CN106489974B - A kind of Herbicidal combinations - Google Patents
A kind of Herbicidal combinations Download PDFInfo
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- CN106489974B CN106489974B CN201510563311.3A CN201510563311A CN106489974B CN 106489974 B CN106489974 B CN 106489974B CN 201510563311 A CN201510563311 A CN 201510563311A CN 106489974 B CN106489974 B CN 106489974B
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- herbicidal combinations
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- clefoxidim
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Abstract
The present invention relates to a kind of Herbicidal combinations.The invention further relates to a kind of methods for controlling undesirable plant.The present invention provides a kind of Herbicidal combinations, and active component is made of compound (A) and compound (B), wherein (A) is the compound described by formula (I):(I) and (B) is the compound described by formula (II):
Description
Technical field
The present invention relates to a kind of Herbicidal combinations.The invention further relates to a kind of methods for controlling undesirable plant.
Background technique
There are many weeds in paddy field type, and paddy field weeding is a great problem in production.Chemical method weeding is control weeds
Main means.But in recent years, since some herbicide kind large area are used alone, already leads to many weeds and generate anti-medicine
Property.Meanwhile grass phase is complicated when weeds generation, the mixed life of gramineae weed, broadleaf weeds, nutgrass flatsedge multiclass weeds, single variety removes
Careless agent is all shown defects and limitations in one aspect using not can solve farmland weed.
Proxazuron-methyl (Propyrisulfuron) is pyrimidine radicals sulfonylurea herbicide developed by Japan Sumitomo Chemical
Agent is mainly used for paddy field and prevents and kill off the grass family such as barnyard grass and broadleaf weeds.The product dosage is low, removes to certain known sulfonylureas
The weeds that careless agent generates resistance have good preventive effect.Proxazuron-methyl to annual and perennial paddy field weed, such as barnyard grass and
Ticklish water chestnut, arrowhead etc. have good preventive effect.Though proxazuron-methyl belongs to sulfonylurea herbicide, it is to certain
The weeds that known sulfonylurea herbicide generates resistance still have good activity.It is primary that proxazuron-methyl is mainly used for early metaphase
Property the herbicide killed, can be used for being made the pesticidal preparations products such as suspending concentrate or large-scale tablet, be directly thrown to field.Third
Piperazine Sulfometuron Methyl, molecular formula C16H18O5N7SCl, molecular structure are as follows:
(I)
Clefoxidim (Clefoxydim), chemical name are (2- [1- [2- (4- chlorophenoxy) propoxyl group imino group] fourth
Base -3- hydroxyl -5- [tetrahydro -2H- thiapyran (thia) -3- base] hexamethylene -2- ketenes, structural formula are as follows:
(II)
Clefoxidim is the cyclohexenone analog herbicide developed by BASF AG.Cyclohexenone compounds are mostly used for
Dry land weeding, clefoxidim are a kind of presently found unique cyclohexenone analog herbicides for paddy field weed-killer.It belongs to water
Field broad-spectrum herbicide is mainly used for preventing and kill off rice field gramineae weed such as barnyard grass, herba digitariae, semen euphorbiae, herba setariae viridis, Tong axis thatch etc.,
It is safe to direct seading rice and transplanting rice.Clefoxidim is acetyl-CoA carboxylase (ACCase) inhibitor, after foliage application
Rapid plant absorbs and transfer, is transferred to growing point in bast, inhibits the growth of sprouting, and weeds elder generation chlorosis changes colour withered afterwards,
It is completely withered in 2-3 weeks general, it is fool proof to ecological environment.Clefoxidim is undesirable to broad-leaved and sedge weed preventive effect.
Sulfonylurea herbicide is selective inner-adsorption conduction-type herbicide, can be absorbed by weeds root and blade, in plant body
Interior rapid conduction, after inhibiting cell division and growth, susceptible weeds to absorb medicament, young shoot and root stop growing rapidly, tender group of children
Hair-weaving is yellow, then withered.But there are still some problems in application process for sulfonylurea herbicide, wherein most outstanding is that its is residual
Stay phytotoxicity and weeds to the resistance problem of sulfonylurea herbicide.
Summary of the invention
Object of the present invention is to provide a kind of Herbicidal combinations in view of the above shortcomings, so that those skilled in the art are in rice
Crop is by controlling a variety of weeds or a certain uncontrollable weeds type after applying these herbicides once or several times.
The present invention obtains technical staff by the way that proxazuron-methyl and clefoxidim to be combined in a particularly advantageous manner
Required Weeds distribution is horizontal, or even includes uncontrollable certain weeds types that resistance is generated to sulfonylurea herbicide.
Moreover, the amount of application of single component in combination can be significantly reduced in the application present composition, the plant poison to crop is reduced
Property.
The object of the present invention is to provide a kind of Herbicidal combinations, active component is made of compound (A) and compound (B),
Wherein (A) is the compound proxazuron-methyl described by formula (I),
(I)
It (B) is the compound clefoxidim described by formula (II),
(II)
The weight ratio of the compound (A) and (B) are 50:1-1:50, preferably 25:1-1:25, further preferably 10:1-1:10,
More preferable 5:1-1:5.
A kind of Herbicidal combinations, active component is made of compound (A) and compound (B), filler and/or surface-active
Agent.
In the Herbicidal combinations, the content of compound (A) and compound (B) accounts for the 5%-90% of the Herbicidal combinations.
In the Herbicidal combinations, the content of compound (A) and compound (B) accounts for the Herbicidal combinations 10%-80%.
In the Herbicidal combinations, the content of compound (A) and compound (B) accounts for the Herbicidal combinations 20%-60%.
It further include safener in the Herbicidal combinations, safener is selected from benoxacor, fenclorim, dichlormide, pyrazoles
Cloquitocet_mexyl, isoxadifen, study on brassinolide, wherein the safener is matched relative to the weight of compound (A) and compound (B)
Than for 1:100-20:1.
The dosage form of the Herbicidal combinations is wettable powder, missible oil, suspending agent, microcapsules, microemulsion, aqueous emulsion, hangs
Floating emulsion, water dispersible granules, aqueous emulsion, ultra low volume liquids, tablet, low capacity dispersible granule, pill, microcapsules.
A kind of Herbicidal combinations are preventing and treating the purposes in undesirable plant growth.
A kind of Herbicidal combinations are in prevention and treatment broad-leaved section weeds, sedge weed, the undesirable plant growth of gramineae weed
Purposes.
A kind of Herbicidal combinations are used to prevent and treat the purposes of undesirable plant growth in useful crop.The Herbicidal combination
Object can be used for preventing and treating wheat, corn and soybean, sugar beet, sugarcane, cotton, rice, beans, flax, barley, oat, rye,
In triticale, rape, potato, broomcorn millet, herbage, greenery patches or lawn, broad-leaved section weeds in the crop area Zhong Huofei of fruit plantation,
The purposes of the undesirable plant growth of sedge weed, gramineae weed.Can be especially useful for prevention and treatment rice in broad-leaved section weeds,
The purposes of the undesirable plant growth of sedge weed, gramineae weed.
A kind of Herbicidal combinations are used to prevent and treat the purposes of undesirable plant growth, the Herbicidal combination in useful crop
Object is resistant to by the useful crop.
A method of preventing and treating undesirable plant growth, comprising: (i) before undesirable plant germination (before bud);
(ii) after undesirable plant germination (after bud), or (iii) when (i) and (ii), by the of the invention of herbicidally effective amount
Herbicidal combinations are applied to undesirable plant or it grows place.
A method of preventing and treating undesirable plant growth, the plant that would not want to or its growth place and herbicidally effective amount
Herbicidal combinations contact of the invention or the Herbicidal combinations of the invention of herbicidally effective amount are applied into water.
A method of undesirable plant growth being prevented and treated, by the compound (A) and chemical combination of Herbicidal combinations of the invention
Object (B) collectively or individually is applied to undesirable plant or it grows place.
A method of preventing and treating undesirable plant growth, including by Herbicidal combinations of the invention useful crop plant
It is applied in the presence of other reproductive parts of strain, the seed of useful crop or useful crop.
One kind reducing or preventing compound (A) and compound (B) to plant, the useful crop of the useful crop with its processing
Seed or useful crop other reproductive parts caused by damage method, including with Herbicidal combinations of the present invention
Other reproductive parts of the processing plant of useful crop, the seed of useful crop or useful crop.
A kind of Herbicidal combinations of the present invention are by the way that proxazuron-methyl and clefoxidim to be combined, with particularly advantageous side
Weeds distribution needed for formula obtains technical staff is horizontal, or even includes generating the uncontrollable of resistance to sulfonylurea herbicide
Certain weeds types.Moreover, the amount of application of single component in combination can be significantly reduced in the application present composition, reduce pair
The phytotoxicity of crop.
