CN106431102A - Phenolic foam heat-insulation board for external walls of buildings - Google Patents
Phenolic foam heat-insulation board for external walls of buildings Download PDFInfo
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- CN106431102A CN106431102A CN201610737395.2A CN201610737395A CN106431102A CN 106431102 A CN106431102 A CN 106431102A CN 201610737395 A CN201610737395 A CN 201610737395A CN 106431102 A CN106431102 A CN 106431102A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/40—Porous or lightweight materials
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- Inorganic Chemistry (AREA)
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- Organic Chemistry (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
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Abstract
The invention discloses a phenolic foam heat-insulation board for external walls of buildings. The phenolic foam heat-insulation board comprises main materials and auxiliary materials. A weight ratio of the main materials to the auxiliary materials is 1:0.2-0.5; the main materials comprise, by weight, 40-50 parts of phenolic foam plastics, 2-8 parts of glass wool, 5-15 parts of bisphenol A epoxy resin, 2-10 parts of cement, 5-10 parts of sawdust, 2-15 parts of asbestos fibers, 2-10 parts of silicon carbide, 5-10 parts of activated carbon, 1-5 parts of heavy calcium carbonate, 1-2 parts of sodium hexametaphosphate, 1-2 parts of sodium triphosphate and 50-100 parts of water; the auxiliary materials comprise, by weight, 5-15 parts of sodium silicate, 5-15 parts of rosin soap, 20-50 parts of modified sodium carboxymethyl celluloses, 1-2 parts of zinc oxide, 1-2 parts of copper oxide, 1-2 parts of chitin, 1-2 parts of mustard, 1-3 parts of lecithin, 1-2 parts of foam stabilizers and 1-2 parts of surfactants.
Description
Technical field
The present invention relates to insulation material technical field, more particularly, to a kind of phenolic foam heat insulation plate used for building exterior wall.
Background technology
China's construction unit area energy consumption is 3～5 times of developed country, vigorously promotes the use with residential housing, outward
Wallboard is used for insulation and decoration is widely popularized and approves.But meanwhile, the mechanical property of Side fascia, antibacterial and use the longevity
Life problem is also put in face of us, in recent years for above-mentioned reasons domestic in succession occur the impaired aging feelings of inner wall of building plate
Condition, causes serious personal's injures and deaths and property loss, and Side fascia insulation material has become the new potential safety hazard of a class, therefore, builds
The upgrading building the mechanical property, antibacterial and service life problem of interior wall wallboard has become as problem in the urgent need to address.
Content of the invention
The technical problem being existed based on background technology, the present invention proposes a kind of phenolic foam heat insulation plate used for building exterior wall,
Good heat preservation performance, mechanical property and anti-wear performance are excellent, and anti-microbial property is fabulous, product long service life.
A kind of phenolic foam heat insulation plate used for building exterior wall proposed by the present invention, including major ingredient and adjuvant, major ingredient and adjuvant
Weight is than for 1：0.2～0.5；
The raw material of wherein major ingredient includes by weight：40～50 parts of phenolic foam, 2～8 parts of glass cotton, bisphenol-A ring
5～15 parts of oxygen tree fat, 2～10 parts of cement, 5～10 parts of wood flour, 2～15 parts of asbestos fibre, 2～10 parts of carborundum, activated carbon 5～
10 parts, 1～5 part of ground calcium carbonate, 1～2 part of sodium hexameta phosphate, 1～2 part of sodium tripolyphosphate, 50～100 parts of water；
The raw material of adjuvant includes by weight：5～15 parts of sodium silicate, 5～15 parts of rosin soap, modified carboxy methyl cellulose sodium
20～50 parts, 1～2 part of zinc oxide, 1～2 part of copper oxide, 1～2 part of chitin, 1～2 part of mustard, 1～3 part of lecithin, steady bubble
1～2 part of agent, 1～2 part of surfactant.
Preferably, modified carboxy methyl cellulose sodium adopts following technique preparation：By sodium carboxymethyl cellulose, periodic acid solution
Mix and blend, filters, and washing adds water, guanidine hydrochloride mix and blend, filters, washing, adds Semen arachidis hypogaeae protein, phosphate-buffered molten
Liquid mixing and stirring, adds the stirring of protein transglutaminase to obtain modified carboxy methyl cellulose sodium.
