CN106479044A - A kind of stretch-proof Polywoven Bag and preparation method thereof - Google Patents
A kind of stretch-proof Polywoven Bag and preparation method thereof Download PDFInfo
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/42—Formation of filaments, threads, or the like by cutting films into narrow ribbons or filaments or by fibrillation of films or filaments
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/06—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyolefin as constituent
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04C—BRAIDING OR MANUFACTURE OF LACE, INCLUDING BOBBIN-NET OR CARBONISED LACE; BRAIDING MACHINES; BRAID; LACE
- D04C1/00—Braid or lace, e.g. pillow-lace; Processes for the manufacture thereof
- D04C1/02—Braid or lace, e.g. pillow-lace; Processes for the manufacture thereof made from particular materials
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04C—BRAIDING OR MANUFACTURE OF LACE, INCLUDING BOBBIN-NET OR CARBONISED LACE; BRAIDING MACHINES; BRAID; LACE
- D04C1/00—Braid or lace, e.g. pillow-lace; Processes for the manufacture thereof
- D04C1/06—Braid or lace serving particular purposes
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- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C08L2205/00—Polymer mixtures characterised by other features
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
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Abstract
The invention discloses a kind of stretch-proof Polywoven Bag, with polypropylene as base-material, optimize masterbatch raw material type and formula, production technology is improved, science is compounded and is remarkably improved Polywoven Bag tensile resistance, the modified carbon nano-tube of relative tensile load, intensity, toughness and elastic modelling quantity；It is remarkably improved the calcium fruit fiber of Polywoven Bag shock resistance and easily biological-degradable, reduction production cost；Polyethylene/winter rye the peptide complexes of Polywoven Bag resistance to low temperature are greatly improved, the almond oil of Polywoven Bag lubricity and non-oxidizability can be effectively improved, obtained stretch-proof Polywoven Bag has superior physical property：Stretch-proof load is strong, and its multi tension load is 520 930 (N/50mm), peeling force 6.5 (N/30mm)；With powerful shock resistance：2 meters of height fall, and any direction is nothing bale broken；There is stronger anti-ultraviolet property：After ultraviolet irradiation alternating test 144h, multi tension load conservation rate is 78 85%.
Description
Technical field
The present invention relates to Polywoven Bag, and in particular to a kind of stretch-proof Polywoven Bag and preparation method thereof.
Background technology
Polywoven Bag is with polypropylene (PP), polyethylene (PE) resin as primary raw material, adds a small amount of auxiliary material, after mixing
The melting of extruded machine, extruded plastic foil cut into silk, are stretched under less than resin melt temperature, by molecular orientation with
The flat filament of high intensity, low elongation is made in thermal finalization, then rolled, weave cotton cloth, Polywoven Bag is made in cutting, suture.Plastics are compiled
Knit bag and be divided into TA type, A type, Type B and c-type by loading mass scope, TA type is for allowing 10～20kg of loading mass, A type for allowing
21～30kg of loading mass, Type B are for allowing 31～50kg of loading mass, c-type for allowing 51～60kg of loading mass.Plastic knitting
Bag has that smooth, tension intensity is high, packing is convenient, corrosion-resistant, does not absorb water, does not go mouldy, is easy to handling, pile, carrying and storage
The advantages of, it is adaptable to the packaging of the granular such as industrial chemicals, chemical fertilizer, cement, food, building material and flexible product, is current
Most widely used packaging product on market.
In woven bag production process, the relative pull-off force of flat filament is to control one of key link of woven bag intensity,
It is the most quality index of the Polywoven Bag market quality sampling procedure defective item frequency, manufacturer is in order to reduce into
This, adds reclaimed materials, cheap filling master batch etc. wantonly, causes Polywoven Bag tensile load (with respect to pull-off force) to reduce, with
Industry competition continuous fierce and white-hot, the tensile load for improving Polywoven Bag has become the main side of competition among enterprises
Formula.How to control the relative pull-off force of flat filament, be mainly reflected in the stretching three of the proportioning of raw material, the cooling forming of diaphragm and flat filament
Individual aspect.
The research direction for improving polypropylene plastics woven bag tensile load at present is concentrated mainly on optimizing raw material formula, and
Improvement filling master batch species and performance are the modes main of optimizing raw material proportioning, and the effect of filling master batch is to improve flat filament
Physical property and reduces cost, with the increase of filling master batch loading, the tensile strength of flat filament will be gradually lowered, be because
The Main Ingredients and Appearance of filling master batch is calcium carbonate, without pulling force, after a small amount of filling master batch is added, is dispersed in polyolefin macromolecular chain
Gap in, on the impact of flat filament tensile strength less, now flat filament intensity is improved.
Than later, about in the middle period sixties 20th century, asbestos fibre is filling-modified for the development of Filling and modifying of polypropylene technology
Polypropylene starts in European market appearance.Phase late 1960s calcium carbonate, mica, wood chip especially glass fibre and talcum
The packing materials such as powder start to commonly use.China also begin to study in 20 century 70s polyacrylic filling-modified, and rear
To have carried out substantial amounts of research to polyacrylic filling technique.Packing material species is various, is divided into spherical, cube by shape
Shape, rectangle, slice-shaped and fiber shape；According to chemical composition be divided into inorganic filler and organic filler, inorganic filler include glass, carbon,
Calcium carbonate, metal oxide, metal dust, silica, silicate, other inorganic matters, organic filler include cellulose and modeling
Material etc..
With the development of new technology, polypropylene packing material nanometer also from initial mica and talcum powder expansion till now
(cenosphere, calcium carbonate are brilliant for technical field (nano-calcium carbonate, nano imvite etc.), composite and new material technology field
Palpus, silica-alumina carbon black, magnetic iron oxide etc.) and process for modifying surface field (surfactant, coupling agent, grafting, plasma discharge
Deng), but improve in any case, the performance in a certain respect of polypropylene base-material can only be improved, how by adjusting filling master batch kind
Class and formula, while it is still a difficult problem to improve the stretch-proof of polypropylene plastics woven bag base-material and shock resistance.
CNT has high intensity, toughness and elastic modelling quantity in terms of mechanics.Its elasticity is up to 1TPa, about steel
5 times, almost identical with the elastic modelling quantity of diamond, its elastic strain is about 5%, reaches as high as 12%.CNT no matter
It is intensity or toughness is far superior to all any fibrous material.Using CNT as composite material reinforcement body, can show good
Intensity well, elasticity, fatigue resistance.CNT not only has excellent mechanical property, also has excellent electricity, optical
Energy.Many experiments show, compared with other reinforcements (such as carbon black, carbon fiber or metal charge etc.), CNT is to polymerization
The improvement of thing based composites electric conductivity is more notable, and as CNT has nano-grade size, addition is few, its
Polymer composites can also strengthen its mechanical performance and other performance while good electric conductivity is obtained, while also
Be conducive to the design of macromolecular material other performance, therefore suffer from extensive concern.The active group of carbon nano tube surface is considerably less,
Very weak with the interaction of macromolecular material group, and the draw ratio of CNT and specific surface area are greatly, for preparing height
It is difficult to be uniformly dispersed during molecular composite material in the polymer, agglomeration easily occurs, it is impossible to embodies its excellent properties.Cause
This surface modification to CNT seems particularly important.