A kind of Herbicidal combinations of the present invention, when compound (A) and (B) co-administration, there are chemiluminescences.?
This, the activity of the composition is higher than the expection summation of each herbicidal activity of application.Synergistic effect reduce rate of application can, prevent
Broadleaf weeds, gramineae weed and the sedge of more wide range are controlled, herbicide effect action is faster, the duration is longer, passes through
Only once or application several times just has preferably prevention and treatment to noxious plant and can widen the application phase.It is used in the Herbicidal combinations
Dosage and the effective dose of compound (A) and (B) be all adjustable to lower level so that it reduces the effect of soil
To minimum.
Specific embodiment
The present invention provides a kind of Herbicidal combinations, and active component is made of compound (A) and compound (B), wherein (A) is
The compound proxazuron-methyl described by formula (I),
(I)
It (B) is the compound clefoxidim described by formula (II),
(II)
The weight ratio of the compound (A) and (B) are 50:1-1:50, preferably 25:1-1:25, further preferably 10:1-1:10,
More preferable 5:1-1:5.
Synergistic function can be such that the rate of application of single herbicide reduces, the effectiveness under identical rate of application is higher, prevention and treatment
Also controlled kind, prevention and treatment do not extend single herbicide or a variety of herbicide tolerants or resistant kind, application phase
And/or the required number that is administered alone is reduced；And for user, obtain in economic and ecology advantageously
Control of weeds system.
Herbicidal combinations of the invention make the activity of compound (A) and (B) synergistic in a manner of unexpected, surpass
Go out and has used single compound (A) and (B) accessible activity.
The rate of application of compound (A) can change in a wide range, for example, 0.1g to 500g A.I./ha (hereinafter,
A.I./ha expression " active material/hectare "=based on the reactive compound of 100% purity).With 0.1 g to 500g A.I./
When the rate of application application of ha, when prior to seeding, before plantation or before bud and after bud it is middle using compound (A) when, have relatively
Wide noxious plant spectrum to be prevented and treated, for example, annual and perennial unifacial leaf or dicotyledonous broadleaf weeds, gramineae weed and
Sedge and undesirable crop plants.
The rate of application of compound (B) can change in a wide range, such as 10g to 500g A.I./ha, have relatively
Wide noxious plant spectrum to be prevented and treated.
Compound A) with (B) suitable proportional region for example can by reference to the rate of application of mentioned single compound and
It is fixed.In Herbicidal combinations of the invention, rate of application can be usually reduced.In Herbicidal combinations of the invention, compound (A) with
(B) weight ratio is 50:1-1:50；
Preferably, the weight ratio of compound (A) and (B) are 25:1-1:25；
Particularly, the weight ratio of compound (A) and (B) are 10:1-1:10；
More special, the weight ratio of compound (A) and (B) are 5:1-1:5.
Herbicidal combinations of the invention also may include one or more different from compound (A) and (B) and also serve as choosing
Other reactive compounds of selecting property herbicide.
Herbicidal combinations of the invention also may include the various reactive compounds of other components, for example, selected from safener, kill
Epiphyte pharmaceutical, insecticide, acaricide, nematicide, bird repellent, soil conditioner, nutrient for plants (fertilizer), Yi Jijie
Structure is different from the herbicide and plant growth regulator of compound (A) and (B).
Preferably, the different types of agrochemically active compound includes Acetochlor (acetochlor), Acibenzolar
(acibenzolar), diazosulfide (acibenzolar-S-methyl), acifluorfen (acifluorfen), aclonifen
(aclonifen), alachlor (alachlor), allidochlor (allidochlor), alloxydimsodium (alloxydim), ametryn
(ametryn), amicarbazone (amicarbazone), amidosulfuron (amidosulfuron), chlorine Fampridine acid
(aminopyralid), Amrol (amitrole), Amcide Ammate (ammonium sulfamate), ancymidol
(ancymidol), careless spirit (asulam), atrazine (atrazine), azafenidin of anilofos (anilofos), sulphur
(azafenidin), azimsulfuron (azimsulfuron), benfuresate (benfuresate), bensulfuron-methyl
(bensulfuron), bentazone (bentazone), benzfendizone (benzfendizone), benzobicylon
(benzobicyclon), benzofenap (benzofenap), fluorine sulfanilamide (SN) grass (benzofluor), fluorine benzofenap
(bicyclopyrone), bispyribac-sodium (bispyribac-sodium), Brominal (bromoxynil), butachlor
(butachlor), butafenacil (butafenacil), butralin (butralin), cafenstrole (cafenstrole), double acyls
Careless amine (carbetamide), chlorimuronethyl (chlorimuron, chlorimuron-ethyl), cycocel (chlormequat
Chloride), chlortoluron (chlorotoluron), chlorsulfuron (chlorsulfuron), cinmethylin (cinmethylin),
Cinosulfuron (cinosulfuron), clethodim (clethodim), clomazone (clomazone), clomeprop
(clomeprop), clopyralid (clopyralid), cyanazine (cyanazine), cyclanilide (cyclanilide),
Cypromisulfuron (cyclosulfamuron), cycloxydim (cycloxydim), ring cafenstrole (cyprazole), daimuron
(daimuron/dymron), dicamba (dicamba), diclofop-methyl (diclofop-methyl), smart diclofop-methyl (diclofop-
P-methyl), diclosulam (diclosulam), acetyl alachlor (diethatyl, diethatyl-ethyl), pyrrole fluorine acyl
Careless amine (diflufenican), diflufenzopyr (diflufenzopyr, diflufenzopyr-sodium), dimefuron
(dimefuron), dimepiperate (dimepiperate), dimethachlor (dimethachlor), dimethametryn
(dimethametryn), diphenamide (diphenamid), dipropetryn (dipropetryn), diquat dibromide (diquat), enemy
Grass grand (diuron), ethametsulfuron (ethametsulfuron, ethametsulfuron-methyl), ethephon (CEPHA),2-(chloroethyl) phosphonic acid
(ethephon), ethidimuron (ethidimuron), ethoxysulfuron (ethoxysulfuron), ethobenzanid
(etobenzanid), fenoxaprop-P (fenoxaprop), fenoxapropPethyl (fenoxaprop-P), fenoxaprop-P
(fenoxaprop-ethyl), fentrazamide (fentrazamide), flazasulfuron (flazasulfuron), double fluorine sulphurs grass
Amine (florasulam), fluazifop (fluazifop), efficient fluazifop (fluazifop-P), fluazifop-P-butyl
(fluazifop-butyl), efficient fluazifop butyl ester (fluazifop-P-butyl), fluazolate (fluazolate),
Flucarbazonesodium (flucarbazone, flucarbazone-sodium), flucetosulfuron (flucetosulfuron), flufenacet
(flufenacet), flumetralim (flumetralin), Flumetsulam (flumetsulam), flumioxazin
(flumioxazin), alkynes grass amine (flumipropyn), fluometuron (fluometuron), fluorodifen
(fluorodifen), fluoroglycofen-ethyl (fluoroglycofen, fluoroglycofen-ethyl), flupoxam
(flupoxam), flupyrsulfuron-methyl-sodium (flupyrsulfuron), fluridone (fluridone), fluorochloridone
(flurochloridone), fluroxypyr (fluroxypyr), flurtamone (flurtamone), thiazole oxamide
(fluthiamide), fomesafen (fomesafen), Glufosinate (glufosinate, glufosinate-ammonium),
Glufosinate-P (glufosinate-P, glufosinate-P-ammonium), Glufosinate-P- sodium salt (glufosinate-P-
Sodium), glyphosate (glyphosate), glyphosate-isopropylammonium (glyphosate-isopropylammonium), fluorine nitre
Sulfonamide (halosafen), halosulfuronmethyl (halosulfuron, halosulfuron-methyl), fluazifop-butyl
(haloxyfop), smart fluazifop-butyl (haloxyfop-P), fluorine pyrrole second standing grain clever (haloxyfop-ethoxyethyl), smart fluorine pyrrole
Second standing grain spirit (haloxyfop-P-ethoxyethyl), haloxyfop-P-methyl (haloxyfop-methyl), haloxyfop-methyl
(haloxyfop-P-methyl), hexazinone (hexazinone), miaow oxalic acid (imazamethabenz, imazamethabenz-
Methyl), imazamox (imazamox, imazamox-ammonium), AC 263222 (imazapic), imazapyr
