is fixed on lid.
4. a kind of high effective portable hydrogen generator as claimed in claim 3, is characterized in that, the escape pipe(2)Penetrate institute State baffle plate(3), enter feed tube(1), last from feed tube(1)Tube wall pass.
5. a kind of high effective portable hydrogen generator as claimed in claim 2, is characterized in that, the baffle plate(3)Side-looking is in cone Shape.
6. a kind of high effective portable hydrogen generator as claimed in claim 1, is characterized in that, the solid material(7)With close Envelope inner bag(4)Between be provided with plastic layer(41).
7. a kind of high effective portable hydrogen generator as described in any one of claim 1-6, is characterized in that, also include controlling Device, pressure transducer, electromagnetic valve(11)And electromagnetic pump(12), the escape pipe(2)Export through pressure transducer, electromagnetic valve(11) And electromagnetic pump(12)It is serially connected in feed tube(1)Input, pressure transducer, electromagnetic valve(11)And electromagnetic pump(12)Electrical connection control Device processed.
8. a kind of high effective portable hydrogen generator as claimed in claim 7, is characterized in that, also include sensor(8)And report Alert device, the sensor(8)It is arranged on and is close to sealing inner container(4)The solid material of bottom(7)Interior, work as solid material(7)Surplus Surplus proximity transducer(8)Height when, sensor(8)The output signal of telecommunication, sensor(8)Electrode through wire from the sealing Inner bag(4)Draw, sensor(8)The controller is electrically connected with alarm.
9. a kind of high effective portable hydrogen generator as claimed in claim 7, is characterized in that, the sensor(8)For sensing Formula position sensor, the sensitive surface of inductive position sensor is towards horizontal direction or upward.
10. a kind of control method of high effective portable hydrogen generator, efficient just including one kind as claimed in claim 7 or 8 Formula hydrogen generator is taken, be it is characterized in that, as follows:
A. when the pressure of pressure transducer detection is less than predetermined value, electromagnetic valve(11)And electromagnetic pump(12)It is powered, injects liquid Body;
B. when the pressure of pressure transducer detection is more than predetermined value, electromagnetic valve(11)And electromagnetic pump(12)Power-off, closes liquid Body;
C. work as solid material(7)Height be less than inductive position sensor(8)When, inductive position sensor(8)Output is touched Signal, alarm equipment alarm.
CN201610851031.7A 2016-09-27 2016-09-27 High effective portable hydrogen generator and its control method Expired - Fee Related CN106495094B (en)

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Application Number Priority Date Filing Date Title
CN201610851031.7A CN106495094B (en) 2016-09-27 2016-09-27 High effective portable hydrogen generator and its control method

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Application Number Priority Date Filing Date Title
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CN106495094B CN106495094B (en) 2018-06-15

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109231166A (en) * 2018-09-29 2019-01-18 西安交通大学 Produce hydrogen fuel stick, preparation method and based on the hydrogen generator for producing hydrogen fuel stick
CN110790222A (en) * 2019-12-03 2020-02-14 河南中氢动力研究院有限公司 Device and method for preparing hydrogen

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1354851A1 (en) * 2002-04-16 2003-10-22 Hewlett-Packard Company Hydrogen Production system
CN1518151A (en) * 2003-01-29 2004-08-04 ��������˹�����տ����� Hydrogen generation cylinder and portable hydrogen generator
CN101343035A (en) * 2007-07-13 2009-01-14 法国原子能委员会 Portable gas generator device and power supply with fuel-cell comprising such a device
CN101365530A (en) * 2006-01-06 2009-02-11 法商Bic公司 Hydrogen-generating fuel cell cartridges
CN101495602A (en) * 2005-06-13 2009-07-29 法商Bic公司 Fuels for hydrogen generating cartridges
CN101687158A (en) * 2007-07-06 2010-03-31 三菱铅笔株式会社 Gas generation apparatus
CN206172967U (en) * 2016-09-27 2017-05-17 瑞安市华聚科技有限公司 High -efficient portable hydrogen generator

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1354851A1 (en) * 2002-04-16 2003-10-22 Hewlett-Packard Company Hydrogen Production system
CN1518151A (en) * 2003-01-29 2004-08-04 ��������˹�����տ����� Hydrogen generation cylinder and portable hydrogen generator
CN101495602A (en) * 2005-06-13 2009-07-29 法商Bic公司 Fuels for hydrogen generating cartridges
CN101365530A (en) * 2006-01-06 2009-02-11 法商Bic公司 Hydrogen-generating fuel cell cartridges
CN101687158A (en) * 2007-07-06 2010-03-31 三菱铅笔株式会社 Gas generation apparatus
CN101343035A (en) * 2007-07-13 2009-01-14 法国原子能委员会 Portable gas generator device and power supply with fuel-cell comprising such a device
CN206172967U (en) * 2016-09-27 2017-05-17 瑞安市华聚科技有限公司 High -efficient portable hydrogen generator

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109231166A (en) * 2018-09-29 2019-01-18 西安交通大学 Produce hydrogen fuel stick, preparation method and based on the hydrogen generator for producing hydrogen fuel stick
CN110790222A (en) * 2019-12-03 2020-02-14 河南中氢动力研究院有限公司 Device and method for preparing hydrogen
CN110790222B (en) * 2019-12-03 2021-04-27 河南中氢动力研究院有限公司 Device and method for preparing hydrogen

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