CN106466901A - The processing method producing microbubble using the machine that shapes in polymer - Google Patents

The processing method producing microbubble using the machine that shapes in polymer Download PDF

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Publication number
CN106466901A
CN106466901A CN201510512783.6A CN201510512783A CN106466901A CN 106466901 A CN106466901 A CN 106466901A CN 201510512783 A CN201510512783 A CN 201510512783A CN 106466901 A CN106466901 A CN 106466901A
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China
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microbubble
generating element
polymer
micro
screw rod
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CN201510512783.6A
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CN106466901B (en
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廖伟智
廖翌如
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Job Fox International Ltd By Share Ltd
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Job Fox International Ltd By Share Ltd
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Abstract

A kind of processing method producing microbubble using the machine that shapes in polymer, mainly a microbubble generating element is arranged on an appropriate location, in mould, conveying screw rod or expects pipe, a porous portion of microbubble generating element is enable really to insert in fluid polymer, whereby pressure high temperature hot gas after the porous portion of microbubble generating element produced microbubble just can with fluid polymer between fully and be uniformly mixed together, the product with good foaming effect can be obtained after cooling.

Description

The processing method producing microbubble using the machine that shapes in polymer
Technical field
The present invention relates to foaming technique field, more particularly to a kind of using the machine that shapes in polymer The interior processing method producing microbubble.
Background technology
In general, the foam pattern of polymer generally can be distinguished into following three types:First Type is mechanical foaming, mainly by mechanical strong agitation, makes gas be uniformly mixed into polymerization To form bubble in thing, second type is physical blowing, to mainly use physical blowing agent in polymerization In thing, forming bubble, the third type is chemical blowing, mainly uses for produced physical change What CBA decomposed after being heated that the gas discharging to promote polymer is internally formed bubble.
It is different from aforementioned three kinds of modes, such as previously had Taiwan I233877 patent announcement to be in conveying Bury an air shooter in screw rod, then install multiple micro-porous permeable blocks in the front end of conveying screw rod, when Gas-pressurized can carry out indirectly heat, through too high through an electric heater after entering in air shooter By each micro-porous permeable block, gas is exported to fluid polymer again after temperature heating, make gas with conveying The stirring of screw rod and mix with fluid polymer, finally reinject in a mould, so can Reach the effect forming bubble in polymer.
But in aforementioned patent bulletin, micro-porous permeable block be embedded in the middle of air-vent and with conveying spiral shell Generally assume, between the surface of bar, the state being mutually flush that is to say, that micro-porous permeable block can only connect Contact the surface of fluid polymer and the inside of fluid polymer cannot be stretched into, so in output gas During have no idea gas can fully be mixed with fluid polymer, lead to follow-up poly- The bubble being formed in compound can produce uneven problem.
Content of the invention
Present invention is primarily targeted at it is micro- to provide one kind to produce in polymer using the machine that shapes The processing method of bubble, it can increase the mixed effect between gas and polymer, to lift microbubble It is distributed in the uniformity coefficient in polymer.
In order to reach above-mentioned purpose, the processing method of the present invention the 1st embodiment is mainly by a microbubble Generating element is arranged on a mould.Drive a conveying screw rod that one fluid polymer is pushed to this first In mould, so that this fluid polymer is plugged by the porous portion of this microbubble generating element, then start Producing pressure high temperature hot gas, this pressure high temperature hot gas is by this micro- gas for one micro-bubble generation device Multiple microbubbles can be produced in this mould, these microbubble meetings after one porous portion of bubble generating element Mixed with entering the fluid polymer in this mould, so can be obtained surface light after cooling The sliding and internal product foaming.
