CN106400477A - 一种短流程前处理用精练剂及其制备方法和应用 - Google Patents
一种短流程前处理用精练剂及其制备方法和应用 Download PDFInfo
- Publication number
- CN106400477A CN106400477A CN201611122894.7A CN201611122894A CN106400477A CN 106400477 A CN106400477 A CN 106400477A CN 201611122894 A CN201611122894 A CN 201611122894A CN 106400477 A CN106400477 A CN 106400477A
- Authority
- CN
- China
- Prior art keywords
- parts
- scouring agent
- short route
- scouring
- hydrogen peroxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000009991 scouring Methods 0.000 title claims abstract description 66
- 238000000034 method Methods 0.000 title claims abstract description 42
- 238000002203 pretreatment Methods 0.000 title claims description 22
- 238000002360 preparation method Methods 0.000 title claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 62
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 25
- 239000004744 fabric Substances 0.000 claims abstract description 21
- 229920000742 Cotton Polymers 0.000 claims abstract description 18
- PIWKPBJCKXDKJR-UHFFFAOYSA-N Isoflurane Chemical compound FC(F)OC(Cl)C(F)(F)F PIWKPBJCKXDKJR-UHFFFAOYSA-N 0.000 claims abstract description 17
- 229960002725 isoflurane Drugs 0.000 claims abstract description 17
- XADCESSVHJOZHK-UHFFFAOYSA-N Meperidine Chemical compound C=1C=CC=CC=1C1(C(=O)OCC)CCN(C)CC1 XADCESSVHJOZHK-UHFFFAOYSA-N 0.000 claims abstract description 16
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 claims abstract description 16
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229960000482 pethidine Drugs 0.000 claims abstract description 16
- 239000007788 liquid Substances 0.000 claims abstract description 15
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 14
- 229920000728 polyester Polymers 0.000 claims abstract description 12
- 238000004061 bleaching Methods 0.000 claims abstract description 11
- 238000005406 washing Methods 0.000 claims abstract description 10
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims abstract description 8
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 44
- -1 hydrogen siloxane Chemical class 0.000 claims description 24
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 15
- JHJUUEHSAZXEEO-UHFFFAOYSA-M sodium;4-dodecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCC1=CC=C(S([O-])(=O)=O)C=C1 JHJUUEHSAZXEEO-UHFFFAOYSA-M 0.000 claims description 15
- 229910052739 hydrogen Inorganic materials 0.000 claims description 13
- 239000001257 hydrogen Substances 0.000 claims description 13
- 238000007789 sealing Methods 0.000 claims description 7
