CN106492796B - A kind of tourmaline ceramic loads TiO2The preparation technology of the immobilized photochemical catalysts of-NCP - Google Patents
A kind of tourmaline ceramic loads TiO2The preparation technology of the immobilized photochemical catalysts of-NCP Download PDFInfo
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- CN106492796B CN106492796B CN201610915728.6A CN201610915728A CN106492796B CN 106492796 B CN106492796 B CN 106492796B CN 201610915728 A CN201610915728 A CN 201610915728A CN 106492796 B CN106492796 B CN 106492796B
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- 239000011032 tourmaline Substances 0.000 title claims abstract description 68
- 229940070527 tourmaline Drugs 0.000 title claims abstract description 67
- 229910052613 tourmaline Inorganic materials 0.000 title claims abstract description 67
- 239000000919 ceramic Substances 0.000 title claims abstract description 53
- 238000002360 preparation method Methods 0.000 title claims abstract description 34
- 239000003054 catalyst Substances 0.000 title claims abstract description 33
- 238000005516 engineering process Methods 0.000 title claims abstract description 21
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 91
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 46
- 229910001868 water Inorganic materials 0.000 claims abstract description 39
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000002131 composite material Substances 0.000 claims abstract description 20
- 239000011941 photocatalyst Substances 0.000 claims abstract description 20
- 238000004519 manufacturing process Methods 0.000 claims abstract description 9
- 239000000047 product Substances 0.000 claims description 39
- 239000007864 aqueous solution Substances 0.000 claims description 32
- 239000000203 mixture Substances 0.000 claims description 32
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 30
- 238000010606 normalization Methods 0.000 claims description 29
- 238000000034 method Methods 0.000 claims description 27
- 239000000243 solution Substances 0.000 claims description 26
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 20
- 150000001875 compounds Chemical class 0.000 claims description 19
- 238000001816 cooling Methods 0.000 claims description 19
- LLZRNZOLAXHGLL-UHFFFAOYSA-J titanic acid Chemical compound O[Ti](O)(O)O LLZRNZOLAXHGLL-UHFFFAOYSA-J 0.000 claims description 19
- 229910052757 nitrogen Inorganic materials 0.000 claims description 16
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 15
- 238000005245 sintering Methods 0.000 claims description 15
- 239000007787 solid Substances 0.000 claims description 15
- 239000004927 clay Substances 0.000 claims description 13
- 239000013078 crystal Substances 0.000 claims description 11
- 239000000843 powder Substances 0.000 claims description 11
- 230000015572 biosynthetic process Effects 0.000 claims description 10
- 238000004140 cleaning Methods 0.000 claims description 10
- 238000001027 hydrothermal synthesis Methods 0.000 claims description 10
- 238000002347 injection Methods 0.000 claims description 10
- 239000007924 injection Substances 0.000 claims description 10
- 239000002245 particle Substances 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 10
- 239000000126 substance Substances 0.000 claims description 10
- JUWSSMXCCAMYGX-UHFFFAOYSA-N gold platinum Chemical compound [Pt].[Au] JUWSSMXCCAMYGX-UHFFFAOYSA-N 0.000 claims description 9
- 239000008367 deionised water Substances 0.000 claims description 6
- 229910021641 deionized water Inorganic materials 0.000 claims description 6
- 230000002378 acidificating effect Effects 0.000 claims description 5
- 230000032683 aging Effects 0.000 claims description 5
- 238000013019 agitation Methods 0.000 claims description 5
- 238000005119 centrifugation Methods 0.000 claims description 5
- 238000006243 chemical reaction Methods 0.000 claims description 5
- 229910000245 dravite Inorganic materials 0.000 claims description 5
- 229910000244 elbaite Inorganic materials 0.000 claims description 5
- 238000001125 extrusion Methods 0.000 claims description 5
- 239000010433 feldspar Substances 0.000 claims description 5
- 238000005469 granulation Methods 0.000 claims description 5
- 230000003179 granulation Effects 0.000 claims description 5
- IDIJOAIHTRIPRC-UHFFFAOYSA-J hexaaluminum;sodium;2,2,4,4,6,6,8,8,10,10,12,12-dodecaoxido-1,3,5,7,9,11-hexaoxa-2,4,6,8,10,12-hexasilacyclododecane;iron(2+);triborate;tetrahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Fe+2].[Fe+2].[Fe+2].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-]B([O-])[O-].[O-][Si]1([O-])O[Si]([O-])([O-])O[Si]([O-])([O-])O[Si]([O-])([O-])O[Si]([O-])([O-])O[Si]([O-])([O-])O1 IDIJOAIHTRIPRC-UHFFFAOYSA-J 0.000 claims description 5
- 238000007654 immersion Methods 0.000 claims description 5
- 229910021645 metal ion Inorganic materials 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 238000012856 packing Methods 0.000 claims description 5
- 239000010970 precious metal Substances 0.000 claims description 5
- 239000002243 precursor Substances 0.000 claims description 5
- 229910000246 schorl Inorganic materials 0.000 claims description 5
- 238000004062 sedimentation Methods 0.000 claims description 5
- 239000006228 supernatant Substances 0.000 claims description 5
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims description 5
- 239000003643 water by type Substances 0.000 claims description 5
- 238000001291 vacuum drying Methods 0.000 claims description 4
- 238000002242 deionisation method Methods 0.000 claims description 3
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 2
- -1 platinum ionic compound Chemical class 0.000 claims description 2
- 229910010066 TiC14 Inorganic materials 0.000 claims 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 238000001035 drying Methods 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- 229910052697 platinum Inorganic materials 0.000 claims 1
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims 1
- 239000010936 titanium Substances 0.000 claims 1
- 229910052719 titanium Inorganic materials 0.000 claims 1
- 239000002699 waste material Substances 0.000 abstract description 4