(imazapyr, imazapyr-isopropylammonium), imazaquin (imazaquin, imazaquin-
Ammonium), imazethapyr (imazethapyr, imazethapyr-ammonium), imazosulfuron
(imazosulfuron), inabenfide (inabenfide), iodine metsulfuron-methyl (iodosulfuron, iodosulfuron-methyl-
Sodium), ioxynil (ioxynil), isoproturon (isoproturon), ixoxaben (isoxaben), isoxachlorotole
(isoxachlortole), isoxaflutole (isoxaflutole), isoxapyrifop (isoxapyrifop), lactofen
(lactofen), lenacil (lenacil), mefenacet (mefenacet), chlorine sulphonyl grass amine (mefluidide), first piperazine
Pyridine (mepiquat-chloride), mesosulfuronmethyl (mesosulfuron, mesosulfuron-methyl), mesotrione
(mesotrione), methabenzthiazuron (methabenzthiazuron), azole amide (metamifop), metamitron
(metamitron), metazachlor (metazachlor), methazole (methazole), Sulfonylurea
(methiopyrsulfuron), methoxyphenone (methoxyphenone), methyldymron (methyldymron), isopropyl first grass
Amine (metolachlor), S-metolachlor (S-metolachlor), metosulam (metosulam), metoxuron
(metoxuron), metribuzin (metribuzin), metsulfuron-methyl (metsulfuron, metsulfuron-methyl), molinate
(molinate), monosulfmeturon (monosulfuron), monosulfmeturon ester (monosulfuron ester), telvar
(monuron), napropamide (napropamide), nicosulfuron (nicosulfuron), oxadiargyl (oxadiargyl),
Oxadiazon (oxadiazon), oxasulfuron (oxasulfuron), oxaziclomefone (oxaziclomefone), Oxyfluorfen
(oxyfluorfen), paclobutrazol (paclobutrazol), paraquat (paraquat, paraquat dichloride), diformazan
Penta spirit (pendimethalin), pentoxazone (pentoxazone), pethoxamid (pethoxamid), picloram
(picloram), fluorine pyrrole acyl grass amine (picolinafen), pinoxaden (pinoxaden), piperophos (piperophos), third
Careless amine (pretilachlor), probenazole (probenazole), profluazol (profluazol), profluralin
(prifluraline), clefoxidim (profoxydim), prometryn (prometryn), propanil (propanil), propazine
(propazine), Chem hoe (propham), propisochlor (propisochlor), the phonetic sulphur of piperazine imidazoles
(propyrisulfuron), propyzamide (propyzamide), prosulfocarb (prosulfocarb), prosulfuron
(prosulfuron), prynachlor (prynachlor), pyraclonil (pyraclonil), pyraflufen-ethyl (pyraflufen,
Pyraflufen-ethyl), pyrazosulfuron (pyrazosulfuron, pyrazosulfuron-ethyl)), iso-propyl-ester nitrofen
(pyribambenz-isopropyl), propyl-ester nitorfen (pyribambenz-propyl), pyribenzoxim
(pyribenzoxim), pyributicarb (pyributicarb), pyriftalid (pyriftalid), KIH 6127 (pyriminobac,
Pyriminobac-methyl), Nylar (pyrimisulfan), pyrithiobacsodium (pyrithiobac, pyrithiobac-
Sodium), pyroxasulfone, pyroxsulam (pyroxsulam), dichloro quinolinic acid (quinchlorac), chloromethane quinoline
Acid (quinmerac), quizalofop-ethyl (quizalofop), Quizalotop-ethyl (quizalofop-P), Quizalotop-ethyl ethyl ester
(quizalofop-P-ethyl), rimsulfuron (rimsulfuron), benzene flumetsulam (saflufenacil), Zhong Dingtong
(secbumeton), sethoxydim (sethoxydim), Tupersan (siduron), sulphur humulone (sulcotrione), sulfentrazone
(sulfentrazone), sulfometuronmethyl (sulfometuron, sulfometuron-methyl), Thidiazuron
(thidiazuron), thifensulfuronmethyl (thifensulfuron, thifensulfuron-methyl), benthiocarb
(thiobencarb), tiocarbazil (tiocarbazil), triasulfuron (triasulfuron), triaziflam
(triaziflam), tribenuron-methyl (tribenuron, tribenuron-methyl), trichloroacetic acid (TCA), trichlopyr
(triclopyr), tridiphane (tridiphane), trifloxysulfuron (trifloxysulfuron, trifloxysulfuron-
Sodium), trefanocide (trifluralin), triflusulfuronmethyl (triflusulfuron), triflusulfuronmethyl methyl esters
(triflusulfuron-methyl), trimeturon (trimeturon), TrinexAN_SNacethyl (trinexapac, trinexapac-
Ethyl), tritosulfuron (tritosulfuron), tsitodef, uniconazole P (uniconazole).
Although the compound (A) and (B) have shown good or even enough selectivity, principle in a large amount of crops
On, in some crops, when especially also being mixed with other lesser herbicides of selectivity, it is possible that crop plants
Phytotoxicity.So the composition comprising Herbicidal combinations according to the present invention and one or more safeners is particularly advantageous
's.The safener with detoxify effective quantity use, such as economically important crop or fruit plantation (plantation make
Object) in reduce the plant toxicity side effect of herbicide used.The economically important crop such as cereal is (wheat, barley, black
Wheat, oat, corn, rice and broomcorn millet), sugar beet, sugarcane, rape, cotton and soybean, preferably cereal, specifically for rice.
For example be suitable for below safener compound (including possible stereoisomer and agriculturally common ester or
Salt): benoxacor (benoxacor), cloquitocet_mexyl (cloquintocet (- mexyl)), cyometrinil (cyometrinil),
Cyprosulfamide, dichlormide (dichlormid), dicyclonon, o- phenyl phosphoric acid o, o- diethyl ester
(dietholate), the careless amine of fenchlorazole (fenchlorazole (- ethyl)), fenclorim (fenclorim), solution
(flurazole), fluxofenim (fluxofenim), furilazole (furilazole), isoxadifen (isoxadifen (-
Ethyl)), mefenpyrdiethyl (mefenpyr (- diethyl)), methyl carbamic acid 4- chlorobenzene base ester (mephenate), naphthalene two
Formic anhydride and oxabetrinil (oxabetrinil), study on brassinolide, benthiocarb, vanilla are grand (daimuron).Cloquitocet_mexyl is the present invention
Herbicidal combinations particularly preferred safener, especially for fighting Herbicidal combinations to any nocuousness of rice and cereal
Effect.
Known some safeners are used as herbicide, and correspondingly, other than having herbicide effect to noxious plant, also rise
To the effect of cover crop plant.
The weight ratio of Herbicidal combinations and safener generally depends on the rate of application of herbicide and the effect of the safener,
And can change in a wide range, such as 90000: 1-1: 5000, preferably 7000: 1-1: 1600, especially 3000: 1-1:
In the range of 500, particularly 1:100-20:1.
Safener can be used for pre-processing crop seed or rice shoot.In pretreatment rice shoot, such as it can be sprayed with safener solutions
Root or entire rice shoot are spilt, or is dipped in the solution.Then, it can be removed by mode before seedling or after seedling using of the invention
Careless composition is handled.
It optionally, can be by safener and Herbicidal combinations of the invention simultaneously before plantling or postemergence application.Miao Qian
Processing includes the cultivation area for handling cultivation area before sowing and having sowed crop with processing but do not germinateed.Continuous method
In, after being handled first with safener, preferably and then apply Herbicidal combinations of the invention.
In general, safener can be prepared with finished product preparation with compound (A) and (B) or with mixed with the bucket of the Herbicidal combinations
The form of object is supplied and is used.
The present invention provides a kind of Herbicidal combinations and is preventing and treating the purposes in undesirable plant growth.
The present invention provides a kind of Herbicidal combinations and is not intended to preventing and kill off broad-leaved section weeds, sedge weed, gramineae weed
Plant growth purposes.
Economically important unifacial leaf and the dicotyledonous harmful plants such as broad-leaved of Herbicidal combinations of the invention to wide range
Weeds, gramineae weed or sedge, including there is excellent weeding to the resistant type of weeding active compound
Activity, the weeding active compound are such as glyphosate, Glufosinate, atrazine, imidazolinone herbicide and sulfonylurea.
Can be mentioned that can Herbicidal combinations prevention and treatment through the invention monocotyledon weed and dicotyledonous weed flora group
Certain representative specific examples, but it is not limited to certain kinds.
