CN106480395A - A kind of turbine blade anticorrosion abrasionproof etching method - Google Patents

A kind of turbine blade anticorrosion abrasionproof etching method Download PDF

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Publication number
CN106480395A
CN106480395A CN201611027918.0A CN201611027918A CN106480395A CN 106480395 A CN106480395 A CN 106480395A CN 201611027918 A CN201611027918 A CN 201611027918A CN 106480395 A CN106480395 A CN 106480395A
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China
Prior art keywords
blade surface
flow
pressure
nicrmosib
etching method
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CN201611027918.0A
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Chinese (zh)
Inventor
张达明
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Wuxi Mingsheng Textile Machinery Co Ltd
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Wuxi Mingsheng Textile Machinery Co Ltd
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Priority to CN201611027918.0A priority Critical patent/CN106480395A/en
Publication of CN106480395A publication Critical patent/CN106480395A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/04Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
    • C23C4/06Metallic material
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C19/00Alloys based on nickel or cobalt
    • C22C19/03Alloys based on nickel or cobalt based on nickel
    • C22C19/05Alloys based on nickel or cobalt based on nickel with chromium
    • C22C19/051Alloys based on nickel or cobalt based on nickel with chromium and Mo or W
    • C22C19/056Alloys based on nickel or cobalt based on nickel with chromium and Mo or W with the maximum Cr content being at least 10% but less than 20%

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Turbine Rotor Nozzle Sealing (AREA)

Abstract

The invention discloses a kind of turbine blade anticorrosion abrasionproof etching method, which includes:(1) sandblasting roughening is carried out in blade surface;(2) with acetone and ethanol purge roughening blade surface and dry;(3) 20 45wt%, Si are accounted for according to hard TiN ceramic particle3N4Nano particle accounts for the proportioning of 5 15wt%, NiCrMoSiB powder metallurgy surpluses, makes slurry, by the slurry uniform application in blade surface, dries at 90 130 DEG C;(4) it is fuel to adopt propane gas, and high pressure oxygen is combustion-supporting gas, and nitrogen is powder feeding gas, HVAF is carried out to blade surface, during spraying, propane pressure is 0.55 0.7MPa, and flow is 20 30L/min, oxygen pressure is 0.65 0.7MPa, flow is 180 200L/min, and nitrogen pressure is 0.85 1MPa, and flow is 18 30L/min, coating thickness is 700 μm of 2mm, obtains cladding in the TiN Si of blade surface3N4NiCrMoSiB wear-resistant coating.Through trying out 1 month in waste stream, significantly abrasion and evidence of corrosion is not found.

