CN106479688A - Antistatic waterless carwash liquid - Google Patents
Antistatic waterless carwash liquid Download PDFInfo
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- CN106479688A CN106479688A CN201610781868.9A CN201610781868A CN106479688A CN 106479688 A CN106479688 A CN 106479688A CN 201610781868 A CN201610781868 A CN 201610781868A CN 106479688 A CN106479688 A CN 106479688A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
- C11D1/721—End blocked ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
- C11D1/945—Mixtures with anionic, cationic or non-ionic compounds containing a combination of non-ionic compounds differently alcoxylised or with different alkylated chains
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2096—Heterocyclic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3753—Polyvinylalcohol; Ethers or esters thereof
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
- C11D3/3773—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines in liquid compositions
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
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Abstract
The invention belongs to car surface cleaning field, it is related to cleanout fluid, more specifically automobile washing liquid, more particularly, to a kind of antistatic waterless carwash liquid.Mainly it is made up of the raw material of following weight portion：0.1 4.0 parts of paint film protective agent, 0.8 10 parts of surfactant, 0.1 5.0 parts of ion regulating agent, 0.001 0.5 parts of Daphne giraldii Nitsche extract, 10 90 parts of water and 0.001 0.2 parts of essence；Described ion regulating agent is inorganic salt.Car surface resistance can be significantly reduced so as to reach 108 9 Ω, antistatic is rapid, efficient, lasting, has no effect on storage and the serviceability of car washing liquid.
Description
Technical field
The invention belongs to car surface cleaning field, it is related to cleanout fluid, more specifically automobile washing liquid, more particularly, to
A kind of antistatic waterless carwash liquid.
Background technology
With the development of Domestic Automotive Industry, automobile enters common people family.Automobile decoration, motor vehicle repair, Motor Maintenance etc.
Industry is also into the development passage of growth at full speed.There is floating dust environment in northern China city, and east city with the humid air,
In often many rainwater season, vehicle easily falls to expiring dust, and therefore, carwash has become for a requisite work(in You Che family
Class.
In current carwash industry, carwash form mainly includes traditional carwash and new carwash, and traditional carwash is mainly
With water as medium, large area is rinsed, although washing cleaning is more clean, wastes substantial amounts of water resource；New carwash is main
It is waterless carwash, turn round and look at name and conceive, the new carwash that can disregard without water or water consumption, its main innovation point is car washing liquid
Innovation.
At present, Chinese scholars have been probed into water-saving vehicle washing, such as：Invention entitled waterless automobile cleaning agent, patent
Chinese invention patent number for 200710090967, discloses a kind of waterless automobile cleaning agent, it is mainly by No. 200 solvent naphthas
It is emulsified into waterless automobile cleaning agent；A kind of invention entitled water-free dry washing agent for automobile, the China of Patent No. 200710037268
Patent of invention, discloses a kind of water-free dry washing agent for automobile, using two step method, Brazil wax is emulsified into water wax liquor, for cleaning
Automobile；Invention entitled nursing liquid for automobile, the Chinese invention patent of Patent No. 200610122592x, using tween 1～
60%, polyacrylamide 0.01～50%, remaining is water；Need 100 to 1000 times described of mother solution dilute with water during use
As working solution；A kind of invention entitled cup water car-washing powder, the Chinese invention patent of Application No. 201310074954.2, public
Open a kind of glass of water car-washing powder, it is by high-effective penetrating detergent, dirt adsorbent, paint film protective agent and surfactant group
Become, need during use to be dissolved in minor amount of water；Invention entitled waterless carwash liquid, application number：201510367131.8 in
State's patent of invention, disclose a kind of by paint film protective agent, lubrication of adding lustre to regulator part, ionic liquid, surfactant, help surface
Activating agent, the waterless carwash liquid of cut filler, deionized water and essence composition, there is common lacking in above-mentioned waterless carwash liquid
Fall into, during use, easily produce electrostatic, lead to car surface cleaning to be wasted time and energy, and easily adsorb dust, carwash after the completion of cleaning
Effect on driving birds is not good.
