CN106472550A - A kind of Pesticidal combination containing sulfoxaflor Yu four chlorantraniliproles - Google Patents
A kind of Pesticidal combination containing sulfoxaflor Yu four chlorantraniliproles Download PDFInfo
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- CN106472550A CN106472550A CN201510789771.8A CN201510789771A CN106472550A CN 106472550 A CN106472550 A CN 106472550A CN 201510789771 A CN201510789771 A CN 201510789771A CN 106472550 A CN106472550 A CN 106472550A
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Abstract
The invention provides a kind of Pesticidal combination containing sulfoxaflor and four chlorantraniliproles, the weight percentage of composition is accounted for as 5%-20% by limiting the sulfoxaflor, it is 50%-80% that four chlorantraniliproles account for the weight percentage of composition, so as to improve kill rate of the composition to lepidoptera pest, guarantee that insect is killed in low age, preventing and treating so as to alleviate Larva is born, and also correspondingly reduces the consumption of sulfoxaflor.
Description
Technical field
The present invention relates to pesticide field, and in particular to a kind of Synergistic insecticidal compositions, more particularly to a kind of Pesticidal combination and its application containing sulfoxaflor with four chlorantraniliproles.
Background technology
In agricultural production, chemical agent is to prevent and treat the maximally efficient means of plant pest, but, with the impact of the prolongation of agricultural pests chemical prevention medication history, the agricultural chemicals not factor such as scientifical use, in recent years, agricultural pests resistance is increasingly serious, the pest species for producing resistance are persistently increasing, the Lepidoptera class pest of resistance is particularly easily produced, and resistance level is higher, and resistance development speed is relatively fast.The resistance problem of agricultural pests has become a global problem.
Sulfoxaflor (sulfoxaflor), chemical name is：[1-6- (trifluoromethyl) pyridin-3-yl] ethyl]-λ 4- sulfydryl cyanamide, its molecular structural formula is：
Sulfoxaflor belongs to sulfoximide insecticides, acts on the nervous system of insect, that is, act on unique binding site in nicotinoids acetylcholinergic receptor (nAChR) and play insecticidal function.Can through leaf, stem, root absorption and enter in plant body.Sulfoxaflor is applied to prevents and treats cotton fleahopper, aphid, aleyrodid, all suckings pest such as plant hopper and coccid；Sulfoxaflor is efficient, the quick and lasting period is long, effectively can prevent and treat to nicotinoids, chrysanthemum esters, and organophosphate and carbamate pesticide produces the suction juice class pest of resistance.Sulfoxaflor is regarded as unique Group 4C class brand-new active ingredient by resistance to insecticides Action Committee (IRAC).Sulfoxaflor is low to non-target arthropod toxicity, is integrated pest control preferred agents.
Four chlorantraniliproles (SYP-9080), chemical name：The bromo- N- of 3- (2,4- bis- chloro- 6- (NMF) phenyl) -1- (3,5- dichloro-2-pyridyl base) -1H- pyrazoles -5- formamide, molecular formula：C17H10BrCl4N5O2.Four chlorantraniliproles are the high insecticidal active compounds of ryanodine receptor inhibitor class of Shenyang Chemical Engineering Inst's synthesis, have similar structures with the Rynaxypyr of E.I.Du Pont Company exploitation.Such compound controls calcium ion release channel by acting on ryanodine receptor, affects contraction of muscle, benumbs insect muscle contractility, so as to show insecticidal activity.Ryanodine receptor insecticides have the mechanism of action of uniqueness during desinsection, so as to show wide spectrum, efficiently, low toxicity, safe the features such as.Four chlorantraniliproles have higher insecticidal activity to lepidoptera pests such as rice leaf roller, striped rice borer, corn borer, armyworm, diamondback moth, beet armyworms.
Often there is different degrees of defect on agricultural insect pests control in the insecticide variety containing single-activity component：Continuously easily developed immunity to drugs using rear insect, the pollution of environment more than access times, will be increased.And different component is compounded, disadvantage mentioned above can be effectively overcome.Meanwhile, using the synergistic effect produced by two kinds of active component mixtures, preventive effect can be improved, reduce the consumption of active ingredient, drug cost is saved, delay the drug-fast generation of insect, evil mite, reduce environmental pollution, be the important means of integrated control insect.
CN103931643A discloses a kind of Pesticidal combination for containing four chlorantraniliproles, active ingredient is four chlorantraniliproles, and the one kind in sulfoxaflor, bromine cyanogen insect amide, Rynaxypyr, fipronil bisamide, Tolfenpyrad, flonicamid, and the weight ratio of the two is 1:80-60:1.The composition has synergistic effect to the various pests for endangering agricultural production, and wherein table 19 discloses four chlorantraniliproles with active component B and its compounding preventing and treating Laphygma exigua Hubner test of pesticide effectiveness；The embodiment 65 of table 19 discloses 45% 4 chlorantraniliprole+sulfoxaflor, and (four chlorantraniliproles compare 1 with the weight of sulfoxaflor：8)；Include four chlorantraniliprole 5%+40% sulfoxaflor in embodiment 65；The embodiment 1 of table 15, embodiment 19, embodiment 37 and embodiment 55 disclose four chlorantraniliproles and active component B and its compound prevents and treats the paddy rice rice leaf roller test of pesticide effectiveness.Include+1% sulfoxaflor of 19% 4 chlorantraniliprole in embodiment 1；Include+24% sulfoxaflor of 1% 4 chlorantraniliprole in embodiment 19；Include+1% sulfoxaflor of 14% 4 chlorantraniliprole in embodiment 37；Include+1% sulfoxaflor of 34% 4 chlorantraniliprole in embodiment 55.
Generally, the activity of individual compounds is good, however, low rate of application or for single insect using when they can not meet the high request must are fulfilled for by insecticide, acaricide or nematicide.Therefore, in a typical demand of field of pest control appearance it is, how to research and develop a kind of close rate that can reduce preventing and treating active component and reduction or avoid unfavorable environment or toxicological effects, while still allowing for the control of insect that imitates, and combine and knock down activity and extend the preventing and treating time, i.e., while realizing the pest control agent of snap action and long-acting.
In addition, it is using another difficulty of insecticide, repeat and uniquely insect can be caused in many cases to produce the reactive compound natural or adapt to the resistance to the action of a drug using single Pesticidal compound, therefore, it is also desirable to research and develop contribute to preventing or overcoming drug-fast pest control agent.
Content of the invention
For solving above-mentioned technical problem, the invention provides a kind of Pesticidal combination containing sulfoxaflor and four chlorantraniliproles, on the one hand, in the composition of the present invention, the combination of sulfoxaflor and four chlorantraniliproles has synergistic function；On the other hand, by the weight percentage of sulfoxaflor and four chlorantraniliproles in restriction composition, the desinsection cost of Pesticidal combination is not only reduced, the prevention effect to lepidoptera pest is also improved, be improved particularly the prevention effect to low instar larvae.
For reaching this purpose, the present invention is employed the following technical solutions：
A kind of Pesticidal combination containing sulfoxaflor and four chlorantraniliproles, the weight percentage that sulfoxaflor accounts for composition in the Pesticidal combination is 5%-20%, it is 50%-80%, balance of surfactant and/or carrier that four chlorantraniliproles account for the weight percentage of composition.
On the one hand, the combination of the sulfoxaflor of the present invention and four chlorantraniliproles has synergistic function.The Pesticidal combination of the another aspect present invention is by limiting the percentage composition of sulfoxaflor and the percentage composition of four chlorantraniliproles in composition, not only reduce the desinsection cost of Pesticidal combination, while the prevention effect to lepidoptera pest is also improved, the prevention effect to low instar larvae has been improved particularly.
