Rotary VOCs catalyst oxidation reactor
Technical field
The present invention relates to the purification treatment technology field of organic exhaust gas, more particularly, to a kind of rotary VOCs catalysis oxidation is anti-
Answer device.
Background technology
With China's expanding economy, the volatile organic matter of industrial stationary source(VOCs)To key cities of China group and weight
The impact of point Regional Atmospheric Pollution increasingly shows especially.Industry involved by VOCs is numerous, including coating process, petroleum and petrochemical industry, packaging
Printing, medication chemistry etc..In May, 2010, the General Office of the State Council proposes and strengthens wanting of volatile organic matter prevention and cure of pollution work
Ask, on June 19th, 2015, according to《The Law of the People's Republic of China on the Prevention and Control of Atmospheric Pollution》、《Administrative Regulations on Pollution Discharge Fee Levy》、
《State Council is with regard to printing and distributing the notice of prevention and control of air pollution action plan》In regulation, the Ministry of Finance, the Committee of Development and Reform, ministries and commissions of Chinese Ministry of Environmental Protection three connection
Conjunction is printed and distributed《Volatile organic matter Pollution Charges Site method》, also embody the great attention to VOCs pollution control for the country.
At present, VOCs purification treatment technology can be divided into recovery technology and destruction technology two big class.Recovery technology is by thing
Reason method realizes concentration and separation organic pollution using selective absorption or selectively penetrating, including absorption, absorbs, condenses and film
Separate etc..Destruction technology is by oxidation reaction, organic pollution is oxidized to the side of the harmless small molecule such as carbon dioxide and water
Method, including catalysis burning, catalysis oxidation, biological oxidation, low temperature plasma and photochemical catalytic oxidation etc..For industrial VOCs discharge
Intensity is big, pollutant kind is many, the feature of duration length, the storage of heat accumulating type catalytic oxidation technologies or integrated Adsorption Concentration technology
Heat catalytic oxidation technology becomes the first-selection of industrial VOCs pollution control.
Commonly use at present is two body heat accumulating type catalytic oxidizing equipments, and the patent of Publication No. CN102721073A is open
A kind of regenerative catalytic combustion device with UTILIZATION OF VESIDUAL HEAT IN, maintains catalysis burning by the heat producing in catalyticing combustion process
Continuous service, and residual heat using device is arranged on the top of two catalysis burning beds, produced being catalyzed burning by heat exchanger
Heat transfer give extract heat medium, reclaim waste heat.But, this device volume is big, changes air-flow by reversal valve
Direction, when carrying out switch operation, partly pending waste gas inevitably flows directly into gas vent, causes waste gas to let out
Leakage.
The patent of Publication No. CN103216838A discloses a kind of No leakage regenerative catalytic combustion device, by one
Lift three-way cut-off valve connects two two body regenerative catalytic combustion devices, and in each working cell, switch operation is in not work
Carry out in the state of work, but, this appliance arrangement utilization rate is low, and two regenerative catalytic combustion devices independently separately, ran
In journey, heat loss is serious, floor space is big.
Additionally, situations such as catalytic oxidation in VOCs catalytic oxidizing equipment often easily causes detonation, affect enterprise security
Produce, how both to have realized efficient low-consume removing VOCs, ensure the security of device to be also that need to solving is important ask again
Topic.
Content of the invention
For above-mentioned problem, present invention aim at providing, a kind of heat utilization efficiency is high, operating cost is low, structure is tight
Gather, rotary VOCs catalyst oxidation reactor easy to maintenance.
In order to achieve the above object, the technical solution used in the present invention is as follows:A kind of rotary VOCs catalytic oxidation
Device, described reactor is the housing of sealing, and described housing central section is provided with rotary shaft, is provided with multigroup between rotary shaft and housing
The catalytic reaction module of circular arc, described catalytic reaction module is made up of the catalytic bed on upper strata and the heat storage of lower floor, urges
Change bed and heat storage fixedly mounts on the rotary shaft, the catalytic reaction module in rotary shaft is no less than two groups, adjacent in rotary shaft
Two groups of catalytic reaction modules between be provided with exhausted gas demarcation strip, described case top is communicated with layer, different catalytic reaction
The top of module is both connected on connectivity layer, housing be respectively provided on two sides with air inlet and exhaust outlet, air inlet and exhaust outlet divide
It is not connected to the bottom of the heat storage of different catalytic reaction modules.