Daphne giraldii Nitsche is thymelaeceae (Thymelaeaceae) plant Daphne Giraldii Nitsche (Daphne giraldii Nitsche), recessed leaf
Winter daphne (D.retusa Hemsl), the root bark of the sweet winter daphne in Shan (also known as Tang Gute winter daphne) (D.tangutica Maxim) and peel of stem,
Autumn harvests, and removes radicula, strips root bark and peel of stem then dries and forms.Another name：Dog skin willow, ancestral silk fiber crops etc..The change of Daphne giraldii Nitsche
Learn composition Study and start from nineteen seventies, separate from Daphne giraldii Nitsche first during Wang Ming etc. and obtained Coumarinses chemical combination
Thing, subsequently just gradually carries out to the chemical constitution study of Daphne giraldii Nitsche.Now there are some researches show in Daphne giraldii Nitsche except containing main
Beyond active component coumarin kind compound, also contain the multiple compounds such as flavonoid, lignanoids, Diterpeneses.
Daphne giraldii Nitsche is clinically mainly used in the aspects such as antiinflammatory, analgesia and malaria.Pass through further in recent years
Research finds that Daphne giraldii Nitsche also has significant effect at the aspect such as antitumor and treatment glomerulonephritiies.
But Daphne giraldii Nitsche extract is applied to car washing liquid antistatic, is rarely reported.
Content of the invention
Present invention aims to above-mentioned the deficiencies in the prior art, provide a kind of antistatic waterless carwash liquid, realize
Really anhydrous cleaning automobile dust and spot, using simple and fast, antistatic effect is splendid, ecological, environmental protective.
The technical scheme is that and be achieved in that：
Antistatic waterless carwash liquid, is mainly made up of the raw material of following weight portion：Paint film protective agent 0.1-4.0 part, surface
Activating agent 0.8-10 part, ion regulating agent 0.1-5.0 part, Daphne giraldii Nitsche extract's 0.001-0.5 part, water 0-90 part and essence
0.001-0.2 part；Described for inorganic salt.
Described antistatic waterless carwash liquid, is mainly made up of the raw material of following weight portion：Paint film protective agent 0.5-3.5
Part, surfactant 1.2-8.5 part, ion regulating agent 0.4-4.5 part, Daphne giraldii Nitsche extract's 0.01-0.25 part, water 15-80 part
With essence 0.001-0.2 part.
Described antistatic waterless carwash liquid, is mainly made up of the raw material of following weight portion：2.5 parts of paint film protective agent, table
3.6 parts of face activating agent, 1.2 parts of ion regulating agent, 0.1 part of Daphne giraldii Nitsche extract, 50 parts of water and 0.12 part of essence.
Described paint film protective agent is polyacrylamide, polyvinyl alcohol, plant gum, aluminium polychlorid, polyacrylic acid, polypropylene
One or more of sour sodium, Pregelatinized Starch, polyethylene glycol oxide.
Described plant gum is sesbania gum or guar gum or flax gum or fenugreek gum.
Described surfactant is sodium lauryl sulphate, dodecylbenzene sodium sulfonate, polyoxyethylene groups phenolic group, fatty alcohol
One or more in polyoxyethylene ether, Fatty alcohol polyoxyethylene polyoxypropylene ether, N- alkyl glucose Gemini surface active agent.
Described inorganic salt is anhydrous sodium sulfate, magnesium sulfate, magnesium chloride, a kind of in potassium fluoride.
The structural formula of described Daphne giraldii Nitsche extract is
Operating procedure：A the Daphne giraldii Nitsche being dried is pulverized by (), extracted with 80～90% alcohol heat reflux, united extraction liquid, dense
It is reduced to no alcohol taste, use petroleum ether, ethyl acetate and water saturated n-butanol extraction successively, respectively obtain petroleum ether extract, second
Acetoacetic ester extract and n-butyl alcohol extract；B acetic acid ethyl ester extract macroporous resin remove impurity in () step (a), first with 10%
6 column volumes of ethanol elution, then with 8 column volumes of 80% ethanol elution, collect 80% ethanol elution, concentrating under reduced pressure obtains 80%
Ethanol elution thing extractum；C in () step (b), 80% ethanol elution extractum is separated with purification on normal-phase silica gel, use volume ratio to be 80 successively:1、
50:1、35:1、15:1 and 1:1 methylene chloride-methanol gradient elution obtains 5 components；D in () step (c), component 4 uses positive
Silica gel separates further, uses volume ratio to be 25 successively:1、15:1 and 5:1 methylene chloride-methanol gradient elution obtains 3 groups
Point；E reverse phase silica gel that in () step (d), component 2 octadecylsilane is bonded separates, the first being 75% with concentration expressed in percentage by volume
Alcohol-water solution isocratic elution, collects 8～10 column volume eluents, and eluent is concentrated under reduced pressure to give pure Daphne giraldii Nitsche extract.
