CN106400173A - Preparation method of Chinese herbal medicine fragrant polyarmide fiber - Google Patents

Preparation method of Chinese herbal medicine fragrant polyarmide fiber Download PDF

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Publication number
CN106400173A
CN106400173A CN201610912907.4A CN201610912907A CN106400173A CN 106400173 A CN106400173 A CN 106400173A CN 201610912907 A CN201610912907 A CN 201610912907A CN 106400173 A CN106400173 A CN 106400173A
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China
Prior art keywords
chinese herbal
spinning
herbal medicine
preparation
fypro
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CN201610912907.4A
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Chinese (zh)
Inventor
章云
张贝尼
张娃妮
柯模松
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Anhui Yi Caini Fibrous Material Science And Technology Ltd
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Anhui Yi Caini Fibrous Material Science And Technology Ltd
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Priority to CN201610912907.4A priority Critical patent/CN106400173A/en
Publication of CN106400173A publication Critical patent/CN106400173A/en
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    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/88Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
    • D01F6/90Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyamides
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/10Other agents for modifying properties
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/10Other agents for modifying properties
    • D01F1/103Agents inhibiting growth of microorganisms

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Cosmetics (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The invention discloses a preparation method of a Chinese herbal medicine fragrant polyarmide fiber and belongs to the field of textile materials. The preparation method comprises preparing an aqueous emulsion of Chinese herbal medicines, preparing a microcapsule fragrance agent, preparing a chitosan solution, mixing the aqueous emulsion of Chinese herbal medicines, the microcapsule fragrance agent, the chitosan solution and a polyamide fiber spinning solution and carrying out spinning raw material spinning, washing, drying and tube-shaped yarn formation so that finished product Chinese herbal medicine fragrant polyarmide fibers are obtained. The polyarmide fiber has good traditional Chinese medicine health effects, good drug adhesion and durability, good wearing performances, a natural aroma for masking the smell of Chinese herbal medicines and has antibacterial properties.