To sum up, existing filling master batch feature is single, can not be suitable for mostly polypropylene plastics woven bag shock resistance simultaneously
And the performance requirement of stretch-proof；And the inserts for being used mostly is the inorganic salt filler such as silicate and calcium carbonate and is difficult biological drop
Solve, easily alkalization of soils made, severe environmental pollution can be caused.
Therefore, with polypropylene as base-material, masterbatch raw material type and formula are optimized, science compounds modified CNT,
Inorganic carbonate and silicate are replaced with organic degradable filler, production technology is improved, prepares a kind of stretch-proof environment-friendly type plastic
Woven bag is necessary.
Content of the invention
Technical problem solved by the invention is the defect for overcoming existing stretch-proof woven bag and preparation method thereof, with poly- third
Alkene is base-material, optimizes masterbatch raw material type and formula, improves production technology, and science is compounding to be remarkably improved Polywoven Bag relatively
The modified carbon nano-tube of tensile load, impact strength, toughness and elastic modelling quantity；It is remarkably improved Polywoven Bag impact resistance
Energy and the calcium fruit fiber of easily biological-degradable, reduction production cost；Be greatly improved the polyethylene of Polywoven Bag resistance to low temperature/
Winter rye peptide complexes, can effectively improve the almond oil of Polywoven Bag lubricity and non-oxidizability；With other processing aids
Synergy, is finally obtained a kind of good Environment-friendlytensile tensile of physical property and stretches Polywoven Bag；
In order to achieve the above object, the present invention is employed the following technical solutions：
A kind of stretch-proof Polywoven Bag, is mainly prepared by the raw material of following parts by weight：
100 parts of polypropylene, calcium fruit fiber 16-20 part, LLDPE 10-12 part, modified carbon nano-tube 6-10
Part, polyoxymethylenes 5-7 part, polyethylene/winter rye peptide complexes 3-5 part, ethylene-methyl acrylate copolymer 1.5-2.5 part,
Antiaging agent 1.2-3 part, ATBC 0.8-1.2 part, coupling agent 0.8-1.2 part, Tissuemat E 0.6-1.0 part, it is combined
Antioxidant 0.3-0.5 part, almond oil 0.3-0.5 part；
Further, the calcium fruit fiber is the natural plants calcium stem end higher with calcic, iron, leaf of GAIGUO and waste wood
Consider to be worth doing as raw material, through being cleaned by ultrasonic, ultrasound and high-pressure pulse electric extract, biobleaching and appropriate enzymolysis, microwave drying, extruding
Expanded, ultramicro grinding and be obtained；
Preferably, the preparation method of the calcium fruit fiber, comprises the steps：By fresh calcium stem end, leaf of GAIGUO and waste wood
Bits 3-7 in mass ratio:2-6:1-2 uniformly mixes, and is placed in supersonic wave cleaning machine and cleans 3-5min in 200W, 30KHz, drains,
Broken, the water of addition fragment quality 0.5-1.5 times, room temperature 200-400W, 35-40KHz condition ultrasonic extraction 10-15min, so
Afterwards in electric-field intensity 20-40kV/cm, burst length 400-600 μ s, high-voltage pulse is carried out under the conditions of pulse frequency 200-400Hz
Electric field treatment 10-15min；Regulation pH value is 6-10, adds the biology enzyme of mixture quality 0.1-0.3%, digests in 50-60 DEG C
10-15min；Enzymolysis liquid is evaporated to solid content for 40-60%, is put into microwave dryer in 2000W, 130-150 DEG C
Intermittent drying is carried out, is allowed to moisture and 8-10% is reached, particle diameter 0.4-0.6mm is then crushed to, add crushed material quality 0.2-
0.4% sodium acid carbonate, uniform mixing, adjustment mixture moisture are 15-18%, room temperature, sealing and standing 1.5-2.5h, in
Screw speed 105-115r/min, temperature 140-160 DEG C condition extrusion, then ultramicro grinding is to 10-15 μm of particle diameter, finally
4-6h is dry in 100-115 DEG C and obtain final product calcium fruit fiber；
The biology enzyme be alkalescent xylanase, laccase, dextranase, seminase, pectase, tannase in mass ratio
2-4:1-3:1-3:0.5-1.5:0.4-1:0.2-0.8 uniformly mixes.
Further, the modified carbon nano-tube be by single wall or multi-walled carbon nano-tubes through with ammonium persulfate in aqueous phase system
After processing through ultrasonic disperse and high-pressure pulse electric, gentle reaction purification, modification are obtained；
Preferably, the preparation method of the modified carbon nano-tube, comprises the steps：By SWCN, persulfuric acid
Ammonium and deionized water in mass ratio 1:70-80:1000 uniform mixing, first in power 200-400W, frequency 20-24KHz ultrasound
20-40min is processed, then in electric-field intensity 2-6kV/cm, burst length 100-300 μ s, under the conditions of pulse frequency 200-400Hz
Carry out high-pressure pulse electric and process 10-15min；Mixture after treatment is anti-in rotating speed 100-120r/min, temperature 50-70 DEG C
Answer 0.5-2.5h, reactant liquor is filtered with the PP micropore filtering film in 0.22 μm of aperture, and deionized water cyclic washing in
Property, most constant weight is dried under vacuum to after 70-80 DEG C, crushes, obtain final product modified carbon nano-tube.
Further, the polyethylene/winter rye peptide complexes are gathered with the synthetic resin with good resistance to low temperature
Ethene and the blending of the winter rye antifreeze peptide with excellent anti-freezing property, co-melting, extruding pelletization are formed；
Preferably, the preparation method of the polyethylene/winter rye peptide complexes, comprises the steps：
1) preparation of winter rye peptide：By the seed sabot of winter rye, 6- is processed in electric-field intensity 4-6kV/cm high-pressure electrostatic
8min；Then soaking at room temperature 1-3h in salicylic acid solution of the concentration for 12-18mg/L, while in electric-field intensity 6-10kV/cm,
Burst length 100-200 μ s, carries out high-pressure pulse electric process under the conditions of pulse frequency 200-400Hz；Rinse, drain, in 3-5
DEG C standing 18-24h, then successively 1-3 DEG C refrigeration 2-4d, -3--5 DEG C freezing 1-3d, -15--18 DEG C freezing 10-15h, immediately
Outdoor natural light photograph is placed on, so that seed half is crushed after thawing immediately, crushed material particle diameter 0.5-1.5mm, it is subsequently added into crushing
The water of amount of substance 2-4 times, is 3.5-5.5 with newborn acid for adjusting pH value；It is eventually adding the mixing of mixed liquor quality 1.3-1.7%
Enzyme, digests 10-30min in 35-50 DEG C first, then digests 20-40min in 50-60 DEG C；Enzymolysis liquid is filtered, filtrate decompression is dense
Contracting, freeze-drying obtain final product winter rye peptide；
The mixed enzyme is protease, cellulase, amylase, pectase 5-7 in mass ratio:4-6:1-3:0.5-1.5
Uniform mixing.