Structural identification：Colorless amorphous solid；HR-ESIMS shows [M+Na]+For m/z 351.1618, special in conjunction with nuclear-magnetism
Levying and can obtaining molecular formula is C20H24O4, degree of unsaturation is 9.Hydrogen nuclear magnetic resonance modal data δH(ppm, DMSO-d6, 600MHz)：H-1
(5.62, m), H-2 (5.67, m), H-3 (1.73, m), H-3 (2.01, m), H-5 (2.01, d, J=11.7), H-6 (3.84, d, J
=11.7), H-6 (5.02, m), H-11 (2.09, m), H-11 (2.65, dd, J=16.0,8.8), H-12 (1.86, m), H-12
(1.93, m), H-13 (2.85, m), H-14 (1.91, m), H-14 (3.04, d, J=14.8), H-17 (5.16, br, s), H-17
(5.42, br, s), H-18 (0.89, s), H-19 (0.71, s), H-20 (4.78, d, J=12.2), H-20 (5.03, d, J=
12.2)；Carbon-13 nmr spectra data δC(ppm, DMSO-d6, 150MHz)：130.8 (CH, 1-C), 126.2 (CH, 2-C), 36.7
(CH2, 3-C), 28.8 (C, 4-C), 48.3 (CH, 5-C), 62.2 (CH2, 6-C), 163.8 (C, 7-C), 122.5 (C, 8-C),
161.1 (C, 9-C), 29.6 (C, 10-C), 21.9 (CH2, 11-C), 25.8 (CH2, 12-C), 38.0 (CH, 13-C), 28.7
(CH2, 14-C), 170.2 (C, 15-C), 147.7 (C, 16-C), 120.3 (CH2, 17-C), 32.4 (CH3, 18-C), 21.5
(CH3, 19-C), 66.7 (CH2, 20-C)；Carbon atom labelling is referring to Fig. 1.Infrared spectrum shows that this compound contains hydroxyl and carbonyl
(3484,1708 and 1683cm-1).1H H NMR spectroscopy shows two methyl signals [δ H0.89 (Me-18), 0.71 (Me-19)], one
Outer methylene [the δ H5.42 and 5.16 (H of ring2- 17)], two [δ H5.02 and 3.84 (H containing Oxymethylene2-6)；5.03 and 4.78
(H2- 20)], two olefinic methines [δ H5.62 (H-1), 5.67 (H-2)].13C-NMR spectrum shows 20 carbon signals, including
Two methyl, seven methylene (an olefinic methylene, two contain Oxymethylene), four methine (two olefinic time first
Base), and seven quaternary carbons (two carbonyls, three alkene quaternary carbons).Nuclear magnetic data shows that this compound is containing ten yuan of lactonic rings
Double terpene compound.In HMBC spectrum, H2- 11 with C-8 and C-9, H2- 14 and C-8, and H2- 20 and C-9 dependency shows table
There is double bond between bright C-8 and C-9.H-1 and H-3b, H-3b and H-5 in NOESY spectrum, H-2 and Me-19, and Me-19 and H-
The dependency of 20a shows H-1, H-2, H-3b, H-5, Me-19 and H2- 20 axial orientation.Therefore, this cyclohexene alkane ring (C-1-
C-5 and C-10) it is chair conformation.Additionally, H-11b and H-1 in NOESY spectrum, and the dependency of H-11b and H-5 shows CH2-
11 upsides being located at cyclohexene alkane ring.The presence of ten yuan of lactonic rings limits the orientation of H-13, is α configuration.Comprehensive hydrogen spectrum, carbon
Spectrum, HMBC spectrum and NOESY spectrum, and document is with regard to correlation type nuclear magnetic data, can substantially determine this compound as shown in figure 1,
Spatial configuration tests determination, theoretical value and experiment value basically identical (Fig. 2) by ECD further.
Method and step is as follows：S1：In a kettle. water is warming up to 85-95 DEG C；S2：Under stirring, add paint film and protect
Shield agent, continues stirring 15-55min, rotating speed：50-240r/min, is cooled to 45-65 DEG C；S3：Successively add surfactant, from
Sub- regulator；S4：Continue stirring 5-20min, be cooled to 25-35 DEG C, add remaining component.