Description

A kind of preparation method of Chinese herbal medicine aroma type Fypro
Technical field
The invention belongs to textile material field is and in particular to a kind of preparation method of Chinese herbal medicine aroma type Fypro.
Background technology
Textile is one of most basic demand for the survival of mankind, with increasing of the size of population and carrying of quality of life Height, the also more and more higher of the requirement to textile material.It is desirable to textile material has traditional resisting cold, the general function such as attractive in appearance While, there is special miscellaneous function again, such as medicinal health function, fragrant performance.It is critical only that of Development of Textile Industry is new The exploitation of product.At present, functionalization textile technology is the major trend of World Textile technology development.Using new material, new technology, New technology development has multipurpose, high-performance, high value-added product has become the new development trend of textile, especially health care Medicine is be combined with each other with textile, to obtain new taking and feature.But at present with regard to the research of healthcare face fabric, it need Develop further.In recent years, the health-care textile material having had Chinese medicine improvement emerges, but difficulty has lasting best-selling product on the market Occur, trace it to its cause and mainly have:Drug attachment and persistency are poor, and the wearability of fabric is poor, and Chinese herbal medicine abnormal smells from the patient is too heavy.
Content of the invention
In order to solve the above problems, the invention provides a kind of preparation method of Chinese herbal medicine aroma type Fypro, adopt With the Fypro that the method is obtained, there is good Chinese medicine health-care performance, and drug attachment, persistency are good, wearability Good, there is natural aromatic, can effectively cover the abnormal smells from the patient of Chinese herbal medicine, and there is anti-microbial property.
In order to solve the above problems, the present invention employs the following technical solutions:
A kind of preparation method of Chinese herbal medicine aroma type Fypro, comprises the following steps:
Step one:Adopt super-refinement powder body process equipment by after Radix Glycyrrhizae, the Radix Angelicae Dahuricae, Herba Dendrobii mixing, being processed into particle diameter is 30 ~50 nanometers of super-refinement powder body, and powder body and dispersant are added to the water, mixing and stirring, ultrasonic disperse deaerates, and is obtained Chinese herbal medicine aqueous emulsion;
Step 2:To in the saturated aqueous solution of beta-schardinger dextrin-add jasmin quintessence oil, with magnetic stirring apparatuss with 500r/min Speed stir 30~50min, then stand 24 hours froth breakings, obtain jasmine microcapsule aromatic agent;
Step 3:Shitosan is dissolved in the acetic acid solution that mass concentration is 90%, is stirred at room temperature to being completely dissolved, is obtained Chitosan solution;
Step 4:By Chinese herbal medicine aqueous emulsion, jasmine microcapsule aromatic agent, chitosan solution, Fypro spinning liquid with Weight ratio 3~4.5:0.5~0.6:11~13:86~92 mixed grindings 3~5 hours, then through deaeration, filtration, prepared spinning Stock solution;
Step 5:By spinning solution in spinning coagulation bath spinning moulding, spinning speed is 20~40m/min, and spinning draws Stretch than for 60~100%, technological process is:Spinning solution-spinning-washing-drying-one-tenth cylinder-finished product, obtains Chinese herbal medicine aroma type and gathers Nylon.
Preferably, the saturated aqueous solution temperature control of the beta-schardinger dextrin-described in step 2 is at 40 DEG C.
Preferably, the weight of the beta-schardinger dextrin-described in step 2 and jasmin quintessence oil is than for 6: 1.
Preferably, the dispersant described in step one is polyacrylic acid sodium salt.
Preferably, the weight of the powder body described in step one, dispersant, water is than for 1:0.2:4.
Preferably, in the chitosan solution described in step 3, the mass concentration of shitosan is 1.5~3%.
Preferably, the consisting of of the spinning coagulation bath described in step 5:Sulphuric acid 100~150g/L, sodium sulfate 300~ 350g/L, zinc sulfate 8~10g/L, aluminum sulfate 8~10g/L;The temperature control of spinning coagulation bath is at 40~50 DEG C.
Preferably, in described step 5, drying temperature is 70~80 DEG C.
Preferably, described Fypro spinning liquid is that polyamide is obtained through dipping, squeezing, pulverizing and dissolving.
The beneficial effects of the present invention is:
1) pass through to add Chinese herbal medicine aqueous emulsion in Fypro spinning liquid, give Fypro with excellent Chinese medicine Health-care effect.Wherein Radix Glycyrrhizae has the effects such as heat-clearing and toxic substances removing, antiallergic;The Radix Angelicae Dahuricae has the functions such as dehumidifying, promoting blood circulation and stopping pain that get rid of illness;Stone Dry measure used in former times has functions that anticancer.
2) pass through to microcapsule aromatic agent in Fypro spinning liquid, give Fypro with natural Flos Jasmini Sambac Perfume (or spice), can cover the abnormal smells from the patient of Chinese medicine, add chitosan solution again, improve the antibiotic property of fiber.
3) when the saturated aqueous solution temperature control of beta-schardinger dextrin-is at 40 DEG C, the weight of beta-schardinger dextrin-and jasmin quintessence oil is than for 6: 1, the prepared lasting intensity of microcapsule aromatic agent and slow-release time optimal.
4) the Chinese herbal medicine aroma type Fypro that the present invention is obtained, drug attachment, persistency, taking are good, and make Standby process is simple is it is easy to industrialized production.
Specific embodiment
For making the object, technical solutions and advantages of the present invention clearer, below the present invention is made further to retouch in detail State.Based on the embodiment in the present invention, those of ordinary skill in the art are obtained under the premise of not making creative work Every other embodiment, broadly falls into the scope of protection of the invention.
Embodiment 1
