CN106430880B - A kind of preparation method and application method of disposal of oily sludge agent - Google Patents
A kind of preparation method and application method of disposal of oily sludge agent Download PDFInfo
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- CN106430880B CN106430880B CN201611033160.1A CN201611033160A CN106430880B CN 106430880 B CN106430880 B CN 106430880B CN 201611033160 A CN201611033160 A CN 201611033160A CN 106430880 B CN106430880 B CN 106430880B
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F11/00—Treatment of sludge; Devices therefor
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F11/00—Treatment of sludge; Devices therefor
- C02F11/12—Treatment of sludge; Devices therefor by de-watering, drying or thickening
- C02F11/14—Treatment of sludge; Devices therefor by de-watering, drying or thickening with addition of chemical agents
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/32—Hydrocarbons, e.g. oil
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/10—Nature of the water, waste water, sewage or sludge to be treated from quarries or from mining activities
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1003—Waste materials
Abstract
A kind of preparation method of disposal of oily sludge agent, includes component A preparation method and component B preparation method, and wherein component A preparation method includes step：1. N oleoyl N N-methyltaurines sodium, higher aliphatic PEO ether phosphate salt, non-hydrate sodium metasilicate compounding are stirred; the surfactant compounded is 2. by sodium pyrophosphate, paraformaldehyde, N; the salicylidenes 1 of N' bis-; 2 propane diamine are added to the water; the surfactant of heating, stirring, then the compounding that 1. step is obtained is added; stirring, obtains component A；Component B preparation method includes：By butylphenol PEO ether, sucrose-fatty ester APEO, pull open powder, polyoxyethylene oxypropylene ether, PDDA, 2, the nitrilo allylamine of 2 dibromo 3, polymethylacrylic acid high-carbon alcohol ester, zinc dialkyl dithiophosphate are added into water, heating stirring, cool again, stirring, obtains component B.
Description
Technical field
The invention belongs to petroleum works field, the preparation method of specifically a kind of disposal of oily sludge agent and user
Method.
Background technology
Oily sludge is produced in oil development, transport, refining in sewage disposal process.General oil content in sludge
10%~50%, moisture content produced in 40%~90%, China's oil petrochemical industry, every year on average 800000 ton tank bed muds,
Bottom of pond mud, Shengli Oil Field produces oily sludge more than 100,000 tons every year, wherein containing a large amount of benzene homologues, phenols, anthracene, pyrene etc.
The noxious material of foul smelling, if not being acted upon, not only pollutes environment, and cause the waste of resource.Sludge contains substantial amounts of
Pathogen, parasite（Ovum）, copper, zinc, chromium, the heavy metal, salt and Polychlorinated biphenyls, dioxin, radioactive nucleus element etc. such as mercury
The poisonous and harmful substance of difficult degradation.Extraction is to utilize " similar to mix " principle, selects a kind of suitable organic solvent to be used as extraction
Agent is taken, recovery and utilization for oily sludge Crude Oil.It is at present to use surface for the selection of extractant, it is desirable to higher more
Activating agent.But single surfactant function is single, adaptive surface is narrower.Some medicament formation emulsifying effectivenesses, separation is more
Pathogen and parasite are more in difficulty, the sludge after processing, it is impossible to directly utilize, and place and occur stench etc. after a period of time now
As.What is had has you Treatment of Sludge medicament to be corrosive to the equipment for holding and adding, and makes the service life of equipment and reduces.
The content of the invention
The present invention provides a kind of preparation method and application method of disposal of oily sludge agent, of the prior art to solve
Defect.