As a further improvement on the present invention, the weight percentage that wherein sulfoxaflor accounts for composition is 5%-15%, and it is 50%-70% that four chlorantraniliproles account for the weight percentage of composition.
As a further improvement on the present invention, in the Pesticidal combination, the weight proportion of sulfoxaflor and four chlorantraniliproles is 1:2.5-1:16, preferably 1:4-1:10.
The Pesticidal combination can be configured to any formulation for agriculturally allowing, preferably missible oil, suspending agent, seed treatment, water dispersible granules, wettable powder, suspension emulsion, smoke agent, aqueous emulsion, microcapsule suspending agent, microcapsule suspension-suspendinagent agent, ultra low volume liquids or microemulsion.
The invention further relates to purposes of the Pesticidal combination of the present invention in preventing and treating harmful organism.
The invention further relates to purposes of the Pesticidal combination of the present invention in preventing and treating insect, acarid or nematode.
The invention further relates to purposes of the Pesticidal combination of the present invention in preventing and treating Lepidoptera, Thysanoptera, Homoptera or coleopteran pest；The purposes of lepidoptera pest is particularly prevented and treated.
The Pesticidal combination can be used to prevent and treat fleahopper silk worm, aphid, aleyrodid, plant hopper, scale insect, thrips, rice leaf roller, yellow rice borer, striped rice borer, pachydiplosis oryzae, base of a fruit moth, red spider, prodenia litura, cabbage caterpillar, diamondback moth, beet armyworm, striped flea-beetle, smaller green leaf hopper, root maggot, mythimna separata or nematode, be particularly suitable for preventing and treating diamondback moth, beet armyworm, prodenia litura, rice leaf roller, yellow rice borer or striped rice borer.
Present invention also offers a kind of method of preventing and treating animal pest, including the described Pesticidal combination containing sulfoxaflor and four chlorantraniliproles to be acted on the propagating materials of target useful plant, target animal insect or its environment, target useful plant.The plant propagation material is seedling, rhizome, garden seedling, cutting or seed.
In the Pesticidal combination, sulfoxaflor and four chlorantraniliproles can separate, sequentially or simultaneously use.
A kind of cover crop in case the method for pest infestation, including jointly or separately applying reactive compound sulfoxaflor and four chlorantraniliproles or applying sulfoxaflor and four chlorantraniliproles successively.
A kind of prevention or the method for control harmful organism, wherein sulfoxaflor and four chlorantraniliproles are individually the form of compositions formulated.
Present invention also offers a kind of protection seed is in case soil insect and protection seedling root and branch are in case the method for soil and foliar insect, which includes prior to seeding and/or make after vernalization seed and the Pesticidal combination of the present invention of insecticidal effective dose to contact.
A kind of method of protection vegetable seeds, which includes to make seed prior to seeding and/or the Pesticidal combination of the present invention after vernalization with effective dose is contacted.
The invention further relates to the Pesticidal combination of the present invention is used for the purposes of the veterinary drug of controlling animal parasites.
Present invention also offers a kind of protection animal is in case the method for parasite infestation or invasion and attack, which includes the animal that the Pesticidal combination of effective dose of the present invention is delivered medicine to needs.
Present invention also offers the seed that a kind of Pesticidal combination for applying the present invention is processed.
Compared with prior art, the present invention at least has the advantages that：
The present invention is by the percentage composition of sulfoxaflor in reduction Pesticidal combination, improve the percentage composition of four chlorantraniliproles, on the one hand the desinsection cost of Pesticidal combination is reduced, on the other hand improve to harmful organism, prevention effect particularly to lepidoptera pest, be improved particularly the prevention effect to low instar larvae, after administration 15 days when 96.91% can reach to the preventive effect of larva.
Specific embodiment
On the one hand, the invention provides a kind of Pesticidal combination containing sulfoxaflor and four chlorantraniliproles, the weight percentage that sulfoxaflor accounts for composition in the Pesticidal combination is 5%-20%, can be for example 5%, 8%, 9%, 10%, 11%, 12%, 15%, 18%, 19%, 20%, preferably 5%-15%；It is 50%-80% that four chlorantraniliprole accounts for the weight percentage of composition, for example, can be 50%, 52%, 55%, 58%, 60%, 62%, 65%, 68%, 70%, 72%, 75%, 78%, 80%, preferably 50-70%；Balance of surfactant and/or carrier.
" containing " of the present invention, it is intended which removes described group exceptionally, can also include other components, and these other components give the Pesticidal combination different characteristics.In addition, " containing " of the present invention, may be replaced by enclosed " for " or " by ... constitute ".
" surplus " of the present invention is only intended to meet the content of the Pesticidal combination and reaches 100%.That is, only when the active component is unsatisfactory for 100%, " surplus " herein means various surfactants and/or carrier, is supplied by the adjuvant component with the content for realizing the Pesticidal combination as 100%；If the active component sum has reached 100%, surfactant and/or carrier need not be added.
In the present invention, Surfactant is not particularly limited, and which includes but is not limited to：One or more in emulsifying agent, wetting agent, stabilizer, dispersant, thickener, defoamer, antifreezing agent, disintegrant or binding agent etc..
The dispersant for being suitable for the Pesticidal combination of the preparation present invention is included but is not limited to：Alkylnaphthalene sulfonate, double (alkyl) naphthalenesulfonate formaldehyde condensation compounds, naphthalene sulfonic acid-formaldehyde condensation product, aryl phenol polyoxyethylene succinate sulfonate, octylphenol polyethylene oxyethylene group ether sulfate, polycarboxylate, lignosulfonates, alkylaryl APEO, aliphatic alcohol polyethenoxy base ether, APES formaldehyde condensation products sulfat, alkyl benzene sulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, APES, one or more in aliphatic amine polyoxyethylene ether.
The wetting agent for being suitable for the Pesticidal combination of the preparation present invention is included but is not limited to：One or more in lauryl sodium sulfate, neopelex, Nekal BX, wetting and penetrating agent F, spaonin powder, sldium lauryl sulfate, tea seed cake, silkworm excrement, spaonin powder.
The disintegrant for being suitable for the Pesticidal combination of the preparation present invention is included but is not limited to：One or more in sodium acid carbonate, sodium carbonate, bentonite, urea, ammonium sulfate, glucose, aluminium chloride.
The thickener for being suitable for the Pesticidal combination of the preparation present invention is included but is not limited to：One or more in hydroxymethyl cellulose, hydroxyethyl cellulose, Magnesiumaluminumsilicate, gelatin, guar gum, Arabic gum, xanthans, sodium tripolyphosphate, phenolic resin, sodium alginate, white dextrin, methylcellulose, PAA, polyvinylpyrrolidone, PVPP, polyethylene glycol, polyvinyl alcohol.
The antifreezing agent for being suitable for the Pesticidal combination of the preparation present invention is included but is not limited to：One or more in glycerine, ethylene glycol, propane diols, glycerine, diethylene glycol (DEG), triethylene glycol, polyethylene glycol.
The defoamer for being suitable for the Pesticidal combination of the preparation present invention is included but is not limited to：Silicone, C8-10Aliphatic alcohols, C10-20One or more in saturated fat acids and acid amides, silicone oil, silicone compound.