A kind of preparation method of Chinese herbal medicine aroma type Fypro, comprises the following steps:
Step one:Adopt super-refinement powder body process equipment by after Radix Glycyrrhizae, the Radix Angelicae Dahuricae, Herba Dendrobii mixing, being processed into particle diameter is 30 ~50 nanometers of super-refinement powder body, and powder body and dispersant are added to the water, mixing and stirring, ultrasonic disperse deaerates, and is obtained Chinese herbal medicine aqueous emulsion;
Step 2:To in the saturated aqueous solution of beta-schardinger dextrin-add jasmin quintessence oil, with magnetic stirring apparatuss with 500r/min Speed stirring 30min, then stand 24 hours froth breakings, obtain jasmine microcapsule aromatic agent;
Step 3:Shitosan is dissolved in the acetic acid solution that mass concentration is 90%, is stirred at room temperature to being completely dissolved, is obtained Chitosan solution;
Step 4:By Chinese herbal medicine aqueous emulsion, jasmine microcapsule aromatic agent, chitosan solution, Fypro spinning liquid with Weight compares 3:0.5:11:86 mixed grindings 3 hours, then through deaeration, filtration, prepared spinning solution;
Step 5:By spinning solution in spinning coagulation bath spinning moulding, spinning speed be 20m/min, spin-draw ratio For 60%, technological process is:Spinning solution-spinning-washing-drying-one-tenth cylinder-finished product, obtains Chinese herbal medicine aroma type Fypro.
In described step 2, the saturated aqueous solution temperature control of beta-schardinger dextrin-is at 40 DEG C, the weight of beta-schardinger dextrin-and jasmin quintessence oil Amount ratio is 6: 1.
Powder body in described step one, dispersant, the weight of water are than for 1:0.2:4;Wherein dispersant is polyacrylic acid sodium salt.
In chitosan solution in described step 3, the mass concentration of shitosan is 1.5%.
The consisting of of spinning coagulation bath in described step 5:Sulphuric acid 100g/L, sodium sulfate 300g/L, zinc sulfate 8g/L, Aluminum sulfate 8g/L;The temperature of spinning coagulation bath is 40 DEG C;Drying temperature is 70 DEG C.
Embodiment 2
A kind of preparation method of Chinese herbal medicine aroma type Fypro, comprises the following steps:
Step one:Adopt super-refinement powder body process equipment by after Radix Glycyrrhizae, the Radix Angelicae Dahuricae, Herba Dendrobii mixing, being processed into particle diameter is 30 ~50 nanometers of super-refinement powder body, and powder body and dispersant are added to the water, mixing and stirring, ultrasonic disperse deaerates, and is obtained Chinese herbal medicine aqueous emulsion;
Step 2:To in the saturated aqueous solution of beta-schardinger dextrin-add jasmin quintessence oil, with magnetic stirring apparatuss with 500r/min Speed stirring 40min, then stand 24 hours froth breakings, obtain jasmine microcapsule aromatic agent;
Step 3:Shitosan is dissolved in the acetic acid solution that mass concentration is 90%, is stirred at room temperature to being completely dissolved, is obtained Chitosan solution;
Step 4:By Chinese herbal medicine aqueous emulsion, jasmine microcapsule aromatic agent, chitosan solution, Fypro spinning liquid with Weight compares 4:0.6:12:90 mixed grindings 4 hours, then through deaeration, filtration, prepared spinning solution;
Step 5:By spinning solution in spinning coagulation bath spinning moulding, spinning speed be 30m/min, spin-draw ratio For 80%, technological process is:Spinning solution-spinning-washing-drying-one-tenth cylinder-finished product, obtains Chinese herbal medicine aroma type Fypro.
In described step 2, the saturated aqueous solution temperature control of beta-schardinger dextrin-is at 40 DEG C, the weight of beta-schardinger dextrin-and jasmin quintessence oil Amount ratio is 6: 1.
Powder body in described step one, dispersant, the weight of water are than for 1:0.2:4;Wherein dispersant is polyacrylic acid sodium salt.
In chitosan solution in described step 3, the mass concentration of shitosan is 2%.
The consisting of of spinning coagulation bath in described step 5:Sulphuric acid 120g/L, sodium sulfate 320g/L, zinc sulfate 9g/L, Aluminum sulfate 9g/L;The temperature of spinning coagulation bath is 45 DEG C;Drying temperature is 75 DEG C.
Embodiment 3
A kind of preparation method of Chinese herbal medicine aroma type Fypro, comprises the following steps:
Step one:Adopt super-refinement powder body process equipment by after Radix Glycyrrhizae, the Radix Angelicae Dahuricae, Herba Dendrobii mixing, being processed into particle diameter is 30 ~50 nanometers of super-refinement powder body, and powder body and dispersant are added to the water, mixing and stirring, ultrasonic disperse deaerates, and is obtained Chinese herbal medicine aqueous emulsion;
Step 2:To in the saturated aqueous solution of beta-schardinger dextrin-add jasmin quintessence oil, with magnetic stirring apparatuss with 500r/min Speed stirring 50min, then stand 24 hours froth breakings, obtain jasmine microcapsule aromatic agent;
Step 3:Shitosan is dissolved in the acetic acid solution that mass concentration is 90%, is stirred at room temperature to being completely dissolved, is obtained Chitosan solution;
Step 4:By Chinese herbal medicine aqueous emulsion, jasmine microcapsule aromatic agent, chitosan solution, Fypro spinning liquid with Weight compares 4.5:0.6:13:92 mixed grindings 5 hours, then through deaeration, filtration, prepared spinning solution;
Step 5:By spinning solution in spinning coagulation bath spinning moulding, spinning speed be 40m/min, spin-draw ratio For 100%, technological process is:Spinning solution-spinning-washing-drying-one-tenth cylinder-finished product, obtains Chinese herbal medicine aroma type polyamide fine Dimension.
In described step 2, the saturated aqueous solution temperature control of beta-schardinger dextrin-is at 40 DEG C, the weight of beta-schardinger dextrin-and jasmin quintessence oil Amount ratio is 6: 1.
Powder body in described step one, dispersant, the weight of water are than for 1:0.2:4;Wherein dispersant is polyacrylic acid sodium salt.
In chitosan solution in described step 3, the mass concentration of shitosan is 3%.
The consisting of of spinning coagulation bath in described step 5:Sulphuric acid 150g/L, sodium sulfate 350g/L, zinc sulfate 10g/L, Aluminum sulfate 10g/L;The temperature of spinning coagulation bath is 50 DEG C;Drying temperature is 80 DEG C.