The example of the weed species of the herbicidal composition useful effect is, for example, in monocotyledon weed with subordinate,
Such as Echinochloa (Echinochloa spp.), Panicum (Panicum spp.), Poa L. (Poa spp), Sprangletop
(Leptochloa spp.), Brachiaria (Brachiaria spp.), knotgrass (Digitaria spp.), setaria
(Setaria spp.), Cyperus (Cyperus), Monochoria (Monochoria spp.), genus fimbristylis, Sagittaria
(Sagittaria spp.), Eleocharis (Eleocharis spp.), Scirpus (Scirpus spp.), Waterplantain (Alisma
Spp.), leaf of bamboo Lepidium (Aneilema spp.), water screening spp (Blyxa spp.), eriocaulon buergerianum (Eriocaulon spp.), eye
Sub- Lepidium (Potamogeton spp.) etc. is all prevented and treated very well, especially following kind: water barnyard grass (Echinochloa
Oryzicola), Monochoria vaginalis (Monochoria vaginalis), yak grass (Eleocharis acicularis), scouring rush's shape water chestnut
Shepherd's purse (Eleocharis kuroguwai), difformed galingale herb (Cyperus difformis), Herba Cyperi Glomerati (Cyperus
Serotinus), short arrowhead (Sagittaria pygmaea), alisma canaliculatum (Alisma canaliculatum), firefly Lin
(Scirpus juncoides).In the case where broadleaf weed, activity profile is extended to subordinate, such as Polygonum
(Polygonum spp.), section section Lepidium (Rotala spp.), Vandellia (Lindernia spp.), Bidens (Bidens
Spp.), sphenoclea (Sphenoclea spp.), horsefly eye belong to (Dopatrium spp.), Eclipta prostrata category (Eclipta spp.),
Elatine ambigua (Elatine spp.), Gratiola (Gratiola spp.), Vandellia (Lindernia spp.), false loosestrife
Belong to (Ludwigia spp.), Oenanthe (Oenanthe spp.), Ranunculus (Ranunculus spp.), damp chilly category
(Deinostema spp.) etc..Kind especially such as below: mexicana (Rotala indica), cusp flower
(Sphenoclea zeylanica), Procumbent Falsepimpernel (Lindernia procumbens), false loosestrife (Ludwigia
Prostrate), bog pondweed (Potamogeton distinctus), waterwort (Elatine triandra) and Chinese celery
(Oenanthe javanica)。
The present invention also provides a kind of Herbicidal combinations for preventing and treating the purposes of undesirable plant growth in useful crop.
Herbicidal combinations of the invention can use on the farmland for for example cultivating following useful crop:
Cereal crops, for example,
Cereal (granule cereal) such as wheat (Triticum aestivum) and small wheat crops such as durum wheat
(T.durum), one grained wheat (T.monococcum), emmer wheat (T.dicoccon) and spelt
(T.spelta), rye (Secale cereale), triticale (Tritiosecale), barley (Hordeum vulgare)；
Corn (Zea mays)；
Sorghum (such as sugar grass (Sorghum bicolour))；
Rice (Oryza (Oryza) such as rice (Oryza sativa) and African rice (Oryzaglaberrima)；
Sugarcane；
Beans (Legumes (pulse family (Fabaceae))), for example including soybean (Glycine max.), peanut (Arachis
Hypogaea) and legume crop such as pea (including pea (Pisum sativum), pigeonpea and cowpea), Kidney bean (including semen viciae fabae
(Vicia faba), black mixed coloured cowpea category (Vigna) and black Phaseolus (Phaseolus)) and hyacinth bean (Lens culinaris (lens
culinaris var.)) ；
Cruciferae, for example including Canola (cabbage type rape (Brassica napus)), rape (Brassica
Napus), cabbage (B.oleracea var.), leaf mustard such as leaf mustard (B.juncea), Chinese cabbage (B.campestris), broadbeaked mustard
(B.narinosa), black mustard (B.nigra) and Mediterranean open country blister beetle (B.tournefortii)；And turnip (Brassica
rapa var.)；
Other broad leaf crops, for example including sunflower, cotton, flax, linseed, sugar beet, potato and tomato；
TNV crop (TNV: tree, kernel and rattan), for example including grape, citrus, a kind of fruit, such as apple, pear, etc., such as apple and pears, coffee are opened
Heart fruit and oil palm, drupe, such as peach, almond, walnut, olive, cherry, Li Hexing；
Turf, herbage and pasture；
Onion and garlic；
Bulb ornamental plant such as tulip and narcissus；
Coniferous tree and deciduous tree such as Pinus (Pinus), fir, Oak Tree, maple, Fructus Corni, hawthorn, Malus spectabilis and Rhamnus
(Rhamnus) (sandlwood)；
Garden ornamental plant such as petunia, marigold, rose and toad's-mouth.
Herbicidal combinations of the invention are particluarly suitable for wheat, barley, rye, triticale, durum wheat, rice, corn, sweet
Sugarcane, sorghum, soybean, legume crop such as pea, Kidney bean and hyacinth bean, peanut, sunflower, sugar beet, potato, cotton, Btassica
Crop, such as rape, Canola, leaf mustard, cabbage and turnip, turf, grape, a kind of fruit, such as apple, pear, etc., such as apple and pears, drupe, such as peach, apricot
Benevolence, walnut, olive, cherry, Li Hexing, citrus, coffee, American pistachios, garden ornamental plant, as rose, petunia, marigold,
Toad's-mouth, bulb ornamental plant such as tulip and narcissus, coniferous tree and deciduous tree for example Pinus, fir, Oak Tree, maple, Fructus Corni,
The growth of undesirable plant is prevented and kill off/prevented and treated in hawthorn, Malus spectabilis.
Herbicidal combinations of the invention are most suitable in wheat, barley, rye, triticale, durum wheat, rice, corn, sweet
Sugarcane, sorghum, legume crop such as pea, Kidney bean and hyacinth bean, peanut, sunflower, sugar beet, potato, cotton, Brassicas crop,
Such as rape, Canola, leaf mustard, cabbage and turnip, turf, grape, drupe, such as peach, almond, walnut, olive, cherry, Li He
The growth of undesirable plant is prevented and kill off/prevented and treated in apricot, citrus and American pistachios.
Especially crop for example wheat, barley, rye, rice, corn, sugarcane, sorghum, legume crop, peanut, sunflower,
Sugar beet, potato, cotton, Brassicas crop, turf, grape, a kind of fruit, such as apple, pear, etc., drupe, citrus, coffee, American pistachios, the ornamental plant in garden
In object, coniferous tree and deciduous tree, they can effectively prevent broadleaf weeds, gramineae weed and sedge weed, and substantially not
Injury can be generated to crop.
Herbicidal combinations of the invention can also admirably prevent and treat the growth of the undesirable plant in non-crop area.
Non- crop area Ru Lu, railway, meadow, utility line, the undesirable plant growth especially in the region there are trees.
Herbicidal combinations of the invention can also be used for following crop plants, and the crop plants are due to genetic engineering or breeding
And it is resistant to one or more herbicides, due to genetic engineering or breeding to one or more pathogen, such as pathogenic
Property fungi is resistant or resistant to insect infestations due to genetic engineering or breeding.Suitable is, for example, that tolerance synthesis plant is raw
The crops of long element, preferably corn, wheat, sunflower, rice, Canola, rape, soybean, cotton and sugarcane, or due to passing through
Gene modification introduces the crops that gene is resistant to certain insect infestations to Bt toxin.
Herbicidal combinations of the invention are highly applicable to selectively prevent and treat the life of the undesirable plant in rice crop
It is long.The rice crop includes all possible forms in most diverse Rice under Condition strain cultivation, such as dry land is cultivated, nonirrigated farmland
It cultivates or paddy field is cultivated, can be natural (rainfall) and/or artificial (pouring) wherein irrigating.Rice for this purpose can
For the seed (being obtained by mutation or transgenosis) of the seed, hybrid seed or resistant-at least tolerance routinely cultivated,
It can be derived by indica type or round-grained rice type kind or its cenospecies.
A kind of Herbicidal combinations are used to prevent and treat the purposes of undesirable plant growth, the Herbicidal combination in useful crop
Object is resistant to by the useful crop.
It, can be by spraying apparatus directed spraying Herbicidal combination if active component cannot be well tolerable by certain crops
Object so that they reach be grown in the following leaf for being not intended to plant or exposed soil when it is tactiosensible as few as possible
Crops.
The present invention also provides a kind of proxazuron-methyl or clefoxidims of reducing or preventing to the useful crop with its processing
The method of damage caused by other reproductive parts of plant, the seed of useful crop or useful crop, including with institute of the present invention
The Herbicidal combinations stated handle other reproductive parts of the plant of useful crop, the seed of useful crop or useful crop.
The amount of application of herbicide can change in very large range, and optimised quantity depends on the herbicide, noxious plant is composed
It is composed with crop.The dosage level of required herbicide depends on specific weed infestation, weeds spectrum to be controlled, auxiliary agent etc..It is optimal
Choosing is using relatively low amounts of herbicide.The activity of Herbicidal combinations of the invention is higher than the pre- of each herbicidal activity of application
Phase summation, there are synergistic functions by compound (A) and (B).
Synergistic function reduces the rate of application of single herbicide, the effectiveness under identical rate of application is higher.The present invention
Herbicidal combinations in, the rate of application of single compound is reduced and Herbicidal combinations maintain good exposure level；Its
In the case where having become useless from the point of view of agronomic point, composition obtains the secondary independent substance when within the scope of low rate of application
High-caliber Weeds distribution.