The emulsifying agent for being suitable for the Pesticidal combination of the preparation present invention is included but is not limited to：Agriculture breast 500# (alkyl benzene calcium sulfonate)、OP series phosphate (thermally coupled distillation columns)、600# phosphate (phenyl phenol polyoxyethanyl ether phosphate)、Styrene polyoxyethylene ether ammonium sulfate salt、Alkyl biphenyl ether disulfonic acid magnesium salts、Triethanolamine salt、Agriculture breast 400# (benzyl dimethyl phenol polyoxyethyl ether)、Agriculture breast 600# (phenyl phenol polyoxyethyl ether)、Nongru-700 # (alkylphenol-formaldehyde resin polyoxyethyl ether)、Agriculture breast 36# (phenethyl phenol formaldehyde resin polyoxyethyl ether)、Agriculture breast 1600# (phenethyl phenol polyoxyethanyl polypropylene-base ether)、Ethylene oxide-propylene oxide block copolymer、OP series (NPE)、By series (castor oil polyoxyethylene ether)、Agriculture breast 33# (alkylaryl polyoxyethylene polyoxypropylene ether again)、Agriculture breast 34# (alkylaryl polyoxyethylene poly-oxygen propylene aether)、Span series (sorbitan monostearate)、TWEEN Series (sorbitan fatty acid ester APEO)、One or more in AEO series (AEO).
The stabilizer for being suitable for the Pesticidal combination of the preparation present invention is included but is not limited to：One or more in BHT, triphenyl phosphite, epoxychloropropane, organic acid, organic base, esters, alcohols, antioxidant, surface-active substance, tributyl phosphate, triethanolamine, diethanol amine, monoethanolamine.
The carrier for being suitable for the Pesticidal combination of the preparation present invention includes liquid-carrier and solid carrier.
Liquid-carrier is included but is not limited to：Water, alcohols (such as methyl alcohol, ethanol), ketone (such as acetone, methyl ethyl ketone), aromatic hydrocarbon (such as benzene, toluene, dimethylbenzene, ethylbenzene, methyl naphthalene), aliphatic hydrocarbon (such as n-hexane, hexamethylene, kerosene), esters (such as ethyl acetate, butyl acetate), nitrile (such as acetonitrile, isobutyronitrile), ethers (such as dioxane, diisopropyl ether), sour amide-type (such as N, dinethylformamide, dimethylacetylamide) and halogenated hydrocarbons (such as dichloroethanes, trichloro ethylene, carbon tetrachloride) etc..
Solid carrier is included but is not limited to：Diatomite, Magnesiumaluminumsilicate, atlapulgite, kaolin, clay, gypsum, bentonite, white carbon, precipitated calcium carbonate, lime stone, wood chip, cornstarch, soluble starch etc..
In the Pesticidal combination of the present invention, the weight proportion of sulfoxaflor and four chlorantraniliproles is 1:2.5-1:16, can be for example 1:2.5、1:3、1:3.5、1:4、1:4.5、1:5、1:5.5、1:6、1:6.5、1:7、1:7.5、1:8、1:9、1:10、1:11、1:12.5、1:13、1:14、1:15、1:16, preferably 1:4-1:10.
The formulation of the Pesticidal combination of the present invention is included but is not limited to：Missible oil, suspending agent, seed treatment, water dispersible granules, wettable powder, suspension emulsion, smoke agent, aqueous emulsion, microcapsule suspending agent, microcapsule suspension-suspendinagent agent, ultra low volume liquids, microemulsion.
The reactive compound can be mixed with conventional additives by known way and prepare by the preparation of the present invention.The conventional additives such as conventional extender and solvent or diluent, emulsifying agent, dispersant, and/or adhesive or fixative, wetting agent, waterproofing agent, if desired, can also be not particularly limited comprising drier and colouring agent, stabilizer, pigment, defoamer, preservative, thickener, water and other processing aids, here.
These compositions not only include to be applied to pending object immediately by suitable equipment such as spraying or dusting equipment, and are additionally included in before being applied to object the concentration commercial composition for needing to be diluted.
The Pesticidal combination of the present invention can make the preparation for being suitable to apply in the form of the composition of its active compound component, it is also possible to be applied in the form of the combination of the commercial preparation of its suitable dosage.
The Pesticidal combination of the present invention can also be applied with other active ingredient combination, other active components described such as fungicide, bactericide, attractant, insecticide, acaricide, nematicide, growth regulator, herbicide, safener, fertilizer or semiochemical etc..
On the other hand, present invention also offers a kind of Pesticidal combination containing sulfoxaflor and four chlorantraniliproles is used for preventing and treating the purposes of animal pest, animal pest is insect, acarid and nematode.While showing the tolerance good to plant, the hypotoxicity to warm blooded species and good Environmental compatibility.Kind to normal sensitive and resistance is active, active to all or special stage of development, particularly to low instar larvae.Above-mentioned animal pest includes：
From Isopoda, such as damp worm (Oniscus aselluse), pillworm (Armadillidium vulgare) and spot pillworm (Porcellio scaber).
From Diplopoda, such as Blaniuus guttulatus.
From chilopoda, such as centipede (Geophilus carpophagus) and common house centipede dragonfly (Scutigera spp.).
From Symphyla, for example clean symphilid (Scutigerella immaculate).
From Thysanoptera, such as silverfiss (Lepisma saccharina).
From Collembola, such as Onychiurus arcticus (Onychiurus armatus).
From Orthoptera, such as house cricket found in a kitchen (Acheta domesticus), Gryllotalpa spp (Gryllotalpa spp.), tropical migratory locusts (Locusta migratoria migratorioides), long volume bear locust category (Melanoplus spp.) and desert locust (Schistocerca gregaria).
From Blattaria, such as oriental cockroach (Blatta orientalis), American cockroach (Periplaneta Americana), leucophaea maderae (Leucophaea maderae) and Groton bug (Blattella germanica).
From Dermaptera, such as European earwig (Forficula auricularia).
From Isoptera, such as Reticulitermes.
From Anoplura, such as body louse (Pediculus humanus corporis), blind pediculus, long volume Pediculus, Trichodectes, Damalinia.
From Thysanoptera, such as greenhouse Hercinothrips spp (Hercinothrips femoralis), cotton thrips (Thrips tabaci), Thrips palmi and Frankliniella accidentalis.
From Heteroptera, such as Eurygasterspp category, middle red cotton bug (Dysdercus intermedius), beet are intended lace bug (Piesma quadrata), the smelly stinkbug in temperate zone (Cimex lectularius), red abdomen and hunt stinkbug (Rhodnius prolixus) and Triatoma.
From Homoptera，Such as wild cabbage aleyrodid (Aleurodes brassicae)、Bemisia tabaci (Bemisia tabaci)、Trialeurodes vaporariorum Westwood (Trialeurodes vaporariorum)、Cotten aphid (Aphis gossypii)、Brevicoryne brassicae (Brevicoryne brassicae)、The hidden knurl volume aphid of tea deer (Cryptomyzus ribis)、Black bean aphid (Brevicoryne brassicae)、Apple aphid (Aphispomi)、Apple aphid (Eriosoma lanigerum)、Mealy plum aphid (Hyalopterus arundinis)、Grape phylloxera (Phylloxera vastatrix)、Pemphigus、Grain aphid (Macrosiphum avenae)、Knurl volume Aphis、Hops knurl volume aphid (Phorodon humuli)、Grain Rhopalosiphum spp (Rhopalosiphum padi)、Leafhopper belongs to、Euscelisbilobatus、Rice green leafhopper (Nephotettix cincticeps)、Brown apricot scale (Lecaniumcorni)、Olive helmet (Saissetia oleae)、Rice small brown rice planthopper (Laodelphaxstriatellus)、Brown back rice plant hopper (Nilaparvata lugens)、California red scale (Aonidiella aurantii)、Oleander circle a red-spotted lizard (Aspidiotus hederae)、Mealybug category and Psylla spp.