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims description 6
- 238000005516 engineering process Methods 0.000 claims description 6
- 239000007789 gas Substances 0.000 claims description 6
- 238000002386 leaching Methods 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 239000011734 sodium Substances 0.000 claims description 6
- 229910052708 sodium Inorganic materials 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 5
- 229940077388 benzenesulfonate Drugs 0.000 claims description 4
- 244000144992 flock Species 0.000 claims description 4
- 229910052943 magnesium sulfate Inorganic materials 0.000 claims description 3
- 235000019341 magnesium sulphate Nutrition 0.000 claims description 3
- 239000000080 wetting agent Substances 0.000 claims description 3
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims 1
- 125000005396 acrylic acid ester group Chemical group 0.000 claims 1
- 150000001335 aliphatic alkanes Chemical class 0.000 claims 1
- 238000009835 boiling Methods 0.000 claims 1
- 229910052731 fluorine Inorganic materials 0.000 claims 1
- 239000011737 fluorine Substances 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 17
- 230000001804 emulsifying effect Effects 0.000 abstract description 10
- 239000004753 textile Substances 0.000 abstract description 6
- 239000007800 oxidant agent Substances 0.000 abstract description 5
- 230000001590 oxidative effect Effects 0.000 abstract description 5
- 238000009990 desizing Methods 0.000 abstract 2
- VFRRWVCMOFUSPN-UHFFFAOYSA-N 4-methylhexane-3,3-diol Chemical compound CCC(C)C(O)(O)CC VFRRWVCMOFUSPN-UHFFFAOYSA-N 0.000 abstract 1
- 238000010923 batch production Methods 0.000 abstract 1
- 239000003599 detergent Substances 0.000 abstract 1
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 abstract 1
- 230000035515 penetration Effects 0.000 abstract 1
- 229920001843 polymethylhydrosiloxane Polymers 0.000 abstract 1
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 abstract 1
- 239000000835 fiber Substances 0.000 description 6
- 239000012535 impurity Substances 0.000 description 5
- 230000008901 benefit Effects 0.000 description 4
- 230000008595 infiltration Effects 0.000 description 4
- 238000001764 infiltration Methods 0.000 description 4
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 4
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- 235000011121 sodium hydroxide Nutrition 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 239000001814 pectin Substances 0.000 description 3
- 235000010987 pectin Nutrition 0.000 description 3
- 229920001277 pectin Polymers 0.000 description 3