2) winter rye peptide is sufficiently mixed in proportion with polyethylene, maleic anhydride, styrene, initiator and antioxidant, weight
Measuring ratio is：Polyethylene: winter rye peptide: maleic anhydride: styrene: initiator: antioxidant=100: 2-10: 3-20: 1-15: 0.1-
5∶0.1-1；
3) by step 2) compound that obtains adds double screw extruder frit reaction, and extruding pelletization, control twin-screw are squeezed
Go out machine and die temperature at 145-180 DEG C, screw speed is 30-200r/min, stop of the reactant in double screw extruder
Time control obtains final product polyethylene/winter rye peptide complexes in the 10-100 second.
Further, the almond oil is with semen armeniacae amarae as raw material, soaking detoxification, microwave irradiation go out enzyme, freezing crushing,
The low temperature extraction processes such as biological enzymolysis, biological demulsifying agent breakdown of emulsion, traditional vacuum are obtained；
Preferably, the preparation method of the almond oil, comprises the steps：Semen armeniacae amarae is immersed mass percent concentration
Rinse, drain for room temperature in the sodium bicarbonate solution of 0.01-0.03%, sealing and standing wetting 1-3h in container is put, is then peeled,
Decortication semen armeniacae amarae is put in microwave dryer in frequency 2450MHz, power 1000-3000W, temperature 80-90 DEG C, thickness of feed layer
3-5cm condition microwave irradiation goes out enzyme 2-4min；Mass percent concentration is then placed in for room in the citric acid solution of 0.1-0.3%
Temperature soaks 2-4h, and clear water is rinsed 1-3 time, is drained, and freezes 3-5h in -20--25 DEG C, thickness of feed layer 8-10cm, is crushed to particle diameter
0.4-0.6mm obtains semen armeniacae amarae powder；The pH value of its quality 3-5 times is added in semen armeniacae amarae powder for the deionized water of 4.5-6.5, uniformly
Mixing, control mixed material temperature is 45-55 DEG C, is added thereto to the compound enzyme of semen armeniacae amarae silty amount 0.03-0.05%, stirring
Uniformly, it is incubated, digests 40-60min；Enzymolysis liquid is put vacuum -0.01--0.03MPa, temperature 10-20 in vacuum centrifuge
DEG C, rotating speed 10000r/min, traditional vacuum 5-8min, isolated free oil, emulsion, hydrolyzate and semen armeniacae amarae from top to bottom
Slag, the emulsion for obtaining control temperature is 30-50 DEG C, adds the biological demulsifying agent breakdown of emulsion of emulsion quality 0.02-0.04%
40-60min, breakdown of emulsion is after vacuum -0.01--0.03MPa, temperature 10-20 DEG C, 5000r/min traditional vacuum 10- again
15min obtains free oil, and the free oil for merging gained obtains final product almond oil；
The quality of the compound enzyme is consisted of：Acid protease:Cellulase:Pectase:Amylase=6-9:2-4:1-
3:1-3；
The quality of the biological demulsifying agent is consisted of：Glycolipid class:Lipopeptid class:Cell wall combines class=4-6:2-4:1-3；
The quality of the glycolipid class biological demulsifying agent is consisted of：Rhamnolipid:APG=2-5:1-3；
Preferably, the ethylene-methyl acrylate copolymer preferably uses Dupont EMA1125AC；
Preferably, the composite antioxidant is antioxidant 1010 and irgasfos 168 1-2 in mass ratio:2-4 uniformly mixes.
The present invention another object is that the preparation method for providing above-mentioned stretch-proof Polywoven Bag, comprise the steps：First
Each raw material is accurately weighed according to formula, according to equal increments method principle, batch mixing, after mixing, controls compound while stirring
Thickness degree is 5-10cm, then dries 20-40min in 100-120 DEG C, and compound after drying is 230 DEG C -250 in temperature
Plastify into molten at DEG C, be extruded into film, cooling, be cut into embryo silk, through wire drawing, weave cotton cloth, be coated with, bag, turn over bag, cutting, print
Brush, sewing, packing obtain final product stretch-proof Polywoven Bag.
Further, the power of agitator is per kilogram compound 2.5-3.5kW；
Further, described when being extruded into film draw ratio be 1:6-6.5, pressure are 9-11Mpa；
Further, described cooling be with the water cooling that temperature is 45-48 DEG C；
Further, the draw ratio of the drawing process is 5-7.
Beneficial effect：
The present invention optimizes masterbatch raw material type and formula with polypropylene as base-material, improves production technology, and science is compounding can be shown
Write and improve Polywoven Bag tensile resistance, the modified carbon nano-tube of relative tensile load, intensity, toughness and elastic modelling quantity；Can
Significantly improve the calcium fruit fiber of Polywoven Bag shock resistance and easily biological-degradable, reduction production cost；It is greatly improved modeling
Polyethylene/winter rye the peptide complexes of material woven bag resistance to low temperature, can effectively improve Polywoven Bag lubricity and anti-oxidant
The almond oil of property；With other processing aid synergies, a kind of good Environment-friendlytensile tensile of physical property is finally obtained and stretches modeling
Material woven bag.Test shows：1) compared with existing stretch-proof Polywoven Bag, stretch-proof Polywoven Bag of the present invention has superior
Physical property：Stretch-proof load is strong, and its multi tension load is 520-930 (N/50mm), peeling force 6.5 (N/30mm), point
Commercially available 351-767 (N/50mm), 4.1 (N/30mms) are not significantly higher than；With powerful shock resistance：2 meters of height fall,
Any direction is nothing bale broken, and commercially available broken rate is 52%；There is stronger anti-ultraviolet property：Through 60 DEG C, 0.63W/m2Spoke
Expose after 4h alternating test 144h according to exposing 8h and 50 DEG C and condensing nothing irradiation, multi tension load conservation rate is 78-85%, significantly
Higher than commercially available 62-70%.2) compared with commercially available stretch-proof Polywoven Bag, after filling material respectively at 0 DEG C, -10 DEG C, -
20 DEG C, -30 DEG C, -40 DEG C of storage 24h, less, nothing bale broken, and commercially available -30 DEG C start greatly Polywoven Bag appearance damage of the present invention
Amount fracture of wire and bale broken, broken rate acutely increase to 15% from 1%, illustrate that the low temperature resistant storage temperature of Polywoven Bag of the present invention is minimum
Up to -40 DEG C, commercially available only -20 DEG C, -30 DEG C of beginnings cannot be used；While Polywoven Bag rupture strength retention of the present invention
It is still：73-91%, and commercially available only 32-63%；Extension at break conservation rate 72-90%, and commercially available only 31-62%, illustrate this
Invention Polywoven Bag remains to after low-temperature storage keep preferable physical property and performance, compared with prior art, resistance to
Cryogenic property is superior.(particular technique effect is shown in embodiment 7-8), particular technique principle is as follows：
1. the calcium fruit fiber that prepared by the present invention is the natural plants calcium stem end higher with calcic, iron, leaf of GAIGUO and gives up
Wood chip is raw material, through ultrasonic cleaning, ultrasound and high-pressure pulse electric extraction, biobleaching and faint enzymolysis, microwave drying, squeezes
Press expanded, ultramicro grinding and be obtained, multiple treatment technologies are combined, synergy, particularly after crushed, add a certain amount of
Sodium acid carbonate, sealing and standing after adjusted moisture, then extrusion, can significantly increase the specific surface area of calcium fruit fiber, net
Lattice structure is more enriched, and puffed degree, dilatancy, thickening property are higher, and cellulose specific surface area increases, and absorption affinity is increased with tensile resistence
By force, merge with metal ions such as calcium therein, iron, you can improve toughness, the elasticity of Polywoven Bag, plastic knitting can be improved again
The shock resistance of bag.While kinds of processes combination can effectively improve draw ratio and the surface adhesion of fiber grain, improve with
Polypropylene base-material and the compatibility of other resins, can be dispersed and compatible in polypropylene base-material, and its science is compounded in filling out
Fill in masterbatch, calcium carbonate of the prior art, nano-calcium carbonate and silicate (clay, actinolite etc.) can be substituted completely, not only
Polywoven Bag shock resistance, and easily biological-degradable, reduction production cost is remarkably improved, is improved soil constituent, increases
The content of organic matter, environmentally friendly.While also improving the value of calcium stem end leaf and waste wood, turn waste into wealth, beneficial to promotion " three
Agriculture " develops.