In housing of the present invention, the top of connectivity layer is provided with explosion venting valve, and the bottom of housing is provided with sewage draining exit;Work as housing
The reaction temperature of interior catalytic bed is too high or during hypertonia, discharges unnecessary heat or pressure by explosion venting valve, it is to avoid thing
Therefore generation, after the completion of device reaction, by sewage draining exit, the particle reacting residual in housing is cleared up, is facilitated the dimension of device
Shield and maintenance.
Be provided with gas distribution pipe in housing of the present invention to be connected on air inlet, gas distribution pipe be arranged on heat storage just under
Side, described gas distribution pipe is connected with electric calorifie installation;When starting not being circulated work due to device, do not exist inside heat storage
Heat, needs to assist heating by electric calorifie installation, after device circulation work, electric calorifie installation avoids the need for lasting heat supply.
The inwall of housing of the present invention is made up of insulation material, and enclosure interior passes through insulation material and demarcation strip will
Multigroup catalytic reaction module is separated into multiple independent reaction zones, prevents the loss of enclosure interior energy.
Heat storage of the present invention is made up of thermal storage ceramic, and described thermal storage ceramic is saddle ring thermal storage ceramic or honeycomb
One of thermal storage ceramic or two kinds.
Catalytic bed of the present invention is provided with catalyst, and described catalyst is industrial VOCs catalyst for catalytic purifying;
Honeycomb type integer catalyzer including Pt, Pd isoreactivity component or beaded catalyst.
Enclosure interior of the present invention is provided with electric rotating machine and control system, and described electric rotating machine is connected to rotary shaft
On;By the working cycles of control system control device, that is, control rotational time and the anglec of rotation of rotary shaft;Working cycles
Switching can be controlled by the temperature of thermal storage ceramic layer, to avoid too high temperature to affect catalyst life;Work as organic waste
It is also possible to set the time of each working cycles in the case that gas change in concentration is little, circulation is operated according to the time
Switching.
It is an advantage of the current invention that:
1)The capacity usage ratio of assembly of the invention is high, and operating cost is low;
2)Assembly of the invention structure is simple, is switched into gas direction, compact conformation by rotation;
3)Any two groups of catalytic reaction modules in the present invention form a working cell, and organic exhaust gas are by one group of catalytic reaction mould
Block enters, and is discharged by another group of catalytic reaction module through catalytic purification, during realize being catalyzed twice deep purifying and more than completing
Heat retention;
4)After rotation is switched into gaseity, the waste heat of retention will be utilized to preheating and newly enter pending waste gas, greatly reduce
Reactor operation energy consumption;
5)When the rotary shaft assembling catalytic reaction module more than two of the present invention, may be implemented in non-stop-machine in the case of
Line service work;
6)Reactor shell installs explosion venting valve and sewage draining exit, improves the security of device.
Brief description
Fig. 1 is assembly of the invention structure diagram;
Fig. 2 is the structure chart of the reactor containing two groups of catalytic reaction modules of the present invention;
Fig. 3 is the structure top view of the reactor containing three groups of catalytic reaction modules of the present invention.
Wherein, 1 housing, 2 catalytic beds(One group), 2-1 catalytic bed(Two groups), 2-2 catalytic bed(Three groups)3 rotary shafts;
4 heat storages(One group), 4-1 heat storage(Two groups), 5 exhaust outlets, 6 sewage draining exits, 7 electric rotating machines, 8 air inlets, 9 gas distributions
Pipe, 10 explosion venting valves, 11 demarcation strips, 12 connectivity layers.
Specific embodiment
The present invention is described in further detail with specific embodiment for explanation below in conjunction with the accompanying drawings.
Embodiment 1:A kind of rotary VOCs catalyst oxidation reactor as shown in Figure 1,2 and 3, described reactor is close
The housing 1 of envelope, the middle part of described housing 1 is provided with rotary shaft 3, and the catalysis being provided with multigroup circular arc between rotary shaft 3 and housing 2 is anti-
Answer module, described catalytic reaction module is made up of the catalytic bed 2 on upper strata and the heat storage 4 of lower floor, catalytic bed 2 and heat storage
4 are fixedly mounted in rotary shaft 3, and the catalytic reaction module in rotary shaft 3 is no less than two groups, and rotary shaft 3 is urged for adjacent two groups
Change and be provided with exhausted gas demarcation strip 11 between reaction module, the top of described housing 1 is communicated with layer 12, different catalytic reaction mould
The top of block is both connected on connectivity layer 12, housing 1 be respectively provided on two sides with air inlet 8 and exhaust outlet 5, air inlet 8 and exhaust
Mouth 5 is connected to the heat storage 4 of different catalytic reaction modules or the bottom of 4-1.
