CN106480469A - The manufacture method of small-sized ammonia machine processed - Google Patents

The manufacture method of small-sized ammonia machine processed Download PDF

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Publication number
CN106480469A
CN106480469A CN201610584198.1A CN201610584198A CN106480469A CN 106480469 A CN106480469 A CN 106480469A CN 201610584198 A CN201610584198 A CN 201610584198A CN 106480469 A CN106480469 A CN 106480469A
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ammonia
volts
voltage
watts
power
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张国权
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    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/50—Processes
    • C25B1/55—Photoelectrolysis
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

Abstract

The present invention is the small-sized ammonia machine processed of one kind of chemical field, describes two kinds of technical schemes, takes simple method to produce ammonia.The technical characteristic of small-sized ammonia machine processed, is to synthesize ammonia with nitrogen and hydrogen.According to claim 1, positive pole is done using Raney nickel, molybdenum, triphenylphosphine are negative pole, graphite FeCl3Potassium ternary compound does solid electrolyte, electro synthesis ammonia.According to claim 2, solar panel is pacified using 150 watts of power, 24.6 volts of voltage, 30.5 volts of open-circuit voltage, electric current 5.47 and replaces 120 watts of power, 12 volts of voltage, 10 safety supervision control power supply of electric current, electricity ammonia processed just switchs to light ammonia.The autofrettage of small-sized ammonia machine processed is studied, is in order to reduce farmer's burdens, for increasing crop yield, allow peasant oneself produce chemical fertilizer.