From Lepidoptera，Such as pink bollworm (Pectinophora gossypiella)、Loose looper (Bupalus piniarius)、Winter geometrid moth (Chemimatobia brumata)、Lithoclletis blancardela、Cherry ermine moth (Hyponomeuta padella)、Diamondback moth (Plutella xylostella)、Tent caterpillar (Malacosoma neustria)、Pornography and drug moth (Euproctis chrysorrhoea)、Euproctis、Cotton shot hole of leaf lyonetid (Bucculatrix thurberiella)、Tangerine leaf miner (Phyllocnis tiscitrella)、Agrotis、Cutworm belongs to、Brown Noctua、Earias insulana (Eariasinsulana)、Noctua、Lopper worm (Mamestra brassicae)、Small noctuid (Panolis flammea)、Noctua、Cabbage looper (Trichoplusiani)、Carpocapsa pononella (Carpocapsa pomonella)、Pier、Snout moth's larva belongs to (Pyrausta nubilalis)、Anagasta kuehniella (Ephestia kuehniella)、Rheum officinale snout moth's larva (Galleriamellonella)、Bag casemaking clothes moth (Tineola bisselliella)、Etting moth (Tineapell ionella)、Brown oecophorid (Hofmannophila pseudospretella)、Yellow tail leaf roller (Cacoecia podana)、Capua reticulana、Choristoneura fumigerana (Choristoneura fumiferana)、Grape codling moth (Clysia ambiguella) (Clysia ambiguella)、Tea yellow leaf curl moth (Homona magnanima)、The green leaf roller of oak (Tortrix viridana)、Volume snout moth's larva category and Oulema oryzae (Oulema oryzae).
From coleoptera，Such as furniture death watch beetle (Anobium punctatum)、Lesser grain borer (Rhizopertha dominica)、Bruchidius obtectus、Bean weevil (Acanthoscelides obtectus)、House longhorn beetle (Hylotrupes bajulus)、Alder purple flea beetle (Agelastica alni)、Colorado potato bug (Leptinotarsadecemlineata)、Horseradish ape chrysomelid (Phaedon cochleariae)、Chrysomelid category、Rape orchid flea beetle (Psylliodes chrysocephala)、Mexican bean ladybird (Epi1achna varivestis)、Hidden wing first category、Saw chest ostomatid (Oryzaephilus surinamensis)、Weevil belongs to、Sitophilus、Vine black ear is as (Otiorrhynchus sulcatus)、Banana spider base weevil (Cosmopolites sordidus)、Wild cabbage English weevil (Ceuthorrhynchusassimilis)、Alfalfa weevil (Hypera postica)、Khapra beetle belongs to、Spot khapra beetle belongs to、Anthrenus、The moth-eaten category of hair、The moth-eaten category of powder、Pollen beetle (Meligethes aeneus)、Ptinus、Golden yellow ptinid (Niptus hololeucus)、Wheat ptinid (Gibbiumpsylloides)、Tribolium、Cabot's Tragopan (Tenebrio molitor)、Click beetle belongs to、Acupuncture needle Eimeria、Angle cockchafer (Melolontha melolontha)、June chafer (Amphimallon solstitialis)、Brown New Zealand's rib wing angle cockchafer (Costelytrazealandica) and Lissorhoptrusoryzophilus (Lissorhoptrus oryzophilus).
From Hymenoptera, such as Neodiprion spp category, tenthredinidae, field ant category, MonomoriumMayr (Monomorium pharaonis) and Vespa.
From Diptera，Such as Aedes、Spot Anopheles、Culex、Drosophila yellow gorilla (Drosophila melanogaster)、Musca、Male servant fly belongs to、Calliphora erythrocephala (Calliphoraerythrocephala)、Lucilia sericata belongs to、Carysomyia、Cuterbrid belongs to、Gasterophilus、Hippobosca、Chela fly belongs to、Nose fly belongs to、Hypoderma、Pituophis、Tannia belongs to、Bibio hortulanus、Sweden's wheat stem chloropid fly (Oscinella frit)、Wheat fly belongs to、Beet fly (Pegomyiahyoscyami)、Mediterranean fruitfly (Ceratitis capitata)、Dacus oleae (Dacusoleae)、European daddy-longlegs (Tipula paludosa)、Hylemyia and Hippelates.
From Siphonaptera, such as Xenopsyllacheopis (Xenopsylla cheopis) and angle leaf lice mouse.
From Arachnoidea, such as scorpion (Scorpio maurus), black widow (Latrodectus mactans), Acarus siro (Acarus siro), Dermanyssus gallinae (Dermanyssys gallinae), tea deer goitre mite (Eriophyesribis), citrus rust mite (Phyllocoptruta oleivora), Boophilus, carrapato belongs to, Amblyomma, Hyalommaspp, Isodesspp, Acarus tritici belongs to, ginger mite belongs to, Sarcoptesspp, the compacted category of line, Bryobia praetiosa (Bryobia praetiosa), red spider belongs to, the compacted category of red autumnal leaves, sharp tenthredinidae, short whisker Acarapis.
Parasitic plant nematode includes such as Pratylenchus, Radopholus similis Throne (Radopholus similis), fuller's teasel Ditylenchus dipsaci (Ditylenchus dipsaci), Tylenchulus Semipenetrans (Tylenchulus semipenetrans), Heterodera, ball Heterodera, Meloidogyne, Aphelenchoides, minute hand Turbatrix, Xiphinema, burr Turbatrix and remote spring dragonfly category.
A kind of Pesticidal combination containing sulfoxaflor and four chlorantraniliproles of the present invention is particularly well-suited to prevent and treat " biting " insect, and these insects specifically include following insect：
From Lepidoptera，Such as pink bollworm (Pectinophora gossypiella)、Loose looper (Bupalus piniarius)、Winter geometrid moth (Cheimatobia brumata)、Lithocolletis blancardella、Cherry ermine moth (Hyponomeuta padella)、Diamondback moth (Plutella xylostella)、Tent caterpillar (Malacosoma neustria)、Pornography and drug moth (Euproctis chrysorrhoea)、Euproctis、Cotton shot hole of leaf lyonetid (Bucculatrix thurberlella)、Tangerine leaf miner (Phyllocnistiscitrella)、Agrotis、Cutworm belongs to、Brown Noctua、Egyptian complete just brill (Eariasinsulana)、Noctua、Lopper worm (Mamestra brassicae)、Small noctuid (Panolisflammea)、Noctua、Powder pattern moth (Trichoplusiani)、Carpocapsa pononella (Carpocapsa pomonella)、Pier、Snout moth's larva belongs to、Pyrausta nubilalis、Anagasta kuehniella (Ephestia kuehniella)、Rheum officinale snout moth's larva (Gal1eriamellonella)、Bag casemaking clothes moth (Tineola bisselliella)、Etting moth (Tineapellionella)、Brown oecophorid (Hofmannophila pseudospretella)、Yellow tail leaf roller (Cacoecia podana)、Capua reticulana、Choristoneura fumigerana (Choristoneura fumiferana)、The slow-witted moth moth (Clysia ambiguella) of grape、Tea yellow leaf curl moth (Homona magnanima)、The green leaf roller of oak (Tortrix viridana)、Volume snout moth's larva category and Oulema oryzae (Oulema oryzae).