- 239000003599 detergent Substances 0.000 abstract description 2
- 239000003651 drinking water Substances 0.000 description 8
- 235000020188 drinking water Nutrition 0.000 description 8
- 238000003825 pressing Methods 0.000 description 8
- 238000000746 purification Methods 0.000 description 8
- 230000015556 catabolic process Effects 0.000 description 7
- 238000006731 degradation reaction Methods 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 6
- 238000000354 decomposition reaction Methods 0.000 description 6
- 239000004575 stone Substances 0.000 description 6
- 239000007788 liquid Substances 0.000 description 5
- 230000003647 oxidation Effects 0.000 description 5
- 238000007254 oxidation reaction Methods 0.000 description 5
- 238000004458 analytical method Methods 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002957 persistent organic pollutant Substances 0.000 description 4
- 238000007146 photocatalysis Methods 0.000 description 4
- 230000001699 photocatalysis Effects 0.000 description 4
- 238000001556 precipitation Methods 0.000 description 4
- 229910021529 ammonia Inorganic materials 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 239000003814 drug Substances 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 238000005286 illumination Methods 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 229910052705 radium Inorganic materials 0.000 description 3
- HCWPIIXVSYCSAN-UHFFFAOYSA-N radium atom Chemical compound [Ra] HCWPIIXVSYCSAN-UHFFFAOYSA-N 0.000 description 3
- 239000000523 sample Substances 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 238000011282 treatment Methods 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 241000127225 Enceliopsis nudicaulis Species 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 231100000704 bioconcentration Toxicity 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000012876 carrier material Substances 0.000 description 1
- 238000003421 catalytic decomposition reaction Methods 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 230000002079 cooperative effect Effects 0.000 description 1
- 108010073357 cyanoginosin LR Proteins 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 239000002384 drinking water standard Substances 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000002290 gas chromatography-mass spectrometry Methods 0.000 description 1
- 238000004128 high performance liquid chromatography Methods 0.000 description 1
- 231100000086 high toxicity Toxicity 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000006101 laboratory sample Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- ZYZCGGRZINLQBL-GWRQVWKTSA-N microcystin-LR Chemical compound C([C@H](OC)[C@@H](C)\C=C(/C)\C=C\[C@H]1[C@@H](C(=O)N[C@H](CCC(=O)N(C)C(=C)C(=O)N[C@H](C)C(=O)N[C@@H](CC(C)C)C(=O)N[C@H]([C@H](C)C(=O)N[C@@H](CCCNC(N)=N)C(=O)N1)C(O)=O)C(O)=O)C)C1=CC=CC=C1 ZYZCGGRZINLQBL-GWRQVWKTSA-N 0.000 description 1
- DIDLWIPCWUSYPF-UHFFFAOYSA-N microcystin-LR Natural products COC(Cc1ccccc1)C(C)C=C(/C)C=CC2NC(=O)C(NC(CCCNC(=N)N)C(=O)O)NC(=O)C(C)C(NC(=O)C(NC(CC(C)C)C(=O)O)NC(=O)C(C)NC(=O)C(=C)N(C)C(=O)CCC(NC(=O)C2C)C(=O)O)C(=O)O DIDLWIPCWUSYPF-UHFFFAOYSA-N 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 230000005693 optoelectronics Effects 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 150000003071 polychlorinated biphenyls Chemical group 0.000 description 1
- 125000005575 polycyclic aromatic hydrocarbon group Chemical group 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000009738 saturating Methods 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 230000001960 triggered effect Effects 0.000 description 1
- 239000000273 veterinary drug Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/656—Manganese, technetium or rhenium
- B01J23/6562—Manganese
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/39—Photocatalytic properties
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/30—Treatment of water, waste water, or sewage by irradiation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/725—Treatment of water, waste water, or sewage by oxidation by catalytic oxidation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
- C02F2305/02—Specific form of oxidant
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
- C02F2305/10—Photocatalysts
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Catalysts (AREA)
Abstract
TiO is loaded the present invention relates to a kind of tourmaline ceramic2The preparation technology of the immobilized photochemical catalysts of-NCP, belongs to water quality cleansing agent manufacture field;Described tourmaline ceramic load TiO2The preparation technology of the immobilized photochemical catalysts of-NCP includes step in detail below:1)The preparation of tourmaline ceramic;2)TiO2The preparation of-NCP composite photo-catalysts;3)Tourmaline ceramic loads TiO2The preparation of the immobilized photochemical catalysts of-NCP.The multi-element doping TiO that the present invention is prepared using tourmaline ceramic2/ TCB composite photo-catalysts, multielement codope TiO2/ TCB composite photo-catalysts, can carry out advanced treating to HOCs in water under field conditions (factors), and " zero " waste is produced, and belongs to environment-friendly Green Product.
Description
Technical field
The invention belongs to water quality cleansing agent manufacture field, specifically, it is related to a kind of tourmaline ceramic load TiO2—NCP
The preparation technology of immobilized photochemical catalyst.
Background technology
With the development of industrial or agricultural, substantial amounts of and ever-increasing HOCs finally necessarily enters the water circulation body of nature
In system, and inevitably appear in drinking water;The particularly abuse of people's veterinary drug thing, electronics and plastic garbage spreads unchecked, and makes
Emerging organic nuisance is continued to bring out in drinking water;High toxicity and extremely strong bioconcentration that they have, even if
Content is atomic, also can constitute great risk to the health of the mankind.The water of indivedual persistence organic pollutants in China, water system
Flat place in the world high-end.