Preferably, modified carboxy methyl cellulose sodium adopts following technique preparation：By weight by 1～5 part of carboxymethyl cellulose
Plain sodium, 12～18 parts of concentration are the periodic acid solution mix and blend of 0.4～0.8mol/L, filter, and washing adds 10～20 parts
Water, 1～4 part of guanidine hydrochloride mix and blend, filter, washing, add 2～6 parts of Semen arachidis hypogaeae proteins, 20～50 parts of concentration be 0.2～
The phosphate buffered solution mixing and stirring of 0.8mmol/L, phosphate buffered solution pH value is in neutrality, adds protein paddy ammonia
Amidase stirring obtains modified carboxy methyl cellulose sodium.
Preferably, modified carboxy methyl cellulose sodium adopts following technique preparation：By weight by 1～5 part of carboxymethyl cellulose
Plain sodium, 12～18 parts of concentration are the periodic acid solution mix and blend 2～5h of 0.4～0.8mol/L, and whipping temp is 40～50 DEG C,
Filter, washing, add 10～20 parts of water, 1～4 part of guanidine hydrochloride mix and blend 1～2h, whipping temp is 40～50 DEG C, filter, wash
Wash, the phosphate buffered solution mix and blend adding 2～6 parts of Semen arachidis hypogaeae proteins, 20～50 parts of concentration to be 0.2～0.8mmol/L is equal
Even, phosphate buffered solution pH value is in neutrality, adds protein transglutaminase to stir 5～15min, and whipping temp is 45～58
DEG C, obtain modified carboxy methyl cellulose sodium.
Preferably, the weight of major ingredient and adjuvant is than for 1：0.3～0.4.
Preferably, the weight of phenolic foam, glass cotton, bisphenol A epoxide resin, cement is than for 42～48：4～6：8
～12：4～8.
Preferably, the weight of sodium silicate, rosin soap, modified carboxy methyl cellulose sodium, lecithin, foam stabilizer is than for 8～12：
7～10：30～40：1.5～2.5：1.3～1.7.
Preferably, including major ingredient and adjuvant, the weight of major ingredient and adjuvant is than for 1：0.3～0.4；The raw material of wherein major ingredient is pressed
Weight portion includes：42～48 parts of phenolic foam, 4～6 parts of glass cotton, 8～12 parts of bisphenol A epoxide resin, 4～8 parts of cement,
6～8 parts of wood flour, 5～10 parts of asbestos fibre, 4～8 parts of carborundum, 7～9 parts of activated carbon, 2～4 parts of ground calcium carbonate, six inclined phosphorus
1.2～1.8 parts of sour sodium, 1.3～1.7 parts of sodium tripolyphosphate, 60～80 parts of water；The raw material of adjuvant includes by weight：Sodium silicate 8
～12 parts, 7～10 parts of rosin soap, 30～40 parts of modified carboxy methyl cellulose sodium, 1.3～1.7 parts of zinc oxide, copper oxide 1.5～
1.8 parts, 1.2～1.5 parts of chitin, 1.2～1.8 parts of mustard, 1.5～2.5 parts of lecithin, 1.3～1.7 parts of foam stabilizer, surface
1.4～1.6 parts of activating agent.
The present invention adopts phenolic foam, glass cotton, bisphenol A epoxide resin, cement to work in coordination with as major ingredient, in Colophonium
Under soap, sodium silicate, modified carboxy methyl cellulose sodium, lecithin, foam stabilizer act on, foaming characteristic is good, and excellent in mechanical performance；Changing
In the preparation process of property sodium carboxymethyl cellulose, sodium carboxymethyl cellulose becomes dialdehyde carboxymethyl cellulose sodium through periodate oxidation,
It is grafted through guanidine hydrochloride, gained modified carboxy methyl cellulose sodium not only has excellent anti-microbial property, and tensile strength pole again
Height, mechanical property is good, acts under certain condition with Semen arachidis hypogaeae protein further, and product dissolubility is good, and emulsifying, frothing capacity are excellent
Different；Modified carboxy methyl cellulose sodium and rosin soap, lecithin synergism, emulsifying, frothing capacity are extremely excellent；Modified carboxy methyl
Sodium cellulosate and zinc oxide, copper oxide, chitin, mustard synergism, not only mixing uniformity is fabulous, and anti-microbial property is extremely
Excellent, product long service life；And modified carboxy methyl cellulose sodium and wood flour, asbestos fibre, carborundum, activated carbon, heavy carbon
The effect of sour calcium, product good heat preservation performance, anti-wear performance is excellent, and can effectively suppress after foaming antibacterial, funguses, yeast, algae and
The growth of virus or breeding, anti-microbial property further enhances.
