CN106477827A - A kind of tow method of wastewater treatment - Google Patents

A kind of tow method of wastewater treatment Download PDF

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Publication number
CN106477827A
CN106477827A CN201611148199.8A CN201611148199A CN106477827A CN 106477827 A CN106477827 A CN 106477827A CN 201611148199 A CN201611148199 A CN 201611148199A CN 106477827 A CN106477827 A CN 106477827A
Authority
CN
China
Prior art keywords
cod
black liquor
waste water
wastewater treatment
biochemical
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611148199.8A
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Chinese (zh)
Inventor
武春艳
袁从艳
姜鑫
谷振华
侯文鹏
致二铨
李诗阳
郑珍雯
蔡震峰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CHINA NORTH ENERGY CONSERVATION AND ENVIRONMENT PROTECTION Co Ltd
Original Assignee
CHINA NORTH ENERGY CONSERVATION AND ENVIRONMENT PROTECTION Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by CHINA NORTH ENERGY CONSERVATION AND ENVIRONMENT PROTECTION Co Ltd filed Critical CHINA NORTH ENERGY CONSERVATION AND ENVIRONMENT PROTECTION Co Ltd
Priority to CN201611148199.8A priority Critical patent/CN106477827A/en
Publication of CN106477827A publication Critical patent/CN106477827A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/66Treatment of water, waste water, or sewage by neutralisation; pH adjustment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/30Aerobic and anaerobic processes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/34Biological treatment of water, waste water, or sewage characterised by the microorganisms used

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  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Purification Treatments By Anaerobic Or Anaerobic And Aerobic Bacteria Or Animals (AREA)

Abstract

The present invention relates to a kind of tow method of wastewater treatment, belongs to field of waste water treatment.Normal water inlet is entered in regulating reservoir, high-concentration waste water is collected in regulating reservoir, uniformly squeezed in original normal water inlet mixing in regulating reservoir by pump, after homogeneous, in regulating reservoir, waste water COD is in 8000mg/L or so, pH is 3.5~4.5 or so, enter in immobilization Black Liquor with Efficient Bacteria biochemistry pool, in immobilization Black Liquor with Efficient Bacteria biochemistry pool, degrade easy biochemical degradation material, after improving wastewater pH, enter hydrolysis acidification pool, after the mass degradation of difficult degradation is easy biochemical degradation material, after entering contact oxidation technology removal remainder COD, enter flocculation sedimentation tank, in waste water COD is removed further.The present invention breaks traditions the method for operation of the neutral water inlet of biochemical system, and the acid water inlet of biochemical system is saved a large amount of neutralization reagents and taken, it is to avoid N-process produces a large amount of sludge and Incrustation of pipe phenomenon.Improve wastewater treatment COD removal effect.

