CN106402898B - The dioxin treatment system of dangerous waste incinerator - Google Patents

The dioxin treatment system of dangerous waste incinerator Download PDF

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Publication number
CN106402898B
CN106402898B CN201610954778.5A CN201610954778A CN106402898B CN 106402898 B CN106402898 B CN 106402898B CN 201610954778 A CN201610954778 A CN 201610954778A CN 106402898 B CN106402898 B CN 106402898B
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China
Prior art keywords
dioxin
tower
waste incinerator
dangerous waste
active carbon
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Application number
CN201610954778.5A
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Chinese (zh)
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CN106402898A (en
Inventor
陆胜
邵文林
谢能
郝继军
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JIANGSU JINGNAN ENVIRONMENTAL PROTECTION TECHNOLOGY Co Ltd
Original Assignee
JIANGSU JINGNAN ENVIRONMENTAL PROTECTION TECHNOLOGY Co Ltd
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Publication of CN106402898A publication Critical patent/CN106402898A/en
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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/44Details; Accessories
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J15/00Arrangements of devices for treating smoke or fumes
    • F23J15/02Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J15/00Arrangements of devices for treating smoke or fumes
    • F23J15/02Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material
    • F23J15/022Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material for removing solid particulate material from the gasflow
    • F23J15/025Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material for removing solid particulate material from the gasflow using filters
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J15/00Arrangements of devices for treating smoke or fumes
    • F23J15/02Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material
    • F23J15/04Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material using washing fluids
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2215/00Preventing emissions
    • F23J2215/30Halogen; Compounds thereof
    • F23J2215/301Dioxins; Furans
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2217/00Intercepting solids
    • F23J2217/10Intercepting solids by filters
    • F23J2217/101Baghouse type
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2217/00Intercepting solids
    • F23J2217/50Intercepting solids by cleaning fluids (washers or scrubbers)
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2219/00Treatment devices
    • F23J2219/10Catalytic reduction devices
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2219/00Treatment devices
    • F23J2219/20Non-catalytic reduction devices
    • F23J2219/201Reducing species generators, e.g. plasma, corona

Abstract

The invention discloses a kind of dioxin treatment system of dangerous waste incinerator, including pretreatment system, incineration system and system for cleaning fume, the incineration system includes rotary kiln and dual firing chamber;The exhanst gas outlet of chilling tower in the system for cleaning fume is to dry type reactor is provided between bag filter, in the injection for wherein carrying out Activity of Lime charcoal;Plasma is provided with after bag filter except dioxin tower;Circulating water pool is provided with active carbon powder adding apparatus, and the water of mixing and doping active carbon powder, which enters back into wet process extracting tower, to be sprayed.The present invention is controlled by the way that many places equipment and technology is arranged in entire dangerous waste incinerator system, effective absorption and control dioxin-like chemical, it is ensured that exhaust emissions is up to standard.High treating effect of the present invention, process range is wide, and versatility is good, and processing depth is high, and there are good treatment effect in operation stability and strong shock resistance, summer in winter.