Thus, the amount of application of single component in composition can be significantly reduced in the application present composition, to reduce
To the phytotoxicity of crop.
The present invention provides a kind of method for preventing and treating undesirable plant growth, by the compound of Herbicidal combinations of the invention
(A) and compound (B) collectively or individually is applied to undesirable plant or it grows place.
A method of preventing and treating undesirable plant growth, comprising: (i) before undesirable plant germination (before bud);
(ii) after undesirable plant germination (after bud), or (iii) when (i) and (ii), by the of the invention of herbicidally effective amount
Herbicidal combinations are applied to undesirable plant or it grows place.It is preferred that also to having germinateed before the undesirable plant germination
Undesirable plant (such as broadleaf weeds, gramineae weed, sedge or undesirable crop plants) is administered, and
It is unrelated with the growth period of sowing/plantation crop.
Herbicidal combinations of the invention include that a effective amount of compound (A) and (B) has synergistic function.When common or
It can be observed to act synergistically when compound (A) and (B) is almost administered simultaneously；When application compound (A) respectively in different times
When (B), synergistic effect is also observed that；It can also be with application and then bud before sequential application compound (A) and (B), such as first bud
After apply, or apply after first early stage bud, then applied after mid-term or later period bud.Preferably common herein or almost being administered simultaneously
It closes object (A) and (B), and is particularly preferably co-administered.
If Herbicidal combinations of the invention are applied to soil surface before germination, weeds seedling is entirely prevented to send out
Bud or weed growth are to cotyledon period, but then it just stops growing, and finally completely dead after two weeks to surrounding.
If the reactive compound to be applied to the green parts of plant after germination, growth equally can be after treatment
Just sharply stop in the suitable short time, and growth period when the ruderal plant is maintained at administration time point or its in a timing
Between after it is completely dead, it is relatively early in this way and constantly eliminate by the competition for the weeds generation for being harmful to crop plants.It is right
In rice, the Herbicidal combinations can also be applied in water, then it is absorbed by soil, bud and root.
When compound (A) and (B) are co-administered, there are chemiluminescences.Here, the activity of the composition is higher than
The expection summation of each herbicidal activity of application.Synergistic effect reduce rate of application can, prevent and treat broadleaf weeds, the grass of more wide range
Section weeds and sedge, herbicide effect action is faster, the duration is longer, pass through only once or application several times is just to nocuousness
Plant has preferably prevention and treatment and can widen the application phase.Dosage used in the Herbicidal combinations and compound (A) and (B)
Effective dose be all adjustable to lower level so that it is reduced to minimum to the effect of soil.This makes the present invention
Herbicidal combinations can not only be applied to sensitive crop, also almost avoid underground water pollution.Herbicidal combinations of the present invention make
Rate of application needed for obtaining active component reduces significantly.
Above-mentioned characteristics and advantages keep control of weeds agricultural/forestry/garden crop or greenery patches/meadow from not wishing
The competitive plant of prestige, to ensure and/or increase useful crop yield level to be necessary from the angle of quality and quantity.
For the characteristic, this Herbicidal combinations have surmounted the state of the art of this field significantly.
The present invention also provides a kind of methods for preventing and treating undesirable plant growth, including Herbicidal combinations of the invention exist
It is applied in the presence of other reproductive parts of the plant of useful crop, the seed of useful crop or useful crop.
The present invention also provides a kind of methods for preventing and treating undesirable plant, preferably in useful crop plants, particularly water
Undesirable plant is prevented and treated in rice crops, this method includes will be as the compound (A) of Herbicidal combinations of the present invention and (B), example
As collectively or individually being applied to plant (such as undesirable plant, as unifacial leaf or dicotyledonous broadleaf weeds, grass family are miscellaneous
Grass, sedge or undesirable crop plants), seed (such as caryopsis, seed or vegetative propagation organ, for example, stem tuber and
Branch portion with bud), or it is applied to the region (such as region of cultivation, can also be covered with water) of plant growth.A kind of weeding
Agent can before another herbicide, be applied to the region of plant, seed or plant growth later or concurrently and (such as cultivate
Region).
Herbicidal combinations of the invention can be applied in a usual manner by using technology well known to those skilled in the art.
Suitable technology includes by spraying, atomization, dusting, broadcasts sowing or pour.Application type depends on desired in a well-known manner
Purpose；The technology is it is ensured that the best of active component of the present invention may distribution under any circumstance.
The method of the present invention is most preferably for undesirable plant or it grows place prevention and treatment plant growth area or will be used to plant
Weeds in the region of plant.When being used for plant growth area, amount of application should be enough to control weed growth but will not be to work
Object generates serious permanent injury.
" undesirable plant " is understood to mean that all plants for being grown in the place for being not intended to its growth.These can
For, for example, noxious plant (such as unifacial leaf or broadleaf weed, gramineae weed, sedge or undesired crop are planted
Object), including for example to certain weeding active compounds (such as glyphosate, Glufosinate, atrazine, imidazolinone herbicide and
Sulfonylurea) those of resistant plant.
Herbicidal combinations of the invention can be applied by being usually used in the various method of administration of rice herbicide.Particularly preferably
Ground is applied by spraying application and/or by dipping application.In dipping application, when application, the water in paddy field had covered ground
Face is up to 3-20cm.Then Herbicidal combinations of the invention are placed directly in the water in paddy field.Worldwide, it applies by spraying
With the rice for being mainly used for directly sowing, and impregnate the rice that application is mainly used for transplanting.
The present invention also provides a kind of method for preventing and treating undesirable plant growth, the plant that would not want to or its growth place
The Herbicidal combination of the invention of herbicidally effective amount is contacted or applied into water with the Herbicidal combinations of the invention of herbicidally effective amount
Object.
The present invention also provides a kind of Herbicidal combinations, active component is made of compound (A) and compound (B), filler
And/or surfactant.In the Herbicidal combinations, the content of compound (A) and compound (B) accounts for the Herbicidal combinations
5%-90%, preferably 10%-80%, more preferable 20%-60%.
Herbicidal combinations of the invention can be converted into conventional formulation, for example, wettable powder, missible oil, suspending agent, microcapsules,
Microemulsion, aqueous emulsion, suspended emulsion, water dispersible granules, aqueous emulsion, ultra low volume liquids, tablet, low capacity dispersible granule, ball
Agent, microcapsules.
According to the present invention, term " filler ", which refers to, can be combined or be combined with active component to make it easier for being administered to pair
As the natural or synthetic organic or inorganic compound of (such as plant, crop or careless class).Therefore, the filler is preferably lazy
Property, it is acceptable at least to should be agricultural.The filler can be solid or liquid.
Applicable solid carrier are as follows: for example phyteral powdery type (such as soy meal, starch, grain dust, wood powder, bark powder,
Sawdust, walnut shell powder, wheat bran, cellulose powder, coconut husk, corncob and tobacco stem particle, extract plant essence after it is residual
Slag etc.), clay class (such as kaolin, bentonite, acid china clay etc.), talcum powder class.Silica (such as diatomite, silica sand, cloud
Female, aqueous silicic acid, calcium silicates), active carbon, natural mineral matter class (float stone, attapulgite and zeolite etc.), fire diatomite, sand,
The inorganic mineral of plastics medium etc. (such as polyethylene, polypropylene, polyvinylidene chloride etc.), potassium chloride, calcium carbonate, calcium phosphate etc.
Chemical fertilizer, the clay fertilizer of property powder, ammonium sulfate, ammonium phosphate, urea, ammonium chloride etc., these substances can be used alone or 2 kinds
It is above mixed.
Applicable liquid-carrier can select in llowing group of materials, such as water, alcohol type (such as methanol, ethyl alcohol, isopropyl
Alcohol, butanol, ethylene glycol etc.), ketone (such as acetone, methyl ethyl ketone, isobutyrone, cyclohexanone etc.), ethers (such as second
Ether, dioxanes, methylcellulose, tetrahydrofuran etc.), aliphatic hydrocarbon class (such as kerosene, mineral oil etc.), aromatic series
Hydrocarbon (such as benzene,toluene,xylene, solvent naphtha, alkylnaphthalene, chlorinated aromatic hydrocarbons, chlorinated aliphatic hydrocarbon, chlorobenzene etc.), halogen
Change hydrocarbon, amides, sulfone class, dimethyl sulfoxide, mineral and vegetable oil, animal oil etc..
