CN106479691B - 一种具有固色功能的凤眼蓝洗衣液及其制备方法和应用 - Google Patents
一种具有固色功能的凤眼蓝洗衣液及其制备方法和应用 Download PDFInfo
- Publication number
- CN106479691B CN106479691B CN201610821274.6A CN201610821274A CN106479691B CN 106479691 B CN106479691 B CN 106479691B CN 201610821274 A CN201610821274 A CN 201610821274A CN 106479691 B CN106479691 B CN 106479691B
- Authority
- CN
- China
- Prior art keywords
- water hyacinth
- ethyl alcohol
- liquid detergent
- juice
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000007788 liquid Substances 0.000 title claims abstract description 62
- 239000003599 detergent Substances 0.000 title claims abstract description 53
- 238000002360 preparation method Methods 0.000 title claims abstract description 26
- 240000003826 Eichhornia crassipes Species 0.000 title description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 144
- 241000169203 Eichhornia Species 0.000 claims abstract description 131
- 235000019441 ethanol Nutrition 0.000 claims abstract description 66
- 235000011389 fruit/vegetable juice Nutrition 0.000 claims abstract description 50
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims abstract description 30
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims abstract description 17
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims abstract description 15
- 235000017557 sodium bicarbonate Nutrition 0.000 claims abstract description 15
- 238000004140 cleaning Methods 0.000 claims abstract description 11
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims abstract description 8
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000001768 carboxy methyl cellulose Substances 0.000 claims abstract description 8
- 150000002191 fatty alcohols Chemical class 0.000 claims abstract description 8
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims abstract description 8
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims abstract description 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 6
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims abstract description 5
- 229910052938 sodium sulfate Inorganic materials 0.000 claims abstract description 4
- 235000011152 sodium sulphate Nutrition 0.000 claims abstract description 4
- 239000000843 powder Substances 0.000 claims description 15
- 239000003755 preservative agent Substances 0.000 claims description 10
- 230000002335 preservative effect Effects 0.000 claims description 10