Specific embodiment
Below, by specific embodiment, technical scheme is described in detail.
Embodiment 1
A kind of phenolic foam heat insulation plate used for building exterior wall proposed by the present invention, including major ingredient and adjuvant, major ingredient and adjuvant
Weight is than for 1：0.2；The raw material of wherein major ingredient includes by weight：50 parts of phenolic foam, 2 parts of glass cotton, bisphenol-A epoxy
15 parts of resin, 2 parts of cement, 10 parts of wood flour, 2 parts of asbestos fibre, 10 parts of carborundum, 5 parts of activated carbon, 5 parts of ground calcium carbonate, six is inclined
1 part of sodium phosphate, 2 parts of sodium tripolyphosphate, 50 parts of water；The raw material of adjuvant includes by weight：15 parts of sodium silicate, 5 parts of rosin soap, change
50 parts of sodium carboxymethyl cellulose of property, 1 part of zinc oxide, 2 parts of copper oxide, 1 part of chitin, 2 parts of mustard, 1 part of lecithin, foam stabilizer 2
Part, 1 part of surfactant.
Embodiment 2
A kind of phenolic foam heat insulation plate used for building exterior wall proposed by the present invention, including major ingredient and adjuvant, major ingredient and adjuvant
Weight is than for 1：0.5；The raw material of wherein major ingredient includes by weight：40 parts of phenolic foam, 8 parts of glass cotton, bisphenol-A epoxy
5 parts of resin, 10 parts of cement, 5 parts of wood flour, 15 parts of asbestos fibre, 2 parts of carborundum, 10 parts of activated carbon, 1 part of ground calcium carbonate, six is inclined
2 parts of sodium phosphate, 1 part of sodium tripolyphosphate, 100 parts of water；The raw material of adjuvant includes by weight：5 parts of sodium silicate, 15 parts of rosin soap,
20 parts of modified carboxy methyl cellulose sodium, 2 parts of zinc oxide, 1 part of copper oxide, 2 parts of chitin, 1 part of mustard, 3 parts of lecithin, foam stabilizer
1 part, 2 parts of surfactant.
Modified carboxy methyl cellulose sodium adopts following technique preparation：Sodium carboxymethyl cellulose, the mixing of periodic acid solution are stirred
Mix, filter, washing, add water, guanidine hydrochloride mix and blend, filter, washing, add Semen arachidis hypogaeae protein, phosphate buffered solution mixing
Stir, add the stirring of protein transglutaminase to obtain modified carboxy methyl cellulose sodium.
Embodiment 3
A kind of phenolic foam heat insulation plate used for building exterior wall proposed by the present invention, including major ingredient and adjuvant, major ingredient and adjuvant
Weight is than for 1：0.3；The raw material of wherein major ingredient includes by weight：48 parts of phenolic foam, 4 parts of glass cotton, bisphenol-A epoxy
12 parts of resin, 4 parts of cement, 8 parts of wood flour, 5 parts of asbestos fibre, 8 parts of carborundum, 7 parts of activated carbon, 4 parts of ground calcium carbonate, six inclined phosphorus
1.2 parts of sour sodium, 1.7 parts of sodium tripolyphosphate, 60 parts of water；The raw material of adjuvant includes by weight：12 parts of sodium silicate, 7 parts of rosin soap,
40 parts of modified carboxy methyl cellulose sodium, 1.3 parts of zinc oxide, 1.8 parts of copper oxide, 1.2 parts of chitin, 1.8 parts of mustard, lecithin
1.5 parts, 1.7 parts of foam stabilizer, 1.4 parts of surfactant.
Modified carboxy methyl cellulose sodium adopts following technique preparation：By weight by 5 parts of sodium carboxymethyl cellulose, 12 parts dense
Spend the periodic acid solution mix and blend 2h for 0.8mol/L, whipping temp is 50 DEG C, filter, washing, add 10 portions of water, 4 portions of salt
Sour guanidine mix and blend 1h, whipping temp is 50 DEG C, filters, washing, adds 2 parts of Semen arachidis hypogaeae proteins, 50 parts of concentration to be 0.2mmol/L's
Phosphate buffered solution mixing and stirring, phosphate buffered solution pH value is in neutrality, adds the stirring of protein transglutaminase
15min, whipping temp is 45 DEG C, obtains modified carboxy methyl cellulose sodium.