Applicable surfactant have emulsifier, dispersing agent or wetting agent with ion or non-ionic nature or these
The mixture of surfactant.The suitable of these surfactants has fatty alcohol polyoxyethylene ether, polyxyethylated aryl
Ether, polyoxyethylene higher fatty acid esters, polyoxyethylene alcohol or the phosphate of phenol, the aliphatic ester of polyalcohol, alkylaryl sodium sulfonate,
Naphthalene sulfonic acid polymer, lignosulfonates, the dendritic copolymer of macromolecule comb shape, butyl naphthalene sulfonate, alkylaryl sulfonates,
The polyacrylates such as sodium alkylsulfosuccinates, grease, fatty alcohol and ethylene oxide condensate, alkyltaurate, protein
Hydrolysate.Suitable oligosaccharide object or polymer, such as based on individual vinyl monomer, acrylic acid, polyoxyethylene or polyoxy third
The combination of alkene or itself and such as (polynary) alcohol or (polynary) amine.When in one of reactive compound and/or inert carrier
One kind is not soluble in water and when applying in water, it is necessary to which there are surfactants.The ratio of surfactant is of the invention removes
The 5%-40% of careless composition.
If appropriate, there may also be other addO-on therapies, such as protecting colloid, bonding for Herbicidal combinations of the invention
Agent, adhesive, thickener, thixotropic agent, bleeding agent, stabilizer, screening agent, sequestering agent, complex-forming agents.In general, institute
The active component stated can be in conjunction with any solid or liquid additive conventionally used for preparation purpose.
The Herbicidal combinations of the invention can by known way by the active component and following substance at least
It is a kind of to be mixed: liquid-carrier or solid carrier, emulsifier, dispersing agent, wetting agent and/or protecting colloid, adhesive, gluing
Agent, thickener, thixotropic agent, bleeding agent, stabilizer, screening agent, sequestering agent, complex-forming agents, water and other processing
Auxiliary agent.
In the Herbicidal combinations, the content of compound (A) and (B) account for the big 5%-90% of the Herbicidal combinations, preferably
10%-80%, more preferable 20%-60%.
Herbicidal combinations of the invention can be formulated as by known method for example single component-if appropriate, with other work
The mix preparation of property compound, additive and/or common dosage forms auxiliary agent-, then the composition is diluted with water in a usual manner
After apply；Or a barrel mix formulation is formulated as and diluting the independent each component prepared or partially individually prepared jointly with water.
The each component that can be individually prepared with separate administration or partially individually be prepared.Multi-section point can also be divided to use the herbicide or weeding
Composition (sequential application), for example, first seed dressing application or sowing before/plantation pre-treatment or bud before apply followed by carry out bud after
It applies after application or early stage bud, is applied after then carrying out mid-term or later period bud.It is preferably used in conjunction with or almost while using herein
The reactive compound of the composition is particularly preferably co-administered.
It, can be with it is anticipated that object selects method of administration with popular environment, such as blade face be impregnated with, sprays according to formulation properties
Mist dusts, scatters and selected.
Compound (A) and (B) can with itself, its dosage form or by further diluting use form prepared therefrom
Application, such as ready to use solution, suspending agent, lotion, pulvis, paste and granule.It can be with usual manner-for example by pouring, spraying
Mist, be atomized or broadcast sowing-apply them.
Herbicidal combinations of the invention have be easier to using form because the amount of the component has been optimal proportion.
In addition, the auxiliary agent in preparation can adjust each other and optimize.
Example of formulations
+ 10% clefoxidim suspending agent of embodiment 1:50% proxazuron-methyl
Proxazuron-methyl 50%
Clefoxidim 10%
Naphthalene sulfonic acid-formaldehyde condensation product sodium salt 10%
Sorbitan aliphatic ester 5%
Bentonite 1%
Glycerine 5%
Corn oil complements to 100%
The each components such as active component, dispersing agent, wetting agent and corn oil are uniformly mixed according to the ratio of formula, it is ground
And/or+5% clefoxidim suspending agent of 50% proxazuron-methyl is obtained after high speed shear.
+ 8% clefoxidim wettable powder of 2 40% proxazuron-methyl of embodiment
Proxazuron-methyl 40%
Clefoxidim 8%
Sodium butylnaphthalenesulfonate 5%
Polyoxyethylene lauryl ether carboxylic acid sodium 5%
White carbon black 5%
Kaolin complements to 100%
Active component, various auxiliary agents and filler etc. are mixed by the proportional components of formula, after ultra-fine pulverizer disintegrating, i.e.,
Obtain+8% clefoxidim wettable powder of 40% proxazuron-methyl.
+ 10% clefoxidim wettable powder of 3 10% proxazuron-methyl of embodiment
Proxazuron-methyl 10%
Clefoxidim 10%
Glycerine fatty acid polyoxyethylene ether 1%
Sodium lignin sulfonate 2%
White carbon black complements to 100%
Active component, various auxiliary agents and filler etc. are mixed by the proportional components of formula, after ultra-fine pulverizer disintegrating, i.e.,
Obtain+10% clefoxidim wettable powder of 10% proxazuron-methyl.
+ 5% clefoxidim water dispersible granules of 4 50% proxazuron-methyl of embodiment
Proxazuron-methyl 50%
Clefoxidim 5%
To methoxyl group fatty acyl amido benzene sulfonate 6%
Lauryl sodium sulfate 5%
Ammonium sulfate 5%
Kaolin complements to 100%
Active component, dispersing agent, wetting agent, disintegrating agent and filler are mixed according to the formula uniformly, by air-flow powder
It is broken into wettable powder, a certain amount of water mixing extruding is added and makes material.50% proxazuron-methyl+5% is obtained after dry screening
Clefoxidim water dispersible granules.
+ 25% clefoxidim missible oil of 5 5% proxazuron-methyl of embodiment
Proxazuron-methyl 5%
Clefoxidim 25%
Ethoxylated castor oil 5%
Calcium dodecyl benzene sulfonate 3%
N-Methyl pyrrolidone complements to 100%
Mentioned component is proportionally prepared, uniform phase is uniformly mixing to obtain.
+ 25% clefoxidim suspoemulsion of 6 0.5% proxazuron-methyl of embodiment
Proxazuron-methyl 0.5%
Clefoxidim 25%
Methyl naphthalene sulfonate formaldehyde condensate 5%
Ethoxylated castor oil 3%
Bentonite 1%
N-Methyl pyrrolidone 20%
Water complements to 100%
It is phonetic that promazine is obtained by proxazuron-methyl, after methyl naphthalene sulfonate formaldehyde condensate, water is ground and/or high speed shear
The grand suspending agent of sulphur；It is mixed evenly clefoxidim, N-Methyl pyrrolidone, ethoxylated castor oil to obtain clefoxidim
Missible oil；Obtained clefoxidim missible oil is added in proxazuron-methyl suspending agent ,+25% ring benzene of 0.5% proxazuron-methyl is obtained
Humulone suspending agent.
+ 5% clefoxidim wettable powder of 7 5% proxazuron-methyl of embodiment
Proxazuron-methyl 5%
Clefoxidim salt 5%
Lauryl sodium sulfate 6%
Sodium metnylene bis-naphthalene sulfonate 3%
White carbon black 20%
Kaolin complements to 100%
Said components are mixed in proportion, and grinds, crush, are prepared into wettable powder.
+ 10% clefoxidim water dispersible granules of 8 50% proxazuron-methyl of embodiment
Proxazuron-methyl 50%
Clefoxidim 10%
MODIFIED LIGNOSULPHONATE 5%
Lauryl sodium sulfate 3%
Sodium chloride 1%
Kaolin complements to 100%
By proxazuron-methyl, clefoxidim active component, dispersing agent, wetting agent, disintegrating agent and filler in the ratio of formula
It is uniformly mixed, by air-flow crushing at wettable powder；It adds a certain amount of water mixing extruding and makes material.After dry screening
To+10% clefoxidim water dispersible granules of 50% proxazuron-methyl.
+ 4% clefoxidim aqueous emulsion of 9 1% proxazuron-methyl of embodiment
Oily phase:
Proxazuron-methyl 1%
Clefoxidim 4%
SOLVESSOTM 100 10%
Ethoxylated castor oil 5%
Water phase:
Naphthalene sulfonic acids-formaldehyde condensation products sodium salt 1% of sulfonation
Water complements to 100%
Proxazuron-methyl, clefoxidim are dissolved in methyl oleate, ethoxylated castor oil is added and obtains oily phase；According to
By naphthalene sulfonic acids-formaldehyde condensation products sodium salt of sulfonation, water is uniformly mixed and obtains water phase formula；Oil is added under stiring
Water phase obtains aqueous emulsion.
+ 30% clefoxidim wettable powder of 10 60% proxazuron-methyl of embodiment
Proxazuron-methyl 60%
Clefoxidim 30%
Octylphenol polyethylene oxyethylene group ether sulfate 1%
NaLS 2%
The silicic acid 1% of high degree of dispersion
Sodium carbonate 2%
Kaolin complements to 100%
Said components are mixed in proportion, and grinds, crush, are prepared into wettable powder.