- 102000004169 proteins and genes Human genes 0.000 description 3
- 108090000623 proteins and genes Proteins 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- 239000012224 working solution Substances 0.000 description 3
- UZIJLTBYAYIURJ-JAIQZWGSSA-N 2-[(z)-(9-hydroxy-10-methoxy-2,2,4-trimethyl-1h-chromeno[3,4-f]quinolin-5-ylidene)methyl]thiophene-3-carbonitrile Chemical group C1=CC=2NC(C)(C)C=C(C)C=2C2=C1C=1C(OC)=C(O)C=CC=1O\C2=C/C=1SC=CC=1C#N UZIJLTBYAYIURJ-JAIQZWGSSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 229910017053 inorganic salt Inorganic materials 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 239000011265 semifinished product Substances 0.000 description 2
- 206010002091 Anaesthesia Diseases 0.000 description 1
- 241000255789 Bombyx mori Species 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000037005 anaesthesia Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 239000013522 chelant Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000010668 complexation reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 235000018102 proteins Nutrition 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 230000002277 temperature effect Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
- D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/152—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen having a hydroxy group bound to a carbon atom of a six-membered aromatic ring
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/165—Ethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
- D06M13/2246—Esters of unsaturated carboxylic acids
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/345—Nitriles
- D06M13/348—Nitriles unsaturated, e.g. acrylonitrile
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/372—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen containing etherified or esterified hydroxy groups ; Polyethers of low molecular weight
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Detergent Compositions (AREA)
Abstract
本发明属于纺织助剂技术领域，公开了一种短流程前处理用精练剂，包括以下重量份数的组分：十二烷基苯磺酸钠12‑20份、壬基酚1‑4份、异氟烷0.9‑10份、哌替啶1‑1.5份、丙烯酸酯5‑7份、丙烯腈10‑15份、聚甲基氢硅氧烷12‑14份、二乙基丙二醇1‑12份、乙醇90‑150份，本发明同时公布了该精练剂的制备方法，并将其应用至涤棉混纺织物的退/煮一步法工艺中、纯棉织物的退/煮一漂两步法工艺及涤棉混纺织物冷扎堆工艺中，同时公布了上述工艺的工艺流程和浸轧液配方。本申请精练剂渗透迅速、乳化能力强、净洗能力高、耐高温和氧化剂，应用范围广阔，处理效果好。
Description
技术领域：
本发明属于纺织助剂应用技术领域，具体的涉及一种短流程前处理用精练剂。
背景技术：
精练剂是用化学和物理方法去除棉、毛、麻、蚕丝以及合成纤维等各类纺织品上天然杂质、沾污物以及织造浆料的工艺过程叫做精练。因而，广义上说，在精练过程中添加的酸、碱、氧化剂、还原剂和各类表面活性剂等化学物品都可以叫做精练剂。但是在纺织行业中，一般说到精练剂，大多是狭义的概念，主要是指各类阴离子、非离子表面活性剂以及适当的添加剂，经过一定的配比的方法得到的一种以洗涤作用为主的、兼有渗透、乳化、分散、络合等协同作用的复配物。