From coleoptera，Such as furniture death watch beetle (Anobium punctatum)、Lesser grain borer (Rhizopertha dominica)、Bruchidius obtectus、Bean weevil (Acanthoscelides obtectus)、House longhorn beetle (Hylotrupes bajulus)、Alder purple flea beetle (Agelastica alni)、Colorado potato bug (Leptinotarsa decemlineata)、Horseradish ape chrysomelid (Phaedon cochleariae)、Chrysomelid category、Rape orchid flea beetle (Psylliodes chrysocephala)、Mexican bean ladybird (Epilachnavarivestis)、Hidden wing first category、Saw chest ostomatid (Oryzaephilus surinamensis)、Weevil belongs to、Sitophilus、Vine black ear beak (Otiorrhynchus sulcatus)、Banana spider base weevil (Cosmopolites sordidus)、Wild cabbage English weevil (Ceuthorrhynchus assimilis)、Alfalfa weevil (Hypera postica)、Khapra beetle belongs to、Spot khapra beetle belongs to、Anthrenus、The moth-eaten category of hair、The moth-eaten category of powder、Pollen beetle (Meligethes aeneus)、Ptinus、Golden yellow ptinid (Niptus hololeucus)、Wheat ptinid (Gibbium psylloides)、Tribolium、Cabot's Tragopan (Tenebrio molitor)、Click beetle belongs to、Acupuncture needle Eimeria、Angle cockchafer (Melolontha melolontha)、June chafer (Amphimallon solstitialis)、Brown New Zealand's rib wing angle cockchafer (Costelytra zealandica) and Lissorhoptrusoryzophilus (Lissorhoptrus oryzophilus).
A kind of Pesticidal combination containing sulfoxaflor and four chlorantraniliproles of the present invention applies also for preventing and treating " sucking " insect, and these insects specifically include following insect：
From Homoptera，Such as wild cabbage aleyrodid (Aleurodes brassicae)、Bemisia tabaci (Bemisia tabaci)、Trialeurodes vaporariorum Westwood (Trialeurodes vaporariorum)、Cotten aphid (Aphis gossypii)、Brevicoryne brassicae (Brevicoryne brassicae)、The hidden knurl volume aphid of tea deer (Cryptomyzus ribis)、Black bean aphid (Aphis fabae)、Apple aphid (Aphispomi)、Apple aphid (Eriosoma lanigerum)、Mealy plum aphid (Hyalopterusarundinis)、Grape phylloxera (Phylloxera vastatrix)、Goitre cotten aphid belongs to、Grain aphid (Macrosiphum avenae)、Knurl volume Aphis、Hops knurl volume aphid (Phorodonhumuli)、Grain Rhopalosiphum spp (Rhopalosiphum padi)、Leafhopper belongs to、Euscelisbilobatus、Rice green leafhopper (Nephotettix cincticeps)、Brown apricot scale (Lecaniumcorni)、Olive helmet (Saissetia oleae)、Rice small brown rice planthopper (Laodel phaxstriatellus)、Brown back rice plant hopper (Nilaparvata lugens)、California red scale (Aonidiella aurantii)、Oleander circle a red-spotted lizard (Aspidiotus hederae)、Mealybug category and Psylla spp.
From Thysanoptera, such as greenhouse Hercinothrips spp (Hercinothrips femoralis), cotton thrips (Thrips tabaci), Thrips palmi and Frankliniella accidentalis.
From Diptera，Such as Aedes、Spot Anopheles、Culex、Drosophila yellow gorilla (Drosophila melanogaster)、Musca、Male servant fly belongs to、Calliphora erythrocephala (Calliphoraerythrocephala)、Lucilia sericata belongs to、Carysomyia、Cuterbrid belongs to、Gasterophilus、Hippobosca、Chela fly belongs to、Nose fly belongs to、Hypoderma、Pituophis、Tannia belongs to、Bibio hortulanus、Sweden's wheat stem chloropid fly (Oscinella frit)、Wheat fly belongs to、Beet fly (Pegomyiahyoscyami)、Mediterranean fruitfly (Ceratitis capitata)、Dacus oleae (Dacusoleae) and European daddy-longlegs (Tipula paludosa)、Hylemyia and Hippelates.
Present invention also offers a kind of method of prevention or control harmful organism, the Pesticidal combination of the present invention to be acted on the propagating materials of target useful plant, object noxious livings or its environment, target useful plant.
The useful plant that the Pesticidal combination of the present invention is suitable for includes：Cereal such as wheat, oat, barley, triticale and rye, and corn, Chinese sorghum, grain and rice；Beet, such as sugar beet or fodder beet；Fruit, such as apple class fruit, drupe, tree nut or soft water fruit, such as apple, pears, plum, peach, banana, almond, walnut, American pistachios, cherry or berry, such as strawberry or blackberry, blueberry；Legume, such as Kidney bean, pea or soybean；Oil crops, such as rape, leaf mustard, olive, sunflower, castor-oil plant, cocoa chocolate tree or peanut；Cucurbitaceous plant, such as pumpkin, cucurbita pepo, cucumber or muskmelon；Fibre plant such as cotton, flax, hemp or jute；Citrus fruit, such as orange, lemon, grape fruit or orange；Vegetables, such as spinach, lettuce, asparagus, cabbage, carrot, onion, tomato, hot red pepper, potato or bell pepper；Canella, such as avocado, Chinese cassia tree or camphor；And tobacco, nut, coffee, eggplant, sugarcane, tealeaves, pepper, grapevine, hops, Plantaginaceae, lactiferous plant, lawn, lawn, fodder grasses, and ornamental plant, such as Petunia, heartsease and balsamine；And shrub, broad leaf tree and aithullium, such as coniferous tree.
The implication of " plant " herein is interpreted as all plants and plant population.Plant is can to pass through conventional breeding and method for optimizing or can pass through biotechnology and genetic engineering method or can combine, by these methods, the plant for obtaining.The plant includes genetically modified plants, and also including can be by plant breeder's power (plant breeders'rights) protection or the plant variety not being protected.The implication of plant parts is interpreted as plant part all above and below the ground and organ, such as branch, leaf, Hua Hegen, the example that can be mentioned that is leaf, pin, leaf, stem, dry, flower, fructification, fruit and seed, Yi Jigen, stem tuber and rhizome.The plant parts also include harvested material and asexual with generative propagation thing, such as transplant, stem tuber, rhizome, sprout and seed.
The Pesticidal combination of the present invention has systemic action, and therefore the Pesticidal combination of the present invention is also suitable for protecting propagating materials such as seed, fruit, stem tuber or the kernel or plant cutting of plant not to be encroached on by harmful organism particularly insect, acarid, nematode.Therefore the Pesticidal combination of the present invention can be used for protect plants shootses in case foliar pest and for seed and root process in case soil pests.
Therefore, the Pesticidal combination of the present invention is suitable to Seed Treatment to protect seed in case insect pest, particularly soil-borne insects insect, and the plant roots that produce of protection and branch are in case soil pests and foliar pest.
The infringement to crop plants that major part is caused by insect is just there occurs after memory period and seed are sown into soil and during plant germination or after germination early in seed.This stage is particularly critical, because just especially sensitive in the root of growing plant and seedling, even small infringement may also lead to the death of whole plant.Therefore, it is of specific interest to protect seed and germination plant by using suitable composition.After germinateing from soil or after emerging the germination plant of suppression and effective plant be also it can be mentioned that.Young plant can carry out whole or Local treatment by dipping to be protected before transplantation.
Therefore; the invention further relates to a kind of protection seed is with pest control, particularly soil pests, and protection rice shoot root and branch are with pest control; the method of particularly soil and foliar pest, methods described are included prior to seeding and/or so that seed is contacted with the Pesticidal combination of the present invention after vernalization.The present invention be more particularly directed to the method for protection plant roots and branch.Protection plants shootses specifically preferred according to the invention are in case the method for perforation and sucking property insect.Particularly preferably protection plants shootses are in case the method for aphid.
