A kind of method removing pole piece coating and pole piece coating remove device
Technical field
The invention belongs to technical field of lithium-ion battery, more particularly, to a kind of pole piece coating sweep-out method and removing dress
Put.
Background technology
Lithium ion battery is widely used in digital product because energy density is high, self discharge is little, environmentally friendly, and
Recently as the development of unmanned plane, electric automobile, lithium ion battery also obtains more concerns, nowadays using equipment to battery
Energy density, internal resistance, the chemical property aspect such as cycle life put forward higher requirement.At present, in positive and negative electrode active matter
Material gram volume all perform to ultimate attainment in the case of, how to improve the skill that battery core capacity has become field of lithium further
Art bottleneck.
Fig. 1 is the structural representation of conventional batteries pole piece, can coat work during conventionally produced battery pole piece on empty paper tinsel C
Property material thus forming coating A, the blank of one section of uncoated active substance for soldering polar ear B, can be left in the end of empty paper tinsel C
Region D, then lug B is welded in this white space D.
In order to lift battery core energy density, in the industry in clear area by the way of being also coated with active substance in white space
Coating is similarly formed on domain, then again the coating in the soldering polar ear area in white space is removed, finally in lug to be welded
Area's soldering polar ear.
The method of the removing coating commonly used at present is that mechanical scraper removes method or foamed glue removes method.Mechanical scraper removes
Method is to be scraped off, using scraper plate, the coating being coated on paillon foil, but mechanical scraper removes the cleaning after method is difficult to ensure that coating removing
Degree, and scraper plate easily scratch staves sky paper tinsel.When the coating that method is removed on pole piece is removed using foamed glue, need in each pole
Ear welding region all sticks a piece of gummed paper, and operation is more, and production cost is too high;And cathode size aqueouss, are difficult to phase with gummed paper
Molten, the slurry on gummed paper surface can dissociate to gummed paper surrounding, leads to the coating surface density of its surrounding to thicken, thus having influence on battery core
Performance and thickness.
In order to overcome the shortcomings of both the above method, also proposed in the industry laser cleaning method.As Patent No.
The U.S. patent Nos of US8309880B2 disclose a kind of method of the coating removing on pole piece using laser, but this laser
Ablution still suffers from following deficiency:First, the method is cleaned by region with inert blowing gas pole piece while laser cleaning, with
Realize cleaning and the cooling of pole piece, but this can not coating on fully erased pole piece, laser beam can be affected clear to pole piece coating
Wash effect, and can not effectively collect the dust granules being eliminated, thus having influence on the security performance of battery core;Secondly, laser is clear
Heat can be produced during removing coating, and pass to light paper tinsel, light paper tinsel is heated inequality and effectively fixed and can produce deformation, thus shadow
After sound, operation makes.
The Chinese invention patent application of Publication No. CN105406028A discloses another kind of laser and removes pole piece coating
Method, the mode of coating area vac sorb to be removed on pole piece is fixed by the method, then adopts flat roof type laser beam to move
Coating except this region to be removed.But the method there is also some shortcomings:First, by the way of the fixing pole piece of vac sorb,
Need perforate on cleaning platform, thus realizing vac sorb pole piece, but pole piece and vacuum during pole piece fixing using vac sorb
The corresponding region of hole mouth and coating can cave inward under vacuum, make region to be cleaned deviate laser beam foucing, easily deposit
Clean sordid risk, lead to pole piece welding rosin joint;If vacuum hole nozzle aperture footpath is too small, the powder that pole piece cleaning produces
Dirt easily blocks hole, thus adsorption effect cannot be produced;Secondly, produced by laser burns pole piece, heat can constantly be delivered to
Cleaning platform, in batch production process, the temperature of platform can constantly raise, or even beyond temperature during pole piece cleaning, pole piece
Processing intermittent fever measures less than effective transfer, and the foil surface oxidation after leading to clean is serious, thus having influence on battery core performance.
Content of the invention
It is an object of the invention to provide a kind of side that can prevent the good removing pole piece coating of pole piece deformation, cleaning performance
Method and remove device.
To achieve these goals, the present invention takes following technical solution:
A kind of method removing pole piece coating, comprises the following steps:
Pole piece is positioned on cleaning platform, is provided with the circulating cooling pipeline of circulation cooling liquid in described cleaning platform;
With briquetting, pole piece is pressed on cleaning platform, described briquetting is provided with groove, described groove is by treating on pole piece
Cleaning area is exposed, and the side wall of described groove is provided with vacuum slot, described vacuum slot be arranged in described briquetting
Vacuum line connects;
With laser, calcination is carried out to the pole piece region that briquetting groove exposes, to dispose the coating in this region, laser cleaning
While pole piece coating, the cooling liquid in cleaning platform is lowered the temperature to pole piece, the powder that the vacuum slot on briquetting will produce
Dirt powder collection, coating is removed after finishing and is exposed foil by laser, completes to clean.
