CN106436333A - Ageing-resistant and corrosion-resistant coated anti-slip mat and preparation method - Google Patents

Ageing-resistant and corrosion-resistant coated anti-slip mat and preparation method Download PDF

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Publication number
CN106436333A
CN106436333A CN201610757208.7A CN201610757208A CN106436333A CN 106436333 A CN106436333 A CN 106436333A CN 201610757208 A CN201610757208 A CN 201610757208A CN 106436333 A CN106436333 A CN 106436333A
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coating
pvc
base fabric
resistant
plasticizing
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CN106436333B (en
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陈连星
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Zhejiang Feihu New Material Co Ltd
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Zhejiang Feihu New Material Co Ltd
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0015Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
    • D06N3/0036Polyester fibres
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    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02Organic and inorganic ingredients
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    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
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    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
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    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
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    • C08K3/26Carbonates; Bicarbonates
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/04Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C09D127/06Homopolymers or copolymers of vinyl chloride
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
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    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
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    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0063Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
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    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/007Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by mechanical or physical treatments
    • D06N3/0077Embossing; Pressing of the surface; Tumbling and crumbling; Cracking; Cooling; Heating, e.g. mirror finish
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    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0086Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique
    • D06N3/0088Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique by directly applying the resin
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    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/06Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyvinylchloride or its copolymerisation products
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    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
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    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
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    • D06N2209/00Properties of the materials
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    • D06N2209/103Resistant to mechanical forces, e.g. shock, impact, puncture, flexion, shear, compression, tear
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    • D06N2209/10Properties of the materials having mechanical properties
    • D06N2209/106Roughness, anti-slip, abrasiveness
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    • D06N2213/00Others characteristics
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Abstract

The invention provides an ageing-resistant and corrosion-resistant coated anti-slip mat and a preparation method. The ageing-resistant and corrosion-resistant coated anti-slip mat comprises a basic fabric, wherein the basic fabric is formed by weaving high-tenacity polyester filaments, the upper surface of the basic fabric is coated with an upper coating, the upper coating is provided with concave-convex lines or concave-convex points, the lower surface of the basic fabric is coated with a lower coating, the upper coating and the lower coating are made from an environmentally friendly sizing agent, the environmentally friendly sizing agent uses a PVC paste resin as a main raw material, and an environmentally friendly plasticizer, a filling agent and a chemical additive containing not heavy metal are added as auxiliary materials. An anti-slip concave-convex patterned roll device comprises a rack, wherein the rack comprises a worktable and a base, a pair of movable supports is arranged on the base, a heating roll and a patterned roll are arranged above the worktable, the heating roll comprises a heat conducting pipe and a heating body, the heating body is coaxially arranged in the heat conducting pipe in a gapped mode, each movable support is provided with a rotary support, the rotary supports are connected with the movable supports through rotary bearings, and the heating roll and the patterned roll are rotatably connected to the two rotary supports respectively.

Description

Ageing-resistant corrosion-resistant coating slipmat and preparation method
Technical field
The invention belongs to chemical technology field, relate to a kind of Ageing-resistant corrosion-resistant coating slipmat and preparation method.
Background technology
In daily life, in order to prevent the apparatus of placing objects from making to be put because being moved by external force, shake or shaking Object slide, roll or fall, people can use various slipmat to be also referred to as sliding-proof pad, and it divides according to function:Main Preventing mobile phone skidding to be had, skid-proof pad of vehicles, bath mat, Antiskid pad for stairs, Yoga slipmat, carpet skid pad, tool box Slipmat, cup slipmat etc..It divides according to material:Mainly having rubber antiskid pad, PVC slipmat, PU slipmat, AB glue is prevented Skidding, silica-gel antiskid pad, magic power glue slipmat etc..
But, for existing slipmat, generally have that tearing resistance is low, the easy problem such as aging, perishable, service life Low, it is impossible to meet long-term use and require.And the production technology for existing slipmat is also to there is many deficiencies, such as The interpolation of benzene-like compounds is unfavorable for environmental protection and health, so replacing benzene-like compounds with other nontoxic materials, so that anti- Using of skidding is more healthy to the life of people.
Content of the invention
It is an object of the invention to there are the problems referred to above for existing technology, it is proposed that a kind of Ageing-resistant corrosion-resistant coating is prevented Skidding, has the performances such as durable, waterproof, corrosion-resistant, anti-skidding, disclosure satisfy that Hyundai Motor mat, kitchen antiskid pad, bathroom are used The domain requirements such as pad, maritime affairs operation use.
The purpose of the present invention can be realized by following technical proposal:
Ageing-resistant corrosion-resistant coating slipmat, including base fabric, base fabric is formed by high tenacity polyester filament weaving, the upper surface of base fabric Being coated with coating, upper coating is provided with concave convex texture or sags and crests, and the lower surface of base fabric is coated with lower coating, upper coating and lower painting Layer all uses environment-friendly size, and environment-friendly size, with PVC paste resin as main material, adds environment-friendlyplasticizer plasticizer, filler and do not contains The chemical assistant of heavy metal is auxiliary material.