Claims (8)

1. a kind of preparation method of Chinese herbal medicine aroma type Fypro is it is characterised in that comprise the following steps:
Step one:Adopt super-refinement powder body process equipment by after Radix Glycyrrhizae, the Radix Angelicae Dahuricae, Herba Dendrobii mixing, being processed into particle diameter is 30~50 The super-refinement powder body of nanometer, and powder body and dispersant are added to the water, mixing and stirring, ultrasonic disperse deaerates, prepared medium-height grass Liquid medicine emulsion;
Step 2:To in the saturated aqueous solution of beta-schardinger dextrin-add jasmin quintessence oil, with magnetic stirring apparatuss with 500r/min speed Degree stirring 30~50min, then stand 24 hours froth breakings, obtain jasmine microcapsule aromatic agent;
Step 3:Shitosan is dissolved in the acetic acid solution that mass concentration is 90%, is stirred at room temperature to being completely dissolved, prepared shell gathers Sugar juice;
Step 4:By Chinese herbal medicine aqueous emulsion, jasmine microcapsule aromatic agent, chitosan solution, Fypro spinning liquid with weight Ratio 3~4.5:0.5~0.6:11~13:86~92 mixed grindings 3~5 hours, then through deaeration, filtration, prepared spinning solution;
Step 5:By spinning solution in spinning coagulation bath spinning moulding, spinning speed be 20~40m/min, spin-draw ratio For 60~100%, technological process is:Spinning solution-spinning-washing-drying-one-tenth cylinder-finished product, obtains Chinese herbal medicine aroma type polyamide Fiber.
2. a kind of Chinese herbal medicine aroma type Fypro according to claim 1 preparation method it is characterised in that:Step The saturated aqueous solution temperature control of the beta-schardinger dextrin-described in two is at 40 DEG C.
3. a kind of Chinese herbal medicine aroma type Fypro according to claim 1 preparation method it is characterised in that:Step The weight of the beta-schardinger dextrin-described in two and jasmin quintessence oil is than for 6: 1.
4. a kind of Chinese herbal medicine aroma type Fypro according to claim 1 preparation method it is characterised in that:Step Dispersant described in one is polyacrylic acid sodium salt.
5. a kind of Chinese herbal medicine aroma type Fypro according to claim 1 preparation method it is characterised in that:Step Powder body described in one, dispersant, the weight of water are than for 1:0.2:4.
6. a kind of Chinese herbal medicine aroma type Fypro according to claim 1 preparation method it is characterised in that:Step In chitosan solution described in three, the mass concentration of shitosan is 1.5~3%.
7. a kind of Chinese herbal medicine aroma type Fypro according to claim 1 preparation method it is characterised in that:Step The consisting of of spinning coagulation bath described in five:Sulphuric acid 100~150g/L, sodium sulfate 300~350g/L, zinc sulfate 8~10g/ L, aluminum sulfate 8~10g/L;The temperature control of spinning coagulation bath is at 40~50 DEG C.
8. a kind of Chinese herbal medicine aroma type Fypro according to claim 1 preparation method it is characterised in that:Described Step 5 in drying temperature be 70~80 DEG C.
CN201610912907.4A 2016-10-20 2016-10-20 Preparation method of Chinese herbal medicine fragrant polyarmide fiber Pending CN106400173A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106929940A (en) * 2017-03-24 2017-07-07 李军 The spinning fabric and its preparation technology of a kind of delicate fragrance antibacterial
CN107604455A (en) * 2017-10-31 2018-01-19 中原工学院 A kind of preparation method of Chinese herbal medicine fiber
CN109527673A (en) * 2018-11-30 2019-03-29 东华大学 A kind of chargeable Chinese medicine thermotherapy waist support
CN111394818A (en) * 2020-04-07 2020-07-10 江苏金太阳纺织科技股份有限公司 Liquorice regenerated cellulose fiber and preparation method thereof

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CN103233287A (en) * 2013-04-19 2013-08-07 成进学 Multifunctional aromatic type element fiber fabric protective clothing
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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106929940A (en) * 2017-03-24 2017-07-07 李军 The spinning fabric and its preparation technology of a kind of delicate fragrance antibacterial
CN107604455A (en) * 2017-10-31 2018-01-19 中原工学院 A kind of preparation method of Chinese herbal medicine fiber
CN107604455B (en) * 2017-10-31 2020-03-31 中原工学院 Preparation method of Chinese herbal medicine fiber
CN109527673A (en) * 2018-11-30 2019-03-29 东华大学 A kind of chargeable Chinese medicine thermotherapy waist support
CN111394818A (en) * 2020-04-07 2020-07-10 江苏金太阳纺织科技股份有限公司 Liquorice regenerated cellulose fiber and preparation method thereof
CN111394818B (en) * 2020-04-07 2022-09-30 江苏金太阳纺织科技股份有限公司 Liquorice regenerated cellulose fiber and preparation method thereof

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