Pole piece coating remove device, including the cleaning platform for placing pole piece, is located at swashing above described cleaning platform
Shaven head, is provided with the circulating cooling pipeline of circulation cooling liquid in described cleaning platform;It is provided with briquetting on described cleaning platform,
Described briquetting is pressed on pole piece, and described briquetting is provided with groove, and described groove is corresponding with region to be cleaned on pole piece, described logical
Vacuum slot is provided with the side wall of groove, in described briquetting, is provided with the vacuum line connecting with described vacuum slot.
More specifically, described vacuum slot is arranged on one or more sides wall of described groove.
More specifically, it is provided with the circulating cooling pipeline of circulation cooling liquid in described briquetting.
More specifically, the vacuum of described vacuum slot is -10~-90Kpa.
More specifically, described circulating cooling pipeline is connected with outside cooling recirculation system.
More specifically, described vacuum line is connected with pumped vacuum systems.
From above technical scheme, when the present invention removes pole piece coating, attached fixation is pressed using briquetting matching purge platform
Pole piece to be cleaned, can prevent pole piece to be heated generation stress deformation, also avoiding can be on pole piece by the way of vac sorb
Produce depression, then pole piece synchronously leads to recirculated cooling water in laser cleaning Cleaning Process platform or cleaning platform and briquetting,
Preventing pole piece cleaning intermittent fever from measuring makes foil aoxidize less than diffusion, opens pumped vacuum systems simultaneously, is inhaled by the vacuum on briquetting
The dust that produces when mouth siphons away coating cleaning is it is ensured that the cleanliness factor of light paper tinsel and improve production efficiency after coating cleaning.
Brief description
In order to be illustrated more clearly that the embodiment of the present invention, below will be to required use in embodiment or description of the prior art
Accompanying drawing do simple introduce it should be apparent that, drawings in the following description are only some embodiments of the present invention, for ability
For the those of ordinary skill of domain, on the premise of not paying creative work, can also be obtained other attached according to these accompanying drawings
Figure.
Fig. 1 is the structural representation of existing pole piece;
Fig. 2 is the structural representation of pole piece coating remove device;
Pole piece is pressed in the schematic diagram on cleaning platform by Fig. 3 for briquetting;
Fig. 4 is the schematic diagram of embodiment of the present invention cleaning platform;
Fig. 5 is the internal structure schematic diagram of cleaning platform;
Fig. 6 is the schematic diagram of embodiment of the present invention briquetting;
Fig. 7 is the internal structure schematic diagram of briquetting;
Fig. 8 a, Fig. 8 b are that region to be cleaned is located at the unilateral schematic diagram of pole piece;
Fig. 9 a, Fig. 9 b are the schematic diagram that region to be cleaned is located at pole piece both sides;
Figure 10 a, Figure 10 b are the nonoverlapping schematic diagram in region to be cleaned positioned at pole piece both sides.
Specific embodiment
In order to above and other objects of the present invention, feature and advantage can be become apparent from, the embodiment of the present invention cited below particularly,
And coordinate appended diagram, it is described below in detail.
As shown in Figures 2 and 3, the pole piece coating remove device of the present invention includes cleaning platform 1, briquetting 2, laser head 3 and
Pole piece connecting gear 4, cleaning platform 1 is used for placing pole piece 100, and briquetting 2 is arranged on cleaning platform 1, and briquetting 2 can be by pole piece
100 flatten on cleaning platform 1, and laser head 3 is located at the top of cleaning platform 1, and pole piece 100 is in the drive of pole piece connecting gear 4
Lower movement.The laser head of pole piece cleaning device and pole in the laser head of the present invention, the structure of pole piece connecting gear and prior art
The structure of piece connecting gear is identical, no longer goes to live in the household of one's in-laws on getting married herein and chats.
With reference to Fig. 4 and Fig. 5, cleaning platform 1 is the plate armature with smooth surface, is provided with cleaning platform 1
Circulating cooling pipeline 1a, circulating cooling pipeline 1a are connected with outside cooling recirculation system (not shown), in circulating cooling pipeline 1a
The circulation such as cooling liquid such as cooling water, ethanol.The circulating cooling pipeline 1a of the present embodiment is set using the arrangement mode anyhow interlocking
It is placed in cleaning platform 1, but snakelike arrangement mode may also be employed and be arranged in cleaning platform 1.