2. the modified carbon nano-tube that prepared by the present invention is will be multiple to single wall or multi-walled carbon nano-tubes, ammonium persulfate and hydroscience
Join, process through ultrasonic disperse and high-pressure pulse electric, alternate electric field and magnetic field, can produce strong concussion, water mutually ionize, oxygen
Change is acted on, and is formed homogeneous, stable nanotube dispersion, is then reacted at a lower temperature, carry out synthesis to CNT
Surface treatment, to produce hydroxyl, carbonyl and a small amount of carboxyl on the surface of CNT, the presence of these groups makes CNT
Be soluble in water or the organic solvent of DMF isopolarity in, finally give the long CNT of the stronger solubility of dissolubility
And short carbon nanometer tube.It is added in filling master batch comprehensively, uniformly disperseing, is filled in polypropylene base-material, gives full play to
The material property of CNT, is remarkably improved Polywoven Bag tensile resistance, relative tensile load, intensity, toughness and bullet
Property modulus；The advantage of the method is：1) length of carbon nanotube is controlled：The distribution of lengths of CNT can have changing for reaction condition
Become and control, when CNT is processed by the ammonium persulfate solution of high concentration at a higher temperature, can be truncated
CNT；When the concentration of ammonium persulfate is relatively low or reaction temperature is relatively low, CNT will not be truncated；2) biography is avoided
The strong acid of system, the use of highly basic, high safety；3) Processes and apparatus is simple, and reaction is gentle, efficiency high；4) costliness is avoided
The use of surfactant, low cost；5) with water and neutral sulfatase as reaction dissolvent and raw material, environmentally friendly；6) can advise
Modelling and commercially produce.
3. polyethylene/winter rye peptide complexes that prepared by the present invention are gathered with the synthetic resin with good resistance to low temperature
Ethene and the blending of the winter rye antifreeze peptide with excellent anti-freezing property, co-melting, extruding pelletization are formed；The winter rye peptide be to contain
The winter rye seed for having abundant freeze proof matrix is prepared for raw material, and high-pressure electrostatic process, high-pressure pulse electric are aided in salicylic acid
Induction, low temperature segmentation Stress treatment and natural lighting are organically combined so that active seed containing freeze proof matrix itself is in Wai Jie
Under the stress of environment and induction, freeze proof matrix components have obtained most comprehensive, most abundant synthesis and accumulation, after blended enzyme enzymolysis
Maximizing dissolution, while increase can freeze proof peptide content, has significantly delayed the formation of ice crystal, has reduced ice crystal to high score
The effect of stabbing of subtree fat, enhances the cryoprotective effects of polypropylene base-material, improves the resistance to low temperature of Polywoven Bag, and poly-
Ethene science compound, blending, co-melting, generate unexpected cryoprotective effects, its resistance to low temperature is significantly increased；It is particularly which
In the seed fat that contains also can further improve mobility, lubricity and the non-oxidizability of compound and polypropylene base-material.
4. the almond oil that prepared by the present invention is gone out enzyme, freezing crushing, enzymolysis, true with semen armeniacae amarae as raw material through microwave irradiation
Free oil, emulsion, hydrolyzate and almond slag are obtained after empty centrifugation, emulsion therein is carried out after biological demulsifying vacuum again
Centrifugation obtains free oil, free oil is merged and is obtained final product, with respect to the turpentine oil in existing filling master batch, coix seed oil and mandarin oil
Say that the anti-oxidation active substances such as unrighted acid therein and VE are higher, its lubricity, mobility and non-oxidizability are higher.
It should be noted that stretch-proof Polywoven Bag of the present invention have the technical effect that each group split-phase mutually cooperates with, interacts
Result, the superposition of not simple raw material function, the science of each raw material components is compounding and extracts, the effect of generation considerably beyond
Each single component function and the superposition of effect, with preferable advanced and practicality.
Specific embodiment
The present invention is described below by specific embodiment.Unless stated otherwise, technological means used in the present invention
It is method known in those skilled in the art.In addition, embodiment is interpreted as illustrative, and the unrestricted present invention
Scope, the spirit and scope of the invention are limited only by the claims that follow.To those skilled in the art, without departing substantially from this
On the premise of invention spirit and scope, various changes that the material component in these embodiments and consumption are carried out are changed
Belong to protection scope of the present invention.