Embodiment 4
A kind of phenolic foam heat insulation plate used for building exterior wall proposed by the present invention, including major ingredient and adjuvant, major ingredient and adjuvant
Weight is than for 1：0.4；The raw material of wherein major ingredient includes by weight：42 parts of phenolic foam, 6 parts of glass cotton, bisphenol-A epoxy
8 parts of resin, 8 parts of cement, 6 parts of wood flour, 10 parts of asbestos fibre, 4 parts of carborundum, 9 parts of activated carbon, 2 parts of ground calcium carbonate, six inclined phosphorus
1.8 parts of sour sodium, 1.3 parts of sodium tripolyphosphate, 80 parts of water；The raw material of adjuvant includes by weight：8 parts of sodium silicate, 10 parts of rosin soap,
30 parts of modified carboxy methyl cellulose sodium, 1.7 parts of zinc oxide, 1.5 parts of copper oxide, 1.5 parts of chitin, 1.2 parts of mustard, lecithin
2.5 parts, 1.3 parts of foam stabilizer, 1.6 parts of surfactant.
Modified carboxy methyl cellulose sodium adopts following technique preparation：By weight by 1 part of sodium carboxymethyl cellulose, 18 parts dense
Spend the periodic acid solution mix and blend 5h for 0.4mol/L, whipping temp is 40 DEG C, filter, washing, add 20 portions of water, 1 portion of salt
Sour guanidine mix and blend 2h, whipping temp is 40 DEG C, filters, washing, adds 6 parts of Semen arachidis hypogaeae proteins, 20 parts of concentration to be 0.8mmol/L's
Phosphate buffered solution mixing and stirring, phosphate buffered solution pH value is in neutrality, adds the stirring of protein transglutaminase
5min, whipping temp is 58 DEG C, obtains modified carboxy methyl cellulose sodium.
Embodiment 5
A kind of phenolic foam heat insulation plate used for building exterior wall proposed by the present invention, including major ingredient and adjuvant, major ingredient and adjuvant
Weight is than for 1：0.35；The raw material of wherein major ingredient includes by weight：45 parts of phenolic foam, 5 parts of glass cotton, bisphenol-A ring
10 parts of oxygen tree fat, 6 parts of cement, 7 parts of wood flour, 8 parts of asbestos fibre, 6 parts of carborundum, 8 parts of activated carbon, 3 parts of ground calcium carbonate, six is inclined
1.5 parts of sodium phosphate, 1.5 parts of sodium tripolyphosphate, 70 parts of water；The raw material of adjuvant includes by weight：10 parts of sodium silicate, rosin soap 8
Part, 35 parts of modified carboxy methyl cellulose sodium, 1.5 parts of zinc oxide, 1.6 parts of copper oxide, 1.4 parts of chitin, 1.5 parts of mustard, lecithin
2 parts of fat, 1.5 parts of foam stabilizer, 1.5 parts of surfactant.
Modified carboxy methyl cellulose sodium adopts following technique preparation：By weight by 3 parts of sodium carboxymethyl cellulose, 12～18
Part concentration is the periodic acid solution mix and blend of 0.6mol/L, filters, and washing adds 15 parts of water, 2 parts of guanidine hydrochloride mix and blends,
Filter, washing, add 4 parts of Semen arachidis hypogaeae proteins, 30 parts of concentration to be the phosphate buffered solution mixing and stirring of 0.5mmol/L, phosphorus
Hydrochlorate pH value of buffer solution is in neutrality, adds the stirring of protein transglutaminase to obtain modified carboxy methyl cellulose sodium.
The above, the only present invention preferably specific embodiment, but protection scope of the present invention is not limited thereto,
Any those familiar with the art the invention discloses technical scope in, technology according to the present invention scheme and its
Inventive concept equivalent or change in addition, all should be included within the scope of the present invention.