Term " plant propagation material " is understood to mean all plant parts for having fertility, such as seed, and vegetable matter such as cuttage bar or stem tuber (such as potato).Therefore, plant part used herein includes plant propagation material.It is mentioned that such as seed (in the narrow sense), root, fruit, stem tuber, bulb, rhizome and plant part.
Plant part and the plant organ for subsequently growing are any parts of the plant produced by plant propagation material such as seed.Plant part, plant organ and plant can also be benefited from and protect plant to avoid plant disease by composition is applied to plant propagation material.Certain plants part and some plant organs for subsequently growing can also regard plant propagation material as, and its own can be applied with composition (or process)；Plant, other plant parts and other plant organs so as to be produced by treated plant part and treated plant organ can also be benefited from by composition being applied to certain plants part and certain plants Organoprotective plant avoids insect pest of the plant.
The process of plant and plant part is directly carried out with conventional treatment method with the Pesticidal combination of the present invention or carried out by acting on its environment, habitat or storage areas, the conventional treatment method for example impregnates, carry out pouring, spray, atomizing, broadcast sowing, dust, mist formation, broadcast sowing, foam, coating, being coated with, the mode such as drip irrigation applies (foliage applying) to the blade of plant, frequency and the consumption of administration can be adjusted so as to adapt to by the degree of the harmful organism infestation.
Seed is particularly in order to process plant propagation material, can also be by impregnating stem tuber or grain, or the wet or dry preparation coating that has been combined by use in succession with the liquid preparation of each active component, so as to active component is administered on seed (coating).
The Pesticidal combination of the present invention is applied to seed with itself or suitably formulation.It is preferred that, seed is processed at steady state, so that process not causing any infringement.Any time that generally can be between harvesting and sowing to the process of seed is carried out.It has to be noticed that the amount of the amount and/or other additives that are applied to the present composition of seed is chosen as not interfering with the germination of seed or without compromising on gained plant generally during Seed Treatment.Before Seed Treatment is applied in plant seeding and before plant emergence.
The Pesticidal combination of the present invention is particularly advantageous for the seed of process plant propagation material, particularly paddy rice, rape, cotton, wheat, barley, soybean, corn, peanut.
A kind of method of protection seed, which includes to make seed prior to seeding and/or the Pesticidal combination of the present invention after vernalization with cooperative effective quantity is contacted.
Present invention also offers the seed that a kind of Pesticidal combination for applying the present invention is processed.
The present composition can be applied to environment, habitat or the storage areas of plant growth.The environment of plant growth, habitat are the supporters for referring to make crops take root, grow, for example：Soil, water etc., specific raw material can use such as sand, float stone, vermiculite, diatomite, agar-agar, gelling material, polymer substance, asbestos, wood chip, bark etc., preferably soil.
The method for applying medicament in soil, liquid preparation is for example diluted in water or does not dilute the medium method in rice seedling bed of the root or seedling for being directly applied to plant, method during granule to be disseminated to the root of plant or the rice seedling bed of seedling has the method prior to seeding pulvis, water dispersible granules etc. being sprayed in soil and integrally mixed with soil, to be sprayed in implantation hole, seed furrow after pulvis, water-dispersible grain dilution agent before sowing or before serike body, in method that is sowed etc..
Present invention also offers a kind of cover crop is in case the method for pest infestation, including jointly or separately applying reactive compound sulfoxaflor and four chlorantraniliproles or applying sulfoxaflor and four chlorantraniliproles successively and sequentially or simultaneously apply sulfoxaflor and four chlorantraniliproles.In the case of separate administration, result of the order generally on prophylactico-therapeutic measures does not affect.
On the other hand, the process of the present invention can also produce following super additive effect：Improve plant growth, improve to the tolerance of high temperature or low temperature, tolerance to arid or to water or soil salt content improved, Flowering quality is improved, is made that harvesting is easier, it is ripe to accelerate, harvesting yield is improved, improve the quality of harvested products and/or improves its nutritive value, the bin stability for improving harvested products and/or its processing characteristics.
It is common and favourable that the Pesticidal combination of the present invention is generally applied with following dosage：
Leaf portion is processed：0.1-10000g/ha, preferably 10-1000g/ha, more preferably 20-300g/ha；For dipping or administration of instiling, the dosage can also even reduce, particularly when inert base such as asbestos or pearl rock is applied.
For Seed Treatment：2-200g/100kg seed, preferably 3-150g/100kg seed.
For soil treatment：0.1-10000g/ha, preferably 1-5000g/ha.
Above-mentioned dosage is only general exemplary dose, and actual those skilled in the art can be according to actual conditions and needs when applying, and the property and insect pest situation especially in accordance with pending plant or crop is adjusting rate of application.
The Pesticidal combination of the present invention applies also for controlling animal parasites.
The Pesticidal combination of the present invention is in the purposes of the veterinary drug of controlling animal parasites.
Therefore, the present invention also aims to there is provided preventing and treating animal in and animal on parasite new method；It is a further object to provide for the safer agricultural chemicals of animal；It is a further object to provide can the animal-use drug that uses of the dosage lower than existing agricultural chemicals.
The Pesticidal combination of the present invention is suitable to prevent and treat the internal and external parasite in animal and on animal.
The Pesticidal combination of the present invention is preferred for preventing and treating and prevents animal from including that warm-blooded animal and fish be not affected and infects.It is preferred for preventing and treating and preventing domestic animal such as dog or the invasion and attack in cat and infects.The Pesticidal combination of the present invention is suitable to interior suction and/or the non-interior suction internal and/or vermin of preventing and treating.The Pesticidal combination of the present invention is particularly well-suited to preventing and treating from Diptera, Siphonaptera and tick purpose insect.It is preferred for resisting mosquito and fly.
The present invention also provides a kind of process, preventing and treating and protection animal in case parasitic infestation and the method for infecting, and which includes the present composition of parasitical active amount or composition oral comprising it, local or parenteral or is applied to animal.
The Pesticidal combination of the present invention is also applied for preventing and treating the animal pest of closing space, particularly insect, spider and acarid, the closing space such as house, factory floor, office, cabin etc..They can be used in domestic insecticide products preventing and treating these insects, their kinds to sensitive and resistance and active to all of stage of development.These insects include：
Scorpionida, such as pincers scorpion (Buthus occitanus).
Acarina, such as adobe tick, stick up edge sharp-edged tick, Bryobia, Dermanyssus gallinae, family and eat sweet mite, tampan tick, brown dog tick, trombiculid (Trombicula alfreddugesi), Neutrombicula autumnalis, dermatophagoides pteronyssinus, dust mite.
Araneida, such as cockle spider section, Yuan Zhu section.
Opiliones, for example, intend scorpion class (Pseudoscorpiones chelifer), Pseudoscorpiones cheiridium, Opiliones phalangium.
Isopoda, for example damp worm, pillworm；Times sufficient mesh, for example, have zebra land, a mountain cricket Eimeria.
Lip foot mesh, such as Scolopendra.
Silverfish mesh, such as comb silverfish category, TaiWan, China silverfish, Lepismodes inquilinus.
Blattaria, such as oriental cockroach, Groton bug, Blatella (Blattella asahinai), leucophaea maderae, angle abdomen Lian category, wood Lian category, Australian cockroach, American cockroach, Periplanetabrunnea, Peroplaneta fluligginosa, long hair blattaria.
Saltatoria, such as family Shuai.
