CN106434063B - A kind of slow released ClO 2 solid soap and preparation method thereof - Google Patents
A kind of slow released ClO 2 solid soap and preparation method thereof Download PDFInfo
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- CN106434063B CN106434063B CN201610808456.XA CN201610808456A CN106434063B CN 106434063 B CN106434063 B CN 106434063B CN 201610808456 A CN201610808456 A CN 201610808456A CN 106434063 B CN106434063 B CN 106434063B
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- solid soap
- slow released
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Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/06—Inorganic compounds
- C11D9/08—Water-soluble compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0034—Fixed on a solid conventional detergent ingredient
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/44—Perfumes; Colouring materials; Brightening agents ; Bleaching agents
- C11D9/442—Perfumes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/44—Perfumes; Colouring materials; Brightening agents ; Bleaching agents
- C11D9/444—Dyes; Pigments
Abstract
The present invention provides a kind of slow released ClO 2 solid soaps and preparation method thereof.A kind of slow released ClO 2 solid soap, is mainly mixed by chlorine dioxide precursor and its activator and solid fat hydrochlorate.Preparation method：According to formula feeding, the fatty acid salt is heated to molten state, is then mixed into remaining raw material, cooling to obtain the final product.The present invention, which solves, is not easy storage transport, and slow release effect is poor, the technical problems such as complex process.
Description
Technical field
The present invention relates to air purification fields, more particularly, to a kind of slow released ClO 2 solid soap and its preparation side
Method.
Background technology
With the quickening of industrialized level, environmental pollution getting worse.Indoor pollutant concentration is typically the 2-5 of outdoor
Again, but the time of 70% or more the mankind is spent indoors, and the time that urban population is spent indoors has been more than 90%, baby children
The time of youngster and the old and the weak handicapped person indoors is longer, therefore keeps the cleaning of room air, removes the pollutant in room air
Influence to health is significant.The method that indoor pollution is administered mainly has bioanalysis, Physical and chemical method.Bioanalysis
Mainly by the photosynthesis of plant or the metabolism of microorganism, air, but its effect very little are purified, auxiliary can only be used as
Effect.Physical is typically the absorption property using activated carbon, adsorbs the harmful substance in air, selection of the method to pollutant
Property is small, at low cost, but belongs to passive adsorption, and activated carbon is easily saturated.Chemical method mainly has photocatalyst method, Chlorine Dioxide Method etc..
Photocatalyst is safe efficient, but its cost is higher, is limited by light.Chlorine dioxide is classified as A1 grades by the World Health Organization (WHO) and disappears
Toxic agent.It, can be by the toxic flavored substance of some in ambient enviroment, such as formaldehyde, benzene homologues, the Ammonia in family with strong oxidizing property
With the equal energy oxygenolysis such as sulphur class stink.
However ClO 2 solution using and transportational process in there are limitations, usually stablized in inertia solution or
Compound or mixture is made in the certain solid matters of person.
CN103931652A discloses following technique：Chlorite is mixed with polymerized monomer and is polymerize, high score is generated
Sub- gel, then mating acidification stick realize slow release effect, the technique is excessively complicated, needs to make two parts product respectively.
CN104719335A discloses following technique：Thickener, sustained release agent, activator are mixed to the load of viscous liquid
Body, then chlorine dioxide precursor compound is placed in carrier, which is not easy to store, transport, and production technology is equally complicated, needs
Two parts product is made respectively.
CN105145626A discloses following technique：Occur that gelling agent, sustained release agent, activation are added in object to chlorine dioxide
The cleanser of gel state is made in agent, filler etc., which is not easy to store, transport, and slow release effect is bad.
In view of this, special propose the present invention.
Invention content
The first object of the present invention is to provide a kind of slow released ClO 2 solid soap, and the solid soap solves not
Easily storage, transport, the technical problems such as slow release effect difference.
The second object of the present invention is to provide the preparation method of the solid soap, and the method and process is simple, easily
In popularization.
In order to solve the above technical problems, the present invention provides following technical schemes：
A kind of slow released ClO 2 solid soap, mainly by chlorine dioxide precursor and its activator and solid fatty acids
Salt mixes.
Existing chlorine dioxide purification product is confined to gel, there are the shelf-life it is short, be not easy storage transport, of high cost
The problems such as.The limitation has been broken in present invention innovation, is fabricated to the form of solid soap base for the first time, has both solved shelf-life, storage fortune
The problem of defeated aspect, but because materials solve the problems, such as extensively it is of high cost.