The HOCs in drinking water is thoroughly removed to ensureing that human health is required, the drinking water treatment technique of current China
In, the removing to HOCs is not accounted at all.Generally believe at present:To complicated component in water, the complicated HOCs's of physico-chemical property
Remove, belong to the deep level of processing of drinking water, be very difficult.The adsorption method that some research institutes propose not only can not be thorough by its
Bottom is disposed, and, simply serves the effect of concentration transfer from environment on the whole;The oxidation point that other research institutes use
Solution, it is necessary to which using the extensive strong oxidizer of adaptation, and not only cost is high, operational hazards for strong oxidizer, and is easily caused water
The secondary pollution of body.
Nano-TiO2Crystal is less than under the irradiation of 387.5nm ultraviolet in wavelength as photochemical catalyst, can produce electronics and
Hole pair, i.e. carrier, can make oxygen molecule produce the hydroxyl radical free radical with strong oxidation, and then produce oxidation Decomposition work
With the almost all of difficult organic compound decomposed including bacterium that decomposable asymmetric choice net is contacted finally is allowed to change into
CO2, produce " zero " waste.But, because nano-particle hardly possible is reclaimed, it is impossible to reuse;Photo-generated carrier is easy to again multiple
Close, light-catalysed quantum efficiency is very low;Pure nano-TiO2Catalytic reaction could be triggered by needing the auxiliary of ultraviolet, and actual
Sunray middle-ultraviolet lamp only accounts for 3%~5%, and catalytic decomposition is extremely inefficient, etc. various reasons, makes to seem of great value new
Material is very difficult to apply in the depths reason to HOCs in water.
We are by the nano-TiO of the miscellaneous element of the lot of trace that adulterates2It is supported on the material TCB with natural self-purification ability
On (tourmaline ceramic), TiO has been made2/ TCB composite photo-catalysts, by the catalyticing decomposition action of nano TiO 2 and TCB absorption
Effect and special chemical property are combined, and the decomposition damage capability to HOCs in environment greatly improved, can be visible
Under light, significantly strengthen the decomposition efficiency of photochemical catalytic oxidation, be easy to reclaim again and use for a long time.It is demonstrated experimentally that applied in water
Micro HOCs depths reason, is a kind of deep processing method close to natural auto purification.
About the TiO of multielement codope2The photochemical catalyst on TCB is supported on, and is applied to the health environment-friendly of water
In deep level of processing, both at home and abroad without document report.
The content of the invention
In order to overcome problem present in background technology, TiO is loaded the invention provides a kind of tourmaline ceramic2—NCP
The preparation technology of immobilized photochemical catalyst;Multielement codope TiO2The many factors synergy of/TCB composite photo-catalysts, energy
Under visible light, decomposition of organic matter, not only substantially increases the utilization ratio of photocatalysis efficiency and sunshine, and is easy to back
Receive and long-term utilization, can be applied in various water treatments.
In order to achieve the above object, the present invention proposes following technical scheme:
Described tourmaline ceramic load TiO2The preparation technology of the immobilized photochemical catalysts of-NCP includes step in detail below:
1) preparation of tourmaline ceramic
A. by dravite, schorl, elbaite and tsilaisite through over cleaning, dry, crush, covered by thunder
Machine or air-flow crushing are machined to 2000~2500 mesh;
B. by 10kg polycrystals tourmaline powder and clay, blended stirring 60 minutes, in uniform shape;
C. 1 is pressed by concentration 0.85~0.90wt% titanium hydroxide inorganic sols are water-soluble:3~5 parts by weight, which are slowly injected, beats
In pulp grinder, make tourmaline powder and solid-like of the clay formation containing moisture 30%;
D. through high-pressure extrusion, granulation forms the tourmaline ceramic ball of 3~8mm particle diameters;
2)TiO2The preparation of-NCP composite photo-catalysts
A. precursor substance TiC1 is weighed4+H2The chemistry of O formation 50% is pure, and in injection reactor, it is 28% to be dissolved in chemistry pure
Ethanol acidic aqueous solution in, obtain mixture one;Under high velocity agitation, by hydrogen peroxide and the pure ethanol solution of 30% chemistry
In proportion 1:2.8 mixing, obtain mixture two;Mixture two is slowly dropped in mixture one by constant pressure funnel,
The ratio of mixture one and mixture two is 1:0.8, translucent pale yellow solution is made, 1~2 is stood after the completion of reaction small
When, fully precipitation after discharge supernatant liquor, by 3 times centrifugation, clean it is highly purified after, while stirring inject 40 DEG C~60
DEG C deionized water, Hydrothermal Synthesiss process for dispersing produces pH value 3~5;1.0~1.4wt% of concentration titanium hydroxide inorganic sol
The aqueous solution, is designated as normalization product NT-D1;
B. by the normalization product NT-D1 weighed, in injection autoclave, through high temperature, high-pressure sinter, its temperature control
Between 500 DEG C~600 DEG C, 30 minutes temperature controls are shut down after constant pressure and stood, plus nitrogen cooling, stand aging 10~12 hours, by
Titanium hydroxide changes system into Detitanium-ore-type crystalline solid TiO2, concentration is adjusted to 0.85~1.0wt%;PH value 3~5, is designated as normalization
Product NT-D2;
C. 50 kilograms of normalization product NT-D2 are weighed, through more than 800 DEG C of high temperature sintering, optimal sintering temperature temperature control 850
DEG C, nitrogen cooling is added after standing, by anatase crystal TiO2Change into rutile ore type crystalline solid TiO2The aqueous solution, concentration is adjusted
Whole is 0.9~1.0wt%;
D. the rutile ore type crystalline solid TiO after normalization product NT-D2 and concentration adjustment after concentration is adjusted2It is water-soluble
Liquid presses 7:3~4 ratio is stirred 30~45 minutes using solution manufacturing method altogether under the conditions of 40 DEG C~60 DEG C, plus nitrogen is cold
But after, 10~12 hours are stood, milky mixed crystal TiO is formed2Compound aqueous solution, is set as compound NT-D2F;
E. normalization product NT-D1,450g are weighed;Compound NT-D2F, 950g;Deionized water 8000g~9000g, mixes
Miscellaneous water-soluble platinum gold ionization compound 25g is configured to the concentration 2.5wt% aqueous solution, and water-soluble platinum gold ionization compound is commercially available
Commodity, using hydrothermal synthesis method and common solution doping technique, are made precious metal ion doping specialization product TiO2/ NCP is combined
Photochemical catalyst;
3) tourmaline ceramic load TiO2The preparation of the immobilized photochemical catalysts of-NCP
Using 2.5MM-3.5MM step 1) prepared by tourmaline ceramic ball through cleaning, dry, by dried electricity
Gas stone is from step 2) prepared by TiO2The aqueous solution of-NCP inorganic sol is with 1min/m immersion process, then by 500
DEG C -600 DEG C of high temperature sintering 3 minutes, cooling packing.