Description

A kind of turbine blade anticorrosion abrasionproof etching method
Technical field
The present invention relates to field of material technology, more particularly to a kind of turbine blade anticorrosion abrasionproof etching method.
Background technology
Abrasion wear phenomena all generally existing in many industries such as water conservancy, water power, machinery, weaving and metallurgy, and non- Chang Yanchong, the economic loss for thereby resulting in can quite show.China is very huge in the spending of this aspect, especially water conservancy, water power Department more projects.This is because China's silt content of river is big, complete excessively annual fortune river of the sedimentary loading more than 10,000,000 tons reaches 115 Bar, according to first place in the world.Calendar year 2001, relevant statistics showed Ml, and national power station total installation of generating capacity is 80.05GW, gross generation The big areas of silt content of river such as northwest, southwest and North China are located at for 2184.5 hundred million kW/h, wherein 105,600,000,000 kW h, these areas Component of Hydraulic Turbines not only washed away by high-velocity flow, denuded and the acting on of mechanical force, but also by being mingled with current The abrasion of the media such as silt, ablation destruction, therefore the consume of material is very serious.In addition, in the power station of Central-South, East China, Although Component of Hydraulic Turbines is received because silt content of river is few, and sand erosion loss is little, the cavitation of current is to water at deep water The destruction of engine blade wheel material is then quite serious.Data shows according to the relevent statistics, and a large-scale power station is used for changing, repairing every year The expense of water conservancy machinery reaches more than million yuan, therefore, solves hydraulic abrasion, erosion problem, very necessary.
A kind of most economical, most efficient method is exactly the high anti-corrosion painting of coating high abrasion on the blade and arbor of the hydraulic turbine Layer, and wear resistant corrosion resistant metal coating is favored by people deeply as its coating processes is simple, economic and effect is obvious.
Content of the invention
It is an object of the invention to proposing a kind of turbine blade anticorrosion abrasionproof etching method, resist can turbine blade Abrasion is simultaneously anticorrosive.
For reaching this purpose, the present invention is employed the following technical solutions:
A kind of turbine blade anticorrosion abrasionproof etching method, which includes:
(1) sandblasting roughening is carried out in blade surface;
(2) with acetone and ethanol purge roughening blade surface and dry;
(3) 20-45wt%, Si are accounted for according to hard TiN ceramic particle3N4Nano particle accounts for 5-15wt%, NiCrMoSiB powder The proportioning of last alloy surplus, makes slurry, by the slurry uniform application in blade surface, dries at 90-130 DEG C;
(4) it is fuel to adopt propane gas, and high pressure oxygen is combustion-supporting gas, and nitrogen is powder feeding gas, and blade surface is carried out HVAF, during spraying, propane pressure is 0.55-0.7MPa, and flow is 20-30L/min, and oxygen pressure is 0.65- 0.7MPa, flow are 180-200L/min, and nitrogen pressure is 0.85-1MPa, and flow is 18-30L/min, and coating thickness is 700 μ M-2mm, obtains cladding in the TiN-Si of blade surface3N4- NiCrMoSiB wear-resistant coating.
NiCrMoSiB powder metallurgy of the present invention, its composition percentage composition by weight include Cr 10-15%, Ni 3-7%, Mo 2-6%, Si 1-5%, B 2-4%, surplus Ni.
Preferably, TiN ceramic particle accounts for 30-40wt%, further preferred 35wt%.
The wear-resistant coating that the present invention is prepared, goes to form metallurgical binding with matrix, and bond strength is more than 600MPa, coating For even tissue, the as cast condition crystalline structure of dense non-porous, its coating hardness is up to more than 80 Rockwell hardness, service life compared to Blade without coating extends more than 6-7 times, and anti-cavitation ability improves more than 10 times.
The TiN-Si that the present invention is prepared3N4- NiCrMoSiB wear-resistant coating, it possess the advantage of ceramic coating, not only Anti scuffing, also anticorrosive.Through trying out 1 month in waste stream, significantly abrasion and evidence of corrosion is not found.
Specific embodiment
Technical scheme is further illustrated below by specific embodiment.
Embodiment 1
A kind of turbine blade anticorrosion abrasionproof etching method, which includes:
(1) sandblasting roughening is carried out in blade surface;
(2) with acetone and ethanol purge roughening blade surface and dry;
(3) 20wt%, Si are accounted for according to hard TiN ceramic particle3N4Nano particle accounts for 5wt%, NiCrMoSiB powder metallurgy The proportioning of surplus, makes slurry, by the slurry uniform application in blade surface, dries at 90 DEG C;
(4) it is fuel to adopt propane gas, and high pressure oxygen is combustion-supporting gas, and nitrogen is powder feeding gas, and blade surface is carried out HVAF, during spraying, propane pressure is 0.55MPa, and flow is 20L/min, and oxygen pressure is 0.65MPa, flow For 180L/min, nitrogen pressure is 0.85MPa, and flow is 18L/min, and coating thickness is 700 μm, obtains cladding in blade surface TiN-Si3N4- NiCrMoSiB wear-resistant coating.
Embodiment 2
A kind of turbine blade anticorrosion abrasionproof etching method, which includes:
(1) sandblasting roughening is carried out in blade surface;
(2) with acetone and ethanol purge roughening blade surface and dry;
(3) 45wt%, Si are accounted for according to hard TiN ceramic particle3N4Nano particle accounts for 15wt%, NiCrMoSiB powder metallurgy The proportioning of surplus, makes slurry, by the slurry uniform application in blade surface, dries at 130 DEG C;
(4) it is fuel to adopt propane gas, and high pressure oxygen is combustion-supporting gas, and nitrogen is powder feeding gas, and blade surface is carried out HVAF, during spraying, propane pressure is 0.7MPa, and flow is 30L/min, and oxygen pressure is 0.7MPa, and flow is 200L/min, nitrogen pressure are 1MPa, and flow is 30L/min, and coating thickness is 2mm, obtains cladding in the TiN- of blade surface Si3N4- NiCrMoSiB wear-resistant coating.
Embodiment 3
A kind of turbine blade anticorrosion abrasionproof etching method, which includes:
(1) sandblasting roughening is carried out in blade surface;
(2) with acetone and ethanol purge roughening blade surface and dry;
(3) 35wt%, Si are accounted for according to hard TiN ceramic particle3N4Nano particle accounts for 10wt%, NiCrMoSiB powder metallurgy The proportioning of surplus, makes slurry, by the slurry uniform application in blade surface, dries at 100 DEG C;
(4) it is fuel to adopt propane gas, and high pressure oxygen is combustion-supporting gas, and nitrogen is powder feeding gas, and blade surface is carried out HVAF, during spraying, propane pressure is 0.6MPa, and flow is 25L/min, and oxygen pressure is 0.67MPa, and flow is 190L/min, nitrogen pressure are 0.95MPa, and flow is 25L/min, and coating thickness is 1mm, obtains cladding in blade surface TiN-Si3N4- NiCrMoSiB wear-resistant coating.
The turbine blade that embodiment 1-3 is prepared, through trying out 1 month in waste stream, does not find significantly mill Erosion and evidence of corrosion.