It is solid that this microbubble generating element is mainly arranged on one by the processing method of the present invention the 2nd embodiment In reservation, this fixed seat is between this conveying screw rod and a mould.This conveying screw rod is driven to push away first Give this fluid polymer, so that this fluid polymer is produced by this microbubble after flowing through a runner of this fixed seat The porous portion of raw element is plugged, and then starts this micro-bubble generation device to produce this high pressure-temperature gas Body, this pressure high temperature hot gas can produce after the porous portion by this microbubble generating element in this runner Raw multiple microbubbles, these microbubbles can be mixed with entering the fluid polymer in this runner, such as This can obtain smooth surface and the product of internal foaming after the cooling period.
It is solid that this microbubble generating element is mainly arranged on one by the processing method of the present invention the 3rd embodiment Determine on ring, this retainer ring is arranged on the front end of this conveying screw rod.Driving this conveying screw rod to push first should Fluid polymer, makes this polymerizable fluid portion by the porous portion of this microbubble generating element in flow process Plugged, then restart this micro-bubble generation device and one pressure-air is injected the one of this conveying screw rod In air flue, this pressure-air can heated along during the flowing of this air flue simultaneously, this high pressure Gas can enter this microbubble generating element from the air flue of this conveying screw rod after completing to heat, and then exists Multiple microbubbles can be produced after the porous portion of this microbubble generating element, enable the plurality of microbubble Mixed with this fluid polymer by the rotation of this conveying screw rod.
One microbubble generating element is mainly arranged on a material by the processing method of the present invention the 4th embodiment On one discharge end of pipe, in addition a liquid transfer element is arranged on a feeding end of this expects pipe.First This conveying screw rod is driven to push this fluid polymer, this fluid polymer is from the feeding end of this expects pipe towards this Can be heated and by this microbubble generating element during the direction flowing of the discharge end of expects pipe Porous portion is plugged, and now can inject a foaming liquid using this liquid transfer element in this expects pipe, So that this foaming liquid is mixed with this fluid polymer and be heated together in flow process, connect This micro-bubble generation device of startup to inject a pressure-air in one air flue of this expects pipe, make this high pressure Air is heated along during the flowing of this air flue simultaneously, the meeting after completing heating of this gases at high pressure Enter this microbubble generating element from the air flue of this expects pipe, in the porous by this microbubble generating element Multiple microbubbles can be produced in this expects pipe, these microbubbles can pass through the rotation of this conveying screw rod behind portion And mixed with this fluid polymer, additionally, this foaming liquid can be because heating in flow process Relation and gradually gasify, multiple microbubbles can be produced in this fluid polymer after gasification, both The product with good foaming effect can be obtained under being collocated with each other.
Brief description
Fig. 1 is the schematic flow sheet of the present invention the 1st embodiment;
Fig. 2 is the structural plan figure of the micro-bubble generation device of the present invention the 1st embodiment;
Fig. 3 is the schematic flow sheet of the present invention the 2nd embodiment;
Fig. 4 is the structural representation of the present invention the 3rd embodiment, and main display check ring is resisted against conveying State during the block ring portion of screw rod;
Fig. 5 is analogous to Fig. 4, and main display check ring is in the state of the block ring portion departing from conveying screw rod;
Fig. 6 is the structural representation of the present invention the 4th embodiment;
Fig. 7 is the structural representation of the present invention the 5th embodiment;
Fig. 8 is the structural representation of the present invention the 6th embodiment.