- 239000000243 solution Substances 0.000 claims description 10
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 8
- 239000011734 sodium Substances 0.000 claims description 6
- 229910052708 sodium Inorganic materials 0.000 claims description 6
- 239000007787 solid Substances 0.000 claims description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 5
- 241000233805 Phoenix Species 0.000 claims description 5
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 5
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 5
- 239000000654 additive Substances 0.000 claims description 4
- 238000004090 dissolution Methods 0.000 claims description 4
- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical compound [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 claims description 3
- 241000675108 Citrus tangerina Species 0.000 claims description 3
- 235000007688 Lycopersicon esculentum Nutrition 0.000 claims description 3
- 240000003768 Solanum lycopersicum Species 0.000 claims description 3
- 230000000996 additive effect Effects 0.000 claims description 3
- 235000010241 potassium sorbate Nutrition 0.000 claims description 3
- 239000004302 potassium sorbate Substances 0.000 claims description 3
- 229940069338 potassium sorbate Drugs 0.000 claims description 3
- 235000005979 Citrus limon Nutrition 0.000 claims description 2
- 239000011259 mixed solution Substances 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical group [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims description 2
- 235000010234 sodium benzoate Nutrition 0.000 claims description 2
- 239000004299 sodium benzoate Substances 0.000 claims description 2
- 244000248349 Citrus limon Species 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 3
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 abstract description 2
- 238000005406 washing Methods 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 238000000034 method Methods 0.000 description 5
- 229920000742 Cotton Polymers 0.000 description 4
- 239000000835 fiber Substances 0.000 description 4
- 239000000706 filtrate Substances 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 238000002390 rotary evaporation Methods 0.000 description 3
- 230000009182 swimming Effects 0.000 description 3
- 241000251468 Actinopterygii Species 0.000 description 2