Further, since during solid fat hydrochlorate is mixed with chlorine dioxide precursor and its activator, one side itself
Crosslinking net resistance structure can be formed, one side fatty acid salt has higher affinity, therefore titanium dioxide with chlorine dioxide precursor
Chlorine precursor is can be uniformly dispersed in the cross-linked structure of soap base, and preferable slow release effect is finally presented.
Chlorine dioxide precursor of the present invention and activator are mating, and the type of chlorine dioxide precursor determines activation
The type of agent, for the purpose of it can release chlorine dioxide.
The type and content of fatty acid salt of the present invention all have a major impact slow release, shelf-life, both can be with
For single compound, or compound, compound are also not limited to the mixture of a variety of fatty acid salts, can also contain it
The accessory ingredient of its non-fat hydrochlorate.Such as：
Preferably, the fatty acid salt is the fatty acid salt of C6~C26, the preferred fatty acid salt of C12~C20, more preferably
Stearate.
Preferably, the fatty acid salt is selected from the vegetable oil of saponification, and the vegetable oil is selected from coconut oil, olive oil, palm
It is one or more in oil, palm-kernel oil, SIMMONDSIA CHINENSIS SEED OIL.
Preferably, the content of the fatty acid salt is 59~99wt%, more preferable 80~90wt%.
Chlorine dioxide precursor of the present invention can select the chlorite and/or chlorate for being easy activation, corresponding
Activator is acid.The type and content of acid influence rate of release.
Preferably, the activator is weak acid, preferably hydrophosphate, metasilicic acid, carbonic acid, organic acid, You Jiduo
It is one or more in first acid；
The organic acid is preferably the organic acid of C1~C6, a kind of or more in more preferable acetic acid, propionic acid, butyric acid
Kind；
The organic multicomponent acid is preferably one or more in citric acid, oxalic acid, tartaric acid.
Preferably, the content of the chlorine dioxide precursor is in terms of chlorine dioxide：1wt%~30wt%, more preferably
5wt%-15wt%；
Preferably, the content of the activator is 0.05-2wt%, more preferable 0.1-1wt%.
Compared with existing product, solid soap of the invention still had higher chlorine dioxide rate of release at 30 days, released
It is 30-80 days, preferably 50-80 days to put time of the rate more than 150 μ g/h.
Preferably, essence and/or edible coloring agent are also contained in raw material.Essence, edible coloring agent according to consumer groups come
Selection keeps less additive amount as possible, the feature for keeping solid soap original, safe and harmless.
The manufacture craft of slow released ClO 2 solid soap of the present invention is very simple, it is only necessary to mix this process：
According to formula feeding, the fatty acid salt is heated to molten state, is then mixed into remaining raw material, cooling to obtain the final product.
In mixed process, the concentration and pH value of chlorine dioxide precursor solution have a major impact the molding difficulty of product.
Preferably, the chlorine dioxide precursor is mixed into as a solution, and the solution containing chlorine dioxide precursor
It is dissolved in alkaline solution and being made for chlorine dioxide, pH value 8-10.
Other additives can be added on arbitrary opportunity, be preferably added after chlorine dioxide precursor, activator, improve dispersion
Degree.
Compared with prior art, invention achieves following technique effects：
(1) a kind of chlorine dioxide purification product-solid soap of neomorph is provided；
(2) the advantages of solid soap also has preferable slow release effect, and formula is simple, cost, is widely used, not only office
It is limited to be placed in the small space such as wardrobe, drawer and uses, while in combination with air cleaning facilities such as air purifier, fresh air system
Middle use；And different shaping can be made, have both aesthetics while ensureing clean-up effect；
(3) manufacture craft is very simple, industrialized production preferably.
Description of the drawings
It, below will be to specific in order to illustrate more clearly of the specific embodiment of the invention or technical solution in the prior art
Embodiment or attached drawing needed to be used in the description of the prior art are briefly described, it should be apparent that, in being described below
Attached drawing is some embodiments of the present invention, for those of ordinary skill in the art, before not making the creative labor
It puts, other drawings may also be obtained based on these drawings.
Fig. 1 is the sustained release rate curve for the product that the embodiment of the present invention 1 provides.
Specific implementation mode
Technical scheme of the present invention is clearly and completely described below in conjunction with the drawings and specific embodiments, but
Be it will be understood to those of skill in the art that it is following described embodiments are some of the embodiments of the present invention, rather than it is whole
Embodiment is merely to illustrate the present invention, and is not construed as limiting the scope of the invention.Based on the embodiments of the present invention, ability
The every other embodiment that domain those of ordinary skill is obtained without making creative work, belongs to guarantor of the present invention
The range of shield.The person that is not specified actual conditions in embodiment, carries out according to conventional conditions or manufacturer's recommended conditions.Agents useful for same
Or production firm person is not specified in instrument, is the conventional products that can be obtained by commercially available purchase.