退煮漂一浴汽蒸法工艺，在高浓度碱和高温情况下，很易引起双氧水的快速分解和加重织物的损伤。这只能通过降低烧碱用量和加入高温强碱的稳定剂来实现。但降低烧碱用量会降低退煮效果，尤其对重浆和含杂量大的纯棉厚重织物。故此工艺适用于轻浆的中、薄型织物和涤棉混纺织物。
短流程前处理工艺主要含有三个环节，即浸轧→反应→洗涤，所以无论是汽蒸法还是冷轧堆法工艺，提高织物带液量是短流程前处理取得好的效果之主要关键。同时短流程前处理过程的水洗过程比较频繁造成大量废液产生。
发明内容：
本发明的目的是针对现有技术的问题，提供一种短流程前处理用精练剂，有效降低无机盐和双氧水的添加，显著提高轧液率，减少水洗次数，渗透迅速、乳化能力强、净洗能力高、耐高温和氧化剂。
为实现上述目的，本发明采用以下技术方案：
一种短流程前处理用精练剂，包括以下重量份数的组分：
十二烷基苯磺酸钠12-20份、壬基酚1-4份、异氟烷0.9-10份、哌替啶1-1.5份、丙烯酸酯5-7份、丙烯腈10-15份、聚甲基氢硅氧烷12-14份、二乙基丙二醇1-12份、乙醇90-150份。
优选的，十二烷基苯磺酸钠14-18份、壬基酚2-3份、异氟烷0.9-1份、哌替啶1.2-1.5份、丙烯酸酯6-7份、丙烯腈12-14份、聚甲基氢硅氧烷12-14份、二乙基丙二醇9-12份、乙醇110-120份。
上述短流程前处理用精练剂的制备方法：
将十二烷基苯磺酸钠、壬基酚、哌替啶、丙烯酸酯与丙烯腈按照重量份数混合密封缓慢滴加异氟烷，滴加完毕后密封缓慢搅拌加热处理2-3小时后静置过夜，静置后与其他组分混合后即可。
通过密封添加异氟烷，保障加工的安全防护，还能够起到提高精练剂的乳化能力的作用，加速精练剂的制备合成过程。
将上述精练剂应用为涤棉混纺织物的退/煮一步法工艺中，可以代替无机盐钠盐的添加，缩短反应时间减少水洗的次数，提高精练效果。
浸轧液组成为：精练剂2-3g/L、30％浓度的双氧水10-15g/L、湿润剂JFC 1g/L；
工艺流程：织物首先经过二浸二扎后在100℃气蒸10-15分钟，最后用热水洗涤两遍，冷水洗涤两遍即可。
将上述精练剂应用于纯棉织物的退/煮一漂两步法工艺中，代替了无机钠盐的添加，并且降低了双氧水的添加量，降低反应的能耗需求，提高经济效益和生态效益。
退煮浸轧液组成：精练剂1-3g/L、30％浓度的双氧水5-10g/L；
漂白浸轧液组成：30％浓度的双氧水5-10g/L、硫酸镁0.1g/L；
工艺流程为：织物首先经过二浸二扎，然后再100℃气蒸20分钟，再浸轧漂液，在80℃漂白10分钟，最后用热水洗涤两遍，冷水洗涤两遍即可。
将上述精练剂应用于涤棉混纺织物冷扎堆工艺中，可以提高双氧水的稳定性，代替了双氧水稳定剂的添加，并且降低了氢氧化钠和双氧水的添加，提高反应的经济效益和工艺效果。
浸轧液组成：精练剂3-4g/L、30％浓度的双氧水5-10g/L、氢氧化钠20-25g/L；
工艺流程为：织物经多浸多轧后在40℃卷堆5-7小时，然后经过热水洗涤两遍即可。
十二烷基苯磺酸钠与聚甲基氢硅氧烷及其他组分结合制成的新型短流程前处理精练剂具有渗透迅速、乳化能力强、净洗能力高、耐高温和氧化剂的效果，可以在短时间内出去纤维中的油蜡、果胶、蛋白质等杂质，还能够除去纤维上的浆料和油污，提高半成品的毛细效果，并且对双氧水的添加要求量降低，降低应用加工的能耗。
异氟烷的化学名为1-氯-2,2,2-三氟乙基二氟甲基醚，是一种吸入性麻醉药，在医学上应用为麻醉剂，本申请将其应用到纺织助剂技术领域，其能够提高精练剂的乳化效果，使得混合精练剂在短时间便可以达到良好的除去纤维上果胶、蛋白质、油脂等杂质的能力。
本发明具有以下有益效果：
(1)本发明精练剂具有渗透迅速、乳化能力强、净洗能力高、耐高温和氧化剂的效果，可以在短时间内除去纤维中的油蜡、果胶、蛋白质等杂质，还能够除去纤维上的浆料和油污，提高半成品的毛细效果。
(2)本发明精练剂应用广发，可以用于涤棉混纺织物的退/煮一步法工艺中、纯棉织物的退/煮一漂两步法工艺及涤棉混纺织物冷扎堆工艺中，处理效果优异，经济环保。
(3)本发明精练剂在应用过程中对双氧水的添加要求量降低，同时减少了无机钠盐的添加，降低加工的能耗。
(4)本发明精练剂对工艺过程的温度要求降低，较低温度下可以达到优异的处理效果，处理时间短，提高加工的经济效益。
(5)本发明精练剂热稳定性高，同时耐酸耐碱耐电解质性能好，应用范围广阔。
(6)本发明精练剂还能够有效螯合工作液中的重金属离子，减少了工作液中金属螯合剂的添加。
(7)本发明精练剂对双氧水起到良好的稳定作用，减少了双氧水稳定剂的添加。
(8)本发明精练剂可以显著提高轧液率，提高精练效果。
具体实施方式：
为了更好的理解本发明，下面通过实施例对本发明进一步说明，实施例只用于解释本发明，不会对本发明构成任何的限定。
实施例一
一种短流程前处理用精练剂，包括以下重量份数的组分：
十二烷基苯磺酸钠12份、壬基酚1份、异氟烷0.9份、哌替啶1份、丙烯酸酯5份、丙烯腈10份、聚甲基氢硅氧烷12份、二乙基丙二醇1份、乙醇90份。
实施例二
一种短流程前处理用精练剂，包括以下重量份数的组分：
十二烷基苯磺酸钠20份、壬基酚4份、异氟烷10份、哌替啶1.5份、丙烯酸酯7份、丙烯腈15份、聚甲基氢硅氧烷14份、二乙基丙二醇12份、乙醇150份。
实施例三
一种短流程前处理用精练剂，包括以下重量份数的组分：
十二烷基苯磺酸钠12份、壬基酚4份、异氟烷0.9份、哌替啶1.5份、丙烯酸酯5份、丙烯腈15份、聚甲基氢硅氧烷12份、二乙基丙二醇12份、乙醇90份。
实施例四
一种短流程前处理用精练剂，包括以下重量份数的组分：
十二烷基苯磺酸钠14份、壬基酚2份、异氟烷0.9份、哌替啶1.5份、丙烯酸酯6份、丙烯腈12份、聚甲基氢硅氧烷12份、二乙基丙二醇9份、乙醇110份。
实施例五
一种短流程前处理用精练剂，包括以下重量份数的组分：
十二烷基苯磺酸钠18份、壬基酚3份、异氟烷1份、哌替啶1.5份、丙烯酸酯7份、丙烯腈14份、聚甲基氢硅氧烷14份、二乙基丙二醇12份、乙醇120份。