Prepared by 1 raw material of embodiment
1. the preparation of calcium fruit fiber：
The preparation method of the calcium fruit fiber, comprises the steps：Fresh calcium stem end, leaf of GAIGUO and waste wood are pressed quality
Than 5:4:1.5 uniform mixing, are placed in supersonic wave cleaning machine and clean 4min in 200W, 30KHz, drain, and crush, and add fragment
The water that 1 times of quality, room temperature 300W, 35KHz condition ultrasonic extraction 12min, then in electric-field intensity 30kV/cm, the burst length 500
μ s, carries out high-pressure pulse electric and processes 12min under the conditions of pulse frequency 300Hz；It is 8 to adjust pH value, adds mixture quality
0.2% biology enzyme, digests 12min in 55 DEG C；It is 50% that enzymolysis liquid is evaporated to solid content, is put into microwave dryer
Intermittent drying is carried out in 2000W, 140 DEG C, be allowed to moisture and 9% is reached, particle diameter 0.5mm is then crushed to, add comminuted material
The sodium acid carbonate of amount 0.3%, uniform mixing, adjustment mixture moisture are 16%, and room temperature, sealing and standing 2h turn in screw rod
Fast 110r/min, 150 DEG C of condition extrusions of temperature, then ultramicro grinding most dry 5h after 105 DEG C and obtain final product to 12 μm of particle diameter
Calcium fruit fiber；
The biology enzyme be alkalescent xylanase, laccase, dextranase, seminase, pectase, tannase in mass ratio
3:2:2:1:0.7:0.5 uniform mixing.
2. the preparation of modified carbon nano-tube：
The preparation method of the modified carbon nano-tube, comprises the steps：By SWCN, ammonium persulfate and go from
Sub- water in mass ratio 1:75:1000 uniform mixing, first in power 300W, the ultrasonically treated 30min of frequency 22KHz, then in electricity
Field intensity 4kV/cm, 200 μ s of burst length, high-pressure pulse electric is carried out under the conditions of pulse frequency 300Hz processes 12min；Through place
Mixture after reason reacts 1.5h in rotating speed 110r/min, temperature 60 C, the reactant liquor PP micropore filtering film in 0.22 μm of aperture
Filtered, and deionized water cyclic washing is most dried under vacuum to constant weight after 75 DEG C to neutrality, crush, obtain final product carbon modified
Nanotube.
3. the preparation of polyethylene/winter rye peptide complexes：
The preparation method of the polyethylene/winter rye peptide complexes, comprises the steps：
1) preparation of winter rye peptide：By the seed sabot of winter rye, 7min is processed in electric-field intensity 5kV/cm high-pressure electrostatic；
Then soaking at room temperature 2h in salicylic acid solution of the concentration for 15mg/L, while in electric-field intensity 8kV/cm, 150 μ of burst length
S, carries out high-pressure pulse electric process under the conditions of pulse frequency 300Hz；Rinse, drain, 21h are stood in 4 DEG C, then successively 2
DEG C refrigeration 3d, -4 DEG C of freezing 2d, -17 DEG C of freezing 12h, outdoor natural light photograph is immediately placed at, so that seed half is carried out after thawing immediately
Crush, crushed material particle diameter 1mm, the water of 3 times of crushed material quality is subsequently added into, be 4.5 with newborn acid for adjusting pH value；It is eventually adding mixing
The mixed enzyme of feed liquid quality 1.5%, digests 20min in 42 DEG C first, then digests 30min in 55 DEG C；Enzymolysis liquid is filtered, filtrate
Reduced pressure concentration, freeze-drying obtain final product winter rye peptide；
The mixed enzyme is protease, cellulase, amylase, pectase in mass ratio 6:5:2:1 uniform mixing；
2) winter rye peptide is sufficiently mixed in proportion with polyethylene, maleic anhydride, styrene, initiator and antioxidant, weight
Measuring ratio is：Polyethylene: winter rye peptide: maleic anhydride: styrene: initiator: antioxidant=100: 6: 10: 7: 2.6: 0.5；
3) by step 2) compound that obtains adds double screw extruder frit reaction, and extruding pelletization, control twin-screw are squeezed
Go out machine and die temperature at 162 DEG C, screw speed is 115r/min, time of staying control of the reactant in double screw extruder
At 55 seconds, polyethylene/winter rye peptide complexes are obtained final product.
4. the preparation of almond oil：
The preparation method of the almond oil, comprises the steps：Semen armeniacae amarae immersion mass percent concentration is
In 0.02% sodium bicarbonate solution, room temperature is rinsed, is drained, and is put sealing and standing wetting 2h in container, is then peeled, will be bitter for decortication
Almond is put in microwave dryer in frequency 2450MHz, power 2000W, 85 DEG C of temperature, thickness of feed layer 4cm condition microwave irradiation
Go out enzyme 3min；Soaking at room temperature 3h in the citric acid solution that mass percent concentration is 0.2% is then placed in, clear water is rinsed 2 times, drip
Dry, 4h is freezed in -23 DEG C, thickness of feed layer 9cm, be crushed to particle diameter 0.5mm and obtain semen armeniacae amarae powder；Its quality is added in semen armeniacae amarae powder
4 times of pH value is 5.5 deionized water, uniform mixing, and control mixed material temperature is 50 DEG C, is added thereto to semen armeniacae amarae silty
The compound enzyme of amount 0.04%, stirs, insulation, digests 50min；By enzymolysis liquid put vacuum in vacuum centrifuge-
0.02MPa, 15 DEG C of temperature, rotating speed 10000r/min, traditional vacuum 6min, isolated free oil, emulsion, water from top to bottom
Solution liquid and semen armeniacae amarae slag, the emulsion for obtaining control temperature are 40 DEG C, add the biological demulsifying agent of emulsion quality 0.03%
Breakdown of emulsion 50min, after vacuum -0.02MPa, 15 DEG C of temperature, 5000r/min, traditional vacuum 12min's breakdown of emulsion is dissociated again
Oil, the free oil for merging gained obtain final product almond oil；
The quality of the compound enzyme is consisted of：Acid protease:Cellulase:Pectase:Amylase=7.5:3:2:2；
The quality of the biological demulsifying agent is consisted of：Glycolipid class:Lipopeptid class:Cell wall combines class=5:3:2；
The quality of the glycolipid class biological demulsifying agent is consisted of：Rhamnolipid:APG=3:2.
Calcium fruit fiber, modified carbon nano-tube, polyethylene/winter rye peptide complexes used in example 2 below -6, hardship
Apricot kernel oil is prepared for embodiment 1, and other are commercial.
Embodiment 2
A kind of stretch-proof Polywoven Bag, is mainly prepared by the raw material of following parts by weight：
100 parts of polypropylene, 18 parts of calcium fruit fiber, 11 parts of LLDPE, 8 parts of modified carbon nano-tube, polyoxygenated
6 parts of methylene, polyethylene/4 parts of winter rye peptide complexes, 2 parts of ethylene-methyl acrylate copolymer, 2 parts of antiaging agent, citric acid
1 part of tributyl, 1 part of coupling agent, 0.8 part of Tissuemat E, 0.4 part of composite antioxidant, 0.4 part of almond oil；
The ethylene-methyl acrylate copolymer preferably uses Dupont EMA1125AC；
The composite antioxidant is antioxidant 1010 and irgasfos 168 in mass ratio 1.5:3 uniform mixing.