A kind of using method according to antistatic waterless carwash liquid described in claim 1, comprises step used below：(1) hair
Car washing liquid 100-500ml is drawn in towel leaching；(2) gently wipe car surface.
Compared with prior art, the Advantageous Effects that the present invention has：
Daphne giraldii Nitsche extract of the present invention is used as antistatic additive, can significantly reduce car surface resistance so as to reach 108-9Ω,
Antistatic is rapid, efficient, lasting, has no effect on storage and the serviceability of car washing liquid, can eliminate the quiet of car surface easily
Electricity, more conventional highly effective antistatic agent such as ionic liquid etc., tool low amounts is efficient, do not affect the advantage that properties of product etc. project.
And Daphne giraldii Nitsche extract is biodegradable, environmental protection, and expanded the application of Daphne giraldii Nitsche extract.
Brief description
Fig. 1 is compound (I) structural formula；
Fig. 2 is that compound (I) theory ECD value is compared with experiment ECD value.
Specific embodiment
Raw material explanation：
Chemical reagent does not do specified otherwise, is purchased from Chemical Reagent Co., Ltd., Sinopharm Group, without any process, directly
Use；Essence brand is fragrance benefit, purchased from Fa Fulaier essence company limited of Jinjiang City；Water is conventional tap water.
With reference to specific embodiment, the present invention is described in further detail, but does not constitute any to the present invention
Limit.
The preparation of Daphne giraldii Nitsche extract：A the Daphne giraldii Nitsche (8kg) being dried is pulverized by (), extracted with 85% alcohol heat reflux
(25L × 3 time), united extraction liquid, it is concentrated into no alcohol taste (3L), use petroleum ether (3L × 3 time), ethyl acetate (3L × 3 successively
Secondary) and water saturated n-butyl alcohol (3L × 3 time) extraction, respectively obtain petroleum ether extract, acetic acid ethyl ester extract (359g) and
N-butyl alcohol extract；B acetic acid ethyl ester extract AB-8 type macroporous resin remove impurity in () step (a), first with 10% ethanol elution 6
Individual column volume, then with 8 column volumes of 80% ethanol elution, collect 80% ethanol elution, concentrating under reduced pressure obtains 80% ethanol elution
Thing extractum (138g)；C in () step (b), 80% ethanol elution extractum is separated with purification on normal-phase silica gel, use volume ratio to be 80 successively:1(8
Individual column volume), 50:1 (8 column volumes), 35:1 (6 column volumes), 15:1 (8 column volumes) and 1:The two of 1 (5 column volumes)
Chloromethanes-methanol elution gradient obtains 5 components；D in () step (c), component 4 (32g) is separated further with purification on normal-phase silica gel, according to
Secondary use volume ratio is 25:1 (8 column volumes), 15:1 (10 column volumes) and 5:The methylene chloride-methanol ladder of 1 (6 column volumes)
Degree affords 3 components；E reverse phase silica gel that in () step (d), component 2 (17g) octadecylsilane is bonded separates, and uses body
Long-pending percentage concentration is 75% methanol aqueous solution isocratic elution, collects 8-10 column volume eluent, and eluent concentrating under reduced pressure obtains
To pure Daphne giraldii Nitsche extract (29mg).
Embodiment 1
Antistatic waterless carwash liquid, is mainly made up of the raw material of following weight portion：0.1 part of paint film protective agent, surface activity
0.8 part of agent, 0.1 part of ion regulating agent, Daphne giraldii Nitsche extract's 0.001- part, 10 parts of water and 0.001 part of essence；Described ion-select electrode
Agent is inorganic salt.
Described paint film protective agent is polyacrylamide.
Described surfactant be sodium lauryl sulphate,.
Described inorganic salt is anhydrous sodium sulfate.
Method and step is as follows：S1：In a kettle. water is warming up to 85 DEG C；S2：Under stirring, add paint film protection
Agent, continues stirring 15min, rotating speed：50r/min, is cooled to 45 DEG C；S3：Add surfactant, ion regulating agent successively；S4：
Continue stirring 5min, be cooled to 25 DEG C, add remaining component.
A kind of using method according to antistatic waterless carwash liquid described in claim 1, comprises step used below：(1) hair
Car washing liquid 100ml is drawn in towel leaching；(2) gently wipe car surface.