+ 5% clefoxidim granule of 11 50% proxazuron-methyl of embodiment
Proxazuron-methyl 50%
Clefoxidim 5%
Polyethylene glycol 3%
The silicic acid 1% of high degree of dispersion
Calcium carbonate complements to 100%
It in a mixer, will be on levigate active component even spread to the carrier soaked by polyethylene glycol.By this method
It can get granule.
+ 5% clefoxidim wettable powder of 12 15% proxazuron-methyl of embodiment
Proxazuron-methyl 15%
Clefoxidim 5%
Lauryl sodium sulfate 5%
Sodium lignin sulfonate 5%
Attapulgite complements to 100%
Said components are mixed in proportion, and grinds, crush, are prepared into wettable powder.
+ 5% clefoxidim of 13 25% proxazuron-methyl of embodiment squeezes out granule
Proxazuron-methyl 25%
Clefoxidim 5%
Sodium lignin sulfonate 4%
Carboxymethyl cellulose 2%
Kaolin complements to 100%
Active component is mixed and ground with auxiliary agent, mixture is soaked with water.The mixture is squeezed out, then in air stream
Middle drying.
+ 5% clefoxidim seed coat agent of 14 0.5% proxazuron-methyl of embodiment
Proxazuron-methyl 0.5%
Clefoxidim 5%
Fatty alcohol polyoxyethylene ether sulfosuccinic acid monoesters disodium 10%
MODIFIED LIGNOSULPHONATE 5%
Xanthan gum 1%
Bentonite 1%
Glycerine 5%
PVP-K30 1%
Water complements to 100%
Above-mentioned each component is mixed in proportion, and is sanded, seed coat agent is prepared into.
+ 10% clefoxidim microcapsule suspension-suspendinagent agent of 15 5% proxazuron-methyl of embodiment
Synperonic PE/64 5%
Citric acid 0.05%
Catalyst 0.1%
Water 10%
Clefoxidim 10%
PAPI 1.35%
SOLVESSOTM 100 5%
Synperonic PE/64 5%
Dispersing agent LFH 0.15%
Defoaming agent 0.16%
Urea 2%
Proxazuron-methyl 5%
Water complements to 100%
By PAPI, clefoxidim, SOLVESSOTM100 oil formed are added to the water-soluble of the PE/64 containing Synperonic
In liquid, emulsion is formed.Then it heats and keeps the temperature 50oIt is added catalyst reaction 2 hours under C.Clefoxidim is obtained after cooling
Microcapsules.
Synperonic PE/64, dispersing agent LFH, defoaming agent, urea, proxazuron-methyl and water mix in proportion
It is even, and be sanded, it is prepared into suspending agent.
Obtained clefoxidim microcapsules is added in the suspending agent of proxazuron-methyl, is uniformly mixing to obtain the phonetic sulphur of 5% promazine
Grand+10% clefoxidim microcapsule suspension-suspendinagent agent.
+ 6% clefoxidim suspended emulsion of 16 30% proxazuron-methyl of embodiment
Proxazuron-methyl 30%
Clefoxidim 6%
SOLVESSOTM 200 10%
Ethoxylated castor oil 4%
Fatty alcohol polyoxyethylene ether sulfosuccinic acid monoesters disodium 5%
MODIFIED LIGNOSULPHONATE 5%
Xanthan gum 1%
Bentonite 1%
Glycerine 5%
Water complements to 100%
Clefoxidim is dissolved in SOLVESSOTMIn 200, ethoxylated castor oil is added, obtains the cream of clefoxidim
Oil；
By proxazuron-methyl, fatty alcohol polyoxyethylene ether sulfosuccinic acid monoesters disodium, above-mentioned each component mixes in proportion
Uniformly, it and is sanded, is prepared into suspending agent.
Oil containing clefoxidim is added in suspending agent containing proxazuron-methyl, suspended emulsion is obtained.
+ 4% clefoxidim missible oil of 17 1% proxazuron-methyl of embodiment
Proxazuron-methyl 1%
Clefoxidim 4%
Ethoxylated castor oil 5%
Calcium dodecyl benzene sulfonate 3%
SOLVESSOTM 200 complement to 100%
Above-mentioned each component is mixed, stirring is to obtaining transparent homogeneous phase.
+ 40% clefoxidim of 19 60% proxazuron-methyl of embodiment
Proxazuron-methyl 60%
Clefoxidim 40%
Proxazuron-methyl, clefoxidim are proportionally uniformly mixed.
+ 40% isoxadifen of+20% clefoxidim of 20 40% proxazuron-methyl of embodiment
Proxazuron-methyl 40%
Clefoxidim 20%
Isoxadifen 40%
Proxazuron-methyl, clefoxidim, isoxadifen are proportionally uniformly mixed.
+ 60% clefoxidim of 21 40% proxazuron-methyl of embodiment
Proxazuron-methyl 40%
Clefoxidim 60%
Proxazuron-methyl, clefoxidim are proportionally uniformly mixed.
+ 20% cloquitocet_mexyl of+30% clefoxidim of 22 50% proxazuron-methyl of embodiment
Proxazuron-methyl 50%
Clefoxidim 30%
Cloquitocet_mexyl 20%
Proxazuron-methyl, clefoxidim, cloquitocet_mexyl are proportionally uniformly mixed.
Above embodiments per distribution ratio is weight per distribution ratio.
Biological Examples
Pre-emergence test:
Under greenhouse experiment, test plant is seeded in seedling alms bowl.Use standard soil as cultivation matrix.The rank before bud
Herbicide individually or is in combination administered to soil surface by section.It is true that dosage depends on the institute under field or greenhouse experiment
Fixed optium concentration.(100% effect=plant is completely dead for evaluation test after 2 ~ 4 weeks；0% effect=plant-less toxicity effect).
The combination of proxazuron-methyl and clefoxidim is shown than better preventive effect is administered alone in this test, and display is apparent
Synergistic effect.
When Herbicidal combinations of the invention are applied before rudiment, weeds emergence or weed growth can be entirely prevented to cotyledon
Phase then stops growing and the death completely after 3 ~ 4 weeks.
It is tested after seedling
Using potting cauline leaf process method (NY/T 1155.4-2006): high 6cm, diameter 9cm polypots in dress it is quantitative
Soil is placed on after the fine earth of lid 0.5 ~ 1cm thickness by unifacial leaf and 15 ~ 20, the seed of dicots weeds sowings in polypots
It is cultivated in greenhouse, long to 2 ~ 4 leaf phases progress cauline leaf spraying treatment to weeds, every spraying liquid 1mL, every processing is repeated 4 times, and is set
Processing without medicament is control.Processing is placed in greenhouse and cultivates, the growing state of regular observation of target weeds, mesh after 21d
Target victim symptom and growth inhibition situation are surveyed, and claims aerial part fresh weight or strain fresh weight, medicine is evaluated with target fresh weight inhibition rate
Toxicity action of the agent to target weeds.
Three kinds of reagents: 1, proxazuron-methyl are prepared according to constant weight percentage；2, clefoxidim；3, proxazuron-methyl+
Clefoxidim.Above-mentioned each reagent is diluted with water later, obtains medicament dilution.
Investigation method:
Target victim symptom and growth inhibition situation are estimated after test process 21d, and claims aerial part fresh weight, calculate fresh weight
Inhibiting rate (%).
Evaluation to the mixed synergistic effect for applying middle display of two or more herbicidal active components is to be based on
“CalculationSynergistic and Antagonistic Response of Herbicide Combinations”
What Colby ' s method described in (Weeds 15/1 (1967), S.R.Colby) determined.
In formula, X is proxazuron-methyl when using a single dose to the fresh weight inhibition rate of target weeds；
Y is clefoxidim when using a single dose to the fresh weight inhibition rate of target weeds；
E0To the theoretical value of target weed fresh weight inhibition rate for proxazuron-methyl and when two kinds of pharmacy mix of clefoxidim；
To the measured value of target weed fresh weight inhibition rate when E is proxazuron-methyl and two kinds of pharmacy mix of clefoxidim.
If the actual control of weeds rate (E) observed in biologic test is more than to be calculated using Colby ' s method
Desired value (the E arrived0), then it represents that the effect of Herbicidal combinations is greater than the summation of each agent effectiveness, it means that composition has
Synergistic effect.