Preparation method, comprises the steps：It is first according to formula and each raw material is accurately weighed, according to equal increments method principle,
Batch mixing, after mixing, controls and mixes thickness of feed layer for 6cm, then dry 30min in 110 DEG C, after drying while stirring
Compound temperature be 240 DEG C at plastify into molten, be extruded into film, cooling, be cut into embryo silk, through wire drawing, weave cotton cloth, be coated with,
Bag, turn over bag, cutting, printing, sewing, packing obtain final product stretch-proof Polywoven Bag.
The power of agitator is per kilogram compound 3kW；
Described when being extruded into film draw ratio be 1:6.2, pressure is 10Mpa；
Described cooling be with the water cooling that temperature is 46 DEG C；
The draw ratio of the drawing process is 6.
It is 930 (N/50mm) through Polywoven Bag radial drawing power obtained in above-mentioned preparation method, broadwise tensile force is 905
(N/50mm).
Embodiment 3
A kind of stretch-proof Polywoven Bag, is mainly prepared by the raw material of following parts by weight：
100 parts of polypropylene, 16 parts of calcium fruit fiber, 10 parts of LLDPE, 6 parts of modified carbon nano-tube, polyoxygenated
5 parts of methylene, polyethylene/3 parts of winter rye peptide complexes, 1.5 parts of ethylene-methyl acrylate copolymer, 1.2 parts of antiaging agent, lemon
Lemon 0.8 part of tributyl of acid, 0.8 part of coupling agent, 0.6 part of Tissuemat E, 0.3 part of composite antioxidant, 0.3 part of almond oil；
The ethylene-methyl acrylate copolymer preferably uses Dupont EMA1125AC；
The composite antioxidant is antioxidant 1010 and irgasfos 168 in mass ratio 1:2 uniform mixing.
Preparation method, comprises the steps：It is first according to formula and each raw material is accurately weighed, according to equal increments method principle,
Batch mixing, after mixing, controls and mixes thickness of feed layer for 5cm, then dry 20min in 100 DEG C, after drying while stirring
Compound temperature be 230 DEG C at plastify into molten, be extruded into film, cooling, be cut into embryo silk, through wire drawing, weave cotton cloth, be coated with,
Bag, turn over bag, cutting, printing, sewing, packing obtain final product stretch-proof Polywoven Bag.
The power of agitator is per kilogram compound 2.5kW；
Described when being extruded into film draw ratio be 1:6, pressure is 9Mpa；
Described cooling be with the water cooling that temperature is 45 DEG C；
The draw ratio of the drawing process is 5.
It is 925 (N/50mm) through Polywoven Bag radial drawing power obtained in above-mentioned preparation method, broadwise tensile force is 900
(N/50mm).
Embodiment 4
A kind of stretch-proof Polywoven Bag, is mainly prepared by the raw material of following parts by weight：
100 parts of polypropylene, 20 parts of calcium fruit fiber, 12 parts of LLDPE, 10 parts of modified carbon nano-tube, polyoxygenated
7 parts of methylene, polyethylene/5 parts of winter rye peptide complexes, 2.5 parts of ethylene-methyl acrylate copolymer, 3 parts of antiaging agent, lemon
1.2 parts of sour tributyl, 1.2 parts of coupling agent, 1.0 parts of Tissuemat E, 0.5 part of composite antioxidant, 0.5 part of almond oil；
The ethylene-methyl acrylate copolymer preferably uses Dupont EMA1125AC；
The composite antioxidant is antioxidant 1010 and irgasfos 168 in mass ratio 2:4 uniform mixing.
Preparation method, comprises the steps：It is first according to formula and each raw material is accurately weighed, according to equal increments method principle,
Batch mixing, after mixing, controls and mixes thickness of feed layer for 10cm, then dry 40min in 120 DEG C, after drying while stirring
Compound temperature be 250 DEG C at plastify into molten, be extruded into film, cooling, be cut into embryo silk, through wire drawing, weave cotton cloth, apply
Multiple, bag, turn over bag, cutting, printing, sewing, packing obtains final product stretch-proof Polywoven Bag.
The power of agitator is per kilogram compound 3.5kW；
Described when being extruded into film draw ratio be 1:6.5, pressure is 11Mpa；
Described cooling be with the water cooling that temperature is 48 DEG C；
The draw ratio of the drawing process is 7.
It is 920 (N/50mm) through Polywoven Bag radial drawing power obtained in above-mentioned preparation method, broadwise tensile force is 902
(N/50mm).
Embodiment 5
A kind of stretch-proof Polywoven Bag, is mainly prepared by the raw material of following parts by weight：
100 parts of polypropylene, 16 parts of calcium fruit fiber, 12 parts of LLDPE, 6 parts of modified carbon nano-tube, polyoxygenated
7 parts of methylene, polyethylene/3 parts of winter rye peptide complexes, 2.5 parts of ethylene-methyl acrylate copolymer, 1.2 parts of antiaging agent, lemon
Lemon 1.2 parts of tributyl of acid, 0.8 part of coupling agent, 1.0 parts of Tissuemat E, 0.3 part of composite antioxidant, 0.5 part of almond oil；
The composite antioxidant is antioxidant 1010 and irgasfos 168 in mass ratio 1:4 uniform mixing.
Preparation method, comprises the steps：It is first according to formula and each raw material is accurately weighed, according to equal increments method principle,
Batch mixing, after mixing, controls and mixes thickness of feed layer for 5cm, then dry 20min in 120 DEG C, after drying while stirring
Compound temperature be 250 DEG C at plastify into molten, be extruded into film, cooling, be cut into embryo silk, through wire drawing, weave cotton cloth, be coated with,
Bag, turn over bag, cutting, printing, sewing, packing obtain final product stretch-proof Polywoven Bag.
The power of agitator is per kilogram compound 2.5kW；
Described when being extruded into film draw ratio be 1:6.5, pressure is 9Mpa；
Described cooling be with the water cooling that temperature is 48 DEG C；
The draw ratio of the drawing process is 5.
It is 918 (N/50mm) through Polywoven Bag radial drawing power obtained in above-mentioned preparation method, broadwise tensile force is 898
(N/50mm).
Embodiment 6
A kind of stretch-proof Polywoven Bag, is mainly prepared by the raw material of following parts by weight：
100 parts of polypropylene, 20 parts of calcium fruit fiber, 10 parts of LLDPE, 10 parts of modified carbon nano-tube, polyoxygenated
5 parts of methylene, polyethylene/5 parts of winter rye peptide complexes, 1.5 parts of ethylene-methyl acrylate copolymer, 3 parts of antiaging agent, lemon
0.8 part of sour tributyl, 1.2 parts of coupling agent, 0.6 part of Tissuemat E, 0.5 part of composite antioxidant, 0.3 part of almond oil；
The composite antioxidant is antioxidant 1010 and irgasfos 168 in mass ratio 2:2 uniform mixing.
Preparation method, comprises the steps：It is first according to formula and each raw material is accurately weighed, according to equal increments method principle,
Batch mixing, after mixing, controls and mixes thickness of feed layer for 10cm, then dry 40min in 100 DEG C, after drying while stirring
Compound temperature be 230 DEG C at plastify into molten, be extruded into film, cooling, be cut into embryo silk, through wire drawing, weave cotton cloth, apply
Multiple, bag, turn over bag, cutting, printing, sewing, packing obtains final product stretch-proof Polywoven Bag.