Embodiment 2
Antistatic waterless carwash liquid, is mainly made up of the raw material of following weight portion：4.0 parts of paint film protective agent, surface activity
10 parts of agent, 5.0 parts of ion regulating agent, 0.5 part of Daphne giraldii Nitsche extract, 90 parts of water and 0.2 part of essence；Described for inorganic salt.
Described paint film protective agent is 0.2 part of polyacrylamide, 0.15 part of polyvinyl alcohol, 0.4 part of plant gum, aluminium polychlorid
0.3 part, 0.01 part of polyacrylic acid, 2.56 parts of sodium polyacrylate, 0.2 part of Pregelatinized Starch, 0.18 part of polyethylene glycol oxide.
Described plant gum is sesbania gum.
Described surfactant is 1.2 parts of sodium lauryl sulphate, 1.2 parts of dodecylbenzene sodium sulfonate, polyoxyethylene groups
1.2 parts of phenolic group, 1.2 parts of fatty alcohol-polyoxyethylene ether, 1.2 parts of Fatty alcohol polyoxyethylene polyoxypropylene ether, N- alkyl glucose are double
4.0 parts of sub- surfactant.
Described inorganic salt is fluoride-free potassium.
Method and step is as follows：S1：In a kettle. water is warming up to 95 DEG C；S2：Under stirring, add paint film protection
Agent, continues stirring 55min, rotating speed：240r/min, is cooled to 65 DEG C；S3：Add surfactant, ion regulating agent successively；
S4：Continue stirring 20min, be cooled to 35 DEG C, add remaining component.
A kind of using method according to antistatic waterless carwash liquid described in claim 1, comprises step used below：(1) hair
Car washing liquid 500ml is drawn in towel leaching；(2) gently wipe car surface.
Embodiment 3
Antistatic waterless carwash liquid, is mainly made up of the raw material of following weight portion：0.5 part of paint film protective agent, surface activity
1.2 parts of agent, 0.4 part of ion regulating agent, 0.01 part of Daphne giraldii Nitsche extract, 15 parts of water and 0.001 part of essence.
Described paint film protective agent is polyvinyl alcohol.
Described surfactant is dodecylbenzene sodium sulfonate.
Described inorganic salt is magnesium chloride.
Method and step is as follows：S1：In a kettle. water is warming up to 86 DEG C；S2：Under stirring, add paint film protection
Agent, continues stirring 20min, rotating speed：80r/min, is cooled to 50 DEG C；S3：Add surfactant, ion regulating agent successively；S4：
Continue stirring 10min, be cooled to 26 DEG C, add remaining component.
A kind of using method according to antistatic waterless carwash liquid described in claim 1, comprises step used below：(1) hair
Car washing liquid 150ml is drawn in towel leaching；(2) gently wipe car surface.
Embodiment 4
Antistatic waterless carwash liquid, is mainly made up of the raw material of following weight portion：Paint film protective agent .5 part, surfactant
8.5 parts, 4.5 parts of ion regulating agent, 0.25 part of Daphne giraldii Nitsche extract, 80 parts and 0.2 part of essence.
Described paint film protective agent is poly- plant gum.
Described plant gum is guar gum.
Described surfactant is polyoxyethylene groups phenolic group.
Described inorganic salt is no magnesium chloride.
Method and step is as follows：S1：In a kettle. water is warming up to 90 DEG C；S2：Under stirring, add paint film protection
Agent, continues stirring 25min, rotating speed：110r/min, is cooled to 52 DEG C；S3：Add surfactant, ion regulating agent successively；
S4：Continue stirring 10min, be cooled to 31 DEG C, add remaining component.
A kind of using method according to antistatic waterless carwash liquid described in claim 1, comprises step used below：(1) hair
Car washing liquid 180ml is drawn in towel leaching；(2) gently wipe car surface.
Embodiment 5
Antistatic waterless carwash liquid, is mainly made up of the raw material of following weight portion：2.5 parts of paint film protective agent, surface activity
3.6 parts of agent, 1.2 parts of ion regulating agent, 0.1 part of Daphne giraldii Nitsche extract, 50 parts of water and 0.12 part of essence.
Described paint film protective agent is polyethylene glycol oxide.
Described surfactant is N- alkyl glucose Gemini surface active agent.
Described inorganic salt is potassium fluoride.