Claims (3)

1. a kind of turbine blade anticorrosion abrasionproof etching method, which includes:
(1) sandblasting roughening is carried out in blade surface;
(2) with acetone and ethanol purge roughening blade surface and dry;
(3) 20-45wt%, Si are accounted for according to hard TiN ceramic particle3N4Nano particle accounts for the conjunction of 5-15wt%, NiCrMoSiB powder The proportioning of golden surplus, makes slurry, by the slurry uniform application in blade surface, dries at 90-130 DEG C;
(4) it is fuel to adopt propane gas, and high pressure oxygen is combustion-supporting gas, and nitrogen is powder feeding gas, carries out Supersonic to blade surface Fast flame-spraying, during spraying, propane pressure is 0.55-0.7MPa, and flow is 20-30L/min, and oxygen pressure is 0.65- 0.7MPa, flow are 180-200L/min, and nitrogen pressure is 0.85-1MPa, and flow is 18-30L/min, and coating thickness is 700 μ M-2mm, obtains cladding in the TiN-Si of blade surface3N4- NiCrMoSiB wear-resistant coating.
2. turbine blade anticorrosion abrasionproof etching method as claimed in claim 1, it is characterised in that described NiCrMoSiB Powder metallurgy, its composition percentage composition by weight include Cr 10-15%, Ni 3-7%, Mo 2-6%, Si 1-5%, B 2- 4%, surplus Ni.
3. turbine blade anticorrosion abrasionproof etching method as claimed in claim 1 or 2, it is characterised in that TiN ceramic particle is accounted for 30-40wt%, further preferred 35wt%.
CN201611027918.0A 2016-11-18 2016-11-18 A kind of turbine blade anticorrosion abrasionproof etching method Pending CN106480395A (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102925847A (en) * 2012-11-06 2013-02-13 华北水利水电学院 Method for preparing submicron abrasion and corrosion resisting coating of flow passage component of water turbine
CN103510035A (en) * 2012-06-15 2014-01-15 西安宇丰喷涂技术有限公司 Anti-scuffing treatment method for surface of water turbine
CN104862571A (en) * 2015-06-16 2015-08-26 武汉理工大学 Multi-scale nanostructured WC-CoCr metal ceramic composite powder

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103510035A (en) * 2012-06-15 2014-01-15 西安宇丰喷涂技术有限公司 Anti-scuffing treatment method for surface of water turbine
CN102925847A (en) * 2012-11-06 2013-02-13 华北水利水电学院 Method for preparing submicron abrasion and corrosion resisting coating of flow passage component of water turbine
CN104862571A (en) * 2015-06-16 2015-08-26 武汉理工大学 Multi-scale nanostructured WC-CoCr metal ceramic composite powder

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
徐润生等: "《NiCrBSi/WC涂层及涂层开裂处抗蚀行为研究》", 《中国表面工程》 *

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Application publication date: 20170308