【Symbol description】
10 shape machine
12 fluid polymers
14 moulds
16 arrival ends
20 expects pipes
21 feeding ends
22 discharge ends
23 air flues
30 heaters
40 conveying screw rods
42 air flues
44 block ring portions
50 micro-bubble generation devices
51 pressurized cylinder
52 air reservoirs
53 electric heating pieces
54 microbubble generating elements
542 porous portion
55 fixed seats
552 runners
56 static mixers
57 retainer ring
58 check rings
59 pipelines
60 liquid transfer element
Specific embodiment
Please referring initially to Fig. 6, the processing method of the present invention is to shape machine 10 to execute through one, front State the machine of shaping 10 to be extrusion shaper in the present embodiment and include an expects pipe 20, a heating Device 30, a conveying screw rod 40, heater 30 is installed in the outer peripheral edge of expects pipe 20, in order to by solid Polymer melted becomes fluid polymer 12, conveying screw rod 40 in expects pipe 20, in order to fluid to be gathered Compound 12 pushes toward the direction of a mould 14, additionally, as shown in Fig. 2 aforementioned shape machine 10 There is a micro-bubble generation device 50, this micro-bubble generation device 50 can be air compressor or its His equivalent air pressurized equipment, in the present embodiment this micro-bubble generation device 50 there is a pressurization Cylinder 51, an air reservoir 52, multiple electric heating piece 53, and multiple microbubble generating element 54, pressurization Cylinder 51 is used for increasing the pressure of the air from extraneous injection, and air reservoir 52 connects pressurized cylinder 51, is used for Air after storage pressurization, electric heating piece 53 is installed in the outer peripheral edge of air reservoir 52, in order to air reservoir Air stored by 52 is heated, and microbubble generating element 54 is connected to air reservoir 52, in order to defeated Go out a high pressure-temperature air.Additionally, the material of microbubble generating element 54 porous portion 542 can be The mixture of metal, pottery or metal and pottery, here is not especially limited, in the present invention the In 1 embodiment, each microbubble generating element 54 is arranged on an arrival end 142 of mould 14 and has One stretches into the porous portion 542 in mould 14.
Referring again to Fig. 1, the processing method of the present invention the 1st embodiment includes the following step:
Step a):Drive conveying screw rod 40 to push to fluid polymer 12 in mould 14, work as stream Body polymer 12 can be inserted by the porous portion 542 of microbubble generating element 54 after flowing in mould 14 If.
Step b):Start micro-bubble generation device 50 to produce pressure high temperature hot gas, work as high pressure-temperature Gas can produce after the porous portion 542 by microbubble generating element 54 in fluid polymer 12 Multiple microbubbles, these microbubbles can be mixed with entering the fluid polymer 12 in mould 14, The polymeric articles with good foaming effect can be obtained after cooling.
Referring again to Fig. 3, the processing method of the present invention the 2nd embodiment can using extrusion shaper or Emission forming machine, to execute, is with the difference of aforementioned 1st embodiment that each microbubble produces in structure Element 54 is arranged in a fixed seat 55 in an inclined manner, fixed seat 55 between conveying screw rod 40 with Between mould 14 and there is a runner 552 pass through for fluid polymer 12, microbubble generating element 54 There is a porous portion 542 stretching in runner 552, thus, each microbubble generating element 54 is produced Raw microbubble can be injected in fluid polymer 12 in the way of low pressure, additionally, microbubble produces dress Put 50 and have more a static mixer 56, static mixer 56 is arranged on the runner 552 of fixed seat 55 And between microbubble generating element 54 and mould 14, in order to make microbubble and fluid polymer 12 Between can smoothly mix.From the foregoing, under the processing method of the present invention the 2nd embodiment includes Row step:
Step a):Conveying screw rod 40 is driven to push fluid polymer 12, when fluid polymer 12 flows into Can be plugged by the porous portion 542 of microbubble generating element 54 during the runner 552 of fixed seat 55, connect Reinject in mould 14 after the runner 552 by fixed seat 55.
Step b):Start micro-bubble generation device 50 to produce pressure high temperature hot gas, work as high pressure-temperature Gas can produce after the porous portion 542 by microbubble generating element 54 in fluid polymer 12 Multiple microbubbles, then pass through static mixer 56 allow these microbubbles can with enter in air stream enter runner 552 Fluid polymer 12 be sufficiently mixed, can obtain having good after entering mould 14 and being cooled down The polymeric articles of foaming effect.