Embodiment 1
It weighs 50g odium stearate (sodium stearate) and is heated to 150 DEG C of thawings, stir evenly.It is added dropwise 5ml's a concentration of 10%
High concentration sodium chlorite solution, after stirring evenly, the oxalic acid that 0.1g is added is activated, and is sequentially added in solution after activation
1ml essence and 0.1g edible coloring agents, pour into mold after stirring evenly and are cooled and shaped.
The sample of preparation is put into 0.125m3Close test case in, concentration of formaldehyde is added dropwise to 1.38mg/m3, after 90min
Concentration of formaldehyde is down to 0.01mg/m3。
Sustained release rate is detected with reference to the test method in patent document CN105145626A, as a result such as Fig. 1, is as a result shown：
Time of the rate of release more than 150 μ g/h is 64 days.
Embodiment 2
It weighs after 40g odium stearate is heated to 150 DEG C and melts, stir evenly.The high concentration of 10ml a concentration of 10% is added dropwise
Sodium chlorite solution, after stirring evenly, the citric acid that 0.25g is added is activated, and 2ml is sequentially added in solution after activation
Essence and 0.2g edible coloring agents, pour into mold after stirring evenly and are cooled and shaped.
The sample of preparation is put into 0.125m3Close test case in, concentration of formaldehyde is added dropwise to 1.25mg/m3, after 40min
Concentration of formaldehyde is down to 0.01mg/m3。
Sustained release rate is detected with reference to the test method in patent document CN105145626A, is as a result shown：Product release speed
Time of the rate more than 150 μ g/h is 39 days.
Embodiment 3
It weighs after 50g odium stearate is heated to 155 DEG C and melts, stir evenly.The high concentration that 7ml a concentration of 10% is added dropwise is sub-
Sodium chlorate solution, after stirring evenly, the phosphate that 0.2g is added is activated, and 1ml perfume is sequentially added in solution after activation
Essence and 0.1g edible coloring agents, pour into mold after stirring evenly and are cooled and shaped.
The sample of preparation is put into 0.125m3Close test case in, concentration of formaldehyde is added dropwise to 1.18mg/m3, after 60min
Concentration of formaldehyde is down to 0.01mg/m3。
Sustained release rate is detected with reference to the test method in patent document CN105145626A, is as a result shown：Product release speed
Time of the rate more than 150 μ g/h is 51 days.
Embodiment 4
It weighs after 50g odium stearate is heated to 150 DEG C and melts, stir evenly.The high concentration of 10ml a concentration of 15% is added dropwise
Sodium chlorite solution, after stirring evenly, the acetic acid that 0.5g is added is activated, and 2ml perfume is sequentially added in solution after activation
Essence and 0.2g edible coloring agents, pour into mold after stirring evenly and are cooled and shaped.
The sample of preparation is put into 0.125m3Close test case in, concentration of formaldehyde is added dropwise to 1.20mg/m3, after 30min
Concentration of formaldehyde is down to 0.01mg/m3。
Sustained release rate is detected with reference to the test method in patent document CN105145626A, is as a result shown：Product release speed
Time of the rate more than 150 μ g/h is 30 days.
Embodiment 5
It weighs after 40g odium stearate is heated to 150 DEG C and melts, stir evenly.The high concentration that 5mL a concentration of 15% is added dropwise is sub-
Sodium chlorate solution, after stirring evenly, the oxalic acid that 0.3g is added is activated, and 1ml essence is sequentially added in solution after activation
And 0.2g edible coloring agents, it pours into mold and is cooled and shaped after stirring evenly.
The sample of preparation is put into 0.125m3Close test case in, concentration of formaldehyde is added dropwise to 1.09mg/m3, after 45min
Concentration of formaldehyde is down to 0.01mg/m3。
Sustained release rate is detected with reference to the test method in patent document CN105145626A, is as a result shown：Product release speed
Time of the rate more than 150 μ g/h is 40 days.
Embodiment 6
It is different from the dosage for differing only in odium stearate of embodiment 1, be：
It weighs 35g odium stearate and is heated to 150 DEG C of thawings, stir evenly.The high concentration Asia chlorine of 5ml a concentration of 10% is added dropwise
Acid sodium solution, after stirring evenly, the oxalic acid that 0.1g is added is activated, sequentially added in solution after activation 1ml essence and
0.1g edible coloring agents are poured into mold after stirring evenly and are cooled and shaped.