- 241000195493 Cryptophyta Species 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- XLYOFNOQVPJJNP-ZSJDYOACSA-N Heavy water Chemical compound [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 description 2
- 238000009395 breeding Methods 0.000 description 2
- 230000001488 breeding effect Effects 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 238000004043 dyeing Methods 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 210000004209 hair Anatomy 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- -1 sodium alkyl sulfonate Chemical class 0.000 description 2
- 241000894007 species Species 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 244000131522 Citrus pyriformis Species 0.000 description 1
- 241001573881 Corolla Species 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 244000061458 Solanum melongena Species 0.000 description 1
- 244000269722 Thea sinensis Species 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000002775 capsule Substances 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 239000000982 direct dye Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 210000004907 gland Anatomy 0.000 description 1
- 230000000762 glandular Effects 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 235000019239 indanthrene blue RS Nutrition 0.000 description 1
- UHOKSCJSTAHBSO-UHFFFAOYSA-N indanthrone blue Chemical compound C1=CC=C2C(=O)C3=CC=C4NC5=C6C(=O)C7=CC=CC=C7C(=O)C6=CC=C5NC4=C3C(=O)C2=C1 UHOKSCJSTAHBSO-UHFFFAOYSA-N 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229920000554 ionomer Polymers 0.000 description 1
- 238000003973 irrigation Methods 0.000 description 1
- 230000002262 irrigation Effects 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000008239 natural water Substances 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- 210000001672 ovary Anatomy 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 229910000498 pewter Inorganic materials 0.000 description 1
- 239000010957 pewter Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000000985 reactive dye Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- IZPNTDOWOBGHEG-UHFFFAOYSA-M sodium benzene formate Chemical group [Na+].[O-]C=O.C1=CC=CC=C1 IZPNTDOWOBGHEG-UHFFFAOYSA-M 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- 230000002792 vascular Effects 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/04—After-treatment with organic compounds
- D06P5/08—After-treatment with organic compounds macromolecular