Refer to Fig. 4, the processing method of the present invention the 3rd embodiment is to execute using extrusion shaper, It is each microbubble generating element 54 with radially in structure with the difference of the aforementioned 1st, the 2nd embodiment Mode is arranged in a retainer ring 57, and retainer ring 57 is arranged on the front end of conveying screw rod 40, and, The porous portion 542 of each microbubble generating element 54 projects on the surface of conveying screw rod 40, additionally, respectively Microbubble generating element 54 jointly connects an air compressor (not shown) and forms microbubble Generator 50, and it is provided with a static mixer 56 in this conveying screw rod 40 front end, from the foregoing, The processing method of the present invention the 3rd embodiment includes the following step:
Step a):Drive conveying screw rod 40 to push fluid polymer 12, make fluid polymer 12 in stream Plugged by the porous portion 542 of microbubble generating element 54 during dynamic.
Step b):The air compressor starting micro-bubble generation device 50 will be defeated for a pressure-air injection Send in an air flue 42 of screw rod 40, make pressure-air along air flue 42 flowing during simultaneously by Heater 30 is heated.
Step c):Gases at high pressure can enter gas in a subtle way from the air flue 42 of conveying screw rod 40 after completing to heat Bubble generating element 54, then can produce many after the porous portion 542 by microbubble generating element 54 Individual microbubble so that these microbubbles can by the rotation of conveying screw rod 40 with fluid polymer 12 Mixed and further can be upon mixing again via this static mixer again mixed Close.
On the other hand, the front end of conveying screw rod 40 has the block ring portion 44 that a neighbour is located at retainer ring 57 On, and the front end of conveying screw rod 40 is arranged with a check ring 58, as shown in figure 5, working as conveying screw rod 40 start rotation when carrying out storing, and check ring 58 can depart from the block ring portion 44 of conveying screw rod 40, Make to be stored into, in expects pipe 20, the volume being large enough to hold pressure high temperature hot gas and fluid polymer 12, During in project fluid polymer 12 to mould 14, check ring 58 can be resisted against conveying In the block ring portion 44 of screw rod 40, make fluid polymer 12 will not adverse current and can avoid microbubble produce The porous portion 542 of raw element 54 produced tiny molecule when height injects by pressure by fluid polymer 12 Blocked.
Refer to Fig. 6, be to be held using extrusion shaper in the processing method of the present invention the 4th embodiment OK, the difference of foregoing embodiments is that microbubble generating element 54 is arranged on expects pipe 20 in structure A discharge end 22 and the porous portion 542 of microbubble generating element 54 stretch in expects pipe 20, additionally, Each microbubble generating element 54 jointly connects an air compressor (not shown) and forms micro- gas Bubble generator 50.The processing method of the present invention the 4th embodiment includes the following step:
Step a):Conveying screw rod 40 is driven to push fluid polymer 12, fluid polymer 12 is from expects pipe 20 feeding end 21 can be by heater 30 towards during the direction flowing of the discharge end 22 of expects pipe 20 Heated and plugged by the porous portion 542 of microbubble generating element 54.
Step b):Pressure-air is injected expects pipe by the air compressor starting micro-bubble generation device 50 In 20 air flue 23, make pressure-air simultaneously by heater along during air flue 23 flowing 30 are heated.
Step c):Gases at high pressure can enter via a pipeline 59 from the air flue of expects pipe 20 after completing to heat Enter microbubble generating element 54, then meeting after the porous portion 542 by microbubble generating element 54 Produce multiple microbubbles, these microbubbles can be gathered with fluid in the rotary course of conveying screw rod 40 Compound 12 is mixed.
On the other hand, micro-bubble generation device 50 has more a liquid transfer element 60, and liquid conveys Element 60 is arranged on a feeding end 21 of expects pipe 20 and stretches in expects pipe 20, thus, in aforementioned step Rapid a) in, using liquid transfer element 60 to injection one foaming liquid in expects pipe 20, allow foaming liquid Mixed with fluid polymer 12 and heated by heater 30 together in flow process, when send out Bubble liquid can produce multiple microbubbles after gasification in fluid polymer 12, and these microbubbles can To coordinate microbubble produced by microbubble generating element 54 to allow polymeric articles have good sending out Bubble effect.