Method and step is as follows：S1：In a kettle. water is warming up to 85-95 DEG C；S2：Under stirring, add paint film and protect
Shield agent, continues stirring 35min, rotating speed：200r/min, is cooled to 60 DEG C；S3：Add surfactant, ion regulating agent successively；
S4：Continue stirring 18min, be cooled to 32 DEG C, add remaining component.
A kind of using method according to antistatic waterless carwash liquid described in claim 1, comprises step used below：(1) hair
Car washing liquid 350ml is drawn in towel leaching；(2) gently wipe car surface.
The method of testing of the car surface resistivity after the cleaning of embodiment 1-5 is carried out according to GB/T 1410-2006.
The each embodiment antistatic effect of table 1 contrasts
| Surface resistivity (Ω/cm2) | |
| Embodiment 1 | 2.0×109 |
| Embodiment 2 | 3.2×108 |
| Embodiment 3 | 2.4×109 |
| Embodiment 4 | 1.8×108 |
| Embodiment 5 | 2.1×108 |
| Commercially available car washing liquid 1# | 18.2×106 |
| Commercially available car washing liquid 2# | 22.6×106 |
Automobile washing liquid of the present invention and the performance synopsis of water and foam cleaning agent：
Table 2 automobile washing liquid of the present invention and the performance synopsis of water and foam cleaning agent
| Sequence number | Test event | Technical requirements | The present invention | Water | Foam |
| 1 | Outward appearance | Transparency liquid | Transparency liquid | Transparent | Milky white liquid |
| 2 | PH value | 7.5-9.5 | 8.0 | 6.3 | 12 |
| 3 | Lubricity | There is lubrication sense after spray | Object has lubrication sense after touching | Unlubricated sense | Unlubricated sense |
| 4 | Bactericidal property | There is bactericidal property | Have | No | No |
Note：Performance indications are taking embodiment 5 as a example.
Table 3 automobile washing glass surface cleaning force of the present invention, rate of drying and dry rear stain mark experimental result contrast
| Test sample | Cleaning force/% | Rate of drying v/ (kg m-2·s-1×103) | Stain mark after dry |
| Embodiment 1 | 97 | 9.12 | No obvious stain mark |
| Embodiment 2 | 98 | 9.67 | No obvious stain mark |
| Embodiment 3 | 92 | 9.45 | More apparent stain mark |
| Embodiment 4 | 99 | 9.86 | No obvious stain mark |
| Embodiment 5 | 99 | 9.73 | No obvious stain mark |
| Commercially available 1# waterless carwash liquid | 58 | 5.34 | Substantially stain mark |
| Commercially available 2# waterless carwash liquid | 69 | 4.78 | More apparent stain mark |
Note：Method of testing is tested testing according to the experimental technique of GB/T23436 2009 standard.
Table 3 embodiment 5 is to metal erosion experimental result
Note：Method of testing is tested testing according to the experimental technique of GB/T23436 2009 standard.
The result that table 4 embodiment 5 affects on rubber
Note：Method of testing is tested testing according to the experimental technique of GB/T23436 2009 standard.
The result that table 5 embodiment 5 affects on organic coating film
Claims (10)
1. antistatic waterless carwash liquid it is characterised in that：Mainly it is made up of the raw material of following weight portion：Paint film protective agent 0.1-
4.0 parts, surfactant 0.8-10 part, ion regulating agent 0.1-5.0 part, Daphne giraldii Nitsche extract's 0.001-0.5 part, water 10-90
Part and essence 0.001-0.2 part；Described ion regulating agent is inorganic salt.
2. antistatic waterless carwash liquid according to claim 1 it is characterised in that：The main raw material group by following weight portion
Become：Paint film protective agent 0.5-3.5 part, surfactant 1.2-8.5 part, ion regulating agent 0.4-4.5 part, Daphne giraldii Nitsche extract
0.01-0.25 part, water 15-80 part and essence 0.001-0.2 part.
3. antistatic waterless carwash liquid according to claim 1 it is characterised in that：The main raw material group by following weight portion
Become：2.5 parts of paint film protective agent, 3.6 parts of surfactant, 1.2 parts of ion regulating agent, 0.1 part of Daphne giraldii Nitsche extract, 50 parts of water and
0.12 part of essence.
4. antistatic waterless carwash liquid according to claim 1 it is characterised in that：Described paint film protective agent is polyacrylamide
In amine, polyvinyl alcohol, plant gum, aluminium polychlorid, polyacrylic acid, sodium polyacrylate, Pregelatinized Starch, polyethylene glycol oxide one
Plant or multiple.