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Textile Engineering (AREA)
- Inorganic Chemistry (AREA)
- Molecular Biology (AREA)
- Detergent Compositions (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
本发明公开了本发明涉及一种具有固色功能的凤眼蓝洗衣液及其制备方法和应用，该具有固色功能的凤眼蓝洗衣液的主要成分包括：凤眼蓝混合液、脂肪醇聚氧乙烯醚硫酸钠，磺酸和羧甲基纤维素钠，其中，凤眼蓝混合液为凤眼蓝乙醇汁液和碳酸氢钠与EDTA的混合液，且乙醇含量小于3％。同时，本发明还提供了该洗衣液的制备方法，具体步骤包括：凤眼蓝乙醇榨汁，加活性白土和碳酸氢钠，加EDTA，减压蒸发乙醇，配制凤眼蓝洗衣液等步骤。本发明凤眼蓝洗衣液的制备方法简单，不仅可以为凤眼蓝的清理做出贡献，并且本发明的凤眼蓝洗衣液也在固色的同时保持了洗衣液的清洁效果。
Description
技术领域
本发明属于洗衣液及其制备方法技术领域，具体涉及一种具有固色功能的凤眼蓝洗衣液及其制备方法和应用。
背景技术
凤眼蓝(学名：Eichhornia crassipes(Mart.)Solms)浮水草本。须根发达，棕黑色。茎极短，匍匐枝淡绿色。叶在基部丛生，莲座状排列；叶片圆形，表面深绿色；叶柄长短不等，内有许多多边形柱状细胞组成的气室，维管束散布其间，黄绿色至绿色；叶柄基部有鞘状黄绿色苞片；花葶多棱；穗状花序通常具9-12朵花；花瓣紫蓝色，花冠略两侧对称，四周淡紫红色，中间蓝色，在蓝色的中央有1黄色圆斑，花被片基部合生成筒；雄蕊贴生于花被筒上；花丝上有腺毛；花药蓝灰色；花粉粒黄色；子房长梨形；花柱长约2厘米；柱头上密生腺毛。蒴果卵形。花期7-10月，果期8-11月。
凤眼蓝又叫水葫芦，原产巴西。现广布于中国长江、黄河流域及华南各省。喜欢温暖湿润、阳光充足的环境，适应性也很强，具有一定的耐寒能力，生于海拔200-1500米的水塘、沟渠及稻田中。亚洲热带地区也已广泛生长。凤眼蓝在生长适宜区，常由于过度繁殖，阻塞水道，影响交通。凤眼蓝曾一度被很多国家引进，广泛分布于世界各地，亦被列入世界百大外来入侵种之一，一度成为水生祸害，不好处理。
洗衣液的工作原理与传统的洗衣粉，肥皂类同，有效成分都是表面活性剂。区别在于：传统的洗衣粉，肥皂采用的是阴离子型表面活性剂，是以烷基磺酸钠和硬脂酸钠为主，碱性较强(洗衣粉PH一般大于12)，进而在使用时对皮肤的刺激和伤害较大。而洗衣液多采用非离子型表面活性剂，PH接近中性，对皮肤温和，并且排入自然界后，降解比洗衣粉快，所以成为了新一代的洗涤剂。
人们一般都喜欢穿色彩鲜艳的衣服,但这些衣服的一大缺点是随着洗涤次数的增加,颜色会越来越暗，看上去非常陈旧；而且在洗涤过程中还很容易沾染其他衣物,尤其是一起洗涤的浅色衣物,给消费者带来极大的不便和烦恼。一些深色衣物之所以褪色或沾染其他衣物的原因主要有以下几个方面:直接染料本身的水洗牢度不够；一些染料在染色过程中的控制条件不合适而造成牢度不够,如一些活性染料；织物在染色过程中漂洗不充分；洗涤条件的影响,如现在很多洗衣机都具有高温煮洗等。导致衣物颜色越来越淡，因此，需要一种新型环保的洗衣液以保证洗涤后的衣物闪亮如新。
发明内容
根据以上现有技术的不足，本发明所要解决的技术问题是提出一种具有固色功能的凤眼蓝洗衣液及其制备方法和应用，目的是使洗衣液具有固色功能。
为了解决上述技术问题，本发明采用的技术方案为：
一种具有固色功能的凤眼蓝洗衣液，所述凤眼蓝洗衣液包括凤眼蓝混合液和添加剂，凤眼蓝混合液以1L计，所述添加剂包括10～30g脂肪醇聚氧乙烯醚硫酸钠、2～30g磺酸和0.5～2g羧甲基纤维素钠，所述凤眼蓝混合液为凤眼蓝乙醇汁液、碳酸氢钠与EDTA的混合液，其中碳酸氢钠为3～20g，EDTA为0.2～5g，且凤眼蓝混合液中乙醇的含量小于3％。
所述凤眼蓝洗衣液还包括0.5～2g香精和1～3g防腐剂。
所述香精为橘味香精、番茄味香精、青檬味香精中的一种或多种，所述防腐剂为苯甲酸钠或山梨酸钾。
所述具有固色功能的凤眼蓝洗衣液的制备方法，所述制备方法包括如下步骤，
A、凤眼蓝混合溶液的制备：将凤眼蓝先与乙醇混合榨汁，之后加入活性白土、碳酸氢钠混合、过滤，再加入EDTA溶解后，经减压蒸发乙醇得到；
B、凤眼蓝洗衣液的配制：在每L凤眼蓝混合液中加入10～30g的脂肪醇聚氧乙烯醚硫酸钠，2～30g磺酸和0.5～2g的羧甲基纤维素钠，混合均匀，得到凤眼蓝洗衣液。
步骤A的制备方法包括：
a、凤眼蓝乙醇榨汁：取洗净后凤眼蓝叶片，按照料液的质量体积比4:1～2:1加入60～75％乙醇溶液，混合榨汁，得到凤眼蓝乙醇汁液Ⅰ；
b、加活性白土和碳酸氢钠：在每L上述凤眼蓝乙醇汁液Ⅰ中加入10～30g活性白土粉末和3～20g碳酸氢钠粉末，混合后过滤，去除固体成分，得到凤眼蓝乙醇汁液Ⅱ；
c、加EDTA：在每L凤眼蓝乙醇汁液Ⅱ中添加0.2～5g的EDTA，溶解后得到凤眼蓝乙醇汁液Ⅲ；
d、减压蒸发乙醇，将凤眼蓝乙醇汁液Ⅲ中的乙醇含量经减压蒸发降低到3％以下，得到凤眼蓝混合液。
步骤d中所述减压蒸发在真空度为50～55kPa，温度30～40℃的条件下进行。
步骤B中还添加有香精和防腐剂。
所述凤眼蓝洗衣液在处理凤眼蓝的应用。