The sample of preparation is put into 0.125m3Close test case in, concentration of formaldehyde is added dropwise to 1.28mg/m3, after 60min
Concentration of formaldehyde is down to 0.01mg/m3。
Sustained release rate is detected with reference to the test method in patent document CN105145626A, is as a result shown：Product release speed
Time of the rate more than 150 μ g/h is 49 days.
Embodiment 7
It is different from the dosage for differing only in odium stearate of embodiment 1, be：
It weighs 40g odium stearate and is heated to 155 DEG C of thawings, stir evenly.The high concentration Asia chlorine of 5ml a concentration of 10% is added dropwise
Acid sodium solution, after stirring evenly, the oxalic acid that 0.1g is added is activated, sequentially added in solution after activation 1ml essence and
0.1g edible coloring agents are poured into mold after stirring evenly and are cooled and shaped.
The sample of preparation is put into 0.125m3Close test case in, concentration of formaldehyde is added dropwise to 1.38mg/m3, after 72min
Concentration of formaldehyde is down to 0.01mg/m3。
Sustained release rate is detected with reference to the test method in patent document CN105145626A, is as a result shown：Product release speed
Time of the rate more than 150 μ g/h is 53 days.
Embodiment 8
Odium stearate is replaced with to the coconut oil of saponification with differing only in for embodiment 1, is：
The coconut oil of saponification is heated to 85 DEG C of thawings, is stirred evenly.The high concentration chlorous acid of 5ml a concentration of 10% is added dropwise
Sodium solution, after stirring evenly, the oxalic acid that 0.1g is added is activated, sequentially added in solution after activation 1mL essence and
0.1g edible coloring agents are poured into mold after stirring evenly and are cooled and shaped.
The sample of preparation is put into 0.125m3Close test case in, concentration of formaldehyde is added dropwise to 1.38mg/m3, after 68min
Concentration of formaldehyde is down to 0.01mg/m3。
Sustained release rate is detected with reference to the test method in patent document CN105145626A, is as a result shown：Product release speed
Time of the rate more than 150 μ g/h is 52 days.
Embodiment 9
Odium stearate is replaced with to the palm oil of saponification with differing only in for embodiment 1, is：
The palm oil of saponification is heated to 85 DEG C of thawings, is stirred evenly.The high concentration chlorous acid of 5ml a concentration of 10% is added dropwise
Sodium solution, after stirring evenly, the oxalic acid that 0.1g is added is activated, sequentially added in solution after activation 1ml essence and
0.1g edible coloring agents are poured into mold after stirring evenly and are cooled and shaped.
The sample of preparation is put into 0.125m3Close test case in, concentration of formaldehyde is added dropwise to 1.38mg/m3, after 65min
Concentration of formaldehyde is down to 0.01mg/m3。
Sustained release rate is detected with reference to the test method in patent document CN105145626A, is as a result shown：Product release speed
Time of the rate more than 150 μ g/h is 50 days.
Embodiment 10
Odium stearate is replaced with into sodium laurate (hendecanoic acid sodium) with differing only in for embodiment 1, is：
Sodium laurate is heated to 100 DEG C of thawings, is stirred evenly.The high concentration sodium chlorite of 5ml a concentration of 10% is added dropwise
Solution, after stirring evenly, the oxalic acid that 0.1g is added is activated, and 1ml essence and 0.1g are sequentially added in solution after activation
Edible coloring agent is poured into mold after stirring evenly and is cooled and shaped.
The sample of preparation is put into 0.125m3Close test case in, concentration of formaldehyde is added dropwise to 1.38mg/m3, after 50min
Concentration of formaldehyde is down to 0.01mg/m3。
Sustained release rate is detected with reference to the test method in patent document CN105145626A, is as a result shown：Product release speed
Time of the rate more than 150 μ g/h is 45 days.
Embodiment 11
Odium stearate is replaced with into pentadecanoic acid sodium with differing only in for embodiment 1, is：
Pentadecanoic acid sodium is heated to 120 DEG C of thawings, is stirred evenly.The high concentration chlorous acid of 5ml a concentration of 10% is added dropwise
Sodium solution, after stirring evenly, the oxalic acid that 0.1g is added is activated, sequentially added in solution after activation 1ml essence and
0.1g edible coloring agents are poured into mold after stirring evenly and are cooled and shaped.