It is noted that it is base fabric that the present invention selects the woven woven fabric of high tenacity polyester fiber silk, use special braiding Density, is effectively improved the tearing resistance of coated fabric, overcomes the defects such as low, the poor durability of old product tearing resistance.At base Coating on cloth forms upper coating and lower coating, further increases product strength, arranges concave convex texture and concavo-convex in upper coating Point can improve the grasp force on this slipmat surface, improves coefficient of friction so that different from conventional coating material, thus realizes Skidproof effect.In addition the improvement to the formula of size of coating, overcomes not anti-skidding, corrosion-resistant of conventional coating products etc. no Foot, this slipmat has environmental protection, the excellent properties such as ageing-resistant, corrosion-resistant and anti-skidding, disclosure satisfy that Hyundai Motor mat, kitchen The demand in the fields such as slipmat, bathroom pad, maritime affairs operation use.
In above-mentioned Ageing-resistant corrosion-resistant coating slipmat, base fabric is by the woven anti-wicking screen cloth of high tenacity polyester filament.
In above-mentioned Ageing-resistant corrosion-resistant coating slipmat, environment-friendly size includes the component of following weight portion:60~100 Part foaming special PVC sticks with paste resin;80~120 parts of plasticizer;1~10 part of stabilizer;10~20 parts of foaming agents;30~90 parts fire-retardant Agent;40~80 parts of fillers;10~40 parts of PB-1000;5~20 parts of XP-140;5~20 parts of PSM-31;5~20 parts of PR-415.
In above-mentioned Ageing-resistant corrosion-resistant coating slipmat, plasticizer is DINP, and stabilizer is potassium zinc, and foaming agent is AC-5000, filler is the powdered whiting of 800 mesh.
In above-mentioned Ageing-resistant corrosion-resistant coating slipmat, fire retardant include 10~30 parts of antimony oxides, 20~50 Part aluminium hydroxide and 1~10 part of DPK.
In above-mentioned Ageing-resistant corrosion-resistant coating slipmat, environment-friendly size also includes 1~15 part of colorant.
In above-mentioned Ageing-resistant corrosion-resistant coating slipmat, upper coating includes applying the upper PVC being formed in base fabric front one The first, layer two applies the upper layer of PVC three that the upper layer of PVC two and three being formed applies formation, and upper layer of PVC one is attached to the upper surface of base fabric, on Layer of PVC two is attached to layer of PVC one, and upper layer of PVC three is attached to layer of PVC two.
In above-mentioned Ageing-resistant corrosion-resistant coating slipmat, lower coating includes applying, at base fabric reverse side one, the lower PVC being formed The first, layer two applies the lower layer of PVC three that the lower layer of PVC two and three being formed applies formation, and lower layer of PVC one is attached to the lower surface of base fabric, under Layer of PVC two is attached to lower layer of PVC one, and lower layer of PVC three is attached to lower layer of PVC two.
Another object of the present invention is to there are the problems referred to above for existing technology, it is proposed that a kind of Ageing-resistant corrosion-resistant The preparation method of coating slipmat, the slipmat integraty prepared by the method is strong, and resistance to extent of exfoliation is high, environmental friendliness and no harm.
The purpose of the present invention can be realized by following technical proposal:
The preparation method of a kind of Ageing-resistant corrosion-resistant coating slipmat, comprises the following steps:
1) woven base fabric:Use high tenacity polyester filament woven base fabric;
2) environment-friendly size is prepared:Weigh each raw material in slurry each ingredients weight parts ratio, then put in mixing container, stir Mix mixing 10~30 minutes, obtain environment-friendly size;
3) front surface coated process:Using one group of heated steel roll flatiron base fabric, preheating base fabric, preheating temperature is 100 ~150 DEG C, after preheating sending base fabric on coating machine, through scraper at the front surface coated slurry of base fabric, slurry viscosity is 20000CPS;Sending into after coating in baking oven and drying and plasticizing, oven temperature is 180~190 DEG C, forms upper layer of PVC one after plasticizing;
4) reverse side coating processing:Sending base fabric on coating machine, coating slurry through scraper at base reverse of the cloth, slurry glues Degree is 20000CPS;Sending into after coating in baking oven and drying and plasticizing, oven temperature is 180~190 DEG C, forms lower PVC after plasticizing Layer one;
5) front second time coating processing:Base fabric is sent on coating machine, through roller cutter at the front surface coated slurry of base fabric, Slurry viscosity is 6000CPS, and coated weight is 0.3~0.35mm;Sending into after coating in baking oven and drying and plasticizing, oven temperature is 160~180 DEG C, after plasticizing, form upper layer of PVC two;
6) reverse side second time coating processing:Base fabric is sent on coating machine, coats slurry through roller cutter at base reverse of the cloth, Slurry viscosity is 6000CPS, and coated weight is 0.3~0.35mm;Sending into after coating in baking oven and drying and plasticizing, oven temperature is 160~180 DEG C, after plasticizing, form upper layer of PVC two;
7) reverse side third time coating processing:Base fabric is sent on coating machine, coats slurry through roller cutter at base reverse of the cloth, Slurry viscosity is 6000CPS, and coated weight is 4~4.5mm;Sending into after coating in baking oven and drying and plasticizing, oven temperature is:First Gradient is 220 DEG C, the second gradient is 220 DEG C, the 3rd gradient is 230 DEG C, forms lower layer of PVC three after plasticizing;
8) front third time coating processing:Base fabric is sent on coating machine, through roller cutter at the front surface coated slurry of base fabric, Slurry viscosity is 6000CPS, and coated weight is 4~4.5mm;Sending into after coating in baking oven and drying and plasticizing, oven temperature is:First Gradient is 200 DEG C, the second gradient is 210 DEG C, the 3rd gradient is 220 DEG C, uses anti-skidding ridge design roller arrangement to it during plasticizing Roll-in, forms upper layer of PVC three after plasticizing;
9) cool down:Use one group of chill roll to carry out roll-in, after cooling, obtain Ageing-resistant corrosion-resistant coating slipmat.