The power of agitator is per kilogram compound 3.5kW；
Described when being extruded into film draw ratio be 1:6, pressure is 11Mpa；
Described cooling be with the water cooling that temperature is 45 DEG C；
The draw ratio of the drawing process is 7.
It is 922 (N/50mm) through Polywoven Bag radial drawing power obtained in above-mentioned preparation method, broadwise tensile force is 901
(N/50mm).
The stretch-proof Polywoven Bag physical property of the present invention of embodiment 7, drop performance and anti-ultraviolet property
Open middle bagging-B-1050 × 650/40 of the polypropylene film that prepared with the preparation method of the embodiment of the present invention 2 ×
36 is detection object with commercially available identical category, model, the polypropylene stretch-proof Polywoven Bag through weft density, according to GB/
T8946-2013《Polywoven Bag generic specifications》It is sampled, the physics of detection sample, falls and anti-ultraviolet property,
Testing result such as table 1：
Table 1：Stretch-proof Polywoven Bag correlated performance detection result
Result above shows, compared with existing stretch-proof Polywoven Bag, stretch-proof Polywoven Bag of the present invention has excellent
Physical property more：Stretch-proof load is strong, and its multi tension load is 520-930 (N/50mm), peeling force 6.5 (N/30mm),
Commercially available 351-767 (N/50mm), 4.1 (N/30mms) are significantly higher than respectively；With powerful shock resistance：2 meters of height fall
Under, any direction is nothing bale broken, and commercially available broken rate is 52%；There is stronger anti-ultraviolet property：Through 60 DEG C, 0.63W/m2
Irradiation exposes 8h and 50 DEG C and condenses nothing irradiation and exposes after 4h alternating test 144h, and multi tension load conservation rate is 78-85%, shows
It is higher than commercially available 62-70% to write.There is preferably advanced and practicality compared with prior art.
It should be noted that：Polywoven Bag prepared by embodiment of the present invention 3-6 equally has above-mentioned experiment effect, each reality
Apply between example and little with above-mentioned experiment effect otherness.
The resistance to low temperature test of the stretch-proof Polywoven Bag of the present invention of embodiment 8
Open middle bagging-B-1050 × 650/40 of the polypropylene film that prepared with the preparation method of the embodiment of the present invention 2 ×
36, packagings normally filling with commercially available identical category, model, the polypropylene stretch-proof Polywoven Bag through weft density, filling system
Number stores 24h, the bag weaved difference of each type plastics in 0.80-0.85 respectively at 0 DEG C, -10 DEG C, -20 DEG C, -30 DEG C, -40 DEG C
Filling 100, the damage such as observation Polywoven Bag bale broken, material leakage, and determine the fracture strength of Polywoven Bag flat filament
Conservation rate and extension at break conservation rate, take its Testing index mean value (round numbers percentage), statistics such as table 2
Table 2：The resistance to low temperature of stretch-proof Polywoven Bag
Result above shows, compared with commercially available stretch-proof Polywoven Bag, after filling material respectively at 0 DEG C, -10 DEG C, -
20 DEG C, -30 DEG C, -40 DEG C of storage 24h, less, nothing bale broken, and commercially available -30 DEG C start greatly Polywoven Bag appearance damage of the present invention
Amount fracture of wire and bale broken, broken rate acutely increase to 15% from 1%, the low temperature resistant storage temperature highest of Polywoven Bag of the present invention are described
Up to -40 DEG C, commercially available only -20 DEG C, -30 DEG C of beginnings cannot be used；While Polywoven Bag rupture strength retention of the present invention
It is still：73-91%, and commercially available only 32-63%；Extension at break conservation rate 72-90%, and commercially available only 31-62%, illustrate this
Invention Polywoven Bag remains to after low-temperature storage keep preferable physical property and performance, compared with prior art, resistance to
Cryogenic property is superior, with preferable advanced and practicality.
It should be noted that：Polywoven Bag prepared by embodiment of the present invention 3-6 equally has above-mentioned experiment effect, each reality
Apply between example and little with above-mentioned experiment effect otherness.
Claims (10)
1. a kind of stretch-proof Polywoven Bag, is mainly prepared by the raw material of following parts by weight：100 parts of polypropylene, calcium fruit fiber
16-20 part, LLDPE 10-12 part, modified carbon nano-tube 6-10 part, polyoxymethylenes 5-7 part, polyethylene/winter
Rye peptide complexes 3-5 part, ethylene-methyl acrylate copolymer 1.5-2.5 part, antiaging agent 1.2-3 part, ATBC
0.8-1.2 part, coupling agent 0.8-1.2 part, Tissuemat E 0.6-1.0 part, composite antioxidant 0.3-0.5 part, almond oil 0.3-
0.5 part；
The calcium fruit fiber be with calcium stem end, leaf of GAIGUO and waste wood as raw material, through be cleaned by ultrasonic, ultrasound and high-pressure pulse electric
Extract, biobleaching and appropriate enzymolysis, microwave drying, extrusion, ultramicro grinding and be obtained.
2. a kind of stretch-proof Polywoven Bag as claimed in claim 1, it is characterised in that：The preparation side of the calcium fruit fiber
Method, comprises the steps：By fresh calcium stem end, leaf of GAIGUO and waste wood 3-7 in mass ratio:2-6:1-2 uniformly mixes, and is placed in super
3-5min is cleaned in 200W, 30KHz in sound wave cleaning machine, drain, crush, add the water of fragment quality 0.5-1.5 times, room temperature
200-400W, 35-40KHz condition ultrasonic extraction 10-15min, then in electric-field intensity 20-40kV/cm, burst length 400-
600 μ s, carry out high-pressure pulse electric and process 10-15min under the conditions of pulse frequency 200-400Hz；Regulation pH value is 6-10, adds
The biology enzyme of mixture quality 0.1-0.3%, digests 10-15min in 50-60 DEG C；Enzymolysis liquid is evaporated to solid content
For 40-60%, being put into microwave dryer carries out intermittent drying in 2000W, 130-150 DEG C, is allowed to moisture and reaches 8-10%, so
After be crushed to particle diameter 0.4-0.6mm, add the sodium acid carbonate of crushed material quality 0.2-0.4%, uniform mix, adjust mixture water
It is 15-18% to divide content, and room temperature, sealing and standing 1.5-2.5h, in screw speed 105-115r/min, temperature 140-160 DEG C bar
Part extrusion, then ultramicro grinding most dry 4-6h after 100-115 DEG C and obtain final product calcium fruit fiber to 10-15 μm of particle diameter；
The biology enzyme is alkalescent xylanase, laccase, dextranase, seminase, pectase, tannase 2-4 in mass ratio:
1-3:1-3:0.5-1.5:0.4-1:0.2-0.8 uniformly mixes.