Further, described step 1) b step in the composition of raw material be tourmaline 60%~70%, clay 30%~
40% is constituted.
Further, described step 1) step c in titanium hydroxide inorganic sol be by the ammoniacal liquor of titanium tetrachloride+35%+mistake
Hydrogen oxide 50%, by high-speed stirred, constant temperature and pressure is centrifuged, natural sedimentation, and 3 times clean, highly purified, 40 DEG C of vacuum
Dry 8 hours, after crushed using hydrothermal preparing process, disperseed with 120 DEG C of deionized waters, be made translucent light yellow
The aqueous solution.
Percentage in file is mass percent without special instruction.
Beneficial effects of the present invention:
(1) the multi-element doping TiO prepared using tourmaline ceramic2/ TCB composite photo-catalysts, multielement codope
TiO2/ TCB composite photo-catalysts, can carry out advanced treating to HOCs in water under field conditions (factors), and " zero " waste is produced, and is belonged to
Environment-friendly Green Product.
(2) performance for making modern nanometer technology improve water quality with tourmaline ceramic is organically combined, and the effect of synergy is not
Only substantially increase nano-TiO2The ability of degraded Organic substance in water, and be expected to handle out the health with certain physiological action
Drinking water.
(3) the multielement codope TiO prepared by2/ TCB composite photo-catalysts, not only purify ring with utilization sunshine
The premium properties in border, and be easy to reclaim and reuse, be conducive to being widely used in various green technologies.
Brief description of the drawings
Fig. 1 is the immobilized photochemical catalyst schematic diagram of tourmaline ceramic;
Fig. 2 is tourmaline ceramic carrier schematic diagram;
Fig. 3 is TiO2- NCP is in tourmaline ceramic surface microscope schematic diagram;
Fig. 4 is that tourmaline ceramic loads TiO2The immobilized photochemical catalysts of-NCP;
Fig. 5 is purification of water quality experimental provision I;
Fig. 6 is purification of water quality experimental provision II;
Fig. 7 is purification of water quality experimental provision III.
Embodiment
Below in conjunction with embodiments of the invention and accompanying drawing, the technical scheme in the embodiment of the present invention is carried out clear, complete
Site preparation is described, it is clear that described embodiment is only a part of embodiment of the invention, rather than whole embodiments, is based on
Embodiment in the present invention, it is all other that this area control technical staff is obtained under the premise of creative work is not made
Embodiment, belongs to the scope of protection of the invention.
Embodiment 1
Described tourmaline ceramic load TiO2The preparation technology of the immobilized photochemical catalysts of-NCP includes step in detail below:
1) preparation of tourmaline ceramic
A. by dravite, schorl, elbaite and tsilaisite through over cleaning, dry, crush, covered by thunder
Machine or air-flow crushing are machined to 2000 mesh;
B. by 6kg polycrystals tourmaline powder and 4kg clay, blended stirring 60 minutes, in uniform shape;
C. 1 is pressed by concentration 0.85wt% titanium hydroxide inorganic sols are water-soluble:3 parts by weight are slowly injected in beater, make
Tourmaline powder and solid-like of the clay formation containing moisture content 30%, titanium hydroxide inorganic sol is by the ammonia of titanium tetrachloride+35%
Water+hydrogen peroxide 50%, by high-speed stirred, constant temperature and pressure is centrifuged, natural sedimentation, and 3 times are clean, highly purified, and 40
DEG C vacuum drying 8 hours, after crushed using hydrothermal preparing process, disperseed with 120 DEG C of deionized waters, be made translucent
Shape light yellow solution;
D. through high-pressure extrusion, granulation forms the tourmaline ceramic ball of 5mm particle diameters;
2)TiO2The preparation of-NCP composite photo-catalysts
A. precursor substance TiC1 is weighed4+H2The chemistry of O formation 50% is pure, and in injection reactor, it is 28% to be dissolved in chemistry pure
Ethanol acidic aqueous solution in, obtain mixture one;Under high velocity agitation, by hydrogen peroxide and the pure ethanol solution of 30% chemistry
In proportion 1:2.8 mixing, obtain mixture two;Mixture two is slowly dropped in mixture one by constant pressure funnel,
The ratio of mixture one and mixture two is 1:0.8, translucent pale yellow solution is made, stands 1 hour after the completion of reaction, fills
Supernatant liquor is discharged after fractional precipitation, by 3 centrifugations, clean it is highly purified after, 40 DEG C of deionization is injected while stirring
Water, Hydrothermal Synthesiss process for dispersing produces pH value 3;The concentration 1.0wt% titanium hydroxide inorganic sol aqueous solution, is designated as normalization production
Product NT-D1;
B. by the normalization product NT-D1 weighed, in injection autoclave, through high temperature, high-pressure sinter, its temperature control
Between 500 DEG C, 30 minutes temperature controls are shut down after constant pressure and stood, plus nitrogen cooling, are stood aging 10 hours, are changed by titanium hydroxide
Detitanium-ore-type crystalline solid TiO is made2, concentration is adjusted to 0.85wt%;PH values 3, are designated as normalization product NT-D2;
C. 50 kilograms of normalization product NT-D2 are weighed, through more than 800 DEG C of high temperature sintering, optimal sintering temperature temperature control 850
DEG C, nitrogen cooling is added after standing, by anatase crystal TiO2Change into rutile ore type crystalline solid TiO2The aqueous solution, concentration is adjusted