The present invention is achieved by the following technical programs：
A kind of preparation method of disposal of oily sludge agent, includes component A preparation method and component B preparation method, its
Middle component A preparation method comprises the steps：1. by N- oleoyls-N methyl taurine sodium, higher aliphatic polycyclic oxygen second
Alkane ether phosphate salt, non-hydrate sodium metasilicate compounding stir, the surfactant compounded, it is stand-by 2. by sodium pyrophosphate,
Paraformaldehyde, N, salicylidene -1, the 2- propane diamine of N'- bis- are added to the water, and are warming up to 40-50 DEG C, insulated and stirred 20min, then will
The surfactant for the compounding that 1. step obtains is added, and is continued to stir 20min, is obtained component A；Wherein component B preparation side
Method comprises the steps：By butylphenol PEO ether, sucrose-fatty ester APEO, pull open powder, PEO
The bromo- 3- nitrilo allylamine of polypropylene oxide, PDDA, 2,2- bis-, polymethylacrylic acid high-carbon alcohol ester
5-10 parts, zinc dialkyl dithiophosphate add into water, be warming up to 50-55 DEG C, insulated and stirred 15min, then be cooled to 25-
30 DEG C, 10min is stirred, component B is obtained；Wherein component A is made up of the raw material of following weight parts：N- oleoyl-N- methyl ox sulphurs
Sour sodium 25-30 parts, 15-20 parts of higher aliphatic PEO ether phosphate salt, 5-10 parts of non-hydrate sodium metasilicate, sodium pyrophosphate
2-10 parts, 3-5 parts of paraformaldehyde, N, 7-12 parts of the salicylidene -1,2- propane diamine of N'- bis-, 40-70 parts of water；Wherein component B is under
State the raw material composition of parts by weight：5-15 parts of butylphenol PEO ether, 5-10 parts of sucrose-fatty ester APEO, pull open
6-10 parts of powder, 3-5 parts of polyoxyethylene oxypropylene ether, 3-5 parts of PDDA, the bromo- 3- nitrogen of 2,2- bis-
Allylamine 4-8 parts of river, 5-10 parts of polymethylacrylic acid high-carbon alcohol ester, 3-8 parts of zinc dialkyl dithiophosphate, 30-50 parts of water.
A kind of preparation method of disposal of oily sludge agent as described above, described component A by following weight parts original
Material composition：N- oleoyls -25 parts of N methyl taurine sodium, 17 parts of higher aliphatic PEO ether phosphate salt, nine water are inclined
10 parts of sodium metasilicate, 2 parts of sodium pyrophosphate, 4 parts of paraformaldehyde, N, 12 parts of the salicylidene -1,2- propane diamine of N'- bis-, 40 parts of water.
A kind of preparation method of disposal of oily sludge agent as described above, it is characterised in that：Described component A is by following
The raw material composition of parts by weight：N- oleoyls -27 parts of N methyl taurine sodium, higher aliphatic PEO ether phosphate salt 20
Part, 5 parts of non-hydrate sodium metasilicate, 6 parts of sodium pyrophosphate, 5 parts of paraformaldehyde, N, 7 parts of the salicylidene -1,2- propane diamine of N'- bis-, water 55
Part.
A kind of preparation method of disposal of oily sludge agent as described above, it is characterised in that：Described component A is by following
The raw material composition of parts by weight：N- oleoyls -30 parts of N methyl taurine sodium, higher aliphatic PEO ether phosphate salt 15
Part, 8 parts of non-hydrate sodium metasilicate, 10 parts of sodium pyrophosphate, 3 parts of paraformaldehyde, N, 9 parts of the salicylidene -1,2- propane diamine of N'- bis-, water
70 parts.
A kind of preparation method of disposal of oily sludge agent as described above, it is characterised in that：Described component B is by following
The raw material composition of parts by weight：5 parts of butylphenol PEO ether, 7 parts of sucrose-fatty ester APEO, 10 parts of pull open powder,
It is 3 parts of polyoxyethylene oxypropylene ether, 4 parts of PDDA, 8 parts of the bromo- 3- nitrilo allylamines of 2,2- bis-, poly-
5 parts of methylacrylic higher alcohols ester, 6 parts of zinc dialkyl dithiophosphate, 50 parts of water.
A kind of preparation method of disposal of oily sludge agent as described above, it is characterised in that：Described component B is by following
The raw material composition of parts by weight：10 parts of butylphenol PEO ether, 10 parts of sucrose-fatty ester APEO, 6 parts of pull open powder,
It is 4 parts of polyoxyethylene oxypropylene ether, 5 parts of PDDA, 4 parts of the bromo- 3- nitrilo allylamines of 2,2- bis-, poly-
8 parts of methylacrylic higher alcohols ester, 8 parts of zinc dialkyl dithiophosphate, 30 parts of water.
