CN106492708B - Granulation Equipments for vulcanized sodium - Google Patents

Granulation Equipments for vulcanized sodium Download PDF

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Publication number
CN106492708B
CN106492708B CN201610932737.6A CN201610932737A CN106492708B CN 106492708 B CN106492708 B CN 106492708B CN 201610932737 A CN201610932737 A CN 201610932737A CN 106492708 B CN106492708 B CN 106492708B
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granulation
granulation tower
tower
screening machine
groove
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CN106492708A (en
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赵仁怀
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Nantong Tiansheng plastic packaging Co., Ltd
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CHONGQING CITY NANCHUAN DISTRICT QINGYAN WELFARE ALKALI FACTORY
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2/00Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic
    • B01J2/02Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic by dividing the liquid material into drops, e.g. by spraying, and solidifying the drops
    • B01J2/06Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic by dividing the liquid material into drops, e.g. by spraying, and solidifying the drops in a liquid medium

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Glanulating (AREA)
  • Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)

Abstract

This patent discloses a kind of Granulation Equipments for vulcanized sodium,Including granulation tower,Granulation tower inner upper is equipped with prilling spry,It is provided with cooling device above the inner wall of granulation tower,N-butyl ether is equipped in cooling device,Granulation tower lower end is equipped with discharge port,The lower section of granulation tower discharge port is equipped with screening machine,The top of screening machine is equipped with delivery sheet,Several through-holes is offered on delivery sheet,L-type groove is offered on screening machine,L-type groove includes vertical groove and transverse concave groove,Vertical groove is located at the underface of discharge port,Tension spring and diversion rod are equipped in transverse concave groove,One end of diversion rod is connect with tension spring,The diversion rod other end stretches out screening machine and is connect with delivery sheet,Discharge orifice is further opened on screening machine,Discharge orifice is communicated with transverse concave groove,Collecting tank is additionally provided with below discharge orifice,Collecting tank is connect by pipeline and pump with cooling device.This programme is to be effectively guaranteed the granulation quality of vulcanized sodium.