Whole is 0.9wt%;
D. the rutile ore type crystalline solid TiO after normalization product NT-D2 and concentration adjustment after concentration is adjusted2It is water-soluble
Liquid presses 7:3 ratio is stirred 30 minutes using solution manufacturing method altogether under the conditions of 40 DEG C, plus after nitrogen cooling, stands 10 small
When, form milky mixed crystal TiO2Compound aqueous solution, is set as compound NT-D2F;
E. normalization product NT-D1,450g are weighed;Compound NT-D2F, 950g;Deionized water 8000g~9000g, mixes
Miscellaneous water-soluble platinum gold ionization compound 25g is configured to the concentration 2.5wt% aqueous solution, and water-soluble platinum gold ionization compound is commercially available
Commodity, using hydrothermal synthesis method and common solution doping technique, are made precious metal ion doping specialization product TiO2/ NCP is combined
Photochemical catalyst;
3) tourmaline ceramic load TiO2The preparation of the immobilized photochemical catalysts of-NCP
Using 2.5MM step 1) prepared by tourmaline ceramic ball through cleaning, dry, by dried tourmaline from
Step 2) prepared by TiO2The aqueous solution of-NCP inorganic sol is with 1min/m immersion process, then by 500 DEG C of high temperature
Sintering 3 minutes, cooling packing.
Embodiment 2
Described tourmaline ceramic load TiO2The preparation technology of the immobilized photochemical catalysts of-NCP includes step in detail below:
1) preparation of tourmaline ceramic
A. by dravite, schorl, elbaite and tsilaisite through over cleaning, dry, crush, covered by thunder
Machine or air-flow crushing are machined to 2200 mesh;
B. by 6.5kg polycrystals tourmaline powder and 3.5kg clay, blended stirring 60 minutes, in uniform shape;
C. 1 is pressed by concentration 0.87wt% titanium hydroxide inorganic sols are water-soluble:4 parts by weight are slowly injected in beater, make
Tourmaline powder and solid-like of the clay formation containing moisture content 30%, titanium hydroxide inorganic sol is by the ammonia of titanium tetrachloride+35%
Water+hydrogen peroxide 50%, by high-speed stirred, constant temperature and pressure is centrifuged, natural sedimentation, and 3 times are clean, highly purified, and 40
DEG C vacuum drying 8 hours, after crushed using hydrothermal preparing process, disperseed with 120 DEG C of deionized waters, be made translucent
Shape light yellow solution;
D. through high-pressure extrusion, granulation forms the tourmaline ceramic ball of 5mm particle diameters;
2)TiO2The preparation of-NCP composite photo-catalysts
A. precursor substance TiC1 is weighed4+H2The chemistry of O formation 50% is pure, and in injection reactor, it is 28% to be dissolved in chemistry pure
Ethanol acidic aqueous solution in, obtain mixture one;Under high velocity agitation, by hydrogen peroxide and the pure ethanol solution of 30% chemistry
In proportion 1:2.8 mixing, obtain mixture two;Mixture two is slowly dropped in mixture one by constant pressure funnel,
The ratio of mixture one and mixture two is 1:0.8, translucent pale yellow solution is made, 1.5 hours are stood after the completion of reaction,
Fully precipitation after discharge supernatant liquor, by 3 times centrifugation, clean it is highly purified after, while stirring inject 50 DEG C go from
Sub- water, Hydrothermal Synthesiss process for dispersing produces pH value 4;The concentration 1.2wt% titanium hydroxide inorganic sol aqueous solution, is designated as normalization
Product NT-D1;
B. by the normalization product NT-D1 weighed, in injection autoclave, through high temperature, high-pressure sinter, its temperature control
Between 550 DEG C, 30 minutes temperature controls are shut down after constant pressure and stood, plus nitrogen cooling, are stood aging 11 hours, are changed by titanium hydroxide
Detitanium-ore-type crystalline solid TiO is made2, concentration is adjusted to 0.90wt%;PH values 4, are designated as normalization product NT-D2;
C. 50 kilograms of normalization product NT-D2 are weighed, through more than 800 DEG C of high temperature sintering, optimal sintering temperature temperature control 850
DEG C, nitrogen cooling is added after standing, by anatase crystal TiO2Change into rutile ore type crystalline solid TiO2The aqueous solution, concentration is adjusted
Whole is 0.95wt%;
D. the rutile ore type crystalline solid TiO after normalization product NT-D2 and concentration adjustment after concentration is adjusted2It is water-soluble
Liquid presses 7:3 ratio is stirred 40 minutes using solution manufacturing method altogether under the conditions of 50 DEG C, plus after nitrogen cooling, stands 11 small
When, form milky mixed crystal TiO2Compound aqueous solution, is set as compound NT-D2F;
E. normalization product NT-D1,450g are weighed;Compound NT-D2F, 950g;Deionized water 8000g~9000g, mixes
Miscellaneous water-soluble platinum gold ionization compound 25g is configured to the concentration 2.5wt% aqueous solution, and water-soluble platinum gold ionization compound is commercially available
Commodity, using hydrothermal synthesis method and common solution doping technique, are made precious metal ion doping specialization product TiO2/ NCP is combined
Photochemical catalyst;
3) tourmaline ceramic load TiO2The preparation of the immobilized photochemical catalysts of-NCP
Using 3.0MM step 1) prepared by tourmaline ceramic ball through cleaning, dry, by dried tourmaline from
Step 2) prepared by TiO2The aqueous solution of-NCP inorganic sol is with 1min/m immersion process, then by 550 DEG C of high temperature
Sintering 3 minutes, cooling packing.