实施例六
十二烷基苯磺酸钠14份、壬基酚3份、异氟烷0.9份、哌替啶1.5份、丙烯酸酯6份、丙烯腈14份、聚甲基氢硅氧烷12份、二乙基丙二醇12份、乙醇110份。
实施例七
一种短流程前处理用精练剂，包括以下重量份数的组分：
十二烷基苯磺酸钠18份、壬基酚2份、异氟烷1份、哌替啶1.2份、丙烯酸酯7份、丙烯腈12份、聚甲基氢硅氧烷14份、二乙基丙二醇9份、乙醇120份。
实施例八
一种短流程前处理用精练剂，包括以下重量份数的组分：
十二烷基苯磺酸钠16份、壬基酚2份、异氟烷0.9份、哌替啶1.3份、丙烯酸酯7份、丙烯腈13份、聚甲基氢硅氧烷13份、二乙基丙二醇10份、乙醇110份。
上述短流程前处理用精练剂的制备方法：
将十二烷基苯磺酸钠、壬基酚、哌替啶、丙烯酸酯与丙烯腈按照重量份数混合密封缓慢滴加异氟烷，滴加完毕后密封缓慢搅拌加热处理2-3小时后静置过夜，静置后与其他组分混合后即可。
将上述精练剂应用为涤棉混纺织物的退/煮一步法工艺中，
浸轧液组成为：精练剂2-3g/L、30％浓度的双氧水10-15g/L、湿润剂JFC 1g/L；
工艺流程：织物首先经过二浸二扎后在100℃气蒸10-15分钟，最后用热水洗涤两遍，冷水洗涤两遍即可。
将上述精练剂应用于纯棉织物的退/煮一漂两步法工艺中
退煮浸轧液组成：精练剂1-3g/L、30％浓度的双氧水5-10g/L；
漂白浸轧液组成：30％浓度的双氧水5-10g/L、硫酸镁0.1g/L；
工艺流程为：织物首先经过二浸二扎，然后再100℃气蒸20分钟，再浸轧漂液，在80℃漂白10分钟，最后用热水洗涤两遍，冷水洗涤两遍即可。
将上述精练剂应用于涤棉混纺织物冷扎堆工艺中。
浸轧液组成：精练剂3-4g/L、30％浓度的双氧水5-10g/L、氢氧化钠20-25g/L；
工艺流程为：织物经多浸多轧后在40℃卷堆5-7小时，然后经过热水洗涤两遍即可。
表一：本发明精练剂效果评价(棉混纺织物的退/煮一步法工艺)
| 去污能力 | 乳化能力 | 轧液率 | |
| 实施例一 | + | + | 110％ |
| 实施例二 | + | + | 110％ |
| 实施例三 | + | ++ | 110％ |
| 实施例四 | + | + | 120％ |
| 实施例五 | ++ | +++ | 110％ |
| 实施例六 | ++ | +++ | 120％ |
| 实施例七 | +++ | +++ | 120％ |
| 实施例八 | +++ | ++++ | 120％ |
| 烷基酚聚氧乙烯醚组 | + | + | 100％ |
| 烷基苯磺酸钠组 | + | + | 100％ |
| 磷酸酯盐组 | + | + | 100％ |
| 空白对照 | 0 | 0 | 100％ |
表二：本发明精练剂效果评价(纯棉织物的退/煮一漂两步法工艺)
表三：本发明精练剂效果评价(涤棉混纺织物冷扎堆工艺)
所述空白对照为不添加精练剂，所述烷基酚聚氧乙烯醚组、烷基苯磺酸钠组及磷酸酯盐组为仅添加烷基酚聚氧乙烯醚、烷基苯磺酸钠及磷酸酯盐作为精练剂应用于所述工艺中进行效果评价。
以空白对照为标准，记作0。精练剂提高工作液的去污能力、乳化能力及净洗能力、漂白效果记作+，+越多代表效果越明显；精练剂降低去污能力、乳化能力及净洗能力、漂白效果记作－。
Claims (6)
1.一种短流程前处理用精练剂，其特征在于，包括以下重量份数的组分：
十二烷基苯磺酸钠12-20份、壬基酚1-4份、异氟烷0.9-10份、哌替啶1-1.5份、丙烯酸酯5-7份、丙烯腈10-15份、聚甲基氢硅氧烷12-14份、二乙基丙二醇1-12份、乙醇90-150份。
2.根据权利要求1所述的一种短流程前处理用精练剂，其特征在于，包括以下重量份数的组分：
十二烷基苯磺酸钠14-18份、壬基酚2-3份、异氟烷0.9-1份、哌替啶1.2-1.5份、丙烯酸酯6-7份、丙烯腈12-14份、聚甲基氢硅氧烷12-14份、二乙基丙二醇9-12份、乙醇110-120份。
3.权利要求1或2所述的一种短流程前处理用精练剂的制备方法，其特征在于：将十二烷基苯磺酸钠、壬基酚、哌替啶、丙烯酸酯与丙烯腈按照重量份数混合密封缓慢滴加异氟烷，滴加完毕后密封缓慢搅拌加热处理2-3小时后静置过夜，静置后与其他组分混合后即可。
4.权利要求1或2所述的一种短流程前处理用精练剂的应用，其特征在于：
应用为涤棉混纺织物的退/煮一步法工艺中：
浸轧液组成为：精练剂2-3g/L、30％浓度的双氧水10-15g/L、湿润剂JFC 1g/L；
工艺流程：织物首先经过二浸二扎后在100℃气蒸10-15分钟，最后用热水洗涤两遍，冷水洗涤两遍即可。
5.权利要求1或2所述的一种短流程前处理用精练剂的应用，其特征在于：
应用于纯棉织物的退/煮一漂两步法工艺中：
退煮浸轧液组成：精练剂1-3g/L、30％浓度的双氧水5-10g/L；
漂白浸轧液组成：30％浓度的双氧水5-10g/L、硫酸镁0.1g/L；
工艺流程为：织物首先经过二浸二扎，然后再100℃气蒸20分钟，再浸轧漂液，在80℃漂白10分钟，最后用热水洗涤两遍，冷水洗涤两遍即可。
6.权利要求1或2所述的一种短流程前处理用精练剂的应用，其特征在于：
应用于涤棉混纺织物冷扎堆工艺中：
浸轧液组成：精练剂3-4g/L、30％浓度的双氧水5-10g/L、氢氧化钠20-25g/L；
工艺流程为：织物经多浸多轧后在40℃卷堆5-7小时，然后经过热水洗涤两遍即可。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611122894.7A CN106400477A (zh) | 2016-12-08 | 2016-12-08 | 一种短流程前处理用精练剂及其制备方法和应用 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611122894.7A CN106400477A (zh) | 2016-12-08 | 2016-12-08 | 一种短流程前处理用精练剂及其制备方法和应用 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106400477A true CN106400477A (zh) | 2017-02-15 |