Description

Granulation Equipments for vulcanized sodium
Technical field
The present invention relates to the production equipment of vulcanized sodium, specially a kind of Granulation Equipments.
Background technology
Vulcanized sodium is also known as smelly alkali, smelly soda, yellow alkali, akali sulphide.Vulcanized sodium is inorganic compound, and pure vulcanized sodium is colourless knot Crystalline flour end.Moisture absorption is strong, soluble easily in water.Aqueous solution is reacted in strong basicity.It can cause to burn when touching skin and hair.Therefore vulcanize Sodium is commonly called as akali sulphide.Vulcanized sodium as a kind of basic chemical raw materials, the necessity of national economy, be widely used in papermaking, leather, Non-ferrous metal ore, weaving, printing and dyeing, dyestuff, pigment, polysulfide rubber, polyphenylene sulfide, medicine, organic chemical industry's intermediate, lithopone The industries such as manufacture.
The production method of akali sulphide mainly has coal(Carbon)High temperature reduction mirabilite method, barium sulfate by-product method, caustic lye of soda absorb secondary Produce three kinds of hydrogen sulfide method.Production process includes mainly the upper material process of stock, calcination process, changes base washery slag process, precipitates and wash bricklayer's Sequence, low iron akali sulphide liquid process, evaporization process, shaping packaging process.In the shaping packaging process of granular akali sulphide, it is granulated Machine is most important production equipment.
In melt material pelletizing equipment, there are three types of forms mostly:One is high-tower melting granulation, i.e., set in granulation tower Prilling head is set to do the movement of falling object in granulation tower after fused materials granulation head sprays, in dropping process gradually cure, This equipment needs corresponding height that could meet solidifying requirements, therefore general granulation tower is relatively high, equipment once investment compared with Height, and energy consumption is higher;The second is steel band type melt pelletization, manufactured particle is mostly semicircle shape particle, and particle diameter is larger, simultaneously Steel band is regularly replaced, maintenance cost is higher;The third is roller slicer, finished product is mostly sheet, and material fluidity is poor, gradually It is replaced by circular granular.
A kind of water curtain style melt pelletization system is disclosed in China Patent No. ZL201310086432.4, including is granulated Tower, the granulation tower inner upper are equipped with prilling spry, and the granulation tower is up big and down small conical shell, the prilling spry It is arranged above granulation tower, is granulated above inner wall of tower and is provided with drenching installation, cooling water is flowed out by drenching installation bores along granulation tower Shape cylinder inboard wall flows downward, and granulation tower lower end is equipped with discharge port.Said program carries out curing by the way of direct water-cooling cold But, drenching installation forms water curtain in granulation tower cone inner wall, and the fused materials drop that prilling spry ejects connects with cooling water Cured rapidly after touch, discharge port flowed downward to then as cooling water, into screening machine after carry out object water separation, material into Fluidized bed is dried, and cooling water enters water tank reuse, big using the cured form of direct water-cooling since fused materials are not soluble in water The big height for reducing prior art granulation tower, simple in structure, height is relatively low, and investment is less, and maintenance cost is low.
But said program still can there is a problem of following in actual use:The cooling water that drenching installation sprays is along granulation Tower taper barrel flows downward, and is flowed into water tank after discharge port and screening machine, and the cooling water being flowed into water tank passes through again Pipeline and pump turn again in drenching installation, and are ejected again, since the cooling water of drenching installation ejection is in taper barrel The amount of heat of material generation can be absorbed, therefore the cooling water being discharged to out of taper barrel in water tank will have higher temperature, The water in water tank is ejected after turning again in drenching installation at this time, the cooling water sprayed at this time due to higher temperature, And then can cause to weaken the cooling effect of material significantly, the serious granulation outcome that will influence whether material, reduce yield rate.
Invention content
The invention is intended to provide a kind of Granulation Equipments ensureing cooling effect in vulcanized sodium production process.
The Granulation Equipments for vulcanized sodium in this programme, including granulation tower, granulation tower inner upper are equipped with prilling spry, Granulation tower is up big and down small conical shell, and prilling spry is arranged above granulation tower, is provided with above the inner wall of granulation tower cold But device, is equipped with n-butyl ether in cooling device, n-butyl ether sprayed from cooling device after along granulation tower conical shell inner wall to flowing down Dynamic, granulation tower lower end is equipped with discharge port, and the lower section of granulation tower discharge port is equipped with screening machine, and the top of screening machine is equipped with delivery sheet, Several through-holes is offered on delivery sheet, L-type groove is offered on screening machine, and L-type groove includes that vertical groove and transverse direction are recessed Slot, vertical groove are located at the underface of discharge port, and tension spring and diversion rod are equipped in transverse concave groove, and one end and the tension spring of diversion rod connect It connects, the diversion rod other end stretches out screening machine and connect with delivery sheet, and discharge orifice, discharge orifice and transverse direction are further opened on screening machine Groove communicates, and collecting tank is additionally provided with below discharge orifice, and collecting tank is connect by pipeline and pump with cooling device.
The principle of this programme is:When to being granulated by the high temperature vulcanized sodium molten liquid of evaporization process, vulcanize sodium fusion Melt liquid to spray from prilling spry, while n-butyl ether is also sprayed from cooling device, the high temperature energy of vulcanized sodium molten liquid is by positive fourth After ether absorbs, vulcanized sodium will cure rapidly, then be flowed downwardly together with n-butyl ether and cause discharge port.
The n-butyl ether and granular vulcanized sodium flowed out from discharge port will be fallen on the delivery sheet of screening machine after discharge port outflow, Wherein granular vulcanized sodium will stay on delivery sheet, and n-butyl ether will then be flowed into the L-type of screening machine from the through-hole of delivery sheet In groove, the n-butyl ether being flowed into L-type groove will push diversion rod that the active force of tension spring is overcome to move, and diversion rod is mobile Delivery sheet connected to it will be driven to move together simultaneously, so that the granular vulcanized sodium being discharged from discharge port will uniformly divide Cloth is on delivery sheet.