Embodiment 3
Described tourmaline ceramic load TiO2The preparation technology of the immobilized photochemical catalysts of-NCP includes step in detail below:
1) preparation of tourmaline ceramic
A. by dravite, schorl, elbaite and tsilaisite through over cleaning, dry, crush, covered by thunder
Machine or air-flow crushing are machined to 2500 mesh;
B. by 7kg polycrystals tourmaline powder and 3kg clay, blended stirring 60 minutes, in uniform shape;
C. 1 is pressed by concentration 0.90wt% titanium hydroxide inorganic sols are water-soluble:5 parts by weight are slowly injected in beater, make
Tourmaline powder and solid-like of the clay formation containing moisture content 30%, titanium hydroxide inorganic sol is by the ammonia of titanium tetrachloride+35%
Water+hydrogen peroxide 50%, by high-speed stirred, constant temperature and pressure is centrifuged, natural sedimentation, and 3 times are clean, highly purified, and 40
DEG C vacuum drying 8 hours, after crushed using hydrothermal preparing process, disperseed with 120 DEG C of deionized waters, be made translucent
Shape light yellow solution;
D. through high-pressure extrusion, granulation forms the tourmaline ceramic ball of 5mm particle diameters;
2)TiO2The preparation of-NCP composite photo-catalysts
A. precursor substance TiC1 is weighed4+H2The chemistry of O formation 50% is pure, and in injection reactor, it is 28% to be dissolved in chemistry pure
Ethanol acidic aqueous solution in, obtain mixture one;Under high velocity agitation, by hydrogen peroxide and the pure ethanol solution of 30% chemistry
In proportion 1:2.8 mixing, obtain mixture two;Mixture two is slowly dropped in mixture one by constant pressure funnel,
The ratio of mixture one and mixture two is 1:0.8, translucent pale yellow solution is made, stands 2 hours after the completion of reaction, fills
Supernatant liquor is discharged after fractional precipitation, by 3 centrifugations, clean it is highly purified after, 60 DEG C of deionization is injected while stirring
Water, Hydrothermal Synthesiss process for dispersing produces pH value 5;The concentration 1.4wt% titanium hydroxide inorganic sol aqueous solution, is designated as normalization production
Product NT-D1;
B. by the normalization product NT-D1 weighed, in injection autoclave, through high temperature, high-pressure sinter, its temperature control
Between 600 DEG C, 30 minutes temperature controls are shut down after constant pressure and stood, plus nitrogen cooling, are stood aging 12 hours, are changed by titanium hydroxide
Detitanium-ore-type crystalline solid TiO is made2, concentration is adjusted to 1.0wt%;PH values 5, are designated as normalization product NT-D2;
C. 50 kilograms of normalization product NT-D2 are weighed, through more than 800 DEG C of high temperature sintering, optimal sintering temperature temperature control 850
DEG C, nitrogen cooling is added after standing, by anatase crystal TiO2Change into rutile ore type crystalline solid TiO2The aqueous solution, concentration is adjusted
Whole is 1.0wt%;
D. the rutile ore type crystalline solid TiO after normalization product NT-D2 and concentration adjustment after concentration is adjusted2It is water-soluble
Liquid presses 7:4 ratio is stirred 45 minutes using solution manufacturing method altogether under the conditions of 60 DEG C, plus after nitrogen cooling, stands 12 small
When, form milky mixed crystal TiO2Compound aqueous solution, is set as compound NT-D2F;
E. normalization product NT-D1,450g are weighed;Compound NT-D2F, 950g;Deionized water 8000g~9000g, mixes
Miscellaneous water-soluble platinum gold ionization compound 25g is configured to the concentration 2.5wt% aqueous solution, and water-soluble platinum gold ionization compound is commercially available
Commodity, using hydrothermal synthesis method and common solution doping technique, are made precious metal ion doping specialization product TiO2/ NCP is combined
Photochemical catalyst;
3) tourmaline ceramic load TiO2The preparation of the immobilized photochemical catalysts of-NCP
Using 3.5MM step 1) prepared by tourmaline ceramic ball through cleaning, dry, by dried tourmaline from
Step 2) prepared by TiO2The aqueous solution of-NCP inorganic sol is with 1min/m immersion process, then by 600 DEG C of high temperature
Sintering 3 minutes, cooling packing.
Experimental analysis:
1. different catalyst is tested the degradation efficiency of HOCs in water under visible light.