Description

A kind of tow method of wastewater treatment
Technical field
The present invention relates to a kind of tow method of wastewater treatment, belongs to field of waste water treatment.
Background technology
Tow waste water mainly has two strands, and wherein one is normally intake for waste water station, and continuous discharge, major pollutants are second The material such as cellulose produced in alcohol, acetic acid, ethyl acetate, secondary cellulose acetate sheets, phosphate, a small amount of benzene and production process, its feature is It is 5000 ± 500mg/l that inlet flow-patterm is 4-5, COD, and organic pollution concentration is higher, containing in sub-fraction benzene and production process The intermediate products (cellulose acetate etc.) that does not collect completely, other pollutant good biodegradability.Another strand of waste water is highly concentrated Degree waste water, interval discharge, major pollutants are waste liquor, and it is 1-3 that COD is 20000 ± 2000mg/l, pH.
The existing technology for processing tow waste water is waste water-neutralization reaction pond-aeration and biological pond-flocculation sedimentation tank-water outlet.Deposit Problem as follows:
(1) before waste water enters biochemical system, pH need to be added lime to adjust to 6~9, causes chemical feeding quantity and sludge quantity greatly, after The problems such as continuous pipeline configuration, annual neutralization medicament expense about 1,000,000 or so.
(2) treatment effeciency is low, effluent quality COD≤300mg/L.
Content of the invention
The invention aims to above-mentioned technical problem is solved, a kind of tow method of wastewater treatment is provided.
The purpose of the present invention is achieved through the following technical solutions.
A kind of tow method of wastewater treatment, comprises the following steps that:
Step one, low concentration wastewater and high-concentration waste water are uniformly squeezed in regulating reservoir by pump, obtain mixed waste liquor;Need Ensure the COD in mixed waste liquor in 8000mg/L or so, pH 3.5~4.5 or so;
Step 2, the mixed waste liquor of step one are entered in immobilization Black Liquor with Efficient Bacteria biochemical treatment tank, are given birth in immobilization Black Liquor with Efficient Bacteria Change easy biochemical degradation material of degrading in processing pond, after improving wastewater pH;Subsequently into hydrolysis acidification pool, the material of difficult degradation is dropped Solve as after easy biochemical degradation material, entering after contact-oxidation pool removal remainder COD, flocculation sedimentation tank is entered, is gone further Except COD in waste water.
Black Liquor with Efficient Bacteria in the immobilization Black Liquor with Efficient Bacteria biochemical treatment tank is photosynthetic bacteria;
With catalytic oxidation microorganism in the contact-oxidation pool;
Beneficial effect
The method of operation of the neutral water inlet of the biochemical system that the 1st, breaks traditions, the acid water inlet of biochemical system, save a large amount of neutralization examinations Agent expense, it is to avoid N-process produces a large amount of sludge and Incrustation of pipe phenomenon.
2nd, wastewater treatment COD removal effect is improved.
Description of the drawings
Fig. 1 is the process chart of embodiment 1.
Specific embodiment
The invention will be further described with embodiment below in conjunction with the accompanying drawings.
Embodiment 1
A kind of tow method of wastewater treatment, comprises the following steps that:
Step one, low concentration wastewater and high-concentration waste water are uniformly squeezed in regulating reservoir by pump, obtain mixed waste liquor;Need Ensure the COD in mixed waste liquor in 8000mg/L or so, pH 3.5~4.5 or so;
Step 2, the mixed waste liquor of step one are entered in immobilization Black Liquor with Efficient Bacteria biochemical treatment tank, are given birth in immobilization Black Liquor with Efficient Bacteria Change easy biochemical degradation material of degrading in processing pond, the wastewater pH that pH is 3.5~4.5 is improved to 6~9 or so, dissolving need to be ensured Oxygen is in 0.2~1mg/L;Subsequently into contact-oxidation pool.Remainder COD is removed using microorganism in contact-oxidation pool, need to protect Card dissolved oxygen is between 2~6mg/L;Enter coagulative precipitation tank, add PAC in coagulative precipitation tank, chemical feeding quantity be mass ratio 1~ 1.5 ‰ PAC, remove COD in waste water further, and final outflow water meets COD≤100mg/L requirement.
Immobilization Black Liquor with Efficient Bacteria in the immobilization Black Liquor with Efficient Bacteria biochemical treatment tank is:Using process for fixation be activated carbon With flyash with volume ratio 1:After 1 mixing, the photosynthetic bacteria of 10 times of volumes is added, 10min is stirred every 2h, continue 1 day.To enter Water is diluted to COD=2000mg/L or so, continuum micromeehanics, after stable water outlet, improves influent COD=4000mg/L, treats water outlet After stable, influent COD=6000mg/L is improved, after stable water outlet, influent COD=8000mg/L is improved, after stable water outlet, Complete immobilization Black Liquor with Efficient Bacteria culture.
With catalytic oxidation microorganism in the contact-oxidation pool, in contact-oxidation pool, filler is combined stuffing, contacts oxygen Change microorganism in pond:With sludge seeding in the original aeration and biological pond of waste water station, immobilization Black Liquor with Efficient Bacteria biochemical treatment tank water outlet is passed through, By the survival of the fittest, the microorganism for adapting to immobilization Black Liquor with Efficient Bacteria biochemical treatment tank water outlet stays, it is impossible to which accommodator is dead to be eliminated, Ultimately form contact-oxidation pool microorganism;
Middle and high concentration wastewater equalization pond of the present invention act as the high-concentration waste water of collection interval discharge, mixes, it is ensured that The subsequent processing units influent quality water yield is stable.
Perforated pipe air stirring is provided with regulating reservoir pond in main system, mixes water by air stirring, protect Card subsequent processing units influent quality is stable.
1. service data
Table one
As seen from the above table, when system inlet flow-patterm is 4.12, after immobilization Black Liquor with Efficient Bacteria biochemical treatment tank, system pH is carried 8~9 are risen to, is neutralized without the need for feeding lime.Coagulating sedimentation system final outflow water is stable in below 100mg/L.