A kind of preparation method of disposal of oily sludge agent as described above, it is characterised in that：Described component B is by following
The raw material composition of parts by weight：15 parts of butylphenol PEO ether, 5 parts of sucrose-fatty ester APEO, 8 parts of pull open powder,
It is 5 parts of polyoxyethylene oxypropylene ether, 3 parts of PDDA, 6 parts of the bromo- 3- nitrilo allylamines of 2,2- bis-, poly-
10 parts of methylacrylic higher alcohols ester, 3 parts of zinc dialkyl dithiophosphate, 40 parts of water.
A kind of application method of disposal of oily sludge agent as described above, it is characterised in that：Comprise the steps： ①
Component A is added into water dilution, component A medicaments are made, the weight ratio of component A and water is 1:2500-5000；Component B is added
Enter into water dilution, be made component B medicaments, the weight ratio of component B and water is 1：2500-5000；2. component A medicaments are added
In pending greasy filth, 15-20min is stirred, the weight of pending greasy filth and component A medicaments compares 1：2-3, obtains primary treatment
Greasy filth；3. component B medicaments are added in the primary treatment greasy filth 2. obtained to step, stirred, until oil, water, mud three-phase separate
From the weight of pending greasy filth and component B medicaments compares 1：1-2.
It is an advantage of the invention that：The present invention can be to the comprehensive utilization of oil field silt particle or harmless treatment.The present invention is using double
Pending greasy filth, is sufficiently mixed, the active ingredient in component A is filled with greasy filth by the mode that component coordinates by component A first
Tap is touched, so that the separation that oil, water, mud are tried one's best, then the effect for by component B reach demulsification, flocculate, improve separation effect
Rate, is effectively increased separating rate.Two kinds of components are applied in combination, and crude oil recovery rate is more than 99%.Plurality of raw materials compounding of the present invention, phase
Mutually synergy, can construct colloidal liquid aphrons system, environmental suitability is strong in greasy filth（Particularly alkalescence and oxidant are deposited
It is more stable in case）, have certain penetration.The present invention have certain bactericidal effect, reduce sludge in pathogen,
Parasite（Ovum）, there are antioxygen anti-corrosion effects for the equipment for participating in processing, in the equipment surface formation layer of metal of metal
Passivating film, protection equipment.The preparation method technique of the present invention is simple, easy to operate.Using process using adding twice, it can make
Each raw material components fully reacts, and effectively improves the rate of recovery of crude oil.
Embodiment
, below will be in the embodiment of the present invention to make the purpose, technical scheme and advantage of the embodiment of the present invention clearer
Technical scheme be clearly and completely described, it is clear that described embodiment is a part of embodiment of the invention, rather than
Whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art are not making creative work premise
Lower obtained every other embodiment, belongs to the scope of protection of the invention.
A kind of disposal of oily sludge agent and preparation method thereof and application method, are made up of component A and component B；Wherein component
A is made up of the raw material of following weight parts：N- oleoyls -25-30 parts of N methyl taurine sodium, higher aliphatic PEO ether
15-20 parts of phosphate ester salt, 5-10 parts of non-hydrate sodium metasilicate, 2-10 parts of sodium pyrophosphate, 3-5 parts of paraformaldehyde, N, the sub- bigcatkin willows of N'- bis-
7-12 parts of base -1,2- propane diamine, 40-70 parts of water；Wherein component B is made up of the raw material of following weight parts：Butylphenol polycyclic oxygen second
5-15 parts of alkane ether, 5-10 parts of sucrose-fatty ester APEO, 6-10 parts of pull open powder, polyoxyethylene oxypropylene ether 3-5
Part, 3-5 parts of PDDA, 4-8 parts of the bromo- 3- nitrilo allylamines of 2,2- bis-, polymethylacrylic acid higher alcohols
5-10 parts of ester, 3-8 parts of zinc dialkyl dithiophosphate, 30-50 parts of water.