Description

The manufacture method of small-sized ammonia machine processed
First, technical field：
The present invention is chemical field, is related to a kind of small-sized ammonia machine processed, takes simple method to produce ammonia.
2nd, background technology：
Industrial production chemical fertilizer, price are higher, peasant burden weight, are not easy to implement.In order to reduce farmer's burdens, for farming Thing increases production, and therefore studies the autofrettage of small-sized ammonia machine processed, allows peasant oneself produce chemical fertilizer.
3rd, content of the invention：
Small-sized ammonia machine processed is invented, is synthesized ammonia with nitrogen and hydrogen, takes two ways：1. electrically separated nitrogen, electricity hydrolysis Hydrogen, electro synthesis ammonia；2. light separation of nitrogen, light hydrolyze hydrogen, light ammonia.
4th, illustrate：
Fig. 1 water electrolysis hydrogen making
Fig. 2 water electrolysis hydrogen making schematic diagram
Fig. 3 transformation method separates air nitrogen
Fig. 4 transformation method separates air nitrogen schematic diagram
Fig. 5 electro synthesis ammonia
Fig. 6 electro synthesis ammonia schematic diagram
Fig. 7 light hydrolytic hydrogen production gas
Fig. 8 light separates in the air nitrogen
Fig. 9 light separates in the air nitrogen schematic diagram
Figure 10 light ammonia
5th, specific embodiment：
1st, electro synthesis ammonia
(1) water electrolysis hydrogen making, i.e., toward H2In O, water electrolyzer positive pole adds cobaltous dichloride CoCl2, Co2+Positive pole betatopic Co3+, Co3+Make H2O chemically reactive generates H2And O2, low price cation ionization energy is very big, Co2+Betatopic is not easy very much, Plus triphenylphosphine makes Co2+Easily betatopic, makes Co2+Easily become Co3+.
Water electrolyzer negative pole is by zinc granule, Zn+2Cl-1 2, starch uniformly constitute, positive pole interruption will be electronically entered Zn in negative pole2+, Make Zn2++ e=Zn0, while positive pole is by H+Input negative pole, makes Zn0+2H+=H2↑, make negative pole obtain H2, positive pole obtains O2.
Note：Water electrolyzer is permissible without barrier film, if using barrier film, uses Xu Jiaye《High organic synthesis》The F101 of page 200 Type film, E105 type film, the SPE film of page 224.
(2) separate air with transformation method and produce nitrogen, i.e., N2 processed.
Inflate method：Inflate hole and Air inflating valve is connected, air outlet valve cuts out, the slip-knot between aspirating hole and air outlet valve must be pulled out Open, 220V power supply is inserted, air gauge has a power failure to 5 air pressure, stops inflating.At this moment air outlet valve is decontroled, and pressure gauge drops to normal pressure, at this moment Gas out is exactly N2.
Air-exhaust method：Aspirating hole and air outlet valve are connected, and air outlet valve is opened, and are inflated hole and must be unpluged, plug 220V power supply, open Begin to be evacuated.By above method of operating, I really tests, and obtains nitrogen N2.
Transformation method separates air nitrogen N2, 5 atmospheric pressure of absorption phase, power consumption are less than 1.0kWh/m3, obtain 99.9% Nitrogen.
(3) electro synthesis ammonia NH3, i.e., NH processed3.
Electro synthesis figure constitutes：Raney nickel does positive pole, and molybdenum, triphenylphosphine are negative pole, graphite-FeCl3- potassium ternary compound does Solid electrolyte.
H2Input positive pole, N2Input negative pole, H22 bonding electrons of molecule lose electronics to negative pole, and negative electricity is more, has made Backdonation is imitated into, makes negative pole N2Decompose nitrogen-atoms, produce nitrogen-atoms and hydrogen atom combines NH3.
Above-mentioned (1) H processed2Experiment, (2) N processed2Experiment, (3) NH processed3Experiment, I really tests, and experiment effect is all suitable Good.
2nd, light ammonia
(1) photolysis water hydrogen gas
Pacify solar panel with 150 watts of power, 24.6 volts of voltage, 30.5 volts of open-circuit voltage, electric current 5.47 and replace power 120 watts, 12 volts of voltage, 10 safety supervision control power supply of electric current, water electrolysis hydrogen production gas reformed into photolysis water hydrogen gas.
Water electrolysis hydrogen production gas and photolysis water hydrogen gas pluses and minuses：
Water electrolysis hydrogen production gas, 200 yuan of equipment investment, pay tariff to country.
Photolysis water hydrogen gas, 1100 yuan of equipment investment, do not pay tariff to country.
Photolysis water hydrogen gas is very good through testing hydrogen producing effect.
(2) light separates in the air nitrogen
Pacify solar panel with 150 watts of power, 24.6 volts of voltage, 30.5 volts of open-circuit voltage, electric current 5.47, through control Device, batteries, inverter, obtain voltage 220V power supply, and this power supply drives compressor for refrigeration just to separate in the air nitrogen for light Gas.
Electrically separated in the air nitrogen separates in the air nitrogen pluses and minuses with light：
Electrically separated in the air nitrogen, invests about 350 yuan, pays tariff to household electrical appliances department of state.
Light separates in the air nitrogen, invests about 2600 yuan, does not pay tariff to household electrical appliances department of state.
(3) light ammonia
Pacify solar panel with 150 watts of power, 24.6 volts of voltage, 30.5 volts of open-circuit voltage, electric current 5.47 and replace power 120 watts, 12 volts of voltage, 10 safety supervision control power supply of electric current, electricity ammonia processed just become light ammonia.
Electricity ammonia processed and light ammonia pluses and minuses：
Electricity ammonia processed, invests 300 yuan, pays tariff to household electrical appliances department of state.
Light ammonia, invests 1200 yuan, does not pay tariff to household electrical appliances department of state.
Peasant's productive prospecting be sow in spring, shovel within 1 year, deinsectization, uprooting weed, product farm manure, many farm work such as autumn harvest, never make A kind of fertile farm work of chemistry, so ammonia mechanism ammonia processed time limit one year；Scientifically accumulator capacity=current strength × when Between, i.e., current strength is less, longer with the time, and according to peasant's productive prospecting, peasant has the time to store tired electric energy, produces ammonia.
I tests above, and effect is fine.