In the preparation method of above-mentioned Ageing-resistant corrosion-resistant coating slipmat, anti-skidding ridge design roller arrangement includes machine Frame, frame includes workbench and base, and base is provided with a pair traversing carriage, and workbench is between two traversing carriages, work Platform is arranged over a heating roller and a patterned roll, and the surface of patterned roll is provided with ridge design or sags and crests;Heating roller bag Including heat pipe and calandria, calandria gap coaxially is arranged in heat pipe;It is respectively equipped with a rotation on each traversing carriage Turning support, runing rest is connected with traversing carriage by floating bearing, and heating roller and patterned roll are rotationally connected with two rotations respectively Turn support, and heating roller and patterned roll spacing predeterminable range;Base has two rectilinear orbits corresponding with traversing carriage, each Being provided with Timing Belt in rectilinear orbit, Timing Belt is connected with motor one transmission, and the bottom of traversing carriage is provided with slide block, slide block and synchronization Band is connected;Floating bearing includes bearing inner race and bearing outer ring, and bearing outer ring is fixed with traversing carriage, and bearing inner race props up with rotating Frame is fixed, and bearing inner race has internal gear, and bearing inner race is equipped with gear shaft, and bearing inner race is connected with gear shaft tooth, gear shaft It is connected with motor two transmission.
Compared with prior art, the present invention has the advantage that:
The slipmat that the present invention produces has fabulous stretching, tearing strength and peel load, has preferably anti-skidding, resistance to By property, anticorrosion, acid and alkali-resistance and environmental protection feature, overcome conventional old product not environmentally, to the person have potential hazard and The shortcomings such as corrosion-resistant, disclosure satisfy that the fields such as Hyundai Motor mat, kitchen antiskid pad, bathroom pad, maritime affairs operation use Demand.
Brief description
Fig. 1 is the structural representation of the Ageing-resistant corrosion-resistant coating slipmat of the present invention.
Fig. 2 is the structural representation of the anti-skidding ridge design roller arrangement of the present invention.
Fig. 3 is the sectional view of the heating roller of the anti-skidding ridge design roller arrangement of the present invention.
Fig. 4 is the runing rest sectional view of the anti-skidding ridge design roller arrangement of the present invention.
In figure, the 1st, base fabric;2nd, upper layer of PVC one;3rd, upper layer of PVC two;4th, upper layer of PVC three;5th, lower layer of PVC one;6th, lower layer of PVC Two;7th, lower layer of PVC three;8th, workbench;9th, base;10th, traversing carriage;11st, heating roller;12nd, patterned roll;13rd, heat pipe;14、 Calandria;15th, runing rest;16th, rectilinear orbit;17th, slide block;18th, bearing inner race;19th, bearing outer ring;20th, gear shaft;21、 Motor two.
Detailed description of the invention
The following is the specific embodiment of the present invention and combine accompanying drawing, technical scheme is further described, But the present invention is not limited to these embodiments.
As it is shown in figure 1, the invention provides a kind of Ageing-resistant corrosion-resistant coating slipmat, including base fabric 1, base fabric 1 is by height Strong dacron thread weaving forms, and the upper surface of base fabric 1 is coated with coating, and upper coating is provided with concave convex texture or sags and crests, base fabric 1 Lower surface is coated with lower coating, and upper coating and lower coating all use environment-friendly size, environment-friendly size with PVC paste resin as main material, Environment-friendlyplasticizer plasticizer, filler and the chemical assistant without heavy metal is added to be auxiliary material.