Wherein component A is made up of the embodiment raw material of following weight parts：
Embodiment 1：N- oleoyls -25 parts of N methyl taurine sodium, higher aliphatic PEO ether phosphate salt 17
Part, 10 parts of non-hydrate sodium metasilicate, 2 parts of sodium pyrophosphate, 4 parts of paraformaldehyde, N, 12 parts of the salicylidene -1,2- propane diamine of N'- bis-, water
40 parts.
Embodiment 2：N- oleoyls -27 parts of N methyl taurine sodium, higher aliphatic PEO ether phosphate salt 20
Part, 5 parts of non-hydrate sodium metasilicate, 6 parts of sodium pyrophosphate, 5 parts of paraformaldehyde, N, 7 parts of the salicylidene -1,2- propane diamine of N'- bis-, water 55
Part.
Embodiment 3：N- oleoyls -30 parts of N methyl taurine sodium, higher aliphatic PEO ether phosphate salt 15
Part, 8 parts of non-hydrate sodium metasilicate, 10 parts of sodium pyrophosphate, 3 parts of paraformaldehyde, N, 9 parts of the salicylidene -1,2- propane diamine of N'- bis-, water
70 parts.
Wherein component B is made up of the embodiment raw material of following weight parts：
Embodiment 1：It is 5 parts of butylphenol PEO ether, 7 parts of sucrose-fatty ester APEO, 10 parts of pull open powder, poly-
3 parts of ethylene oxide propylene oxide ether, 4 parts of PDDA, 8 parts of the bromo- 3- nitrilo allylamines of 2,2- bis-, poly- first
5 parts of base Long Chain Alkyl Acrylate, 6 parts of zinc dialkyl dithiophosphate, 50 parts of water.
Embodiment 2：10 parts of butylphenol PEO ether, 10 parts of sucrose-fatty ester APEO, 6 parts of pull open powder,
It is 4 parts of polyoxyethylene oxypropylene ether, 5 parts of PDDA, 4 parts of the bromo- 3- nitrilo allylamines of 2,2- bis-, poly-
8 parts of methylacrylic higher alcohols ester, 8 parts of zinc dialkyl dithiophosphate, 30 parts of water.
Embodiment 3：It is 15 parts of butylphenol PEO ether, 5 parts of sucrose-fatty ester APEO, 8 parts of pull open powder, poly-
5 parts of ethylene oxide propylene oxide ether, 3 parts of PDDA, 6 parts of the bromo- 3- nitrilo allylamines of 2,2- bis-, poly- first
10 parts of base Long Chain Alkyl Acrylate, 3 parts of zinc dialkyl dithiophosphate, 40 parts of water.
A kind of disposal of oily sludge agent and preparation method thereof and application method, include component A preparation method and component B
Preparation method, wherein component A preparation method comprises the steps：1. by N- oleoyls-N methyl taurine sodium, senior fat
Fat alcohol PEO ether phosphate salt, non-hydrate sodium metasilicate compounding stir, and the surfactant compounded is stand-by
2. by sodium pyrophosphate, paraformaldehyde, N, salicylidene -1, the 2- propane diamine of N'- bis- is added to the water, and is warming up to 40-50 DEG C, insulation is stirred
20min is mixed, then the surfactant for the compounding that 1. step is obtained is added, and is continued to stir 20min, is obtained component A；Wherein group
B preparation method is divided to comprise the steps：By butylphenol PEO ether, sucrose-fatty ester APEO, pull open
The bromo- 3- nitrilo allylamine of powder, polyoxyethylene oxypropylene ether, PDDA, 2,2- bis-, poly- methyl-prop
5-10 parts of olefin(e) acid high-carbon alcohol ester, zinc dialkyl dithiophosphate are added into water, are warming up to 50-55 DEG C, insulated and stirred
15min, then it is cooled to 25-30 DEG C, 10min is stirred, component B is obtained.