The sample of preparation is put into 0.125m3Close test case in, concentration of formaldehyde is added dropwise to 1.38mg/m3, after 80min
Concentration of formaldehyde is down to 0.01mg/m3。
Sustained release rate is detected with reference to the test method in patent document CN105145626A, is as a result shown：Product release speed
Time of the rate more than 150 μ g/h is 58 days.
Finally it should be noted that：The above embodiments are only used to illustrate the technical solution of the present invention., rather than its limitations；To the greatest extent
Present invention has been described in detail with reference to the aforementioned embodiments for pipe, it will be understood by those of ordinary skill in the art that：Its according to
So can with technical scheme described in the above embodiments is modified, either to which part or all technical features into
Row equivalent replacement；And these modifications or replacements, various embodiments of the present invention technology that it does not separate the essence of the corresponding technical solution
The range of scheme.
Claims (20)
1. a kind of slow released ClO 2 solid soap, which is characterized in that mainly by chlorine dioxide precursor and its activator, Yi Jigu
State fatty acid salt mixes；
The content of the fatty acid salt is 59~99wt%；
The content of the chlorine dioxide precursor is in terms of chlorine dioxide：1~30wt%.
2. slow released ClO 2 solid soap according to claim 1, which is characterized in that the content of the fatty acid salt is
80~90wt%.
3. slow released ClO 2 solid soap according to claim 1, which is characterized in that the chlorine dioxide precursor contains
Amount is 5~15wt% in terms of chlorine dioxide.
4. slow released ClO 2 solid soap according to claim 1, which is characterized in that the content of the activator is
0.05~2wt%.
5. slow released ClO 2 solid soap according to claim 1, which is characterized in that the content of the activator is
0.1~1wt%.
6. slow released ClO 2 solid soap according to claim 1, which is characterized in that the solid soap sustained release rate is big
It it is 30-80 days in the time of 150 μ g/h.
7. slow released ClO 2 solid soap according to claim 1, which is characterized in that the solid soap sustained release rate is big
It it is 50-80 days in the time of 150 μ g/h.
8. slow released ClO 2 solid soap according to claim 1, which is characterized in that the chlorine dioxide precursor is Asia
Chlorate and/or chlorate, the activator are acid.
9. slow released ClO 2 solid soap according to claim 1, which is characterized in that the activator is weak acid.
10. slow released ClO 2 solid soap according to claim 1, which is characterized in that the activator is phosphoric acid hydrogen
It is one or more in salt, metasilicic acid, carbonic acid, organic acid, organic multicomponent acid.
11. slow released ClO 2 solid soap according to claim 10, which is characterized in that the organic acid is C1
The organic acid of~C6.
12. slow released ClO 2 solid soap according to claim 10, which is characterized in that the organic acid is vinegar
It is one or more in acid, propionic acid, butyric acid.
13. slow released ClO 2 solid soap according to claim 10, which is characterized in that the organic multicomponent acid is lemon
It is one or more in lemon acid, oxalic acid, tartaric acid.
14. slow released ClO 2 solid soap according to claim 1, which is characterized in that the fatty acid salt be C6~
The fatty acid salt of C26.
15. slow released ClO 2 solid soap according to claim 1, which is characterized in that the fatty acid salt be C12~
The fatty acid salt of C20.
16. slow released ClO 2 solid soap according to claim 1, which is characterized in that the fatty acid salt is tristearin
Hydrochlorate.
17. slow released ClO 2 solid soap according to claim 1, which is characterized in that the fatty acid salt is selected from soap
The vegetable oil of change, the vegetable oil are one or more in coconut oil, olive oil, palm oil, palm-kernel oil, SIMMONDSIA CHINENSIS SEED OIL.
18. slow released ClO 2 solid soap according to claim 1, which is characterized in that also contain essence in raw material,
And/or edible coloring agent.
19. the preparation method of claim 1-18 any one of them slow released ClO 2 solid soaps, which is characterized in that according to
It is formulated feeding, the fatty acid salt is heated to molten state, be then mixed into remaining raw material, cooling to obtain the final product.
20. the preparation method of slow released ClO 2 solid soap according to claim 19, which is characterized in that the dioxy
Change chlorine precursor to be mixed into as a solution, and the solution containing chlorine dioxide precursor is that chlorine dioxide is dissolved in alkaline solution
It is made, pH value 8-10.
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| CN108029688A (en) * | 2017-12-07 | 2018-05-15 | 成都顺发消洗科技有限公司 | A kind of recyclable remaining air purifying and sterilizing piece and preparation method thereof |
| CN114532339A (en) * | 2021-12-23 | 2022-05-27 | 武汉轻工大学 | Preparation method of saponification-coated antibacterial drug for aquaculture |
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