5. antistatic waterless carwash liquid according to claim 4 it is characterised in that：Described plant gum is sesbania gum or Guar
Glue or flax gum or fenugreek gum.
6. antistatic waterless carwash liquid according to claim 1 it is characterised in that：Described surfactant is dodecyl
Sodium sulfate, dodecylbenzene sodium sulfonate, polyoxyethylene groups phenolic group, fatty alcohol-polyoxyethylene ether, aliphatic alcohol polyethenoxy polyoxy third
One or more in alkene ether, N- alkyl glucose Gemini surface active agent.
7. antistatic waterless carwash liquid according to claim 1 it is characterised in that：Described inorganic salt be anhydrous sodium sulfate,
A kind of in magnesium sulfate, magnesium chloride, potassium fluoride.
8. antistatic waterless carwash liquid according to claim 1 it is characterised in that：The preparation side of described Daphne giraldii Nitsche extract
Method step is as follows：A the Daphne giraldii Nitsche being dried is pulverized by (), extracted with 80-90% alcohol heat reflux, united extraction liquid, is concentrated into no
Alcohol taste, uses petroleum ether, ethyl acetate and water saturated n-butanol extraction successively, respectively obtains petroleum ether extract, ethyl acetate
Extract and n-butyl alcohol extract；B acetic acid ethyl ester extract macroporous resin remove impurity in () step (a), is first washed with 10% ethanol
De- 6 column volumes, then with 8 column volumes of 80% ethanol elution, collect 80% ethanol elution, concentrating under reduced pressure obtains 80% ethanol and washes
De- thing extractum；C in () step (b), 80% ethanol elution extractum is separated with purification on normal-phase silica gel, use volume ratio to be 80 successively:1、50:1、
35:1、15:1 and 1:1 methylene chloride-methanol gradient elution obtains 5 components；D in () step (c), component 4 uses purification on normal-phase silica gel
Separate further, use volume ratio to be 25 successively:1、15:1 and 5:1 methylene chloride-methanol gradient elution obtains 3 components；(e)
The reverse phase silica gel that in step (d), component 2 octadecylsilane is bonded separates, and the methanol being 75% with concentration expressed in percentage by volume is water-soluble
Liquid isocratic elution, collects 8-10 column volume eluent, and eluent is concentrated under reduced pressure to give pure Daphne giraldii Nitsche extract.
9. a kind of preparation method according to antistatic waterless carwash liquid described in claim 1 it is characterised in that：Method and step is as follows：
S1：In a kettle. water is warming up to 85-95 DEG C；S2：Under stirring, add paint film protective agent, continue stirring 15-55min,
Rotating speed：50-240r/min, is cooled to 45-65 DEG C；S3：Add surfactant, ion regulating agent successively；S4：Continue stirring 5-
20min, is cooled to 25-35 DEG C, adds remaining component.
10. a kind of using method according to antistatic waterless carwash liquid described in claim 1 it is characterised in that：As follows using step：
(1) car washing liquid 100-500ml is drawn in towel leaching；(2) gently wipe car surface.
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| CN201610781868.9A CN106479688A (en) | 2016-08-30 | 2016-08-30 | Antistatic waterless carwash liquid |
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| Application Number | Priority Date | Filing Date | Title |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111961547A (en) * | 2020-08-07 | 2020-11-20 | 开源智德科技(深圳)有限公司 | Efficient environment-friendly waterless car washing cleaning solution and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104974859A (en) * | 2015-06-29 | 2015-10-14 | 陈士县 | Anhydrous car washing liquid |
| CN105481802A (en) * | 2015-12-29 | 2016-04-13 | 吴金凤 | Clerodane diterpenoid compounds, and preparation method and medical application thereof |
-
2016
- 2016-08-30 CN CN201610781868.9A patent/CN106479688A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104974859A (en) * | 2015-06-29 | 2015-10-14 | 陈士县 | Anhydrous car washing liquid |
| CN105481802A (en) * | 2015-12-29 | 2016-04-13 | 吴金凤 | Clerodane diterpenoid compounds, and preparation method and medical application thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111961547A (en) * | 2020-08-07 | 2020-11-20 | 开源智德科技(深圳)有限公司 | Efficient environment-friendly waterless car washing cleaning solution and preparation method thereof |
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