A kind of disposal of oily sludge agent and preparation method thereof and application method, comprise the steps：1. component A is added
Diluted into water, be made component A medicaments, the weight ratio of component A and water is 1:2500-5000；Component B is added into water dilute
Release, be made component B medicaments, the weight ratio of component B and water is 1：2500-5000；2. component A medicaments are added to pending oil
In mud, 15-20min is stirred, the weight of pending greasy filth and component A medicaments compares 1：2-3, obtains primary treatment greasy filth；3. will
Component B medicaments are added in the primary treatment greasy filth 2. obtained to step, stirring, pending until oil, water, mud three phase separation
The weight of greasy filth and component B medicaments compares 1：1-2.
With reference to experiment, illustrate the using effect of the present invention.
The greasy filth sludge of Daqing oil field is taken, 10 test groups are divided into（1 blank test group and 9 test groups）, respectively
The sludge oil content before and after every group of greasy filth Treatment of Sludge is measured, each test group result is as follows：
As can be seen from the above table, the oil content before and after the processing in sludge is significantly reduced, and original rate of recovery is more than 99%.
Finally it should be noted that：The above embodiments are merely illustrative of the technical solutions of the present invention, rather than its limitations；Although
The present invention is described in detail with reference to the foregoing embodiments, it will be understood by those within the art that：It still may be used
To be modified to the technical scheme described in foregoing embodiments, or equivalent substitution is carried out to which part technical characteristic；
And these modification or replace, do not make appropriate technical solution essence depart from various embodiments of the present invention technical scheme spirit and
Scope.
Claims (8)
1. a kind of preparation method of disposal of oily sludge agent, it is characterised in that：The system of preparation method and component B including component A
Preparation Method, wherein component A preparation method comprises the steps：1. by N- oleoyls-N methyl taurine sodium, higher aliphatic
Alcohol PEO ether phosphate salt, non-hydrate sodium metasilicate compounding stir, the surfactant compounded, it is stand-by 2.
By sodium pyrophosphate, paraformaldehyde, N, salicylidene -1, the 2- propane diamine of N'- bis- is added to the water, and is warming up to 40-50 DEG C, insulated and stirred
20min, then the surfactant for the compounding that 1. step is obtained are added, and are continued to stir 20min, are obtained component A；Wherein component B
Preparation method comprise the steps：By butylphenol PEO ether, sucrose-fatty ester APEO, pull open powder, poly-
The bromo- 3- nitrilo allylamine of ethylene oxide propylene oxide ether, PDDA, 2,2- bis-, polymethylacrylic acid
5-10 parts of high-carbon alcohol ester, zinc dialkyl dithiophosphate are added into water, are warming up to 50-55 DEG C, insulated and stirred 15min, then
25-30 DEG C is cooled to, 10min is stirred, obtains component B；Wherein component A is made up of the raw material of following weight parts：N- oleoyls-N-
25-30 parts of N-methyltaurine sodium, 15-20 parts of higher aliphatic PEO ether phosphate salt, 5-10 parts of non-hydrate sodium metasilicate,
2-10 parts of sodium pyrophosphate, 3-5 parts of paraformaldehyde, N, 7-12 parts of the salicylidene -1,2- propane diamine of N'- bis-, 40-70 parts of water；Wherein
Component B is made up of the raw material of following weight parts：5-15 parts of butylphenol PEO ether, sucrose-fatty ester APEO 5-
10 parts, 6-10 parts of pull open powder, 3-5 parts of polyoxyethylene oxypropylene ether, 3-5 parts of PDDA, 2,2-
Two bromo- 4-8 parts of 3- nitrilo allylamines, 5-10 parts of polymethylacrylic acid high-carbon alcohol ester, 3-8 parts of zinc dialkyl dithiophosphate,
30-50 parts of water.
2. a kind of preparation method of disposal of oily sludge agent according to claim 1, it is characterised in that：Described component A
It is made up of the raw material of following weight parts：N- oleoyls -25 parts of N methyl taurine sodium, higher aliphatic PEO ether phosphoric acid
17 parts of ester salt, 10 parts of non-hydrate sodium metasilicate, 2 parts of sodium pyrophosphate, 4 parts of paraformaldehyde, N, the salicylidene -1,2- propane diamine of N'- bis-
12 parts, 40 parts of water.