As shown in Figure 6 and Figure 7, briquetting 2 is provided with the groove 2a for exposing region to be cleaned on pole piece, groove 2a's
Shape can be the shapes such as square, rectangle or circle, and the size and shape of groove is true by the size and shape in tab welding region
Fixed.It is provided with vacuum line 2b in briquetting 2, vacuum line 2b is connected with outside pumped vacuum systems, in the side wall of groove 2a
On be provided with the vacuum slot 2c connecting with vacuum line 2b, vacuum slot 2c be used for absorb the dust producing during laser cleaning
Grain.Vacuum slot 2c can be arranged on a side wall of groove it is also possible to arrange on each side wall of groove, and vacuum is inhaled
The quantity of mouth can be arranged according to demand, can be one or more, and the shape of vacuum slot requires setting, vacuum slot according to dust suction
Vacuum can be -10~-90Kpa.
The method of the removing pole piece coating of the present invention comprises the following steps:
Pole piece is positioned on cleaning platform, with pole pressure piece under briquetting, pole piece is flattened on cleaning platform 1, briquetting pressure
The effect of pole piece positioning is also acted as, the groove on briquetting exposes region to be cleaned (the tab welding area of pole piece while mean pole piece
Domain);
Start cooling recirculation system, so that cooling liquid is circulated in the circulating cooling pipeline in cleaning platform;
Start pumped vacuum systems, make the groove region of briquetting form vacuum (negative pressure) region;
Start laser head, with laser, calcination is carried out to corresponding with briquetting groove position region to be cleaned on pole piece, with
Dispose the coating on pole piece, the dust granules producing are collected by the vacuum slot that briquetting leads in groove sidewall simultaneously, and laser will apply
Layer is removed after finishing, and exposes foil, thus completing the cleaning in this region.
During present invention cleaning pole piece, with briquetting, pole piece is pushed down, on the one hand pole piece is positioned, on the other hand also by pole piece
No clean region cover, laser is only carried out to the pole piece in groove region;The smooth surface of cleaning platform is smooth, internal
Logical circulating cooling liquid, can take away the heat of laser burns pole piece generation, make platform be in constant low temperature state all the time, to prevent
The heat of pole piece cleaning area cannot spread and foil oxidation seriously or deform;Open vacuum during cleaning to inhale dust granules
Walk it is ensured that foil clean surface is it is ensured that the cleanliness factor of pole piece after pole piece cleaning.
When removing pole piece coating using the inventive method, the startup of cooling cycle system, pumped vacuum systems and laser head is suitable
Sequence does not require, can first start as mentioned above cooling recirculation system restart pumped vacuum systems restart laser head it is also possible to
First startup pumped vacuum systems is restarted cooling recirculation system and is restarted laser head, or it is first-class, as long as ensureing to start laser at first
In laser cleaning, cooling recirculation system and pumped vacuum systems are all in running status.Additionally, in order to pole is better achieved
The cooling of piece, can also arrange circulating cooling pipeline, cleaning platform and the pressure connecting with outside cooling recirculation system in briquetting
All circulate in block cooling liquid, and cooling-down effect is more preferably it is ensured that pole piece is in low temperature state all the time.
The inventive method can be carried out to the pole piece 100 of the active matter coatings of One-sided coatings, as Fig. 8 a and Fig. 8 b institute
Show.The pole piece 100 that bilateral can also be each coated with coating layer of active substance is carried out, as shown in Fig. 9 a and Fig. 9 b.Pole piece 100
When both sides all need cleaning area, the region to be cleaned of pole piece both sides can overlapping (Fig. 9 a, Fig. 9 b), pole piece both sides to be cleaned
(Figure 10 a, Figure 10 b) can also be mutually staggered in region.The shape in region to be cleaned, position, quantity can set according to actual demand
Put.
Compared with prior art, the present invention has advantages below:
1st, in cleaning process, cleaning platform and/or briquetting persistent loop coolant are it is ensured that pole piece cleaning area is permanent for pole piece
Surely it is in low temperature state, thus preventing cleaning area sky paper tinsel oxidation.
2nd, pole piece, in cleaning process, is pushed down to no clean region briquetting, is only exposed pole piece cleaning area;Thus preventing
Cleaning area pole piece deforms.
3rd, in cleaning process, the side of briquetting leads to vacuum to pole piece, and the dust that laser cleaning coating produces is inhaled by vacuum-energy
Except clean, thus ensureing the cleanliness factor of pole piece after cleaning.
Described above to the disclosed embodiments, makes professional and technical personnel in the field be capable of or uses the present invention.
Multiple modifications to these embodiments will be apparent from for those skilled in the art, as defined herein
General Principle can be realized without departing from the spirit or scope of the present invention in other embodiments.Therefore, the present invention
It is not intended to be limited to embodiment illustrated herein, and be to fit to consistent with principles disclosed herein and features of novelty
Widest range.