本发明有益效果是:本发明利用纯天然原料凤眼蓝来制备洗衣液。首先，凤眼蓝是一种外来入侵物种，繁殖快速，易浮游扩散，能够迅速掩盖水体，导致水体透光性差；因此在自然水域中，凤眼蓝通过与其他水生(浮水与沉水)植物、藻类竞争矿物质营养、阳光等资源，从而抑制其它水生生物与藻类生物的生长。此外，凤眼蓝的爆发以及其腐烂阶段同时会大量地消耗水体中的溶解氧，水下动物比如鱼类活动繁殖空间将会减少，甚至会鱼类大量死亡。相类似于改变了水体中原来固有得食物链，从而减少此水域中生态系统的稳定性。而本发明正是利用了这种对环境有害的植物，采用乙醇混合榨汁的方法，再添加活性白土和碳酸氢钠等添加剂，以凤眼蓝为主要原料，成本低廉，同时也对人体无危害；其次，本发明的凤眼蓝洗衣液如果长期使用，能有效的保护棉质、PET纤维、麻质的色泽，在经过多次洗涤后，颜色几乎没有变化，保持其原有的颜色，而普通洗衣液洗过后，其色差明显高于本发明的凤眼蓝洗衣液。本发明可保持衣物颜色的同一，申请人分析，可能是凤眼蓝中含有某种阳离子聚合物,可与衣物表面上的色素形成络合物,使衣物上的染料不易溶入洗涤液中,而达到固色作用。它还可与溶液中的色素形成络合物,防止色素沾染至衣物表面,到防止染料转移的作用。
本发明凤眼蓝洗衣液的制备方法简单，原料成本低，易获取，制备过程操作简单，适合工业化生产。如果推广开来，不仅可以为凤眼蓝的清理做出贡献，并且本发明的凤眼蓝洗衣液也保持了洗衣液的高效清洁效果。
具体实施方式
下面通过对实施例的描述，对发明作进一步详细的说明，以帮助本领域技术人员对本发明的发明构思、技术方案有更完整、准确和深入的理解。
实施例1
本实施例提供一种具有固色功能的凤眼蓝洗衣液的制备方法，具体包括如下步骤：
1、凤眼蓝预处理：将凤眼蓝从水中捞出，除去烂叶子，洗涤干净，剪成小块，得到凤眼蓝小块叶片。
2、凤眼蓝乙醇榨汁：准确称取洗净后的凤眼蓝小块叶片，按照料液比3:1(g/ml)添加60％乙醇溶液，混合至于榨汁机中榨汁，得到凤眼蓝乙醇汁液Ⅰ。
3、加活性白土和碳酸氢钠：在每L上述凤眼蓝乙醇汁液Ⅰ中加入30g活性白土粉末和20g碳酸氢钠粉末，完全混合后过滤，去除固体成分，取滤液部分，得到凤眼蓝乙醇汁液Ⅱ。
4、加EDTA：在每L凤眼蓝乙醇汁液Ⅱ中添加5g的EDTA，得到凤眼蓝乙醇汁液Ⅲ。
5、减压蒸发：采用旋转蒸发仪在真空度为55kPa，温度40℃的条件下，旋转蒸发20min，将凤眼蓝乙醇汁液Ⅲ中的乙醇含量降低到3％以下，得到凤眼蓝混合液。
6、凤眼蓝洗衣液的配制：在每L凤眼蓝混合液中加入30g的脂肪醇聚氧乙烯醚硫酸钠，30g磺酸，2g的羧甲基纤维素钠，混合均匀，得到凤眼蓝洗衣液。
为了测试本发明制备的洗衣液的固色能力，发明人做了如下实验：
取市售棉质、PET纤维、麻质的面料各两件，分别用传统洗衣液和本实施例制备的洗衣液机洗10次，每次洗衣液的使用量为10mL,洗衣机调整为标准洗，水量为30L，洗完后置于室温无直射阳光的环境中晾干，得到干净的衣物，并利用CR-400/410色差计测定样品表面10处相同位置的L*，a*，b*和ΔE值作为色差的指标，取平均值，ΔE＝[(L*-Lo*)2+(a*-ao*)2+(b*-b0*)2]1/2
棉质的色差结果如下：
麻质的色差结果如下：
PET纤维的色差结果如下：
由上表可以看出，本实施例的凤眼蓝洗衣液可以显著减少因为洗涤，对棉质、麻质和PET纤维造成的色差，对衣物的颜色具有很好的保护作用。
实施例2
1、凤眼蓝预处理：将凤眼蓝从水中捞出，出去烂叶子，洗涤干净，剪成小块，得到凤眼蓝小块叶片。
2、凤眼蓝乙醇榨汁：准确称取洗净后的凤眼蓝小块叶片，按照料液比4:1(g/ml)添加75％乙醇溶液，混合至于榨汁机中榨汁，得到凤眼蓝乙醇汁液Ⅰ。
3、加活性白土和碳酸氢钠：在每L上述凤眼蓝乙醇汁液Ⅰ中加入10g活性白土粉末和3g碳酸氢钠粉末，完全混合后过滤，去除固体成分，取滤液部分，得到凤眼蓝乙醇汁液Ⅱ。
4、加EDTA：在每L凤眼蓝乙醇汁液Ⅱ中添加0.2g的EDTA，得到凤眼蓝乙醇汁液Ⅲ。
5、减压蒸发：采用旋转蒸发仪在真空度为50kPa，温度30℃的条件下，旋转蒸发10min，将凤眼蓝乙醇汁液Ⅲ中的乙醇含量降低到3％以下，得到凤眼蓝混合液。
6、凤眼蓝洗衣液的配制：在每L凤眼蓝混合液中加入10g的脂肪醇聚氧乙烯醚硫酸钠，2g磺酸，0.5g的羧甲基纤维素钠，0.5g的香精和1g的防腐剂，混合均匀，得到凤眼蓝洗衣液。
其中，本实施例的防腐剂为苯甲酸钠，香精为市售甜橘味香精。
实施例3
1、凤眼蓝预处理：将凤眼蓝从水中捞出，出去烂叶子，洗涤干净，剪成小块，得到凤眼蓝小块叶片。
2、凤眼蓝乙醇榨汁：准确称取洗净后的凤眼蓝小块叶片，按照料液比2:1(g/ml)添加70％乙醇溶液，混合至于榨汁机中榨汁，得到凤眼蓝乙醇汁液Ⅰ。
3、加活性白土和碳酸氢钠：在每L上述凤眼蓝乙醇汁液Ⅰ中加入20g活性白土粉末和10g碳酸氢钠粉末，完全混合后过滤，去除固体成分，取滤液部分，得到凤眼蓝乙醇汁液Ⅱ。
4、加EDTA：在每L凤眼蓝乙醇汁液Ⅱ中添加2g的EDTA，得到凤眼蓝乙醇汁液Ⅲ。
5、减压蒸发：采用旋转蒸发仪在真空度为52kPa，温度35℃的条件下，旋转蒸发15min，将凤眼蓝乙醇汁液Ⅲ中的乙醇含量降低到3％以下，得到凤眼蓝混合液。
6、凤眼蓝洗衣液的配制：在每L凤眼蓝混合液中加入30g的脂肪醇聚氧乙烯醚硫酸钠，10g磺酸，1g的羧甲基纤维素钠，2g的香精和3g的防腐剂混合均匀，得到凤眼蓝洗衣液。
其中，本实施例的防腐剂为山梨酸钾，香精为市售番茄味香精。
上面对本发明进行了示例性描述，显然本发明具体实现并不受上述方式的限制，只要采用了本发明的方法构思和技术方案进行的各种非实质性的改进，或未经改进将本发明的构思和技术方案直接应用于其它场合的，均在本发明的保护范围之内。本发明的保护范围应该以权利要求书所限定的保护范围为准。
Claims (7)