Description

The dioxin treatment system of dangerous waste incinerator
Technical field
The present invention relates to field of environment protection equipment, especially a kind of dioxin treatment system of dangerous waste incinerator.
Background technique
Dioxin is a kind of colorless and odorless, the serious liposoluble substance of toxicity, is a kind of extremely toxic substance.In atmospheric environment Dioxin source is complicated, and smelting iron and steel, non-ferrous metal metallurgy, vehicle exhaust, burning production, (including pharmaceutical wastewater burns, chemical industry Incineration of waste, consumer waste incineration, coal-burning power plant of factory etc.) dioxin can be generated, wherein the waste incineration of dangerous waste object generates two The mechanism for disliking English is more complicated, thus concerned degree highest.Existing dangerous waste incinerator is less to the processing of dioxin or adopts Dioxin is handled with single equipment, thus cannot be met environmental requirements.
Summary of the invention
The applicant is directed to the disadvantages of above-mentioned existing dangerous waste incinerator is weaker to the processing of dioxin, provides a kind of structure conjunction The dioxin treatment system of the dangerous waste incinerator of reason, so as to reach preferable dioxin treatment effect, it is ensured that exhaust emissions It is up to standard.
The technical solution adopted in the present invention is as follows:
A kind of dioxin treatment system of dangerous waste incinerator, including pretreatment system, incineration system and gas cleaning are handled System, the incineration system include rotary kiln and dual firing chamber;The exhanst gas outlet of chilling tower in the system for cleaning fume To dry type reactor is provided between bag filter, in the injection for wherein carrying out Activity of Lime charcoal;After bag filter Plasma is provided with except dioxin tower;Circulating water pool is provided with active carbon powder adding apparatus, mixing and doping active carbon powder Water enter back into wet process extracting tower and sprayed.
As a further improvement of the above technical scheme:
In the dual firing chamber, air and combustion gas or fuel oil are sprayed into, makes its full combustion, and guarantee flue gas in dual firing chamber 1100 DEG C of temperatures above area residence times are greater than 2 seconds.
The plasma is secondary device except dioxin tower, and the first order is high energy electron ionized region, and the second level is that catalysis is inhaled Attached area.
Beneficial effects of the present invention are as follows:
The present invention is controlled by the way that many places equipment and technology is arranged in entire dangerous waste incinerator system, reaches processing dioxin Effect.In dual firing chamber, dioxin is destroyed by fire with high temperature by spraying into air and combustion gas or fuel oil full combustion.In chilling tower Active carbon powder is sprayed on exhanst gas outlet to the pipeline between bag filter, to the heavy metal and possible regenerated two in flue gas English substance is disliked to be adsorbed.Plasma except made in dioxin tower using high energy electron ray electronics, ion, free radical and in Property particle high speed bombard dioxin macromolecular repeatedly, and realize further reaction using catalysis and absorption.The present invention is by active carbon Powder is added circulating water pool and mixes, and the water for being doped with active carbon powder is sprayed in wet process extracting tower, to more have The absorption of effect and control dioxin-like chemical, it is ensured that exhaust emissions is up to standard.High treating effect of the present invention, process range is wide, general Property it is good, processing depth is high, and there are good treatment effect in operation stability and strong shock resistance, summer in winter.
Detailed description of the invention
Fig. 1 is schematic diagram of the invention.
In figure: 1, hydraulic material-pulling device;2, rotary kiln;3, dual firing chamber;4, waste heat boiler;5, chilling tower;6, dry type is reacted Device;7, bag filter;8, plasma removes dioxin tower;9, first order wet process extracting tower;10, second level wet process extracting tower;11, Smoke re-heater;12, chimney;13, circulating water pool;14, active carbon powder.
Specific embodiment
Specific embodiments of the present invention will be described below with reference to the accompanying drawings.
As shown in Figure 1, dangerous waste incinerator system generally includes waste pretreatment system, feeding system, incineration system, flue gas Several parts such as cleaning treatment system.Waste pretreatment system includes the pretreatment and feed process of waste, and industrial hazard is discarded Object is transported by special-purpose vehicle to disposition center storehouse, is needed broken material to be crushed crusher machine, is grabbed to hang by driving after compatibility and send Enter kiln hood feed inlet on operating platform, is sent into back after kiln hood feed inlet is by the hydraulic insertion plate door of two-stage by hydraulic material-pulling device 1 Rotary kiln 2.
Incineration system by rotary kiln 2 and dual firing chamber 3, slag tap and control system forms;Rotary kiln 2 burn generate flue gas into Enter dual firing chamber 3, in dual firing chamber 3, sprays into air and combustion gas or fuel oil, make its full combustion, and guarantee flue gas in dual firing chamber 3 1100 DEG C of temperatures above area residence times are greater than 2 seconds, destroy dioxin by fire with high temperature.
System for cleaning fume is by waste heat recycling, chilling, dry type reactor 6 and cleaner, sour gas absorption, cigarette Gas reheating, except dioxin equipment forms.The high-temperature flue gas that dual firing chamber 3 generates enters waste heat boiler 4, and recovery section energy production is steamed Vapour, steam for factory steam and other use vapour by gas-distributing cylinder.It is provided in the expansion chamber that flue gas enters waste heat boiler 4 de- Nitre system, it is ensured that the index of exhaust emissions NOX.Flue gas temperature after waste heat boiler 4 drops to 500 DEG C~550 DEG C, flue gas directly into Cooling water is sprayed in chilling tower 5, completes to be down to 200 DEG C of chilling from 500 DEG C in 1 second, ensure that flue gas purification system is transported Capable stability and reliability.In the exhanst gas outlet of chilling tower 5 to dry type reactor 6 is provided between bag filter 7, at it The middle injection for carrying out Activity of Lime charcoal, active carbon powder carry out the heavy metal in flue gas with possible regenerated dioxin-like chemical Absorption, lime carry out moisture absorption and absorb the sour gas in flue gas, and the dust after absorption and absorption enters bag filter 7, It is sent under being drawn of air-introduced machine after being purified by bag filter 7 to plasma except dioxin tower 8, then it is wet to enter the first order for flue gas Carry out depickling once again in method extracting tower 9, second level wet process extracting tower 10, gas up to standard passes through smoke re-heater 11 after flue gas reheat Atmosphere is discharged into chimney 12.Active carbon powder 14 is added circulating water pool 13 and mixed by the present invention, will be doped with active carbon powder 14 water is passed through in wet process extracting tower and is sprayed, to more effectively adsorb and control dioxin-like chemical, it is ensured that tail gas row Unconventional and unrestrained mark.
The plasma that the present invention is arranged after bag filter 7 is secondary device except dioxin tower 8, and the first order is high energy Electron ionization area, the second level are catalytic adsorption area.High energy electron ionized region makes electronics, ion, freedom using high energy electron ray Base and neutral particle high speed bombard dioxin macromolecular repeatedly, and activation ionizes, each component in cracking exhaust gas, are allowed to that oxygen occurs The chemical reaction of a series of complex such as change.High treating effect, process range is wide, and versatility is good, and processing depth is high.Again by latter The catalysis and absorption of grade, can further react no reacted plasma oxygen, improve the utilization rate of plasma oxygen, etc. Ion coefficient of oxygen utilization substantially achieves 100%, reduces generator power, and the dosage of electric energy is few, reduces operating cost.At second level Reason design improves the operation stability of system, strong shock resistance, and there is good treatment effect in summer in winter.With in the market Other reactor ratios, reactor volume is moderate, there is reasonable residence time, fully reacting.
Above description is explanation of the invention, is not intended to limit the invention, without departing from the spirit of the invention, The present invention can make any type of modification.