3. a kind of preparation method of disposal of oily sludge agent according to claim 1, it is characterised in that：Described component A
It is made up of the raw material of following weight parts：N- oleoyls -27 parts of N methyl taurine sodium, higher aliphatic PEO ether phosphoric acid
20 parts of ester salt, 5 parts of non-hydrate sodium metasilicate, 6 parts of sodium pyrophosphate, 5 parts of paraformaldehyde, N, the salicylidene -1,2- propane diamine 7 of N'- bis-
Part, 55 parts of water.
4. a kind of preparation method of disposal of oily sludge agent according to claim 1, it is characterised in that：Described component A
It is made up of the raw material of following weight parts：N- oleoyls -30 parts of N methyl taurine sodium, higher aliphatic PEO ether phosphoric acid
15 parts of ester salt, 8 parts of non-hydrate sodium metasilicate, 10 parts of sodium pyrophosphate, 3 parts of paraformaldehyde, N, the salicylidene -1,2- propane diamine 9 of N'- bis-
Part, 70 parts of water.
5. a kind of preparation method of disposal of oily sludge agent according to claim 1, it is characterised in that：Described component B
It is made up of the raw material of following weight parts：5 parts of butylphenol PEO ether, 7 parts of sucrose-fatty ester APEO, pull open powder
10 parts, 3 parts of polyoxyethylene oxypropylene ether, 4 parts of PDDA, the bromo- 3- nitrilo allylamines 8 of 2,2- bis-
Part, 5 parts of polymethylacrylic acid high-carbon alcohol ester, 6 parts of zinc dialkyl dithiophosphate, 50 parts of water.
6. a kind of preparation method of disposal of oily sludge agent according to claim 1, it is characterised in that：Described component B
It is made up of the raw material of following weight parts：10 parts of butylphenol PEO ether, 10 parts of sucrose-fatty ester APEO, pull open
6 parts of powder, 4 parts of polyoxyethylene oxypropylene ether, 5 parts of PDDA, the bromo- 3- nitrilo allylamines of 2,2- bis-
4 parts, 8 parts of polymethylacrylic acid high-carbon alcohol ester, 8 parts of zinc dialkyl dithiophosphate, 30 parts of water.
7. a kind of preparation method of disposal of oily sludge agent according to claim 1, it is characterised in that：Described component B
It is made up of the raw material of following weight parts：15 parts of butylphenol PEO ether, 5 parts of sucrose-fatty ester APEO, pull open
8 parts of powder, 5 parts of polyoxyethylene oxypropylene ether, 3 parts of PDDA, the bromo- 3- nitrilo allylamines of 2,2- bis-
6 parts, 10 parts of polymethylacrylic acid high-carbon alcohol ester, 3 parts of zinc dialkyl dithiophosphate, 40 parts of water.
8. a kind of application method for disposal of oily sludge agent that preparation method according to claim 1 is obtained, its feature exists
In：Comprise the steps：1. component A is added into water dilution, is made component A medicaments, the weight ratio of component A and water is 1:
2500-5000；Component B is added into water dilution, component B medicaments are made, the weight ratio of component B and water is 1：2500-5000；
2. component A medicaments are added in pending greasy filth, stirs 15-20min, pending greasy filth and the weight ratio of component A medicaments
1：2-3, obtains primary treatment greasy filth；3. component B medicaments are added in the primary treatment greasy filth 2. obtained to step, stirred, directly
To oil, water, mud three phase separation, the weight of pending greasy filth and component B medicaments compares 1：1-2.
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| JPS62156000A (en) * | 1985-12-28 | 1987-07-10 | Kurita Water Ind Ltd | Treatment of oil-containing sludge |
| CN101368110B (en) * | 2008-09-28 | 2011-12-28 | 中国海洋石油总公司 | Process for producing pre-dehydrating agent cationic polymer for crude oil |
| CN102452783B (en) * | 2010-11-03 | 2015-05-13 | 新奥科技发展有限公司 | Compound agent for raising slurry concentration and method thereof |
| CN103803765B (en) * | 2012-11-07 | 2015-08-12 | 中国石油化工股份有限公司 | A kind of greasy filth emulsion splitter and preparation method thereof |
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