It is noted that it is base fabric 1 that the present invention selects the woven woven fabric of high tenacity polyester fiber silk, use special braiding Density, is effectively improved the tearing resistance of coated fabric, overcomes the defects such as low, the poor durability of old product tearing resistance.At base Coating on cloth 1 forms upper coating and lower coating, further increases product strength, arranges concave convex texture and concavo-convex in upper coating Point can improve the grasp force on this slipmat surface, improves coefficient of friction so that different from conventional coating material, thus realizes Skidproof effect.In addition the improvement to the formula of size of coating, increases environment-friendlyplasticizer plasticizer and the various chemistry without heavy metal helps Agent etc. so that this slipmat has fabulous stretching, tearing strength and peel load, have preferable durability, anticorrosion, resistance to Soda acid and environmental protection feature, overcoming conventional old product not environmentally, to the person has potential hazard and corrosion-resistant etc. to lack Point.This slipmat has environmental protection, the excellent properties such as ageing-resistant, corrosion-resistant and anti-skidding, disclosure satisfy that Hyundai Motor mat, kitchen The demand in the fields such as slipmat, bathroom pad, maritime affairs operation use.
Preferably, base fabric 1 is by the woven anti-wicking screen cloth of high tenacity polyester filament, has fungicidal properties.
Specifically, environment-friendly size includes the component of following weight portion:60~100 parts of foaming special PVCs stick with paste resin;80~ 120 parts of plasticizer;1~10 part of stabilizer;10~20 parts of foaming agents;30~90 parts of fire retardants;40~80 parts of fillers;10~40 Part PB-1000;5~20 parts of XP-140;5~20 parts of PSM-31;5~20 parts of PR-415.
Further, plasticizer is DINP, and stabilizer is potassium zinc, and foaming agent is AC-5000, and filler is the weight of 800 mesh Matter calcium carbonate.
Further, fire retardant includes 10~30 parts of antimony oxides, 20~50 parts of aluminium hydroxides and 1~10 part of DPK.Logical Cross the proportioning mixing of three kinds of fire retardants, make this slipmat have excellent fire resistance, improve safety coefficient.
Selectively, environment-friendly size also includes 1~15 part of colorant, make this slipmat possess color.
Specifically, upper coating includes that applying the upper layer of PVC one 2, two being formed in base fabric 1 front one applies the upper layer of PVC 23 being formed Applying, with three, the upper layer of PVC 34 being formed, upper layer of PVC 1 is attached to the upper surface of base fabric 1, and upper layer of PVC 23 is attached to layer of PVC One 2, upper layer of PVC 34 is attached to layer of PVC 23.Base fabric 1 front is the upper surface side of the above-mentioned base fabric 1 mentioned, Three times, base fabric 1 front coating slurry, sequentially forms layer of PVC 1, upper layer of PVC 23 and upper layer of PVC 34, and upper coating plays anti- The concave convex texture of sliding effect or sags and crests are formed at layer of PVC 34.
Specifically, lower coating includes that applying, at base fabric 1 reverse side one, the lower layer of PVC one 5, two being formed applies the lower layer of PVC 26 being formed Applying, with three, the lower layer of PVC 37 being formed, lower layer of PVC 1 is attached to the lower surface of base fabric 1, and lower layer of PVC 26 is attached to lower layer of PVC One 5, lower layer of PVC 37 is attached to lower layer of PVC 26.Base fabric 1 reverse side is the lower surface side of the above-mentioned base fabric 1 mentioned, Three coating slurries of base fabric 1 reverse side, sequentially form lower layer of PVC 1, lower layer of PVC 26 and lower layer of PVC 37.
Embodiment one
The preparation method of a kind of Ageing-resistant corrosion-resistant coating slipmat, comprises the following steps:
1) woven base fabric 1:Use high tenacity polyester filament woven base fabric 1;
2) environment-friendly size is prepared:Weigh each raw material in slurry each ingredients weight parts ratio, then put in mixing container, stir Mix mixing 15 minutes, obtain environment-friendly size;
Environment-friendly size includes the component of following weight portion:
3) front surface coated process:Using one group of heated steel roll flatiron base fabric 1, preheating base fabric 1, preheating temperature is 100 DEG C, after preheating sending base fabric 1 on coating machine, through scraper at the front surface coated slurry of base fabric 1, slurry viscosity is 20000CPS;Sending into after coating in baking oven and drying and plasticizing, oven temperature is 180 DEG C, forms upper layer of PVC 1 after plasticizing;
4) reverse side coating processing:Base fabric 1 is sent on coating machine, coats slurry, slurry through scraper at the reverse side of base fabric 1 Viscosity is 20000CPS;Sending into after coating in baking oven and drying and plasticizing, oven temperature is 180 DEG C, forms lower layer of PVC one after plasticizing 5;
5) front second time coating processing:Base fabric 1 is sent on coating machine, starches in the front surface coated of base fabric 1 through roller cutter Material, slurry viscosity is 6000CPS, and coated weight is 0.32mm;Sending into after coating in baking oven and drying and plasticizing, oven temperature is 165 DEG C, form upper layer of PVC 23 after plasticizing;
6) reverse side second time coating processing:Base fabric 1 is sent on coating machine, through roller cutter at the reverse side coating materials of base fabric 1 Material, slurry viscosity is 6000CPS, and coated weight is 0.32mm;Sending into after coating in baking oven and drying and plasticizing, oven temperature is 165 DEG C, form upper layer of PVC 23 after plasticizing;
7) reverse side third time coating processing:Base fabric 1 is sent on coating machine, through roller cutter at the reverse side coating materials of base fabric 1 Material, slurry viscosity is 6000CPS, and coated weight is 4mm;Sending into after coating in baking oven and drying and plasticizing, oven temperature is:First ladder Degree is 220 DEG C, the second gradient is 220 DEG C, the 3rd gradient is 230 DEG C, forms lower layer of PVC 37 after plasticizing;
8) front third time coating processing:Base fabric 1 is sent on coating machine, starches in the front surface coated of base fabric 1 through roller cutter Material, slurry viscosity is 6000CPS, and coated weight is 4mm;Sending into after coating in baking oven and drying and plasticizing, oven temperature is:First ladder Degree is 200 DEG C, the second gradient is 210 DEG C, the 3rd gradient is 220 DEG C, uses anti-skidding ridge design roller arrangement to its roller during plasticizing Pressure, forms upper layer of PVC 34 after plasticizing;
9) cool down:Use one group of chill roll to carry out roll-in, after cooling, obtain Ageing-resistant corrosion-resistant coating slipmat.