3. a kind of stretch-proof Polywoven Bag as claimed in claim 1, it is characterised in that：The preparation of the modified carbon nano-tube
Method, comprises the steps：By SWCN, ammonium persulfate and deionized water in mass ratio 1:70-80:1000 is uniform mixed
Close, first in power 200-400W, the ultrasonically treated 20-40min of frequency 20-24KHz, then in electric-field intensity 2-6kV/cm, arteries and veins
Time 100-300 μ s is rushed, and high-pressure pulse electric is carried out under the conditions of pulse frequency 200-400Hz and processes 10-15min；After treatment
Mixture react 0.5-2.5h in rotating speed 100-120r/min, temperature 50-70 DEG C, the reactant liquor PP micropore in 0.22 μm of aperture
Filter membrane is filtered, and deionized water cyclic washing is most dried under vacuum to constant weight after 70-80 DEG C to neutrality, is crushed, i.e.,
Obtain modified carbon nano-tube.
4. a kind of stretch-proof Polywoven Bag as claimed in claim 1, it is characterised in that：The polyethylene/winter rye peptide is multiple
The preparation method of compound, comprises the steps：
1) preparation of winter rye peptide：By the seed sabot of winter rye, 6-8min is processed in electric-field intensity 4-6kV/cm high-pressure electrostatic；
Then soaking at room temperature 1-3h in salicylic acid solution of the concentration for 12-18mg/L, while in electric-field intensity 6-10kV/cm, pulse
Time 100-200 μ s, carries out high-pressure pulse electric process under the conditions of pulse frequency 200-400Hz；Rinse, drain, quiet in 3-5 DEG C
18-24h is put, then successively in 2-4d, -3--5 DEG C of freezing 1-3d of 1-3 DEG C of refrigeration, -15--18 DEG C of freezing 10-15h, is immediately placed at
Outdoor natural light shines, and so that seed half is crushed after thawing immediately, and crushed material particle diameter 0.5-1.5mm is subsequently added into comminuted material
The water of 2-4 times of amount, is 3.5-5.5 with newborn acid for adjusting pH value；The mixed enzyme of mixed liquor quality 1.3-1.7% is eventually adding, first
Prior to 35-50 DEG C of enzymolysis 10-30min, then 20-40min is digested in 50-60 DEG C；Enzymolysis liquid filtration, filtrate reduced in volume, cold
Freeze and be drying to obtain winter rye peptide；
The mixed enzyme is protease, cellulase, amylase, pectase 5-7 in mass ratio:4-6:1-3:0.5-1.5 is uniform
Mixing；
2) winter rye peptide is sufficiently mixed in proportion with polyethylene, maleic anhydride, styrene, initiator and antioxidant, weight ratio
For：Polyethylene: winter rye peptide: maleic anhydride: styrene: initiator: antioxidant=100: 2-10: 3-20: 1-15: 0.1-5:
0.1-1；
3) by step 2) compound that obtains adds double screw extruder frit reaction, extruding pelletization, controls double screw extruder
And die temperature, at 145-180 DEG C, screw speed is 30-200r/min, the time of staying of the reactant in double screw extruder
Control obtains final product polyethylene/winter rye peptide complexes in the 10-100 second.
5. a kind of stretch-proof Polywoven Bag as claimed in claim 1, it is characterised in that：The preparation side of the almond oil
Method, comprises the steps：By room temperature drift in sodium bicarbonate solution of the semen armeniacae amarae immersion mass percent concentration for 0.01-0.03%
Wash, drain, sealing and standing wetting 1-3h in container is put, is then peeled, decortication semen armeniacae amarae is put in frequency in microwave dryer
2450MHz, power 1000-3000W, temperature 80-90 DEG C, thickness of feed layer 3-5cm condition microwave irradiation go out enzyme 2-4min；Then put
Enter mass percent concentration for soaking at room temperature 2-4h in the citric acid solution of 0.1-0.3%, clear water is rinsed 1-3 time, drained, in-
20--25 DEG C, thickness of feed layer 8-10cm freezing 3-5h, are crushed to particle diameter 0.4-0.6mm and obtain semen armeniacae amarae powder；Add in semen armeniacae amarae powder
Enter the deionized water of the pH value for 4.5-6.5 of its quality 3-5 times, uniform mixing, control mixed material temperature are 45-55 DEG C, to
The compound enzyme of semen armeniacae amarae silty amount 0.03-0.05% is wherein added, is stirred, insulation, digest 40-60min；Enzymolysis liquid is put
Vacuum -0.01--0.03MPa, temperature 10-20 DEG C, rotating speed 10000r/min, traditional vacuum 5-8min in vacuum centrifuge, from
Isolated free oil, emulsion, hydrolyzate and semen armeniacae amarae slag under above, the emulsion for obtaining control temperature is 30-50 DEG C,
Add the biological demulsifying agent breakdown of emulsion 40-60min of emulsion quality 0.02-0.04%, breakdown of emulsion is after vacuum -0.01--
Traditional vacuum 10-15min obtains free oil again for 0.03MPa, temperature 10-20 DEG C, 5000r/min, merges the free oil of gained
Obtain final product almond oil；
The quality of the compound enzyme is consisted of：Acid protease:Cellulase:Pectase:Amylase=6-9:2-4:1-3:1-
3.
6. a kind of stretch-proof Polywoven Bag as claimed in claim 5, it is characterised in that：The quality group of the biological demulsifying agent
Become：Glycolipid class:Lipopeptid class:Cell wall combines class=4-6:2-4:1-3.
7. a kind of stretch-proof Polywoven Bag as claimed in claim 6, it is characterised in that：The glycolipid class biological demulsifying agent
Quality is consisted of：Rhamnolipid:APG=2-5:1-3.
8. a kind of stretch-proof Polywoven Bag as claimed in claim 1, it is characterised in that：The composite antioxidant is antioxidant
1010 and irgasfos 168 1-2 in mass ratio:2-4 uniformly mixes.
9. a kind of preparation method of stretch-proof Polywoven Bag as described in claim 1-8 is arbitrary, it is characterised in that：Including as follows
Step：It is first according to formula and each raw material is accurately weighed, according to equal increments method principle, batch mixing, after mixing, controls while stirring
System mixing thickness of feed layer is 5-10cm, then dries 20-40min in 100-120 DEG C, and compound after drying in temperature is
Molten is plastified at 230 DEG C -250 DEG C, film is extruded into, cooling, embryo silk is cut into, through wire drawing, is weaved cotton cloth, be coated with, bag, turning over
Bag, cutting, printing, sewing, packing obtain final product stretch-proof Polywoven Bag.
10. a kind of preparation method of stretch-proof Polywoven Bag as claimed in claim 9, it is characterised in that：Described be extruded into thin
During film, draw ratio is 1:6-6.5, pressure are 9-11Mpa；The draw ratio of the drawing process is 5-7.
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