Claims (8)
1. a kind of phenolic foam heat insulation plate used for building exterior wall is it is characterised in that include major ingredient and adjuvant, the weight of major ingredient and adjuvant
Than for 1：0.2～0.5；
The raw material of wherein major ingredient includes by weight：40～50 parts of phenolic foam, 2～8 parts of glass cotton, bisphenol-A epoxy tree
5～15 parts of fat, 2～10 parts of cement, 5～10 parts of wood flour, 2～15 parts of asbestos fibre, 2～10 parts of carborundum, activated carbon 5～10
Part, 1～5 part of ground calcium carbonate, 1～2 part of sodium hexameta phosphate, 1～2 part of sodium tripolyphosphate, 50～100 parts of water；
The raw material of adjuvant includes by weight：5～15 parts of sodium silicate, 5～15 parts of rosin soap, modified carboxy methyl cellulose sodium 20～
50 parts, 1～2 part of zinc oxide, 1～2 part of copper oxide, 1～2 part of chitin, 1～2 part of mustard, 1～3 part of lecithin, foam stabilizer 1～
2 parts, 1～2 part of surfactant.
2. according to claim 1 phenolic foam heat insulation plate used for building exterior wall it is characterised in that modified carboxy methyl cellulose sodium
Using the preparation of following technique：By sodium carboxymethyl cellulose, periodic acid solution mix and blend, filter, washing, add water, guanidine hydrochloride
Mix and blend, filters, and washing adds Semen arachidis hypogaeae protein, phosphate buffered solution mixing and stirring, adds protein L-Glutamine
Enzyme stirring obtains modified carboxy methyl cellulose sodium.
3. phenolic foam heat insulation plate used for building exterior wall according to claim 1 or claim 2 is it is characterised in that modified carboxy methyl fiber
Plain sodium adopts following technique preparation：By weight by 1～5 part of sodium carboxymethyl cellulose, 12～18 parts of concentration be 0.4～
The periodic acid solution mix and blend of 0.8mol/L, filters, and washing adds 10～20 parts of water, 1～4 part of guanidine hydrochloride mix and blend, mistake
Filter, washing, add the phosphate buffered solution mixing that 2～6 parts of Semen arachidis hypogaeae proteins, 20～50 parts of concentration are 0.2～0.8mmol/L to stir
Mix uniformly, phosphate buffered solution pH value is in neutrality, add the stirring of protein transglutaminase to obtain modified carboxy methyl cellulose
Sodium.
4. according to any one of claims 1 to 3 phenolic foam heat insulation plate used for building exterior wall it is characterised in that modified carboxylic first
Base sodium cellulosate adopts following technique preparation：By weight by 1～5 part of sodium carboxymethyl cellulose, 12～18 parts of concentration be 0.4～
The periodic acid solution mix and blend 2～5h of 0.8mol/L, whipping temp is 40～50 DEG C, filters, and washing adds 10～20 parts
Water, 1～4 part of guanidine hydrochloride mix and blend 1～2h, whipping temp is 40～50 DEG C, filters, washing, 2～6 parts of Semen arachidis hypogaeae proteins of addition,
20～50 parts of concentration are the phosphate buffered solution mixing and stirring of 0.2～0.8mmol/L, and phosphate buffered solution pH value is in
Neutrality, adds protein transglutaminase to stir 5～15min, whipping temp is 45～58 DEG C, obtains modified carboxy methyl cellulose
Sodium.
5. according to any one of Claims 1 to 4 phenolic foam heat insulation plate used for building exterior wall it is characterised in that major ingredient with auxiliary
The weight of material ratio is for 1：0.3～0.4.
6. according to any one of Claims 1 to 5 phenolic foam heat insulation plate used for building exterior wall it is characterised in that phenol formaldehyde foam
Plastics, glass cotton, bisphenol A epoxide resin, the weight of cement are than for 42～48：4～6：8～12：4～8.
7. according to any one of claim 1～6 phenolic foam heat insulation plate used for building exterior wall it is characterised in that sodium silicate, pine
Fancy soap, modified carboxy methyl cellulose sodium, lecithin, the weight of foam stabilizer are than for 8～12：7～10：30～40：1.5～2.5：
1.3～1.7.