Herbicidal combinations of the invention are directed to important noxious plant (gramineae weed, broadleaf weeds, the nutgrass flatsedge of following wide spectrum
Section weeds) it is tested: rice barnyard grass (Echinochloa oryzicola), herba digitariae (Digitaria spp.) herba stellariae mediae
(Stellaria media), Amaranthus retroflexus (Amaranthus retroflexus), volume stem smartweed (Fallopia (ex
Polygonum) Convolvulus), piemarker (Abuthilon theophrasti), anti-sulfonylureas angustifolia arrowhead herb
(Sagittariatrifolia), rhizoma alismatis (Oriental Waterplantain Rhizome), anti-sulfonylureas Monochoria vaginalis
(Herb of Pygmy Arrowhead), Monochoria korsakowii (Monochoria korsakowii), Procumbent Falsepimpernel (Lindernia
Procumbens), black nightshade (Solanum nigrum L.), firefly Lin (Scirpus juncoides Roxb), anti-sulfonylureas it is different
Type nutgrass flatsedge (Cyperus difformis L.), Chenopodiaceae (Chenopodium alum L.), wild avena sativa (Avena fatua L.),
Clearvers (Galium aparine L. var. tenerum Gren.et (Godr.) Rebb.).
To the activity of barnyard grass:
To the activity of semen euphorbiae:
Fight the activity of the angustifolia arrowhead herb of sulfonylureas:
Fight the activity of the difformed galingale herb of sulfonylureas:
Test result is shown: proxazuron-methyl and clefoxidim in the range of 50:1-1:50, prevent and kill off gramineae weed,
Broadleaf weeds, sedge weed show apparent synergistic effect, effectively ensure to the anti-sulfonylurea herbicide in current part
Weeds prevention and treatment, improve the effect of antagonism weed control
In summary, Herbicidal combinations of the invention, activity when preventive effect is administered alone better than each component, pharmacodynamic test are tested
Demonstrate,proving a combination thereof has synergistic effect, expands control of weeds spectrum, the crop fields grass family, broadleaf weeds and Cyperaceae are prevented and kill off in primary application
Weeds reduce spraying times, reduce control cost, slow down the generation of Weed Resistance, good to crop safety, meet pesticidal preparations
Security requirement.Weeding is closed before can be used for rice field, corn and soybean, cereal, sunflower, potato, peanut, Cotton Fields seedling
Or postemergence weed control.
Safety effect
Under greenhouse experiment, test plant rice paddy seed is planted in plastic tank, the 4- leaf phase is grown in plastic tank.
In this stage, by individual proxazuron-methyl, clefoxidim, proxazuron-methyl+clefoxidim, proxazuron-methyl+clefoxidim
The composition of+cloquitocet_mexyl, is administered to test plant.After applying 3 weeks, evaluation herbicide is measured to the plant of crop using percentage
Toxicity.100% indicates that test plant is completely dead, and 0% indicates plant-less toxicity effect.
As can be seen that the combination of proxazuron-methyl and clefoxidim, improves proxazuron-methyl or clefoxidim and farming
The compatibility of object reduces or prevents proxazuron-methyl or clefoxidim to plant, the useful crop of the useful crop with its processing
Seed or useful crop other reproductive parts caused by damage.
Also, specific safener is suitable for the invention Herbicidal combinations.Therefore, the invention further relates to one kind for selecting
Selecting property prevents and treats the selective herbicidal composition of the weeds in useful crop especially rice crops, and the composition contains the phonetic sulphur of promazine
Grand, clefoxidim, and it is selected from cloquitocet_mexyl above-mentioned, benoxacor, fenclorim, dichlormide, mefenpyrdiethyl, double isoxazolyl benzenesulfonamides
The safeners such as acid, study on brassinolide, the composition can protect crop (rather than weeds) to make from the phytotoxicity of herbicide
With further relating to the composition in the application for preventing and treating the undesirable plant in useful crop.
Claims (16)
1. a kind of Herbicidal combinations, which is characterized in that active component is made of compound (A) and compound (B), wherein (A) is
The compound described by formula (I):
And (B) is the compound described by formula (II):
The weight ratio of the compound (A) and (B) are 5:1-1:5.
2. Herbicidal combinations according to claim 1, which is characterized in that the weight ratio of the compound (A) and (B) are 1:
1。
3. Herbicidal combinations according to claim 1, which is characterized in that the Herbicidal combinations further include filler and/
Or surfactant.
4. Herbicidal combinations according to claim 1, which is characterized in that the Herbicidal combinations, dosage form are wettable
Pulvis, missible oil, suspending agent, microcapsules, microemulsion, aqueous emulsion, suspended emulsion, water dispersible granules, ultra low volume liquids, tablet,
Low capacity dispersible granule, pill.
5. Herbicidal combinations according to claim 1, which is characterized in that the content of compound (A) and (B) account for the weeding
The 5%-90% of composition.
6. Herbicidal combinations according to claim 1, which is characterized in that the content of compound (A) and (B) account for the weeding
The 10%-80% of composition.
7. Herbicidal combinations according to claim 1, which is characterized in that the content of compound (A) and (B) account for the weeding
The 20%-60% of composition.
8. Herbicidal combinations according to claim 1, which is characterized in that the Herbicidal combinations further include safener, peace
Full agent is selected from benoxacor, fenclorim, dichlormide, mefenpyrdiethyl, isoxadifen, study on brassinolide, wherein the peace
Full agent is 1:100-20:1 relative to the weight proportion of compound (A) and compound (B).
9. the Herbicidal combinations of claim 1 are preventing and treating the purposes in undesirable plant growth.
10. purposes according to claim 9, which is characterized in that the undesirable plant is broad-leaved section weeds, Cyperaceae
Weeds, gramineae weed.
11. purposes according to claim 9, which is characterized in that the Herbicidal combinations, for preventing and treating wheat, corn, big
Beans, sugarcane, cotton, rice, beans, flax, barley, oat, rye, triticale, rape, potato, broomcorn millet, are herded at sugar beet
Broad-leaved section weeds, sedge weed, gramineae weed be not in grass, greenery patches or lawn, in the crop area Zhong Huofei of fruit plantation
Desired plant growth.
12. a kind of method for preventing and treating undesirable plant growth characterized by comprising (i) undesirable plant germination it
Before (before bud);(ii) after undesirable plant germination (after bud), or (iii) when (i) and (ii), by claim 1 institute
The Herbicidal combinations stated are applied to undesirable plant or it grows place.
13. according to the method for claim 12, which is characterized in that by the compound (A) of the Herbicidal combinations and (B)
It collectively or individually is applied to undesirable plant or it grows place.
14. according to the method for claim 12, which is characterized in that including by the Herbicidal combinations in useful crop
It is applied in the presence of other reproductive parts of plant, the seed of useful crop or useful crop.
15. according to the method for claim 12, which is characterized in that the plant that would not want to or its growth place have with weeding
The Herbicidal combinations contact of effect amount or the Herbicidal combinations that herbicidally effective amount is applied into water.
16. one kind reduces or prevents compound (A) or compound (B) to plant, the useful crop of the useful crop with its processing
Seed or useful crop other reproductive parts caused by damage method, which is characterized in that including with claim 1 institute
The Herbicidal combinations stated handle other reproductive parts of the plant of useful crop, the seed of useful crop or useful crop.
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102057924A (en) * | 2011-01-13 | 2011-05-18 | 青岛瀚生生物科技股份有限公司 | Compound composition containing clefoxidim and penoxsulam |
| CN103271064A (en) * | 2013-06-05 | 2013-09-04 | 江苏龙灯化学有限公司 | Weeding composition |
| CN104304297A (en) * | 2014-10-26 | 2015-01-28 | 山东滨农科技有限公司 | Weeding composition containing metamifop |
| CN104430465A (en) * | 2014-11-18 | 2015-03-25 | 山东滨农科技有限公司 | Herbicide composition containing clefoxidim |
| CN104519740A (en) * | 2012-01-12 | 2015-04-15 | 陶氏益农公司 | Herbicidal compositions containing bentazon and ALS inhibitor and ACCase inhibitor |
| CN104824003A (en) * | 2015-05-13 | 2015-08-12 | 广东中迅农科股份有限公司 | Herbicidal composition containing propyrisulfuron, cyhalofop-butyl and metamifop |
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2015
- 2015-09-07 CN CN201510563311.3A patent/CN106489974B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102057924A (en) * | 2011-01-13 | 2011-05-18 | 青岛瀚生生物科技股份有限公司 | Compound composition containing clefoxidim and penoxsulam |
| CN104519740A (en) * | 2012-01-12 | 2015-04-15 | 陶氏益农公司 | Herbicidal compositions containing bentazon and ALS inhibitor and ACCase inhibitor |
| CN103271064A (en) * | 2013-06-05 | 2013-09-04 | 江苏龙灯化学有限公司 | Weeding composition |
| CN104304297A (en) * | 2014-10-26 | 2015-01-28 | 山东滨农科技有限公司 | Weeding composition containing metamifop |
| CN104430465A (en) * | 2014-11-18 | 2015-03-25 | 山东滨农科技有限公司 | Herbicide composition containing clefoxidim |
| CN104824003A (en) * | 2015-05-13 | 2015-08-12 | 广东中迅农科股份有限公司 | Herbicidal composition containing propyrisulfuron, cyhalofop-butyl and metamifop |
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