1) catalyst:
Using specification, weight be same as tourmaline ceramic ball preparation method (step 1) prepare) prepare Chinese medicine stone ceramic
Ball and thunder feldspar ball are in same step 1) prepare, its purpose passes through different carrier material carried metal element codopes
TiO2/ NCP composite photo-catalysts, analysis 5 kinds of samples of contrast:1. market sale tourmaline ceramic ball product;②TiO2/ electrically
Prepared by feldspar ball (pressing step 1) .C.);3. metallic element codope TiO2Prepared by/tourmaline ceramic ball (pressing step 3));④
Metallic element codope TiO2Prepared by/Chinese medicine stone ceramic ball (pressing step 3));5. metallic element codope TiO2/ radium feldspar ball
Prepared by (pressing step 3))
1. market sale tourmaline ceramic ball product TCB;Particle diameter 2.5~3.5mm, 500g;
②TiO2/ tourmaline ceramic ball TiO2Prepared by/TCB (pressing step 1) .C.);Particle diameter 2.5~3.5mm, 500g;
③TiO2- NCP/ tourmaline ceramic balls TiO2Prepared by-NCP/TCB (pressing step 3));2.5~3.5mm of particle diameter,
500g;
④TiO2- NCP/ Chinese medicine stone ceramic balls TiO2Prepared by-NCP/ medical stones (pressing step 3));2.5~3.5mm of particle diameter,
500g;
⑤TiO2- NCP/ radium feldspar balls TiO2Prepared by-NCP/ radium stone (pressing step 3));Particle diameter 2.5~3.5mm, 500g;
2) experimental method:
The experimental analysis carried out in homemade reactor, the reagent used is that micro HOCs is added in pure water
Afterwards, light is radiated at the above sample in water, experimental analysis photocatalysis HOCs oxidation Decomposition efficiency, to evaluate invention system respectively
The TiO obtained2/ TCB composite photo-catalysts also have naturally-produced representative to the degradation efficiency of the HOCs in drinking water
Microcystin-LR (is purchased from ALEXIS companies).The existing artificial synthesized several class POPs of selected HOCs (such as polycyclic aromatic hydrocarbon,
Polychlorinated biphenyl (being purchased from State center for standard matter)).
3) reactor:
Reactor is made up of reactive tank, light source, constant temperature dashpot and circulating pump.All components are saturating using stainless steel and height
Quartz glass depending on rate is manufactured.Wherein light source (is purchased from the limited public affairs of the special Optoelectronics Technology share of Guangdong Shelley for 8*5W from colour filter lamp
Department), wavelength is respectively from 365nm ultraviolets and 420nm visible ray, and the HOCs contents added in water refer to national standard
GB/T5750-2006《Drinking water standard experimental method》Use HPLC and GC/MS (imported from America liquid chromatograph and gas phase
Chromatograph) detection is sampled before illumination and after illumination two hours respectively, represented with the elimination factor of harmful substance before and after the processing with
The degradation efficiency of upper sample.
4) experimentation:
Water quality experiment purifier be by the high 320mm of diameter 158mm thickness 2mm stainless steel can open from colour filter lamp
Tower cover, built with 8 5W from colour filter lamp.The photo catalysis reactor of the high 250mm quartz glass of built-in diameter 67mm thickness 3mm,
And equipped with reactive tank, constant temperature dashpot and circulating pump.Purification style is circularly purifying, sewage sample:Added in pure water micro-
HOCs, total amount 1.5kg are measured,
Laboratory sample:5 kinds of 2.5~3.5mm of diameter, weight 500g catalyst prods
Experimental situation humidity:30%~40%
Experimental situation temperature:25℃
Test radiation source:Wavelength 365nm (ultraviolet)~420nm (visible ray)
Purification style:Circularly purifying 2h.
5) experimental result:
5 kinds of different catalysts under wavelength 365nm~420nm illumination to water in HOCs degradation efficiency contrast table 1:
The degradation efficiency contrast table of the different catalysts of table 1 under visible light to HOCs in water
As can be seen from Table 1, under 420nm light action, degradation efficiency of several composite photo-catalysts to POPs in water.Its
In, CO is that initial concentration CO about 1mg/L C/CO are the ratio between HOCs contents and initial content, the smaller table of ratio in water after effect 2h
Show that degradation efficiency is higher.It can be seen that, 1. TCB slightly has adsorption capacity, pure TiO to HOCs in water2After being supported on TCB, can
In the presence of seeing under light, though HOCs concentration has further decline, the limited extent declined;2. it is supported on TCB
TiO2Adulterate after Fe, N, S, POPs concentration declines obvious, and 2h is acted under visible light close to being completely eliminated;③Fe、N、S
The TiO of codope2On different carriers, the eradicating efficacy difference to HOCs is obvious, demonstrates the special electrochemical properties of TCB
To TiO2- NCP photocatalysis has cooperative effect.
The multi-element doping TiO that the present invention is prepared using natural Tourmaline2/ TCB composite photo-catalysts, multielement codope
TiO2/ TCB composite photo-catalysts, can carry out advanced treating to HOCs in water under field conditions (factors), and " zero " waste is produced, and is belonged to
Environment-friendly Green Product;The performance for making modern nanometer technology improve water quality with tourmaline ceramic is organically combined, collaboration
The effect of effect not only substantially increases nano-TiO2The ability of degraded Organic substance in water, and be expected to handle out with certain raw
The healthy drinking water of reason effect;Prepared multielement codope TiO2/ TCB composite photo-catalysts, not only with utilizing the sun
The premium properties of light environment purification, and be easy to reclaim and reuse, be conducive to being widely used in various green technologies.
Finally illustrate, preferred embodiment above is merely illustrative of the technical solution of the present invention and unrestricted, although logical
Cross above preferred embodiment the present invention is described in detail, it is to be understood by those skilled in the art that can be
Various changes are made to it in form and in details, without departing from claims of the present invention limited range.