1.一种具有固色功能的凤眼蓝洗衣液，其特征在于，所述凤眼蓝洗衣液包括凤眼蓝混合液和添加剂，凤眼蓝混合液以1L计，所述添加剂包括10～30g脂肪醇聚氧乙烯醚硫酸钠、2～30g磺酸和0.5～2g羧甲基纤维素钠，所述凤眼蓝混合液的制备方法为：a、凤眼蓝乙醇榨汁：取洗净后凤眼蓝叶片，按照料液的质量体积比4:1～2:1g/ml加入60～75％乙醇溶液，混合榨汁，得到凤眼蓝乙醇汁液Ⅰ；b、加活性白土和碳酸氢钠：在每L上述凤眼蓝乙醇汁液Ⅰ中加入10～30g活性白土粉末和3～20g碳酸氢钠粉末，混合后过滤，去除固体成分，得到凤眼蓝乙醇汁液Ⅱ；c、加EDTA：在每L凤眼蓝乙醇汁液Ⅱ中添加0.2～5g的EDTA，溶解后得到凤眼蓝乙醇汁液Ⅲ；d、减压蒸发乙醇，将凤眼蓝乙醇汁液Ⅲ中的乙醇含量经减压蒸发降低到3％以下，得到凤眼蓝混合液。
2.根据权利要求1所述具有固色功能的凤眼蓝洗衣液，其特征在于：所述凤眼蓝洗衣液还包括0.5～2g香精和1～3g防腐剂。
3.根据权利要求2所述具有固色功能的凤眼蓝洗衣液，其特征在于：所述香精为橘味香精、番茄味香精、青檬味香精中的一种或多种，所述防腐剂为苯甲酸钠或山梨酸钾。
4.根据权利要求1所述具有固色功能的凤眼蓝洗衣液的制备方法，其特征在于，所述制备方法包括如下步骤，
A、凤眼蓝混合溶液的制备：
a、凤眼蓝乙醇榨汁：取洗净后凤眼蓝叶片，按照料液的质量体积比4:1～2:1g/ml加入60～75％乙醇溶液，混合榨汁，得到凤眼蓝乙醇汁液Ⅰ；
b、加活性白土和碳酸氢钠：在每L上述凤眼蓝乙醇汁液Ⅰ中加入10～30g活性白土粉末和3～20g碳酸氢钠粉末，混合后过滤，去除固体成分，得到凤眼蓝乙醇汁液Ⅱ；
c、加EDTA：在每L凤眼蓝乙醇汁液Ⅱ中添加0.2～5g的EDTA，溶解后得到凤眼蓝乙醇汁液Ⅲ；
d、减压蒸发乙醇，将凤眼蓝乙醇汁液Ⅲ中的乙醇含量经减压蒸发降低到3％以下，得到凤眼蓝混合液；
B、凤眼蓝洗衣液的配制：在每L凤眼蓝混合液中加入10～30g的脂肪醇聚氧乙烯醚硫酸钠，2～30g磺酸和0.5～2g的羧甲基纤维素钠，混合均匀，得到凤眼蓝洗衣液。
5.根据权利要求4所述具有固色功能的凤眼蓝洗衣液的制备方法，其特征在于，步骤d中所述减压蒸发在真空度为50～55kPa，温度30～40℃的条件下进行。
6.根据权利要求4所述具有固色功能的凤眼蓝洗衣液的制备方法，其特征在于，步骤B中还添加有香精和防腐剂。
7.权利要求1至6任一项所述凤眼蓝洗衣液在处理凤眼蓝的应用。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610821274.6A CN106479691B (zh) | 2016-09-13 | 2016-09-13 | 一种具有固色功能的凤眼蓝洗衣液及其制备方法和应用 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610821274.6A CN106479691B (zh) | 2016-09-13 | 2016-09-13 | 一种具有固色功能的凤眼蓝洗衣液及其制备方法和应用 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106479691A CN106479691A (zh) | 2017-03-08 |
| CN106479691B true CN106479691B (zh) | 2019-03-01 |
Family
ID=58273743
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610821274.6A Expired - Fee Related CN106479691B (zh) | 2016-09-13 | 2016-09-13 | 一种具有固色功能的凤眼蓝洗衣液及其制备方法和应用 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106479691B (zh) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101709152A (zh) * | 2009-12-02 | 2010-05-19 | 中国农业科学院植物保护研究所 | 一种天然植物染料及其制备方法和用途 |
| CA2744352A1 (en) * | 2008-12-04 | 2010-06-10 | Ecolab Inc. | Laundry compositions and method of use |
| CN103215142A (zh) * | 2013-01-06 | 2013-07-24 | 扬州爱丽佳家用化学品有限公司 | 集洗涤柔软二合一的洗衣液 |
| CN104862091A (zh) * | 2015-06-03 | 2015-08-26 | 杜杭华 | 一种牛仔类裤专用清洗剂的制备方法 |
| CN105647706A (zh) * | 2014-12-03 | 2016-06-08 | 沈阳洪达信息科技有限公司 | 一种固色洗衣液 |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007134614A1 (de) * | 2006-05-18 | 2007-11-29 | Henkel Ag & Co. Kgaa | Farbschützendes waschmittel |
-
2016
- 2016-09-13 CN CN201610821274.6A patent/CN106479691B/zh not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2744352A1 (en) * | 2008-12-04 | 2010-06-10 | Ecolab Inc. | Laundry compositions and method of use |