Here it should be added that, as shown in Figures 7 and 8, microbubble generating element 54 with Liquid transfer element 60 is not necessarily intended to arrange simultaneously, can arrange one of according to actual needs, It is illustrated in figure 6 microbubble generating element 54 to arrange with liquid transfer element 60 simultaneously, and Fig. 7 institute It is shown as only arranging microbubble generating element 54, shown in Fig. 8 then for setting liquid transfer element 60 no The state of setting microbubble generating element 54, however, being any setting, micro- produced by both Bubble can allow polymeric articles have good foaming effect, certainly to arrange the side of two simultaneously Formula can reach optimized effect.
Particular embodiments described above, is carried out to the purpose of the present invention, technical scheme and beneficial effect Further describe it should be understood that the foregoing is only the specific embodiment of the present invention, It is not limited to the present invention, all any modifications within the spirit and principles in the present invention, made, Equivalent, improvement etc., should be included within the scope of the present invention.

Claims (10)

1. a kind of processing method producing microbubble using the machine that shapes in polymer, this processing Forming machine includes a conveying screw rod and a micro-bubble generation device, and this micro-bubble generation device has one Microbubble generating element, this microbubble generating element is arranged on a mould and has one and stretch to this mould Interior porous portion, this processing method includes the following step:
A) drive this conveying screw rod to push to a fluid polymer in this mould, so that this fluid is gathered Compound is plugged by the porous portion of this microbubble generating element;And
B) start this micro-bubble generation device to produce pressure high temperature hot gas, this high pressure-temperature gas Body can produce multiple microbubbles after the porous portion by this microbubble generating element, makes this most micro- gas Bubble is mixed with entering the fluid polymer in this mould.
2. produce adding of microbubble in polymer using the machine that shapes as claimed in claim 1 Work method, wherein this micro-bubble generation device have more a pressurized cylinder, the gas storage of this pressurized cylinder of connection Cylinder, and an electric heating piece being sticked on this air reservoir, this microbubble generating element is connected to this gas storage Cylinder.
3. produce adding of microbubble in polymer using the machine that shapes as claimed in claim 1 Work method, wherein this mould have an arrival end, and this microbubble generating element is adjacent to entering of this mould Mouth end.
4. a kind of processing method producing microbubble using the machine that shapes in polymer, this processing Forming machine includes a conveying screw rod and a micro-bubble generation device, and this micro-bubble generation device has one Fixed seat and a microbubble generating element, this fixed seat, should between this conveying screw rod and a mould Microbubble generating element is arranged in this fixed seat and has a porous portion stretching in this runner, should Processing method includes the following step:
A) drive this conveying screw rod to push a fluid polymer, make this fluid polymer flow into this solid Plugged by the porous portion of this microbubble generating element after one runner of reservation;And
B) start this micro-bubble generation device to produce pressure high temperature hot gas, this high pressure-temperature gas Body can produce how several microbubble after the porous portion by this microbubble generating element, makes this how several Microbubble is mixed with entering the fluid polymer in this runner.
5. produce adding of microbubble in polymer using the machine that shapes as claimed in claim 4 Work method, wherein this micro-bubble generation device have more a static mixer, and this static mixer is installed In the runner of fixed seat and between this microbubble generating element and this mould, in order in step b) In allow this most microbubble and this fluid polymer to be sufficiently mixed.
6. produce adding of microbubble in polymer using the machine that shapes as claimed in claim 4 Work method, wherein this micro-bubble generation device have more a pressurized cylinder, the gas storage of this pressurized cylinder of connection Cylinder, and an electric heating piece being sticked on this air reservoir, this microbubble generating element is connected to this gas storage Cylinder.