Family
ID=58084139
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611122894.7A Pending CN106400477A (zh) | 2016-12-08 | 2016-12-08 | 一种短流程前处理用精练剂及其制备方法和应用 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106400477A (zh) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107059434A (zh) * | 2017-04-11 | 2017-08-18 | 东莞德永佳纺织制衣有限公司 | 一种涤棉深色一浴染色方法 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102486003A (zh) * | 2010-12-03 | 2012-06-06 | 上海王港华纶印染有限公司 | 一种纯棉机织物前处理短流程工艺 |
| CN102828415A (zh) * | 2012-09-19 | 2012-12-19 | 吴江市意胜纺织有限公司 | 一种棉纺织物精炼剂 |
| CN104631129A (zh) * | 2013-11-14 | 2015-05-20 | 青岛鑫益发工贸有限公司 | 前处理节能减排生产技术 |
-
2016
- 2016-12-08 CN CN201611122894.7A patent/CN106400477A/zh active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102486003A (zh) * | 2010-12-03 | 2012-06-06 | 上海王港华纶印染有限公司 | 一种纯棉机织物前处理短流程工艺 |
| CN102828415A (zh) * | 2012-09-19 | 2012-12-19 | 吴江市意胜纺织有限公司 | 一种棉纺织物精炼剂 |
| CN104631129A (zh) * | 2013-11-14 | 2015-05-20 | 青岛鑫益发工贸有限公司 | 前处理节能减排生产技术 |
Non-Patent Citations (3)
| Title |
|---|
| 杜建伟: "《实用英汉流行病学词典》", 31 October 2014 * |
| 董永春: "《纺织助剂化学与应用》", 31 July 2007 * |
| 陈旭素等: "《麻醉科护理基本知识与技术》", 31 January 2015 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107059434A (zh) * | 2017-04-11 | 2017-08-18 | 东莞德永佳纺织制衣有限公司 | 一种涤棉深色一浴染色方法 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101629130B (zh) | 一种织物同浴除油剂 | |
| CN101914848B (zh) | 一种棉针织物用前处理助剂、制备方法及其应用 | |
| CN100441767C (zh) | 一种棉织物生物酶高温退浆精练漂白一步法前处理工艺 | |
| CN103741513B (zh) | 化纤织物中性退浆除油染色一浴助剂及其制备方法 | |
| CN105155249B (zh) | 一种低温精练剂、其制备方法及其用途 | |
| CN107988737A (zh) | 纯棉面料短流程前处理工艺 | |
| CN109505134A (zh) | 一种棉针织、纱线一浴低温低碱精练剂 | |
| CN105755813B (zh) | 一种可使纺织品耐磨度提高的纺织助剂及其制备方法 | |
| CN108252000B (zh) | 一种纺织面料前处理工艺 | |
| CN109629271A (zh) | 一种防沾色皂洗剂及其制备方法 | |
| CN108978188A (zh) | 一种低温精练剂及其制备方法 | |
| CN108193517A (zh) | 涤棉针织布直接/分散一浴法短流程染整工艺 | |
| CN106400477A (zh) | 一种短流程前处理用精练剂及其制备方法和应用 | |
| JPH06507213A (ja) | 繊維製品材料への水性処理液の改良された噴霧適用 | |
| CN114746603A (zh) | 柔软基剂 | |
| WO2014082394A1 (zh) | 一种金属配合物氧化体系及其应用 | |
| CN110042647A (zh) | 一种羊绒或羊毛的高白度低温漂白方法 | |
| JP2013506054A (ja) | 染色助剤 | |
| WO2011096553A1 (ja) | 繊維用精練剤組成物 | |
| CN104862112A (zh) | 一种衣物除油剂及其制备方法 | |
| CN111749022A (zh) | 低泡高浓精练剂及其制备方法 | |
| JPH0544161A (ja) | 泡立ちの少ない非シリコーン水性繊維助剤組成物、その製造法及び使用法 | |
| EP4063033A1 (en) | Detergent composition | |
| JP2022102519A (ja) | 柔軟基剤 | |
| TW201842254A (zh) | 精練劑組合物及纖維製品之製造方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170215 |