CN106483046A - The migration evaluation methodology of chloride ion in a kind of Binder Materials containing villaumite - Google Patents
The migration evaluation methodology of chloride ion in a kind of Binder Materials containing villaumite Download PDFInfo
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- CN106483046A CN106483046A CN201611071567.3A CN201611071567A CN106483046A CN 106483046 A CN106483046 A CN 106483046A CN 201611071567 A CN201611071567 A CN 201611071567A CN 106483046 A CN106483046 A CN 106483046A
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- China
- Prior art keywords
- binder materials
- test specimen
- chloride ion
- migration
- materials containing
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- 239000000463 material Substances 0.000 title claims abstract description 35
- 239000011230 binding agent Substances 0.000 title claims abstract description 33
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 title claims abstract description 27
- 238000013508 migration Methods 0.000 title claims abstract description 25
- 230000005012 migration Effects 0.000 title claims abstract description 25
- 238000000034 method Methods 0.000 title claims abstract description 20
- 238000011156 evaluation Methods 0.000 title claims abstract description 15
- 238000012360 testing method Methods 0.000 claims abstract description 41
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 22
- 238000000465 moulding Methods 0.000 claims description 3
- 150000002500 ions Chemical class 0.000 abstract description 11
- 238000005070 sampling Methods 0.000 abstract description 4
- 230000035699 permeability Effects 0.000 abstract description 2
- 238000004904 shortening Methods 0.000 abstract 1
- 239000011398 Portland cement Substances 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 239000004411 aluminium Substances 0.000 description 2
- 239000010430 carbonatite Substances 0.000 description 2
- 239000004568 cement Substances 0.000 description 2
- 238000004587 chromatography analysis Methods 0.000 description 2
- 230000009514 concussion Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000008595 infiltration Effects 0.000 description 2
- 238000001764 infiltration Methods 0.000 description 2
- 230000037427 ion transport Effects 0.000 description 2
- 239000004570 mortar (masonry) Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 241000894007 species Species 0.000 description 2
- 229910021653 sulphate ion Inorganic materials 0.000 description 2
- 230000032258 transport Effects 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000002242 deionisation method Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N13/00—Investigating surface or boundary effects, e.g. wetting power; Investigating diffusion effects; Analysing materials by determining surface, boundary, or diffusion effects
Landscapes
- Physics & Mathematics (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
The invention discloses in a kind of Binder Materials containing villaumite chloride ion migration evaluation methodology.The method is to process the test specimen of Binder Materials containing villaumite using hydraulic pressure pressurization moving apparatus, to the test specimen section after pressurization, measures the concentration of chloride ion.The present invention is pressurizeed to the water in manometer tube by air compressor, pressure permeation is carried out to test specimen by the press water in water tank, after reaching regulation age, uniformly slicing is carried out to test specimen, the chlorine ion concentration gradient of each of sampling and testing after process, the Binder Materials of chloride ion can be contained in its internal migration with effective evaluation, the practical situation of ocean engineering Service Environment can be more conformed to, the effective evaluation of Transport in Binder Materials for the chloride ion can be realized in the short time in laboratory again.Can effectively shortening and be not pressurized longer problem of slow migration led to test period, leading to the Binder Materials more than ion concentration to have the too fast situation of reasonable permeability migration velocity although avoiding voltage shifts using hydraulic pressure migration.
Description
Technical field
The present invention relates in a kind of Binder Materials containing villaumite chloride ion migration evaluation methodology.
Background technology
There is component in corrosive ion, and all ocean engineerings in ocean engineering all in different water levels, have certain
Effect of water pressure, so ion has ion migration in concrete component, when the surface of reinforcing bar in ion migration to component,
Then steel bar corrosion being produced, thus destroying component, the stable of structure and safety being impacted.So ion is in Binder Materials
Transport to research ocean engineering in concrete durability extremely important.But migration in Binder Materials for the ion is one
Individual very long process, the test period is very long, for this reason, a lot of ways are to promote ion using the alive method of concrete at present
Concrete is migrated.But, the species of different Binder Materials, hydrated product is different, the ionic speciess in hole solution
And quantity is also different, in the presence of voltage, due to the difference of electrical conductivity, cause different types of Binder Materials each other
There is no comparability.
Content of the invention
It is an object of the invention to provide one kind is subject under hydraulic pressure effect in marine environment, chloride ion migrates in Binder Materials
Device and chloride ion transport rule evaluation methodology.