Embodiment two
The preparation method of a kind of Ageing-resistant corrosion-resistant coating slipmat, comprises the following steps:
1) woven base fabric 1:Use high tenacity polyester filament woven base fabric 1;
2) environment-friendly size is prepared:Weigh each raw material in slurry each ingredients weight parts ratio, then put in mixing container, stir Mix mixing 20 minutes, obtain environment-friendly size;
Environment-friendly size includes the component of following weight portion:
3) front surface coated process:Using one group of heated steel roll flatiron base fabric 1, preheating base fabric 1, preheating temperature is 120 DEG C, after preheating sending base fabric 1 on coating machine, through scraper at the front surface coated slurry of base fabric 1, slurry viscosity is 20000CPS;Sending into after coating in baking oven and drying and plasticizing, oven temperature is 185 DEG C, forms upper layer of PVC 1 after plasticizing;
4) reverse side coating processing:Base fabric 1 is sent on coating machine, coats slurry, slurry through scraper at the reverse side of base fabric 1 Viscosity is 20000CPS;Sending into after coating in baking oven and drying and plasticizing, oven temperature is 185 DEG C, forms lower layer of PVC one after plasticizing 5;
5) front second time coating processing:Base fabric 1 is sent on coating machine, starches in the front surface coated of base fabric 1 through roller cutter Material, slurry viscosity is 6000CPS, and coated weight is 0.34mm;Sending into after coating in baking oven and drying and plasticizing, oven temperature is 170 DEG C, form upper layer of PVC 23 after plasticizing;
6) reverse side second time coating processing:Base fabric 1 is sent on coating machine, through roller cutter at the reverse side coating materials of base fabric 1 Material, slurry viscosity is 6000CPS, and coated weight is 0.34mm;Sending into after coating in baking oven and drying and plasticizing, oven temperature is 170 DEG C, form upper layer of PVC 23 after plasticizing;
7) reverse side third time coating processing:Base fabric 1 is sent on coating machine, through roller cutter at the reverse side coating materials of base fabric 1 Material, slurry viscosity is 6000CPS, and coated weight is 4.3mm;Sending into after coating in baking oven and drying and plasticizing, oven temperature is:First Gradient is 220 DEG C, the second gradient is 220 DEG C, the 3rd gradient is 230 DEG C, forms lower layer of PVC 37 after plasticizing;
8) front third time coating processing:Base fabric 1 is sent on coating machine, starches in the front surface coated of base fabric 1 through roller cutter Material, slurry viscosity is 6000CPS, and coated weight is 4.3mm;Sending into after coating in baking oven and drying and plasticizing, oven temperature is:First Gradient is 200 DEG C, the second gradient is 210 DEG C, the 3rd gradient is 220 DEG C, uses anti-skidding ridge design roller arrangement to it during plasticizing Roll-in, forms upper layer of PVC 34 after plasticizing;
9) cool down:Use one group of chill roll to carry out roll-in, after cooling, obtain Ageing-resistant corrosion-resistant coating slipmat.