Dermaptera, such as European earwig.
Isoptera, such as kalotermitid category, Reticulitermes.
Worm mesh, such as Lepinatus category, powder breathe heavily Eimeria.
Coleoptera, such as Anthrenus, fur moth category, khapra beetle category, long head lesser grain borer, hidden instep cuckoo Eimeria, Ptinus, lesser grain borer, grain weevil, rice weevil, sitophilus zea-mais, Stegobium paniceum.
Diptera, such as Aedes aegypti, aedes albopictus, Aedes taeniorhynchus, Anopheles, calliphora erythrocephala, great number sarcophagid, Culex quinquefasciatus, northern house, Culex tarsalis, slow-witted fly category, Fannia canicularis, housefly, Bai Ling category, sarcophagid (Sarcophaga carnaria), Simulium, male servant chela fly, daddy-longlegs (Tipula paludosa).
Lepidoptera, such as lesser wax-moth, galleria mellonella waxmoth, India Gu phycitid, rain moth, bag rain moth, Tineolabisselliella.
Siphonaptera, such as dog comb head lice, Ctenocephalides felis felis, humanlice, chigo, Xanthopsyllacheopis.
Hymenoptera, for example, blazon hunchbacked ant, bright hair ant, black wool ant, Lasius umbratus, MonomoriumMayr, Paravespula category, Pavement Ant.
Anoplura, such as head louse, body louse, crab louse.
Stinkbug hunted by Heteroptera, such as cimex hemipterus, bed bug, phodnius prolixus, invasion vertebra.
The Pesticidal combination of the present invention can be used as aerosol, evaporimeter that nothing pressure spray product such as pump spraying and atomizer spray, automatic mist formation system, aerosol producer, foam, gel, the evaporimeter product of evaporating plate that makes with cellulose or polymer, liquid evaporator, gel and film evaporator, screw drive, do not consume energy or passive type vapo(u)rization system, catch moth paper, catch moth bag and insect-catching glue, agent or pulvis are drawn as, in the bait formulation of sprinkling or bait formulation position.
The present invention is further described with reference to specific embodiment, but does not limit the invention to these specific embodiments.One skilled in the art would recognize that present invention encompasses all alternatives, improvement project and the equivalents that are potentially included in Claims scope.
Unless otherwise defined, ratio of the present invention is weight ratio, and content of the present invention is weight percentage.
Example of formulations
Embodiment 1：+ 50% four chlorantraniliprole suspending agent of 5% sulfoxaflor
Each to active component, dispersant, wetting agent and water etc. component is mixed according to the ratio of formula, after ground and/or high speed shear, obtains the aqueous suspension agent of+50% four chlorantraniliprole of 5% sulfoxaflor.
Embodiment 2：+ 50% four chlorantraniliprole wettable powder of 10% sulfoxaflor
By active component, various auxiliary agents and filler etc. by the proportional components mixing of formula, the wettable powder of+50% four chlorantraniliprole of 10% sulfoxaflor after ultra-fine pulverizer disintegrating, that is, is obtained.
Embodiment 3：+ 80% four chlorantraniliprole wettable powder of 15% sulfoxaflor
By active component, various auxiliary agents and filler etc. by the proportional components mixing of formula, the wettable powder of+80% four chlorantraniliprole of 15% sulfoxaflor after ultra-fine pulverizer disintegrating, that is, is obtained.
Embodiment 4：+ 60% four chlorantraniliprole water dispersible granules of 20% sulfoxaflor
Active component, dispersant, wetting agent, disintegrant and filler are mixed in the ratio of formula, become wettable powder through air-flow crushing, add a certain amount of water mixing extruding and material is made, after drying screening, obtain the water dispersible granules of+60% four chlorantraniliprole of 20% sulfoxaflor.
Embodiment 5：+ 60% four chlorantraniliprole missible oil of 15% sulfoxaflor
Mentioned component is proportionally prepared, is uniformly mixing to obtain homogeneous phase, you can obtain the missible oil of+60% four chlorantraniliprole of 15% sulfoxaflor.
Embodiment 6：+ 50% four chlorantraniliprole seed coat agent of 10% sulfoxaflor
Each to active component, dispersant, wetting agent and water etc. component is mixed in the ratio of formula, after ground and/or high speed shear, obtains the seed coat agent of+50% four chlorantraniliprole of 10% sulfoxaflor.
Embodiment 7：+ 60% four chlorantraniliprole wettable powder of 15% sulfoxaflor
Above-mentioned each component is mixed in proportion, and ground, crush, be prepared into the wettable powder of+60% four chlorantraniliprole of 15% sulfoxaflor.
Embodiment 8：+ 60% four chlorantraniliprole water dispersible granules of 20% sulfoxaflor
Active component, dispersant, wetting agent, disintegrant and filler are mixed in the ratio of formula, becomes wettable powder through air-flow crushing；Add a certain amount of water mixing extruding and material is made, after drying screening, obtain the water dispersible granules of+60% four chlorantraniliprole of 20% sulfoxaflor.
Embodiment 9：+ 50% four chlorantraniliprole aqueous emulsion of 5% sulfoxaflor
Water phase：
The sodium salt 1% of the naphthalene sulfonic acids-formaldehyde condensation products of sulfonation
Water complements to 100%
Active component is dissolved in methyl oleate, adds ethoxylated castor oil to obtain oil phase；Oil phase is added to the water under high shear, obtains the aqueous emulsion of+50% four chlorantraniliprole of 5% sulfoxaflor.
Embodiment 10：+ 55% four chlorantraniliprole wettable powder of 10% sulfoxaflor
Said components are mixed in proportion, and ground, crush, be prepared into the wettable powder of+55% four chlorantraniliprole of 10% sulfoxaflor.
Embodiment 11：+ 80% four chlorantraniliprole coated granule of 8% sulfoxaflor
In a mixer, by levigate active component even spread to the carrier soaked by polyethylene glycol, the coated granule of+80% four chlorantraniliprole of dustless 8% sulfoxaflor can be obtained in this way.
Embodiment 12：+ 60% four chlorantraniliprole wettable powder of 10% sulfoxaflor
Said components are mixed in proportion, and ground, crush, be prepared into the wettable powder of+60% four chlorantraniliprole of 10% sulfoxaflor.
Embodiment 13：+ 50% four chlorantraniliprole of 20% sulfoxaflor extrudes granule
Active component is mixed with auxiliary agent and is ground, mixture water-wet.By the mixture extrusion, then dry in the air stream, the extrusion granule of+50% four chlorantraniliprole of 20% sulfoxaflor is obtained.
Embodiment 14：+ 50% four chlorantraniliprole microcapsule suspension-suspendinagent agent of 5% sulfoxaflor
By PAPITM, sulfoxaflor, SOLVESSOTM100 oil phases for being formed are added containing ATLOXTMIn 4913 aqueous solution, emulsion is formed；Then heat and be incubated and catalyst reaction is added 2 hours at 50 DEG C, obtain the microcapsules of sulfoxaflor after cooling.
By ATLOXTM491st, dispersant LFH, defoamer, urea, four chlorantraniliproles and water are mixed in proportion, and obtain the suspending agent of four chlorantraniliproles after ground and/or high speed shear.
Sulfoxaflor microcapsules is added in the suspending agent of four chlorantraniliproles, is uniformly mixing to obtain the microcapsule suspension-suspendinagent agent of+50% four chlorantraniliprole of 5% sulfoxaflor.
Embodiment 15：+ 30% four chlorantraniliprole suspension emulsion of 10% sulfoxaflor
Sulfoxaflor is dissolved in SOLVESSOTMIn 200, ethoxylated castor oil is added, obtains the oil phase of sulfoxaflor.