Claims (3)

1. a kind of dioxin treatment system of dangerous waste incinerator, including pretreatment system, incineration system and gas cleaning processing system System, it is characterised in that: the incineration system includes rotary kiln (2) and dual firing chamber (3);Urgency in the system for cleaning fume The exhanst gas outlet of cold tower (5) carries out Activity of Lime charcoal to dry type reactor (6) are provided between bag filter (7) wherein Injection;Plasma is provided with after bag filter (7) except dioxin tower (8);Circulating water pool (13) is provided with active carbon Powder (14) adding apparatus, the water of mixing and doping active carbon powder (14), which enters back into wet process extracting tower, to be sprayed.
2. the dioxin treatment system of dangerous waste incinerator described in accordance with the claim 1, it is characterised in that: the dual firing chamber (3) In, air and combustion gas or fuel oil are sprayed into, makes its full combustion, and guarantee flue gas 1100 DEG C of temperatures above areas in dual firing chamber (3) Residence time is greater than 2 seconds.
3. the dioxin treatment system of dangerous waste incinerator described in accordance with the claim 1, it is characterised in that: the plasma removes two Disliking Integrata (8) is secondary device, and the first order is high energy electron ionized region, and the second level is catalytic adsorption area.
CN201610954778.5A 2016-11-03 2016-11-03 The dioxin treatment system of dangerous waste incinerator Active CN106402898B (en)

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CN201610954778.5A CN106402898B (en) 2016-11-03 2016-11-03 The dioxin treatment system of dangerous waste incinerator

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Application Number Priority Date Filing Date Title
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Publication number Priority date Publication date Assignee Title
CN107983126A (en) * 2018-01-22 2018-05-04 天津市美好生活科技有限公司 Incineration flue gas minimum discharge purifying treatment method and its processing system
CN110180356A (en) * 2019-03-20 2019-08-30 浙江大维高新技术股份有限公司 The processing unit and method of Cremation Machine incineration flue gas
CN110006050A (en) * 2019-03-20 2019-07-12 浙江大维高新技术股份有限公司 Dangerous waste incineration flue gas purification system and technique
CN110793338B (en) * 2019-11-29 2021-11-02 中国科学院过程工程研究所 Flue gas purification and waste heat utilization system and method
CN112594728A (en) * 2020-12-07 2021-04-02 安徽欣创节能环保科技股份有限公司 Domestic waste incineration fly ash classification treatment system

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CN104637561A (en) * 2015-02-02 2015-05-20 中科华核电技术研究院有限公司 Plasma volume reducing system and method for processing nuclear facility solid waste
CN105202548A (en) * 2015-10-13 2015-12-30 武汉高特维电气有限公司 Flue gas treatment device for domestic refuse incineration
CN105972605A (en) * 2016-03-29 2016-09-28 东南大学 Small household garbage incineration treatment system and incineration treatment method
CN205505013U (en) * 2016-04-06 2016-08-24 山东格润内泽姆环保科技有限公司 Waste liquid, useless burning furnace flue gas processing system that burns admittedly
CN206131008U (en) * 2016-11-03 2017-04-26 江苏景南环保科技有限公司 Useless dioxin processing system who burns burning furnace of danger

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