Embodiment three
The preparation method of a kind of Ageing-resistant corrosion-resistant coating slipmat, comprises the following steps:
1) woven base fabric 1:Use high tenacity polyester filament woven base fabric 1;
2) environment-friendly size is prepared:Weigh each raw material in slurry each ingredients weight parts ratio, then put in mixing container, stir Mix mixing 30 minutes, obtain environment-friendly size;
Environment-friendly size includes the component of following weight portion:
3) front surface coated process:Using one group of heated steel roll flatiron base fabric 1, preheating base fabric 1, preheating temperature is 150 DEG C, after preheating sending base fabric 1 on coating machine, through scraper at the front surface coated slurry of base fabric 1, slurry viscosity is 20000CPS;Sending into after coating in baking oven and drying and plasticizing, oven temperature is 190 DEG C, forms upper layer of PVC 1 after plasticizing;
4) reverse side coating processing:Base fabric 1 is sent on coating machine, coats slurry, slurry through scraper at the reverse side of base fabric 1 Viscosity is 20000CPS;Sending into after coating in baking oven and drying and plasticizing, oven temperature is 190 DEG C, forms lower layer of PVC one after plasticizing 5;
5) front second time coating processing:Base fabric 1 is sent on coating machine, starches in the front surface coated of base fabric 1 through roller cutter Material, slurry viscosity is 6000CPS, and coated weight is 0.35mm;Sending into after coating in baking oven and drying and plasticizing, oven temperature is 175 DEG C, form upper layer of PVC 23 after plasticizing;
6) reverse side second time coating processing:Base fabric 1 is sent on coating machine, through roller cutter at the reverse side coating materials of base fabric 1 Material, slurry viscosity is 6000CPS, and coated weight is 0.35mm;Sending into after coating in baking oven and drying and plasticizing, oven temperature is 175 DEG C, form upper layer of PVC 23 after plasticizing;
7) reverse side third time coating processing:Base fabric 1 is sent on coating machine, through roller cutter at the reverse side coating materials of base fabric 1 Material, slurry viscosity is 6000CPS, and coated weight is 4.5mm;Sending into after coating in baking oven and drying and plasticizing, oven temperature is:First Gradient is 220 DEG C, the second gradient is 220 DEG C, the 3rd gradient is 230 DEG C, forms lower layer of PVC 37 after plasticizing;
8) front third time coating processing:Base fabric 1 is sent on coating machine, starches in the front surface coated of base fabric 1 through roller cutter Material, slurry viscosity is 6000CPS, and coated weight is 4.5mm;Sending into after coating in baking oven and drying and plasticizing, oven temperature is:First Gradient is 200 DEG C, the second gradient is 210 DEG C, the 3rd gradient is 220 DEG C, uses anti-skidding ridge design roller arrangement to it during plasticizing Roll-in, forms upper layer of PVC 34 after plasticizing;
9) cool down:Use one group of chill roll to carry out roll-in, after cooling, obtain Ageing-resistant corrosion-resistant coating slipmat.
The liquid macroimolecule polymer that human non-toxic is harmless is made slurry with multicomponent by the present invention, uses coating technology, Slipmat is made to have excellent tolerance and Reusability.Tow sides in base fabric 1 directly coat spreading mass, dry plasticizing After make whole non-slip mat structure integraty strong, peel strength is high, improves service life.At base fabric 1 front third time coating materials After material, in plasticizing process, carry out roll-in by anti-skidding ridge design roller arrangement, not only act as uniform and balanced action, Er Qiehua Line roller 12 is provided with sags and crests, forms sags and crests, thus play anti-skidding effect after can making slurry sizing.
As in figure 2 it is shown, anti-skidding ridge design roller arrangement includes frame, frame includes workbench 8 and base 9, and base 9 sets Having a pair traversing carriage 10, workbench 8 is between two traversing carriages 10, and workbench 8 is arranged over a heating roller 11 and Individual patterned roll 12, the surface of patterned roll 12 is provided with ridge design or sags and crests;Heating roller 11 includes heat pipe 13 and calandria 14, calandria 14 gap coaxially is arranged in heat pipe 13;It is respectively equipped with a runing rest 15 on each traversing carriage 10, Runing rest 15 is connected with traversing carriage 10 by floating bearing, and heating roller 11 and patterned roll 12 are rotationally connected with two rotations respectively Turn support 15, and heating roller 11 and patterned roll 12 spacing predeterminable range.
It is noted that after to the front surface coated third time slurry of base fabric 1, base fabric 1 is sent into baking oven, and at slurry Before not plastifying completely, base fabric 1 is sent to workbench 8, first pass through the coating in heating roller 11 roll-in base fabric 1 front, make base fabric 1 On slurry can be uniform, then by the coating in patterned roll 12 roll-in base fabric 1 front, the ridge design in patterned roll 12 or Sags and crests is formed in the coating, and as the solidification of slurry is shaped, upper layer of PVC 34 surface forming obtained by making goes out accordingly Ridge design or sags and crests, the ridge design in the front of final finished product or sags and crests are obvious especially, thus play anti- Sliding effect.
Specifically, base 9 has two rectilinear orbits 16 corresponding with traversing carriage 10, is provided with in each rectilinear orbit 16 Timing Belt, Timing Belt is connected with motor one transmission, and the bottom of traversing carriage 10 is provided with slide block 17, and slide block 17 is connected with Timing Belt. Under the driving of Timing Belt, traversing carriage 10 can slide on base 9 along rectilinear orbit 16, thus drive patterned roll 12 and Heating roller 11 moves along base fabric 1 length direction.
Floating bearing includes bearing inner race 18 and bearing outer ring 19, and bearing outer ring 19 is fixed with traversing carriage 10, in bearing Circle 18 is fixed with runing rest 15, and bearing inner race 18 has internal gear, and bearing inner race 18 is equipped with gear shaft 20, bearing inner race 18 Being connected with gear shaft 20 tooth, gear shaft 20 is connected with motor 2 21 transmission.