Four chlorantraniliproles, AEO sulfosuccinic acid monoesters disodium, MODIFIED LIGNOSULPHONATE, xanthans, bentonite, glycerine and water are mixed in proportion, after ground and/or high speed shear, obtains the suspending agent of four chlorantraniliproles.
Oil phase containing sulfoxaflor is added in the suspending agent containing four chlorantraniliproles, obtains the suspension emulsion of+30% four chlorantraniliprole of 10% sulfoxaflor.
Embodiment 16：+ 50% four chlorantraniliprole WP of 5% sulfoxaflor
Sulfoxaflor 5%
Four chlorantraniliproles 50%
White carbon 45%
Sulfoxaflor, four chlorantraniliproles, White Carbon black are proportionally mixed.
Comparative examples 1：+ 5% four chlorantraniliprole suspending agent of 35% sulfoxaflor
Each to active component, dispersant, wetting agent and water etc. component is mixed according to the ratio of formula, after ground and/or high speed shear, obtains the suspending agent of+5% four chlorantraniliprole of 35% sulfoxaflor.
Comparative examples 2：+ 5% four chlorantraniliprole wettable powder of 15% sulfoxaflor
Said components are mixed in proportion, and ground, crush, be prepared into the wettable powder of+5% four chlorantraniliprole of 15% sulfoxaflor.
Biological test example
Prevent and treat the field plot trial of wild cabbage diamondback moth
Using example of formulations 1-16, comparative examples 1 and 2, sulfoxaflor and four chlorantraniliprole single doses do the test of pesticide effectiveness of field control wild cabbage diamondback moth.Test site is Jinhu, and the time is in May, 2014, and larva of the diamondback moth in 1-2 age contains the phase of sending out.Test totally 21 process, each processes three repetitions, cell random alignment.The planting habit of all cells is all identical with local planting habit.
5 points of sample points are taken within 3 days, 7 days, 15 days before dispenser and after dispenser, per fixed point investigates 2 plants, the larva number living that observes on whole strain blade calculates the prevention effect of each treatment region, as a result as shown in table 1 with Revision insect recluced rate.
Borer population living before Revision insect recluced rate (%)=(borer population living after borer population-dispenser living before dispenser) * 100/ dispenser
Prevention effect (%)=(chemicals treatment district Revision insect recluced rate-blank district Revision insect recluced rate) * 100/ (100- blank district Revision insect recluced rate)
Table 1
Can be seen that by the test data of table 1, a kind of Pesticidal combination containing sulfoxaflor and four chlorantraniliproles of the present invention, the weight percentage of composition is accounted for as 5%-20% by limiting sulfoxaflor content, it is 50%-80% that four chlorantraniliproles account for the weight percentage of composition, so as to improve kill rate of the composition to diamondback moth, guarantee that larva is killed in low age, after administration 15 days when 96.91% can reach to the preventive effect of larva, preventing and treating so as to alleviate Larva is born, and also consequently reduces the consumption of sulfoxaflor.
Applicant states that the present invention illustrates the process of the present invention by above-described embodiment, but the invention is not limited in above-mentioned processing step, that is, do not mean that the present invention has to rely on above-mentioned processing step and could implement.Person of ordinary skill in the field it will be clearly understood that any improvement in the present invention, the equivalence replacement to raw material selected by the present invention and the interpolation of auxiliary element, selection of concrete mode etc., all fall within protection scope of the present invention and open within the scope of.
Claims (13)
1. a kind of Pesticidal combination containing sulfoxaflor and four chlorantraniliproles, it is characterised in that described kill
The weight percentage that sulfoxaflor accounts for composition in worm composition is 5%-20%, and four chlorantraniliproles account for group
The weight percentage of compound is 50%-80%, balance of surfactant and/or carrier.
2. Pesticidal combination according to claim 1, it is characterised in that the sulfoxaflor accounts for group
The weight percentage of compound is 5%-15%, and four chlorantraniliproles account for the weight percentage of composition and are
50%-70%.
3. Pesticidal combination according to claim 1, it is characterised in that the sulfoxaflor and four
The weight proportion of chlorantraniliprole is 1:2.5-1:16, preferably 1:4-1:10.
4. Pesticidal combination according to claim 1, it is characterised in that the Pesticidal combination can be joined
Make any formulation for agriculturally allowing.
5. Pesticidal combination according to claim 4, it is characterised in that the formulation is missible oil, outstanding
Floating agent, seed treatment, water dispersible granules, wettable powder, suspension emulsion, smoke agent, aqueous emulsion, micro-
Capsule suspending agent, microcapsule suspension-suspendinagent agent, ultra low volume liquids or microemulsion.
6. Pesticidal combination according to claim 1 preventing and treating harmful organism in purposes.
7. purposes of the Pesticidal combination according to claim 1 in preventing and treating insect, acarid or nematode.
8. Pesticidal combination according to claim 1 is in preventing and treating Lepidoptera, Thysanoptera, Homoptera or sheath
Purposes in wing mesh insect.
9. a kind of preventing and treating animal pest method, it is characterised in that include the desinsection described in claim 1
Composition acts on the breeding material of target useful plant, target animal insect or its environment, target useful plant
Material.
10. a kind of protection seed is in case soil insect and protection seedling root and branch are in case soil and foliar insect
Method, it is characterised in which includes prior to seeding and/or makes after vernalization described in seed and claim 1
Pesticidal combination is contacted.
11. Pesticidal combinations according to claim 1 are used for the veterinary drug of controlling animal parasites
Purposes.
A kind of 12. Pesticidal combinations containing sulfoxaflor and four chlorantraniliproles are used for preventing and treating lepidoptera pest
Purposes, the Pesticidal combination contains active component sulfoxaflor and four chlorantraniliproles, wherein fluorine pyridine worm
Amine nitrile accounts for the weight percent content 5%-20% of composition, and four chlorantraniliproles account for the weight percent of composition and contain
Measure as 50%-80%, balance of surfactant and/or carrier.
13. purposes according to claim 12, it is characterised in that the lepidoptera pest is diamondback moth.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510535336 | 2015-08-27 | ||
| CN2015105353362 | 2015-08-27 |
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| CN106472550A true CN106472550A (en) | 2017-03-08 |
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| CN201510789771.8A Pending CN106472550A (en) | 2015-08-27 | 2015-11-17 | A kind of Pesticidal combination containing sulfoxaflor Yu four chlorantraniliproles |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102217601A (en) * | 2011-04-20 | 2011-10-19 | 青岛海利尔药业有限公司 | Highly efficient and environmentally protective pesticidal composition |
| US20110319262A1 (en) * | 2008-10-08 | 2011-12-29 | Syngenta Crop Protection, Llc | Pesticidal combinations containing sulfoxaflor |
| CN103931643A (en) * | 2013-01-19 | 2014-07-23 | 陕西汤普森生物科技有限公司 | Insecticidal composition containing tetrachloro insect amide |
-
2015
- 2015-11-17 CN CN201510789771.8A patent/CN106472550A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20110319262A1 (en) * | 2008-10-08 | 2011-12-29 | Syngenta Crop Protection, Llc | Pesticidal combinations containing sulfoxaflor |
| CN102217601A (en) * | 2011-04-20 | 2011-10-19 | 青岛海利尔药业有限公司 | Highly efficient and environmentally protective pesticidal composition |
| CN103931643A (en) * | 2013-01-19 | 2014-07-23 | 陕西汤普森生物科技有限公司 | Insecticidal composition containing tetrachloro insect amide |
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