7. a kind of processing method producing microbubble using the machine that shapes in polymer, this processing Forming machine includes a conveying screw rod and a micro-bubble generation device, and this micro-bubble generation device has one Retainer ring and a microbubble generating element, this retainer ring is arranged on the front end of this conveying screw rod, this micro- gas Bubble generating element is arranged in this retainer ring and has a porous portion, and this porous portion protrudes from this conveying spiral shell The surface of bar, this processing method includes the following step:
A) drive this conveying screw rod to push a fluid polymer, so that this polymerizable fluid portion is being flowed over Plugged by the porous portion of this microbubble generating element in journey;
B) start the air flue that a pressure-air is injected this conveying screw rod by this micro-bubble generation device, So that this pressure-air is heated along during the flowing of this air flue simultaneously;And
C) this gases at high pressure can enter this microbubble from the air flue of this conveying screw rod after completing to heat Generating element, then can produce multiple microbubbles after the porous portion by this microbubble generating element, The plurality of microbubble is mixed with this fluid polymer by the rotation of this conveying screw rod.
8. produce adding of microbubble in polymer using the machine that shapes as claimed in claim 7 The front end of work method, wherein this conveying screw rod has a block ring portion being adjacent to this retainer ring, should add Work forming machine has a check ring, and this check ring is axially displaceably set in the front end of this conveying screw rod, This check ring is resisted against this block ring portion and departs from this block ring portion in storing in material feeding.
9. a kind of processing method producing microbubble using the machine that shapes in polymer, this processing Forming machine includes an expects pipe, a conveying screw rod and a micro-bubble generation device, and this expects pipe has one and enters Material end and a discharge end, in this expects pipe, it is micro- that this micro-bubble generation device has one to this conveying screw rod Bubble generating element, this microbubble generating element is arranged on the discharge end of this expects pipe and has and stretch into this Porous portion in expects pipe, this processing method includes the following step:
A) this conveying screw rod is driven to push a fluid polymer, this fluid polymer is from this expects pipe Feeding end can be heated and by this microbubble towards during the direction flowing of the discharge end of this expects pipe The porous portion of generating element is plugged;
B) start this micro-bubble generation device and one pressure-air injected in an air flue of this expects pipe, So that this pressure-air is heated along during the flowing of this air flue simultaneously;And
C) this gases at high pressure can enter this microbubble from the air flue of this expects pipe after completing to heat and produce Element, then can produce multiple microbubbles after the porous portion by this microbubble generating element so that The plurality of microbubble can be mixed with this fluid polymer by the rotation of this conveying screw rod.
10. produce adding of microbubble in polymer using the machine that shapes as claimed in claim 9 Work method, wherein this micro-bubble generation device have more a liquid transfer element, this liquid transfer element It is arranged on the feeding end of this expects pipe, in step a), noted in this expects pipe using this liquid transfer element Enter a foaming liquid, this foaming liquid mixed with this fluid polymer and in flow process together Heated, make this foaming liquid can produce multiple microbubbles after gasification in this fluid polymer.
CN201510512783.6A 2015-08-19 2015-08-19 The processing method of microbubble is generated in polymer using the machine that shapes Active CN106466901B (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1864981A (en) * 2004-12-28 2006-11-22 约伯佛克斯·难得怀德股份有限公司 Method for controlling microscopic bubble nucleation in fluid polymer material production and its apparatus
CN102126274A (en) * 2011-04-19 2011-07-20 北京化工大学 Micro-foaming injection-molding screw rod
CN103042647A (en) * 2012-11-08 2013-04-17 江苏微赛新材料科技有限公司 Method for producing polypropylene micro-porous foamed thick board

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1864981A (en) * 2004-12-28 2006-11-22 约伯佛克斯·难得怀德股份有限公司 Method for controlling microscopic bubble nucleation in fluid polymer material production and its apparatus
CN102126274A (en) * 2011-04-19 2011-07-20 北京化工大学 Micro-foaming injection-molding screw rod
CN103042647A (en) * 2012-11-08 2013-04-17 江苏微赛新材料科技有限公司 Method for producing polypropylene micro-porous foamed thick board

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