When diversion rod is lasting when being moved at discharge orifice under the action of n-butyl ether, the n-butyl ether in L-type groove will be from It is discharged at discharge orifice, the n-butyl ether being discharged from discharge orifice will be flowed into the collecting tank below discharge orifice, be flowed into collecting tank Interior n-butyl ether is absorbed into cooling device under the action of pipeline and pump and is reused again, while when discharge orifice is beaten When opening, the fluid pressure in L-type groove declines, so that diversion rod will back move under the action of tension spring, clears up at this time The vulcanized sodium that completion has been granulated on lower delivery sheet both may be used.
The effect of this programme is:The n-butyl ether that amount of heat is absorbed in granulation tower is discharged this programme from discharge port Afterwards, n-butyl ether is re-introduced into L-type groove, and n-butyl ether does work to diversion rod in L types groove so that diversion rod overcomes the work of tension spring Firmly move, made by way of acting n-butyl ether absorb heat distributed, so when acting after from discharge orifice arrange The n-butyl ether gone out is flowed into collecting tank, and the heat that n-butyl ether absorbs has obtained effective utilization, therefore the n-butyl ether in collecting tank It has been restored to state low in calories when being transmitted to cooling device through piping and pump, sprinkling is carried out for cold to n-butyl ether again But effect when vulcanized sodium will greatly improve, to be effectively guaranteed the cooling effect of vulcanized sodium in process of production, into And it ensure that the granulation quality of vulcanized sodium.
Further, it is equipped with switch in one end that diversion rod is connect with tension spring, gear is hinged on the inner wall of granulation tower side Plate offers card slot on the inner wall of the granulation tower other side, the first electromagnetic block is equipped in card slot, and the first electromagnetic block is equipped with first Magnet exciting coil, the first magnet exciting coil are electrically connected with switch.
When the switch is closed, the first magnet exciting coil powers off, and when the switches are opened, the first magnet exciting coil is powered.
During n-butyl ether pushes deflector movement, when switch is not moved at discharge orifice, switch is in closure State, the power-off of the first magnet exciting coil, the first electromagnetic block do not have electromagnetic force, when deflector movement until switch reaches at discharge orifice When, under the action of discharge orifice, switch is opened, and the first magnet exciting coil is powered at this time, and the first electromagnetic block has electromagnetic force, in the electricity Under the action of magnetic force, the first electromagnetic block will generate attraction to the baffle for being hinged on granulation inner wall of tower and be made under the action of baffle Discharge outlet on grain tower will be blocked, and n-butyl ether cannot be discharged from discharge port, meanwhile, when n-butyl ether pushes deflector to reach When at discharge orifice, the n-butyl ether in L-type groove will be discharged from discharge orifice, and n-butyl ether is to the declines of deflector at this time, Under the action of tension spring, deflector will reset, and after the switch on deflector, which is resetted, to be staggered with discharge orifice, switch is closed again, the One magnet exciting coil powers off, and the first electromagnetic block loses electromagnetic force, and baffle resets, and discharge outlet is opened, and n-butyl ether flows again into L-type In groove.
For this programme when the n-butyl ether in L-type groove at discharge orifice by being discharged, baffle will be in the first electromagnetic block electromagnetic force Under the action of discharge outlet is closed, n-butyl ether will stop flow into L-type groove at this time, to prevent n-butyl ether continual Flow into the case where caused deflector is unable to normal reset in L-type groove.
Further, cooling device is the cooling bath being arranged being granulated above inner wall of tower, and overflow baffle is equipped on the inside of cooling bath, Overflow baffle upper end surface is in same level.Distribution when overflow baffle makes n-butyl ether spray out is more uniform, protects The granulation outcome of vulcanized sodium has been demonstrate,proved, while having been used also very convenient.
Further, diversion rod and delivery sheet are attached by head, and head includes the first link block and the Two link blocks, the first link block are fixedly connected with delivery sheet, and the second link block is fixedly connected with diversion rod, on the second link block Offer mounting groove, equipped with magnet and the second electromagnetic block that can be moved along mounting groove in mounting groove, the second electromagnetic block is equipped with the Two magnet exciting coils, the second magnet exciting coil are electrically connected with switch, and compression spring is equipped between the second electromagnetic block and the first link block.
When the switch is closed, the second magnet exciting coil powers off, and when the switches are opened, the second magnet exciting coil is powered.
When deflector be moved under the action of n-butyl ether make switch reach discharge orifice at before when, switch be in closed form State, the power-off of the second magnet exciting coil, the second electromagnetic block do not have electromagnetic force, magnet that the effect for generating power to electromagnetic block is made electromagnetic block It is bonded with magnet, when switch is moved at discharge orifice, the second magnet exciting coil is powered, and the second electromagnetic block generates identical with magnet Polarity, according to the principle that identical charges repel each other, the second electromagnetic block will be displaced outwardly along mounting groove, while mobile, in the work of compression spring Under firmly, compression spring will push the first link block to move up, so that delivery sheet generates heeling condition, the material on delivery sheet Automatically it is cleaned, so that the use of whole device is more intelligent.
Further, cooling device includes that setting is being granulated equally distributed several spray heads above inner wall of tower.Several sprays Head, which is evenly distributed in, to be granulated above inner wall of tower, ensures entire spray effect.
Description of the drawings
Fig. 1 is the structural schematic diagram of the embodiment of the present invention.
Fig. 2 is the structural schematic diagram of head in Fig. 1 embodiments.
Specific implementation mode
Below by specific implementation mode, the present invention is described in further detail:
Reference numeral in Figure of description includes:Granulation tower 1, prilling spry 2, cooling bath 3, the 4, first electricity of overflow baffle Magnetic patch 5, baffle 6, delivery sheet 7, the first link block 8, the second link block 9, magnet 91, the second electromagnetic block 92, compression spring 10, diversion rod 11, discharge orifice 12, collecting tank 13, switch 14, tension spring 15, screening machine 16.
Embodiment is substantially as shown shown in Figure 1 and Figure 2:For the Granulation Equipments of vulcanized sodium, including granulation tower 1, granulation tower 1 For up big and down small conical shell, prilling spry 2 is installed in the upside of granulation tower 1, prilling spry 2 is for spraying vulcanization sodium fusion Melt liquid, cooling device is equipped on the inner wall of granulation tower 1, cooling device includes the cooling bath 3 being arranged above 1 inner wall of granulation tower With equally distributed several spray heads, 3 inside of cooling bath is equipped with overflow baffle 4, and 4 upper end surface of overflow baffle is in same level On.Distribution when overflow baffle 4 makes n-butyl ether spray out is more uniform, ensure that the granulation outcome of vulcanized sodium, makes simultaneously It uses also very convenient.
It is additionally provided with baffle 6 on the inner wall in 1 left side of granulation tower, baffle 6 and the inner wall of granulation tower 1 are hinged, are making Card slot is offered on the inner wall on 1 right side of grain tower, the first electromagnetic block 5 is equipped in card slot, and the first electromagnetic block 5 is equipped with the first excitation wire Circle.It is further opened with discharge port in the downside of granulation tower 1.
It is equipped with screening machine 16 in the downside of 1 discharge port of granulation tower, the top of screening machine 16 is equipped with delivery sheet 7, on delivery sheet 7 Equipped with several allow liquid by through-hole, offer L-type groove on screening machine 16, L-type groove include vertical groove and Transverse concave groove, vertical groove are located at the underface of discharge port, tension spring 15 and diversion rod 11 are equipped in transverse concave groove, and diversion rod 11 is left End connect with tension spring 15 and is equipped with switch 14, and switch 14 is electrically connected with the first magnet exciting coil, and 11 right end of diversion rod stretches out screening machine It 16 and is attached by head with delivery sheet 7, head includes the first link block 8 and the second link block 9, and first connects It connects block 8 to be fixedly connected with delivery sheet 7, the second link block 9 is fixedly connected with diversion rod 11, and peace is offered on the second link block 9 Tankage, mounting groove is interior equipped with magnet 91 and the second electromagnetic block 92 that can be moved along mounting groove, and the second electromagnetic block 92 is equipped with second Magnet exciting coil, the second magnet exciting coil are electrically connected with switch 14, and compression spring is equipped between the second electromagnetic block 92 and the first link block 8 10。
It is further opened with discharge orifice 12 on the right side of screening machine 16, collecting tank 13, collecting tank are equipped in the lower section of discharge orifice 12 13 are connect by pipeline and pump with cooling device.
When to being granulated by the high temperature vulcanized sodium molten liquid of evaporization process, vulcanized sodium molten liquid is from prilling spry 2 It sprays, while n-butyl ether is also sprayed from uniformly distributed spray head, and the high temperature energy of vulcanized sodium molten liquid will after being absorbed by n-butyl ether Then rapid solidification is flowed with n-butyl ether and causes discharge port downwardly together.
The n-butyl ether and granular vulcanized sodium flowed out from discharge port will fall on the delivery sheet 7 of screening machine 16 after discharge port outflow On, wherein granular vulcanized sodium will stay on delivery sheet 7, n-butyl ether then will be flowed into screening machine from the through-hole of delivery sheet 7 In 16 L-type groove, the n-butyl ether being flowed into L-type groove will push diversion rod 11 that the active force of tension spring 15 is overcome to move, and lead Flow post 11 will drive delivery sheet 7 connected to it to move together while mobile, so that being discharged from discharge port granular Vulcanized sodium will be evenly distributed on delivery sheet 7.
When diversion rod 11 under the action of n-butyl ether lasting when being moved at discharge orifice 12, the n-butyl ether in L-type groove It will be discharged from discharge orifice 12, the n-butyl ether being discharged from discharge orifice 12 will be flowed into the collecting tank 13 of 12 lower section of discharge orifice, The n-butyl ether being flowed into collecting tank 13 is absorbed into cooling device under the action of pipeline and pump and is reused again, Simultaneously when discharge orifice 12 is opened, the switch 14 on diversion rod 11 is opened, and the first magnet exciting coil and the second magnet exciting coil lead to simultaneously Electricity, the first electromagnetic block 5 and electromagnetic block have electromagnetic force, and the first electromagnetic block 5 is by the baffle 6 to being hinged on 1 inner wall of granulation tower at this time Attraction is generated, under the action of baffle 6, the discharge outlet on granulation tower 1 will be blocked, and n-butyl ether cannot be arranged from discharge port Go out, the second electromagnetic block 92 generates polarity identical with magnet 91, and according to the principle that identical charges repel each other, the second electromagnetic block 92 will be along installation Slot is displaced outwardly, and while mobile, under the active force of compression spring 10, compression spring 10 will push the first link block 8 to move up, from And so that delivery sheet 7 generates heeling condition, the material on delivery sheet 7 is cleaned automatically.When in L-type groove n-butyl ether discharge, After vulcanized sodium cleaning on delivery sheet 7, under the action of tension spring 15, diversion rod 11 resets, and switch 14 is in closed state again, First magnet exciting coil and the power-off of the second magnet exciting coil, repeat.
Above-described is only the embodiment of the present invention, and the common sense such as well known concrete structure and characteristic are not made herein in scheme Excessive description.It, without departing from the structure of the invention, can be with it should be pointed out that for those skilled in the art Several modifications and improvements are made, these should also be considered as protection scope of the present invention, these all do not interfere with what the present invention was implemented Effect and patent practicability.The scope of protection required by this application should be based on the content of the claims, in specification The records such as specific implementation mode can be used for explaining the content of claim.