Runing rest 15 realizes rotating under the driving of motor 2 21, and specifically, motor 2 21 is driven by gear shaft 20 Bearing inner race 18 rotates, and bearing inner race 18 rotates and drives runing rest 15 to rotate, thus realizes patterned roll 12 and heating roller 11 Evolution.
During it is noted that patterned roll 12 and heating roller 11 are to base fabric 1 roll-in, base fabric 1 is to be placed on work still In station 8, first runing rest 15 rotates to heating roller 11 and touches with base fabric 1, and now patterned roll 12 is in heating roller 11 It above top or side, is in non-working condition, starts the driving motor of motor one and heating roller 11, make the heating roller 11 can Rolling over the surface of base fabric 1, the temperature of the heat pipe 13 wherein directly touching with the slurry in base fabric 1 is less than its internal heating The temperature of body 14, during hence with heating roller 11 roll-in base fabric 1, will not make slurry promptly solidify, slow down consolidating of slurry Change speed, utilize heating roller 11 roll-in, slurry can be made to be evenly distributed, and by slurry more consolidation can be made after roll-in, Additionally play the shaping of certain heat effect, beneficially ridge design or sags and crests.
Heating roller 11 uses after finishing, and runing rest 15 rotates again, rotates heating roller 11 to the top of base fabric 1 same When, patterned roll 12 is rotated into touching with base fabric 1, and now patterned roll 12 is in use state, and patterned roll 12 rolls over base fabric 1 Surface, so that the ridge design on patterned roll 12 surface or sags and crests on the surface forming of base fabric 1.
Patterned roll 12 uses after finishing, and runing rest 15 rotates again, to revolve heating roller 11 and patterned roll 12 simultaneously Go to the top of base fabric 1, not disturb the solidification of slurry.
The wherein employing lozenge of patterned roll 12, a length of 2.3 meters of patterned roll 12.
The Specifications of Ageing-resistant corrosion-resistant coating slipmat:
1st, fracture strength:(warp/latitude) >=2300N/5cm;
2nd, tearing strength:(warp/latitude) >=220N;
3rd, peel strength: ≥80N/5cm;
4th, ageing-resistant performance:3 years.
Specific embodiment described herein is only explanation for example to present invention spirit.Technology neck belonging to the present invention Described specific embodiment can be made various modification or supplements or use similar mode to replace by the technical staff in territory Generation, but without departing from the spirit of the present invention or surmount scope defined in appended claims.
Although more employing base fabric 1 herein;Upper layer of PVC 1;Upper layer of PVC 23;Upper layer of PVC 34;Lower layer of PVC one 5;Lower layer of PVC 26;Lower layer of PVC 37;Workbench 8;Base 9;Traversing carriage 10;Heating roller 11;Patterned roll 12;Heat pipe 13; Calandria 14;Runing rest 15;Rectilinear orbit 16;Slide block 17;Bearing inner race 18;Bearing outer ring 19;Gear shaft 20;Motor 2 21 It Deng term, but is not precluded from using the possibility of other terms.These terms are used to be only used to describe more easily reconciliation Release the essence of the present invention;It is all contrary with spirit of the present invention for being construed as any additional restriction.

Claims (10)

1. Ageing-resistant corrosion-resistant coating slipmat, it is characterised in that include base fabric, base fabric is formed by high tenacity polyester filament weaving, base The upper surface of cloth is coated with coating, and upper coating is provided with concave convex texture or sags and crests, and the lower surface of base fabric is coated with lower coating, on Coating and lower coating all use environment-friendly size, and environment-friendly size, with PVC paste resin as main material, adds environment-friendlyplasticizer plasticizer, filling Agent and the chemical assistant without heavy metal are auxiliary material.
2. Ageing-resistant corrosion-resistant coating slipmat according to claim 1, it is characterised in that base fabric is by high tenacity polyester filament Woven anti-wicking screen cloth.
3. Ageing-resistant corrosion-resistant coating slipmat according to claim 1, it is characterised in that environment-friendly size includes following heavy The component of amount part:60~100 parts of foaming special PVCs stick with paste resin;80~120 parts of plasticizer;1~10 part of stabilizer;10~20 parts Foaming agent;30~90 parts of fire retardants;40~80 parts of fillers;10~40 parts of PB-1000;5~20 parts of XP-140;5~20 parts PSM-31;5~20 parts of PR-415.
4. Ageing-resistant corrosion-resistant coating slipmat according to claim 3, it is characterised in that plasticizer is DINP is stable Agent is potassium zinc, and foaming agent is AC-5000, and filler is the powdered whiting of 800 mesh.
5. Ageing-resistant corrosion-resistant coating slipmat according to claim 3, it is characterised in that fire retardant includes 10~30 parts Antimony oxide, 20~50 parts of aluminium hydroxides and 1~10 part of DPK.
6. Ageing-resistant corrosion-resistant coating slipmat according to claim 3, it is characterised in that also include 1 in environment-friendly size ~15 parts of colorants.