| CN101709152A (zh) * | 2009-12-02 | 2010-05-19 | 中国农业科学院植物保护研究所 | 一种天然植物染料及其制备方法和用途 |
| CN103215142A (zh) * | 2013-01-06 | 2013-07-24 | 扬州爱丽佳家用化学品有限公司 | 集洗涤柔软二合一的洗衣液 |
| CN105647706A (zh) * | 2014-12-03 | 2016-06-08 | 沈阳洪达信息科技有限公司 | 一种固色洗衣液 |
| CN104862091A (zh) * | 2015-06-03 | 2015-08-26 | 杜杭华 | 一种牛仔类裤专用清洗剂的制备方法 |
Non-Patent Citations (2)
| Title |
|---|
| 凤眼莲净化印染废水过程中根系微生态系统的作用;孙天华等;<<环境科学>>;19900630;第11卷(第3期);第25页左栏倒数第4行-右栏第3行、第26页左栏第4-11行 |
| 凤眼莲及其资源化利用研究进展;周文兵等;<<华中农业大学学报>>;20050830;第24卷(第4期);第425页右栏倒数第5行-第426页左栏第14行 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106479691A (zh) | 2017-03-08 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101469517B (zh) | 牡丹花色素在蛋白质纤维织物上的染色方法 | |
| CN102080028B (zh) | 一种鳞毛蕨、无患子天然生物质洗涤剂的制备及其方法 | |
| CN1952020A (zh) | 板栗壳天然染料的制备及其应用 | |
| CN103725032A (zh) | 天然莲蓬壳色素的制备方法及其应用 | |
| CN103741504A (zh) | 一种用于绿茶染料的内衣及其制备方法 | |
| CN104179037A (zh) | 植物染料染色的柞蚕丝睡衣 | |
| CN102911517A (zh) | 一种蚕丝专用茶叶染料的制备方法及用途 | |
| CN105368598A (zh) | 一种茶皂素洗衣粉 | |
| CN102746706A (zh) | 一种红松树皮天然染料的制备方法及用途 | |
| CN106479691B (zh) | 一种具有固色功能的凤眼蓝洗衣液及其制备方法和应用 | |
| CN105400232A (zh) | 一种菊花植物染料的制备方法 | |
| KR100933423B1 (ko) | 제주 갈천 염색견뢰도 개선을 위한 감태염료를 이용한 염색방법 | |
| Kothari et al. | Natural dyes using plant palette: A brief review | |
| KR20130004623A (ko) | 가자열매를 이용한 고기능성 천연염색방법 | |
| CN111155337A (zh) | 一种绿色助染的密蒙花染布方法 | |
| KR100930885B1 (ko) | 보리잎 분말 천연염료의 제조방법 | |
| KR20220005284A (ko) | 천연재료를 이용한 형광 염색 방법 | |
| KR101348479B1 (ko) | 탄산온천수를 함유한 감물의 분말염료 제조방법 | |
| Ekrami et al. | Dyeing of wool using olive fruit waste | |
| CN106377458A (zh) | 一种含茶籽饼提取物的洗发剂组合物及其制备方法 | |
| CN107974845B (zh) | 一种制取玫瑰花萃取原液染布料的方法 | |
| Wisniak | Dyes from antiquity to synthesis | |
| Adeyanju et al. | Extraction of Indigo dye (powdered form) from the leaf of Indigofera tinctoria | |
| CN109481384A (zh) | 一种含植物黑色生态染料和泡腾崩解剂的快速黑发洗发液 | |
| CN104278569A (zh) | 一种指甲花色素对真丝织物的直接染色工艺 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20221208 Address after: 101100 Room 2938, Room 101, Floor 2, Building 55, Yard 5, Yujing East Road, Tongzhou District, Beijing Patentee after: Beijing Suchun Daily Chemical Co.,Ltd. Address before: 241000 No. 8 Beijing Middle Road, Jiujiang District, Wuhu City, Anhui Province Patentee before: ANHUI POLYTECHNIC University |
|
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20190301 |