The technical solution used in the present invention is：
The migration evaluation methodology of chloride ion in a kind of Binder Materials containing villaumite, processes glue containing villaumite using hydraulic pressure pressurization moving apparatus
Gel material test specimen, to the test specimen section after pressurization, measures the concentration of chloride ion.
Described pressurization moving apparatus include water tank, air compressor machine, test specimen erecting device and pipeline, described water tank and pneumatics
Machine passes through pipeline and is connected, and air compressor machine is connected by pipeline with test specimen erecting device.
Described moulding pressure scope is 0.1 ~ 1.5Mpa.
The invention has the beneficial effects as follows：
The present invention is pressurizeed to the water in manometer tube by air compressor, by the press water in water tank, test specimen is pressed
Power is permeated, and after reaching regulation age, carries out uniformly slicing to test specimen, the chlorine ion concentration gradient of each of sampling and testing after process,
The Binder Materials of chloride ion can be contained in its internal migration with effective evaluation, the reality of ocean engineering Service Environment can be more conformed to
Border situation, can realize the effective evaluation of Transport in Binder Materials for the chloride ion in the short time in laboratory again.This evaluation
Method can effectively shorten and is not pressurized longer problem of slow migration led to test period, avoided using hydraulic pressure migration
Although voltage shifts lead to the Binder Materials more than ion concentration to have the reasonable permeability but too fast situation of migration velocity.
Brief description
Accompanying drawing 1 is pressurization moving apparatus structural representation；
Accompanying drawing 2 is Binder Materials sample pretreating schematic flow sheet.
Specific embodiment
The migration evaluation methodology of chloride ion in a kind of Binder Materials containing villaumite, is processed chloride using hydraulic pressure pressurization moving apparatus
Salt Binder Materials test specimen, to the test specimen section after pressurization, measures the concentration of chloride ion.
Described pressurization moving apparatus include water tank, air compressor machine, test specimen erecting device and pipeline, described water tank and pneumatics
Machine passes through pipeline and is connected, and air compressor machine is connected by pipeline with test specimen erecting device.
Furthermore, it is understood that this pressurization moving apparatus is pressurizeed to the water in pipeline by air compressor, by water tank
In press water pressure permeation is carried out to test specimen.
Preferably, described moulding pressure scope is 0.1 ~ 1.5Mpa.
Preferably, the described pressurization deadline is to treat that test specimen reaches regulation age in pressure permeation, that is, on test specimen mortar
Surface occurs 1 ~ 1.5 hour after infiltration.
Described Binder Materials containing villaumite are portland cement, sulphate aluminium cement, alkali-activated carbonatite Binder Materials, magnesial gelatinized
At least one of material.
The present invention is that Binder Materials containing villaumite are promoted after chloride ion transport by pressurization, test specimen is carried out with section and measures chlorine
Ion concentration, to obtain Concentraton gradient in test specimen for the chloride ion.
Below by way of specific embodiment, present disclosure is described in further detail.
Embodiment：
Referring to the drawings 1, a kind of pressurization moving apparatus promoting villaumite migration in the test specimen of the Binder Materials containing villaumite by hydraulic pressure,
It includes water tank 1, and water tank 1 connects air compressor machine 2 by pipeline, and pipeline arranges valve, and air compressor machine 2 passes through manometer tube 3 and connects examination
Part erecting device 5, manometer tube 3 is provided with pressure gauge 4, and test specimen erecting device 5 top is provided with permeation liquid catcher 6.Empty
Press carries out applying pressure by the water in pipeline.Pipeline is contacted with test specimen, produces pressure by the water in pipeline to test specimen and oozes
Thoroughly.
The 2 test specimen process chart of Binder Materials containing villaumite is described as follows referring to the drawings：Test specimen is on pressurization moving apparatus
After carrying out migration test, vertically even laminating section is carried out to test specimen, pulverize levigate after section, sieve, sampling dilution concussion
Dissolution, finally carries out chlorine ion concentration mensure using chromatography of ions.
Specific as follows：
Test specimen first carries out migration process on pressurization moving apparatus, and the pressure limit of pressurization is 0.1 ~ 1.5Mpa, the completing of pressurization
Time is that test specimen mortar upper surface occurs 1 ~ 1.5 hour after infiltration.