7. Ageing-resistant corrosion-resistant coating slipmat according to claim 1, it is characterised in that upper coating in base fabric just includes Face one applies the upper layer of PVC being formed and the first, two applies the upper layer of PVC three that upper layer of PVC two and three painting being formed is formed, and upper layer of PVC one is adhered to At the upper surface of base fabric, upper layer of PVC two is attached to layer of PVC one, and upper layer of PVC three is attached to layer of PVC two.
8. Ageing-resistant corrosion-resistant coating slipmat according to claim 1, it is characterised in that lower coating includes in base fabric anti- Face one applies the lower layer of PVC being formed and the first, two applies the lower layer of PVC three that lower layer of PVC two and three painting being formed is formed, and lower layer of PVC one is adhered to At the lower surface of base fabric, lower layer of PVC two is attached to lower layer of PVC one, and lower layer of PVC three is attached to lower layer of PVC two.
9. the preparation method of an Ageing-resistant corrosion-resistant coating slipmat, it is characterised in that be used for preparing claim 1 to 8 times Slipmat described in one claim, comprises the following steps:
1) woven base fabric:Use high tenacity polyester filament woven base fabric;
2) environment-friendly size is prepared:Weighing each raw material in slurry each ingredients weight parts ratio, then putting in mixing container, stirring is mixed Close 10~30 minutes, obtain environment-friendly size;
3) front surface coated process:Using one group of heated steel roll flatiron base fabric, preheating base fabric, preheating temperature is 100~150 DEG C, after preheating, base fabric is sent on coating machine, through scraper at the front surface coated slurry of base fabric, slurry viscosity is 20000CPS; Sending into after coating in baking oven and drying and plasticizing, oven temperature is 180~190 DEG C, forms upper layer of PVC one after plasticizing;
4) reverse side coating processing:Sending base fabric on coating machine, coating slurry through scraper at base reverse of the cloth, slurry viscosity is 20000CPS;Sending into after coating in baking oven and drying and plasticizing, oven temperature is 180~190 DEG C, forms lower layer of PVC one after plasticizing;
5) front second time coating processing:Base fabric is sent on coating machine, through roller cutter at the front surface coated slurry of base fabric, slurry Viscosity is 6000CPS, and coated weight is 0.3~0.35mm;To send into after coating in baking oven and dry and plasticizing, oven temperature is 160~ 180 DEG C, after plasticizing, form upper layer of PVC two;
6) reverse side second time coating processing:Base fabric is sent on coating machine, coats slurry, slurry through roller cutter at base reverse of the cloth Viscosity is 6000CPS, and coated weight is 0.3~0.35mm;To send into after coating in baking oven and dry and plasticizing, oven temperature is 160~ 180 DEG C, after plasticizing, form upper layer of PVC two;
7) reverse side third time coating processing:Base fabric is sent on coating machine, coats slurry, slurry through roller cutter at base reverse of the cloth Viscosity is 6000CPS, and coated weight is 4~4.5mm;Sending into after coating in baking oven and drying and plasticizing, oven temperature is:First gradient Be 220 DEG C, the second gradient be 220 DEG C, the 3rd gradient be 230 DEG C, form lower layer of PVC three after plasticizing;
8) front third time coating processing:Base fabric is sent on coating machine, through roller cutter at the front surface coated slurry of base fabric, slurry Viscosity is 6000CPS, and coated weight is 4~4.5mm;Sending into after coating in baking oven and drying and plasticizing, oven temperature is:First gradient Be 200 DEG C, the second gradient be 210 DEG C, the 3rd gradient be 220 DEG C, use anti-skidding ridge design roller arrangement to its roll-in during plasticizing, Form upper layer of PVC three after plasticizing;
9) cool down:Use one group of chill roll to carry out roll-in, after cooling, obtain Ageing-resistant corrosion-resistant coating slipmat.
10. the preparation method of Ageing-resistant corrosion-resistant coating slipmat according to claim 9, it is characterised in that anti-skidding recessed Convex patterned roll device includes frame, and frame includes workbench and base, and base is provided with a pair traversing carriage, and workbench is in two Between traversing carriage, workbench is arranged over a heating roller and a patterned roll, the surface of patterned roll be provided with ridge design or Person's sags and crests;Heating roller includes heat pipe and calandria, and calandria gap coaxially is arranged in heat pipe;Each traversing carriage On be respectively equipped with a runing rest, runing rest is connected with traversing carriage by floating bearing, and heating roller and patterned roll are distinguished It is rotationally connected with two runing rests, and heating roller and patterned roll spacing predeterminable range;Base has corresponding with traversing carriage Two rectilinear orbits, be provided with Timing Belt in each rectilinear orbit, Timing Belt is connected with motor one transmission, and the bottom of traversing carriage sets Having slide block, slide block is connected with Timing Belt;Floating bearing includes bearing inner race and bearing outer ring, and bearing outer ring is solid with traversing carriage Fixed, bearing inner race is fixed with runing rest, and bearing inner race has internal gear, and bearing inner race is equipped with gear shaft, bearing inner race and Gear shaft tooth connects, and gear shaft is connected with motor two transmission.
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