Embodiment 2:As shown in Fig. 2 a kind of rotary VOCs containing two groups of catalytic reaction modules that the present invention provides urges
Oxidation device, every group of catalytic reaction module forms a fan-shaped gas channel by a catalytic bed 2 and a heat storage 4,
The top of catalytic reaction module is connected with another group of catalytic reaction module by the connectivity layer 12 being formed with reactor shell 1;According to
Secondary catalytic bed 2-1 by another kind of catalytic reaction module and heat storage 4-1, finally reach exhaust outlet 5, two groups of catalytic reaction moulds
Block is provided with exhausted gas demarcation strip 11, by being assemblied in rotary shaft 3, by the rotation of rotary shaft 3, change catalytic reaction module it
Between charge air flow direction.
Embodiment 3:As shown in figure 3, a kind of rotary VOCs catalysis oxygen of three groups of catalytic reaction modules of present invention offer
Change reactor, wherein any two groups of catalytic reaction modules form an annular airflow and process working cell, remaining one group of catalysis is anti-
Answer module can realize the work such as cooling maintenance;Whole reactor can be arranged as required to multigroup catalytic reaction module.
Embodiment 4:As shown in Figures 2 and 3, device is operated cyclic switching, according to the catalytic reaction mould of rotary shaft 3 assembling
Number of blocks, sets the anglec of rotation, for example, the reactor of two groups of catalytic reaction modules of assembling, switch the anglec of rotation every time and be 180 °,
Assemble the reactor of three groups of catalytic reaction modules, the switching anglec of rotation is 120 ° every time.
Embodiment 5:As illustrated in fig. 1 and 2, the method for operating of assembly of the invention is as follows:
1)Under the electric calorifie installation effect of gas distribution pipe, the heat storage of first group of catalytic reaction module is preheated, it is suitable to reach
Reaction temperature, after about 350 DEG C, is preheated by heat storage 4 by the VOCs waste gas that air inlet 8 enters housing 1, be warming up to 300 DEG C ~
400℃;
2)The catalyst oxidation of the catalytic bed 2 through top, VOCs is oxidized to harmless little point of carbon dioxide and water etc.
Son, remaining tail gas reaches catalytic bed 2-1 of second group of catalytic reaction module again through connectivity layer 2, carries out the depth of higher temperature
Oxidation;
3)The heat that oxidizing process produces twice, with reacted air motion, enters the accumulation of heat of second group of catalytic reaction module
Body 4-1, the heat in gas is retained by heat storage 4-1, stores, and the gas after the completion of reaction passes through exhaust outlet 5 row
Go out;
4)Electric rotating machine 7 is rotated axle 3 and is rotated, and the heat storage 4-1 of second group of catalytic reaction module is rotated to air inlet
The top of mouth 8, organizes the preheating of pending waste gas for next;Preheat the heat storage of first group of catalytic reaction module after cooling
4 rotate to the top of exhaust outlet 5, organize the heat storage operation of pending waste gas for next.
Embodiment 6:As shown in Figure 1,2 and 3, it is provided with electric rotating machine 7 and control system inside housing 1, described electric rotating
Machine 7 is connected in rotary shaft 3;By the working cycles of control system control device, that is, control rotation opportunity, the rotation of rotary shaft 3
Turn frequency and the anglec of rotation;The switching of working cycles can be controlled by the temperature of thermal storage ceramic layer 4 or 4-1, to avoid
Too high temperature impact catalyst life;It is also possible to set each work in the case that organic exhaust gas change in concentration is little
The time of circulation, it is operated the switching of circulation according to the time.
Embodiment 7:As shown in Figure 1,2 and 3, assembly of the invention VOCs catalytic oxidizing equipment VOCs concentration conveniently>
1.0g/m3If pending exhaust gas concentration is less than 1.0g/m3It is also possible to first adopt zeolite runner Adsorption Concentration skill before this device
Art, VOCs concentration is brought up to the concentration that this device is suitable for.
It should be noted that above-mentioned is only presently preferred embodiments of the present invention, not it is used for limiting the protection model of the present invention
Enclose, any combination made on the basis of above-described embodiment or equivalents belong to protection scope of the present invention.