Claims (5)

1. a kind of Granulation Equipments for vulcanized sodium, including granulation tower, granulation tower inner upper is equipped with prilling spry, and granulation tower is Up big and down small conical shell, prilling spry are arranged above granulation tower, and cooling device is provided with above the inner wall of granulation tower, cold But n-butyl ether is equipped in device, n-butyl ether flows downward after being sprayed by cooling device along granulation tower conical shell inner wall, granulation tower Lower end is equipped with discharge port, which is characterized in that the lower section of granulation tower discharge port is equipped with screening machine, and the top of screening machine is equipped with feeding Plate offers several through-holes on delivery sheet, L-type groove is offered on screening machine, L-type groove includes vertical groove and transverse direction Groove, vertical groove are located at the underface of discharge port, tension spring and diversion rod, one end of diversion rod and tension spring are equipped in transverse concave groove Connection, the diversion rod other end stretch out screening machine and are connect with delivery sheet, and discharge orifice, discharge orifice and cross are further opened on screening machine It is communicated to groove, collecting tank is additionally provided with below discharge orifice, collecting tank is connected by pipeline and pump, and pump connects with cooling device It connects.
2. the Granulation Equipments according to claim 1 for vulcanized sodium, it is characterised in that:It is connect with tension spring in diversion rod One end is equipped with switch, is hinged with baffle on the inner wall of granulation tower side, card slot is offered on the inner wall of the granulation tower other side, The first electromagnetic block is equipped in card slot, the first electromagnetic block is equipped with the first magnet exciting coil, and the first magnet exciting coil is electrically connected with switch.
3. the Granulation Equipments according to claim 1 for vulcanized sodium, it is characterised in that:Cooling device includes that setting is being made Cooling bath above grain inner wall of tower, cooling bath inside are equipped with overflow baffle, and overflow baffle upper end surface is in same level.
4. the Granulation Equipments according to claim 2 for vulcanized sodium, it is characterised in that:Diversion rod and delivery sheet pass through work Dynamic device is attached, and head includes the first link block and the second link block, and the first link block is fixedly connected with delivery sheet, Second link block is fixedly connected with diversion rod, offers mounting groove on the second link block, magnet is equipped in mounting groove and can edge Second electromagnetic block of mounting groove movement, the second electromagnetic block are equipped with the second magnet exciting coil, and the second magnet exciting coil is electrically connected with switch, Compression spring is equipped between the second electromagnetic block and the first link block.
5. the Granulation Equipments according to claim 4 for vulcanized sodium, it is characterised in that:Cooling device is several uniform points Cloth is in the spray head being granulated above inner wall of tower.
CN201610932737.6A 2016-10-31 2016-10-31 Granulation Equipments for vulcanized sodium Active CN106492708B (en)

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