8. according to any one of claim 1～7 phenolic foam heat insulation plate used for building exterior wall it is characterised in that include major ingredient
With adjuvant, the weight of major ingredient and adjuvant is than for 1：0.3～0.4；The raw material of wherein major ingredient includes by weight：Phenolic foam
42～48 parts, 4～6 parts of glass cotton, 8～12 parts of bisphenol A epoxide resin, 4～8 parts of cement, 6～8 parts of wood flour, asbestos fibre 5～
10 parts, 4～8 parts of carborundum, 7～9 parts of activated carbon, 2～4 parts of ground calcium carbonate, 1.2～1.8 parts of sodium hexameta phosphate, tripolyphosphate
1.3～1.7 parts of sodium, 60～80 parts of water；The raw material of adjuvant includes by weight：8～12 parts of sodium silicate, 7～10 parts of rosin soap, change
30～40 parts of sodium carboxymethyl cellulose of property, 1.3～1.7 parts of zinc oxide, 1.5～1.8 parts of copper oxide, 1.2～1.5 parts of chitin,
1.2～1.8 parts of mustard, 1.5～2.5 parts of lecithin, 1.3～1.7 parts of foam stabilizer, 1.4～1.6 parts of surfactant.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610737395.2A CN106431102A (en) | 2016-08-26 | 2016-08-26 | Phenolic foam heat-insulation board for external walls of buildings |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610737395.2A CN106431102A (en) | 2016-08-26 | 2016-08-26 | Phenolic foam heat-insulation board for external walls of buildings |
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| CN106431102A true CN106431102A (en) | 2017-02-22 |
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| CN201610737395.2A Pending CN106431102A (en) | 2016-08-26 | 2016-08-26 | Phenolic foam heat-insulation board for external walls of buildings |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107307160A (en) * | 2017-06-29 | 2017-11-03 | 安徽康博特保健食品有限公司 | A kind of preparation method of shark chondroitin milk calcium pressed candy |
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| CN107382368A (en) * | 2017-07-25 | 2017-11-24 | 合肥欧仕嘉机电设备有限公司 | A kind of insulation material used for building exterior wall and preparation method thereof |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102838770A (en) * | 2012-09-10 | 2012-12-26 | 山东圣泉化工股份有限公司 | Preparation method of phenolic foam boards |
| CN103059503A (en) * | 2013-01-11 | 2013-04-24 | 陕西煤业化工技术研究院有限责任公司 | Phenolic foam plastics and preparation method thereof and preparation method of foam carbon |
| CN103333457A (en) * | 2013-07-25 | 2013-10-02 | 天津城建大学 | High-smoke suppression and high-oxygen index phenolic aldehyde fire-proof heat-preserving board and preparation method thereof |
| CN103450630A (en) * | 2013-08-09 | 2013-12-18 | 江苏德明新材料有限公司 | Preparation method of environment-friendly phenol aldehyde-inorganic composite heat insulating material |
| CN103724437A (en) * | 2014-01-09 | 2014-04-16 | 福建农林大学 | Multifunctional guanidine salt grafted carboxymethyl cellulose paper-making additive and preparation method thereof |
| CN104513454A (en) * | 2013-09-27 | 2015-04-15 | 青岛蓝农谷农产品研究开发有限公司 | Flame-retardant high-temperature-resistant sheet material and producing method thereof |
-
2016
- 2016-08-26 CN CN201610737395.2A patent/CN106431102A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102838770A (en) * | 2012-09-10 | 2012-12-26 | 山东圣泉化工股份有限公司 | Preparation method of phenolic foam boards |
| CN103059503A (en) * | 2013-01-11 | 2013-04-24 | 陕西煤业化工技术研究院有限责任公司 | Phenolic foam plastics and preparation method thereof and preparation method of foam carbon |
| CN103333457A (en) * | 2013-07-25 | 2013-10-02 | 天津城建大学 | High-smoke suppression and high-oxygen index phenolic aldehyde fire-proof heat-preserving board and preparation method thereof |
| CN103450630A (en) * | 2013-08-09 | 2013-12-18 | 江苏德明新材料有限公司 | Preparation method of environment-friendly phenol aldehyde-inorganic composite heat insulating material |
| CN104513454A (en) * | 2013-09-27 | 2015-04-15 | 青岛蓝农谷农产品研究开发有限公司 | Flame-retardant high-temperature-resistant sheet material and producing method thereof |
| CN103724437A (en) * | 2014-01-09 | 2014-04-16 | 福建农林大学 | Multifunctional guanidine salt grafted carboxymethyl cellulose paper-making additive and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 陈复生等: "《蛋白质化学与工艺》", 31 August 2012, 郑州大学出版社 * |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN110482938A (en) * | 2019-09-27 | 2019-11-22 | 安徽虹达道路桥梁工程有限公司 | A kind of environmental-friendly construction material and preparation method thereof |
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Application publication date: 20170222 |