Claims (3)

1. a kind of tow method of wastewater treatment, it is characterised in that:Comprise the following steps that:
Step one, low concentration wastewater and high-concentration waste water are uniformly squeezed in regulating reservoir by pump, obtain mixed waste liquor;Need to ensure COD in mixed waste liquor is in 8000mg/L or so, pH 3.5~4.5 or so;
Step 2, the mixed waste liquor of step one are entered in immobilization Black Liquor with Efficient Bacteria biochemical treatment tank, at immobilization Black Liquor with Efficient Bacteria biochemistry Easy biochemical degradation material of degrading in pond is managed, after improving wastewater pH;Subsequently into hydrolysis acidification pool, the mass degradation of difficult degradation is Easily after biochemical degradation material, after entering contact-oxidation pool removal remainder COD, flocculation sedimentation tank is entered, remove further useless COD in water.
2. a kind of tow method of wastewater treatment as claimed in claim 1, it is characterised in that:At the immobilization Black Liquor with Efficient Bacteria biochemistry Black Liquor with Efficient Bacteria in reason pond is photosynthetic bacteria.
3. a kind of tow method of wastewater treatment as claimed in claim 1, it is characterised in that:Have in the contact-oxidation pool and connect Tactile oxidizing microorganisms.
CN201611148199.8A 2016-12-13 2016-12-13 A kind of tow method of wastewater treatment Pending CN106477827A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611148199.8A CN106477827A (en) 2016-12-13 2016-12-13 A kind of tow method of wastewater treatment

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611148199.8A CN106477827A (en) 2016-12-13 2016-12-13 A kind of tow method of wastewater treatment

Publications (1)

Publication Number Publication Date
CN106477827A true CN106477827A (en) 2017-03-08

Family

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Family Applications (1)

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CN201611148199.8A Pending CN106477827A (en) 2016-12-13 2016-12-13 A kind of tow method of wastewater treatment

Country Status (1)

Country Link
CN (1) CN106477827A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108658395A (en) * 2018-06-27 2018-10-16 贵州楚天环保有限公司 A kind of pharmacy sewage processing system and technique

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102399044A (en) * 2011-11-21 2012-04-04 天津市塘沽鑫宇环保科技有限公司 Integrated treatment method for acrylonitrile production wastewater
CN104129893A (en) * 2014-08-21 2014-11-05 四川北方硝化棉股份有限公司 Method for treating cellulose acetate butyrate production wastewater
CN105040129A (en) * 2015-06-18 2015-11-11 河南永煤碳纤维有限公司 Low-water-consumption washing process method for PAN (Polyacrylonitrile)-based carbon fiber precursor

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102399044A (en) * 2011-11-21 2012-04-04 天津市塘沽鑫宇环保科技有限公司 Integrated treatment method for acrylonitrile production wastewater
CN104129893A (en) * 2014-08-21 2014-11-05 四川北方硝化棉股份有限公司 Method for treating cellulose acetate butyrate production wastewater
CN105040129A (en) * 2015-06-18 2015-11-11 河南永煤碳纤维有限公司 Low-water-consumption washing process method for PAN (Polyacrylonitrile)-based carbon fiber precursor

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108658395A (en) * 2018-06-27 2018-10-16 贵州楚天环保有限公司 A kind of pharmacy sewage processing system and technique

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Application publication date: 20170308

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