Claims (6)

1. the present invention is a kind of manufacture method of small-sized ammonia machine processed, is to synthesize ammonia with nitrogen and hydrogen.Just done using Raney nickel Negative pole, graphite-FeCl are in pole, molybdenum, triphenylphosphine3- potassium ternary compound does solid electrolyte, electro synthesis ammonia.
2. according to claim 1, pacified too using 150 watts of power, 24.6 volts of voltage, 30.5 volts of open-circuit voltage, electric current 5.47 Sun energy cell panel replaces 120 watts of power, 12 volts of voltage, 10 safety supervision control power supply of electric current, and electro synthesis ammonia just switchs to light ammonia.
3. according to claim 1, hydrogen is obtained by water electrolysis, just extremely cobaltous dichloride, triphenylphosphine, and negative pole is by zinc Grain, ZnCl2, starch uniformly constitute, obtain H from the negative pole of electrolyzer2.
4. according to claim 1, nitrogen separates air by transformation method and produces, and when air gauge has a power failure to 5 air pressure, stops Inflate, air outlet valve is decontroled, pressure gauge drops to normal pressure, and the gas of acquisition is exactly N2.
5. according to claim 2, the sun is pacified with 150 watts of power, 24.6 volts of voltage, 30.5 volts of open-circuit voltage, electric current 5.47 Energy cell panel replaces 120 watts of power, 12 volts of voltage, 10 safety supervision control power supply of electric current, and water electrolysis hydrogen production gas has reformed into photocatalytic water system Hydrogen.
6. according to claim 2, the sun is pacified with 150 watts of power, 24.6 volts of voltage, 30.5 volts of open-circuit voltage, electric current 5.47 Energy cell panel, via controller, batteries, inverter, voltage 220V power supply is obtained, this power supply drives compressor for refrigeration just to turn It is changed into light and separates in the air nitrogen.
CN201610584198.1A 2016-07-14 2016-07-14 The manufacture method of small-sized ammonia machine processed Pending CN106480469A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112939023A (en) * 2021-03-31 2021-06-11 西安热工研究院有限公司 System and method for storing energy and denitrating ammonia produced by thermal power plant

Citations (8)

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Publication number Priority date Publication date Assignee Title
CN1852861A (en) * 2003-07-23 2006-10-25 安格斯公司 Method for the point of use production of ammonia from water and nitrogen
CN101006010A (en) * 2004-05-18 2007-07-25 马寺松气体股份有限公司 On-site generation, purification, and distribution of ultra-pure anhydrous ammonia
CN101589176B (en) * 2006-12-21 2012-02-15 代理并代表亚利桑那州立大学的亚利桑那董事会 Method and apparatus for ammonia (NH3) generation
US20120241328A1 (en) * 2011-03-23 2012-09-27 Joshi Ashok V Ammonia synthesis using lithium ion conductive membrane
CN103108994A (en) * 2010-07-21 2013-05-15 日立造船株式会社 Method for synthesizing ammonia
CN103866343A (en) * 2014-03-25 2014-06-18 内蒙古科技大学 Method and device for synthesizing ammonia through carrying out efficient electrocatalytic reduction on nitrogen gas at low temperature and normal pressure
CN104630811A (en) * 2015-02-13 2015-05-20 王海斌 Novel electrolysis ammonia production device
CN105264118A (en) * 2013-03-26 2016-01-20 俄亥俄州立大学 Electrochemical synthesis of ammonia in alkaline media

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1852861A (en) * 2003-07-23 2006-10-25 安格斯公司 Method for the point of use production of ammonia from water and nitrogen
CN101006010A (en) * 2004-05-18 2007-07-25 马寺松气体股份有限公司 On-site generation, purification, and distribution of ultra-pure anhydrous ammonia
CN101589176B (en) * 2006-12-21 2012-02-15 代理并代表亚利桑那州立大学的亚利桑那董事会 Method and apparatus for ammonia (NH3) generation
CN103108994A (en) * 2010-07-21 2013-05-15 日立造船株式会社 Method for synthesizing ammonia
US20120241328A1 (en) * 2011-03-23 2012-09-27 Joshi Ashok V Ammonia synthesis using lithium ion conductive membrane
CN105264118A (en) * 2013-03-26 2016-01-20 俄亥俄州立大学 Electrochemical synthesis of ammonia in alkaline media
CN103866343A (en) * 2014-03-25 2014-06-18 内蒙古科技大学 Method and device for synthesizing ammonia through carrying out efficient electrocatalytic reduction on nitrogen gas at low temperature and normal pressure
CN104630811A (en) * 2015-02-13 2015-05-20 王海斌 Novel electrolysis ammonia production device

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Title
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112939023A (en) * 2021-03-31 2021-06-11 西安热工研究院有限公司 System and method for storing energy and denitrating ammonia produced by thermal power plant

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