Claims (3)
1. a kind of tourmaline ceramic loads TiO2The preparation technology of the immobilized photochemical catalysts of-NCP, it is characterised in that:Described is electric
Feldspar loads TiO2The preparation technology of the immobilized photochemical catalysts of-NCP includes step in detail below:
1)The preparation of tourmaline ceramic
A. by dravite, schorl, elbaite and tsilaisite through over cleaning, dry, crush, by Raymond machine or
Person's air-flow crushing is machined to 2000 ~ 2500 mesh;
B. by 10kg polycrystals tourmaline powder and clay, blended stirring 60 minutes, in uniform shape, the polycrystal tourmaline
The composition of powder and clay is tourmaline 60%~70%, and clay 30%~40% is constituted;
C. 1 is pressed by concentration 0.85 ~ 0.90wt% titanium hydroxide inorganic sols are water-soluble:3 ~ 5 parts by weight are slowly injected in beater,
Make tourmaline powder and solid-like of the clay formation containing moisture 30%;
D. through high-pressure extrusion, granulation forms the tourmaline ceramic ball of 3 ~ 8mm particle diameters;
2)TiO2The preparation of-NCP composite photo-catalysts
A weigh precursor substance TiC14+H2O formation 50% chemistry it is pure, injection reactor in, be dissolved in chemistry it is pure be 28% ethanol
In acidic aqueous solution, mixture one is obtained;Under high velocity agitation, by hydrogen peroxide and the pure ethanol solution of 30% chemistry in proportion
1:2.8 mixing, obtain mixture two;Mixture two is slowly dropped in mixture one by constant pressure funnel, mixture
One is 1 with the ratio of mixture two:0.8, translucent pale yellow solution is made, 1 ~ 2 hour is stood after the completion of reaction, it is fully heavy
Supernatant liquor is discharged behind shallow lake, by 3 centrifugations, clean it is highly purified after, 40 DEG C ~ 60 DEG C of deionization is injected while stirring
Water, Hydrothermal Synthesiss process for dispersing produces pH value 3 ~ 5;1.0 ~ 1.4wt% of the concentration titanium hydroxide inorganic sol aqueous solution, is designated as rule
Format product NT-D1;
B. by the normalization product NT-D1 weighed, in injection autoclave, through high temperature, high-pressure sinter, its temperature control exists
Between 500 DEG C ~ 600 DEG C, 30 minutes temperature controls are shut down after constant pressure and stood, plus nitrogen cooling, aging 10 ~ 12 hours are stood, by hydrogen-oxygen
Change titanium and change system into Detitanium-ore-type crystalline solid TiO2, concentration is adjusted to 0.85 ~ 1.0wt%;PH value 3 ~ 5, is designated as normalization product NT-
D2;
C. 50 kilograms of normalization product NT-D2 are weighed, through more than 800 DEG C of high temperature sintering, after standing plus nitrogen cooling, by anatase
Type crystal TiO2Change into rutile ore type crystalline solid TiO2The aqueous solution, concentration is adjusted to 0.9 ~ 1.0wt%;
D concentration is adjusted after normalization product NT-D2 and concentration adjustment after rutile ore type crystalline solid TiO2The aqueous solution is pressed
7:3 ~ 4 ratio is stirred 30 ~ 45 minutes using solution manufacturing method altogether under the conditions of 40 DEG C ~ 60 DEG C, plus after nitrogen cooling, it is quiet
Put 10 ~ 12 hours, form milky mixed crystal TiO2Compound aqueous solution, is set as compound NT-D2F;
E. normalization product NT-D1,450g are weighed;Compound NT-D2F, 950g;Deionized water 8000g ~ 9000g, adulterates water-soluble
Property platinum ionic compound 25g be configured to the concentration 2.5wt% aqueous solution, water-soluble platinum gold ionization compound is commercial goods, is adopted
With hydrothermal synthesis method and common solution doping technique, precious metal ion doping specialization product TiO is made2/ NCP composite photocatalysts
Agent;
3)Tourmaline ceramic loads TiO2The preparation of the immobilized photochemical catalysts of-NCP
Using 2.5-3.5mm step 1)Prepared tourmaline ceramic ball by cleaning, drying, by dried tourmaline from
Step 2)Prepared TiO2The aqueous solution of-NCP inorganic sol is with 1min/m immersion process, then by 500 DEG C -600 DEG C
High temperature sintering 3 minutes, cooling packing.
2. a kind of tourmaline ceramic load TiO according to claim 12The preparation technology of the immobilized photochemical catalysts of-NCP, its
It is characterised by:Described step 1)Step c in titanium hydroxide inorganic sol be by the ammoniacal liquor of titanium tetrachloride+35%+hydrogen peroxide
50%, by high-speed stirred, constant temperature and pressure is centrifuged, natural sedimentation, and 3 times clean, highly purified, and 40 DEG C of vacuum drying 8 are small
When, after crushed using hydrothermal preparing process, disperseed with 120 DEG C of deionized waters, translucent light yellow solution is made.
3. a kind of tourmaline ceramic load TiO according to claim 12The preparation technology of the immobilized photochemical catalysts of-NCP, its
It is characterised by:Described step 2)Step c in 850 DEG C of sintering temperature temperature control.
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CN103071499A (en) * | 2012-12-19 | 2013-05-01 | 大连市疾病预防控制中心 | Titanium dioxide-doped tourmaline ceramic ball photocatalyst and preparation method thereof |
CN103341356A (en) * | 2013-07-23 | 2013-10-09 | 北京纳琦环保科技有限公司 | Processing method of water purifying agent of ceramic tourmaline-loaded titanium dioxide film |
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CN103071499A (en) * | 2012-12-19 | 2013-05-01 | 大连市疾病预防控制中心 | Titanium dioxide-doped tourmaline ceramic ball photocatalyst and preparation method thereof |
CN103341356A (en) * | 2013-07-23 | 2013-10-09 | 北京纳琦环保科技有限公司 | Processing method of water purifying agent of ceramic tourmaline-loaded titanium dioxide film |
Non-Patent Citations (2)
Title |
---|
提高纳米TiO2可见光催化活性的元素掺杂方法研究进展;郭俊刚等;《宁波化工》;20081231(第1期);第9-13页 * |
蜂窝陶瓷负载TiO2降解甲基橙试验研究;梁华银等;《陶瓷学报》;20111231;第32卷(第2期);第235-238页 * |
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