After having carried out migration test on pressurization moving apparatus, the thick Binder Materials test specimen of 10cm enters according to the thickness of 10mm
Row cutting sampling, is divided into 10 layers, each layer of sample is carried out pulverizing levigate, 0.08 μm excessively sieve respectively, takes 10g to be dissolved in deionization
In water（Water-solid ratio 10:1）, after concussion, carry out the test of chlorine ion concentration using chromatography of ions.
Described Binder Materials containing villaumite can be selected from portland cement, sulphate aluminium cement, alkali-activated carbonatite Binder Materials, magnesium
The one or more of which of matter Binder Materials.
Claims (3)
1. in a kind of Binder Materials containing villaumite chloride ion migration evaluation methodology it is characterised in that：Using hydraulic pressure pressurization migration dress
Put the process test specimen of Binder Materials containing villaumite, to the test specimen section after pressurization, measure the concentration of chloride ion.
2. in a kind of Binder Materials containing villaumite according to claim 1 chloride ion migration evaluation methodology it is characterised in that：
Described pressurization moving apparatus include water tank, air compressor machine, test specimen erecting device and pipeline, and described water tank passes through pipe with air compressor machine
Road is connected, and air compressor machine is connected by pipeline with test specimen erecting device.
3. in a kind of Binder Materials containing villaumite according to claim 1 chloride ion migration evaluation methodology it is characterised in that：
Described moulding pressure scope is 0.1 ~ 1.5Mpa.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611071567.3A CN106483046A (en) | 2016-11-29 | 2016-11-29 | The migration evaluation methodology of chloride ion in a kind of Binder Materials containing villaumite |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611071567.3A CN106483046A (en) | 2016-11-29 | 2016-11-29 | The migration evaluation methodology of chloride ion in a kind of Binder Materials containing villaumite |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106483046A true CN106483046A (en) | 2017-03-08 |
Family
ID=58274275
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611071567.3A Pending CN106483046A (en) | 2016-11-29 | 2016-11-29 | The migration evaluation methodology of chloride ion in a kind of Binder Materials containing villaumite |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106483046A (en) |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06317560A (en) * | 1993-04-30 | 1994-11-15 | Tokyo Electric Power Co Inc:The | Estimation method of compression strength of concrete by rapid chlorine ion permeability test |
| CN102564916A (en) * | 2012-01-16 | 2012-07-11 | 河海大学 | Fast load testing device and method for chloride ion migration coefficient of concrete |
| CN102721637A (en) * | 2012-06-29 | 2012-10-10 | 浙江大学 | Multi-functional test system and method for concrete durability under action of continuous pressure |
| CN104155218A (en) * | 2014-08-12 | 2014-11-19 | 上海化工研究院 | Multi-stage pressurized test device for simulating migration of water pollutants in silt soil layer |
| CN105445164A (en) * | 2015-11-29 | 2016-03-30 | 江山显进机电科技服务有限公司 | Concrete penetrometer |
| CN205120541U (en) * | 2015-11-06 | 2016-03-30 | 佛冈锦华混凝土有限公司 | Concrete anti -permeability apparatus |
| CN205229004U (en) * | 2015-12-10 | 2016-05-11 | 西安科技大学 | Concrete durability test device |
-
2016
- 2016-11-29 CN CN201611071567.3A patent/CN106483046A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06317560A (en) * | 1993-04-30 | 1994-11-15 | Tokyo Electric Power Co Inc:The | Estimation method of compression strength of concrete by rapid chlorine ion permeability test |
| CN102564916A (en) * | 2012-01-16 | 2012-07-11 | 河海大学 | Fast load testing device and method for chloride ion migration coefficient of concrete |
| CN102721637A (en) * | 2012-06-29 | 2012-10-10 | 浙江大学 | Multi-functional test system and method for concrete durability under action of continuous pressure |
| CN104155218A (en) * | 2014-08-12 | 2014-11-19 | 上海化工研究院 | Multi-stage pressurized test device for simulating migration of water pollutants in silt soil layer |
| CN205120541U (en) * | 2015-11-06 | 2016-03-30 | 佛冈锦华混凝土有限公司 | Concrete anti -permeability apparatus |
| CN105445164A (en) * | 2015-11-29 | 2016-03-30 | 江山显进机电科技服务有限公司 | Concrete penetrometer |
| CN205229004U (en) * | 2015-12-10 | 2016-05-11 | 西安科技大学 | Concrete durability test device |
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| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170308 |