CN106398107A - High-wear resistance degradable modified plastic and making method thereof - Google Patents
High-wear resistance degradable modified plastic and making method thereof Download PDFInfo
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- CN106398107A CN106398107A CN201610751702.2A CN201610751702A CN106398107A CN 106398107 A CN106398107 A CN 106398107A CN 201610751702 A CN201610751702 A CN 201610751702A CN 106398107 A CN106398107 A CN 106398107A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/04—Condensation polymers of aldehydes or ketones with phenols only
- C08L61/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/06—Biodegradable
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/16—Applications used for films
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
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Abstract
The invention discloses a high-wear resistance degradable modified plastic. The plastic is made from, by weight, 15-30 parts of polycaprolactone, 40-60 parts of phenolic resin, 4-10 parts of modified starch, 2-4 parts of nanometer titanium dioxide, 1-4 parts of sodium alginate, 2-5 parts of hexamethyltramine, 2-3 parts of zinc stearate, 2-10 parts of nanometer barium sulfate, 5-10 parts of an aluminate ester coupling agent F-1, 0.5-1 part of an antioxidant 1010, 1-2 parts of phosphite ester and 0.1-0.5 parts of UV-531. A making method of the plastic has the advantages of simplicity, no special device, low cost and environmental protection; the plastic has the advantages of degradability, long service life, high wear resistance and good elasticity; and a plastic film formed after deep processing of the plastic has the advantages of good ductility, small wearing degree, and realization of automatic degradation after becoming wastes when the film is used in vegetable or flower greenhouses.
Description
Technical field
The present invention relates to plastics technical field of improvement and in particular to a kind of high modified plastics of wearability of degradable and its
Manufacture method.
Background technology
In recent years, with the generation of high molecular polymer-polrvinyl chloride, polyethylene, plastic sheeting is widely used in agriculture
Industry；Again because hot house can utilize solar energy, and there is certain insulation effect；Simultaneously because can be using light skeleton material
Material, easily builds and appearance, can take lattice on the spot, construction investment is less, and economic benefit is higher；And natural disaster can be resisted, cold-proof
The effect such as insulation, widely uses in agriculture, woods, animal husbandry, thus deep welcome by Producer.With the development of plastics industry,
Commonly used by countries in the world.Modified plastics refers to, on the basis of general-purpose plastics and engineering plastics, through filling, blending, increase
The method processing such as strong, improves the plastic of the performance of the aspects such as anti-flammability, intensity, impact resistance, toughness.Modified plastics blows
The thin film made is widely used in booth.But it is as increasing of usage amount, inevitably environment is caused with white dirt
Dye.
Content of the invention
1st purpose of the present invention is the modified plastics providing a kind of wearability of degradable high.
2nd purpose of the present invention is the manufacture method of the high modified plastics of wearability of above-mentioned degradable.
To achieve these goals, the invention provides a kind of high modified plastics of wearability of degradable, by weighing as follows
The material composition of amount part：
Polycaprolactone 15-30, phenolic resin 40-60, modified starch 4-10, nanometer titanium dioxide
2-4, sodium alginate 1-4, pregnancy urotropine 2-5, zinc stearate 2-3, nanometer sulphuric acid
Barium 2-10, aluminate coupling agent F-1 5-10, antioxidant 1010 0.5-1, phosphorous acid
Ester 1-2, UV-531 0.1-0.5.
A kind of manufacture method of the high modified plastics of wearability of degradable, comprises the following steps：
Step one：It is placed in nanometer titanium dioxide in the ultrasonic cleaning instrument of 30-50KHz, using the ultrasonic 20- of dehydrated alcohol
50min；Ultrasonic finish after, with absolute ethanol washing 2-3 time, 60-90 DEG C of drying is to constant weight, stand-by；
Step 2：According to formula by polycaprolactone, phenolic resin, sodium alginate, modified starch, pregnancy urotropine, nanometer
Nanometer in barium sulfate, zinc stearate, aluminate coupling agent F-1, antioxidant 1010, phosphite ester, UV-531 and step one
Titanium dioxide mixes 20-30min in high-speed mixer；Pour into after taking-up in double screw extruder, melt blending, extruding pelletization.
Furtherd investigate and modified in the enterprising step of the original technical support of our company, retained the excellent of former improvement plastics
Gesture, adds degradable biomaterial, prepares and have the excellent modified plastics of degradability, and through be blow molded into have good every
Heat insulation, performance and the degredation plastic thin film such as toughness is big, intensity is high, and it is widely used in the covering material of hot house.
Nano barium sulfate have chemical inertness strong, easily dispersion, good stability, acid and alkali-resistance, Sun-proof, weather-proof, hardness is moderate,
High specific gravity, high whiteness, the advantages of harm ray can be absorbed, and activation grade is high, as filler, good with the matrix compatibility, combine tight
Close, can improve material modified wearability, strengthen product glossiness, high temperature resistant, uvioresistant, also can improve product intensity,
Rigidity and geometrical stability；It is a kind of material with environment-friendly function.Phenolic resin is cheap, and heat-resist, hardness is big, system
Product contractility is little, insulation, heat-insulated, moistureproof, corrosion-resistant, is also Biodegradable material simultaneously, can degrade, no under natural environment
Can be to environment.
The present invention has following beneficial effect：Compared with prior art, the degradable wearability modified plastics of the present invention, in phenol
Add filler nanometer barium sulfate and antioxidant etc. in urea formaldehyde and polycaprolactone, on the one hand can keep the wearability of plastics,
Plastics can be controlled in non-abandoned to keep due life-span and function again；Simultaneously because using biodegradation material, losing
When abandoning, molecular weight is reduced by oxidation reaction, be conducive to microbial decomposition.Prepared degradable wearability modified plastics deep processing
Become plastic sheeting to be used for vegetable or flower shed, it is long to have a friction durability, and can voluntarily degrade when abandoning, reduce to environment
Pollution the advantages of.
Specific embodiment
Hereinafter the specific embodiment of the present invention is described in detail.It should be appreciated that it is described herein concrete
Embodiment is merely to illustrate and explains the present invention, is not limited to the present invention.In embodiment, polycaprolactone, phenolic resin,
Modified starch, nano antimony tin oxide, nanometer titanium dioxide, sodium alginate, pregnancy urotropine, zinc stearate, aluminate coupling agent F-
1st, antioxidant 1010, phosphite ester, UV-531 are the commercially available product of Shijiazhuang Lang Bo chemical technology company limited；Nanometer sulphuric acid
The specialization chemical product company limited product that barium stands for Zhengzhou.
Embodiment 1
A kind of high modified plastics of wearability of degradable, is prepared by the raw materials in：
Polycaprolactone 20, phenolic resin 44, modified starch 7, nanometer titanium dioxide 3, sodium alginate 4, pregnancy urotropine 2.5,
Zinc stearate 2, nano barium sulfate 8, aluminate coupling agent F-1 7, antioxidant 1010 0.5, phosphite ester 1.5, UV-531
0.5.
The manufacture method of the high modified plastics of the wearability of above-mentioned degradable, comprises the following steps：
Step one：It is placed in nanometer titanium dioxide in the ultrasonic cleaning instrument of 30KHz, using the ultrasonic 20-50min of dehydrated alcohol；
Ultrasonic finish after, with absolute ethanol washing 3 times, 60 DEG C of dryings are to constant weight, stand-by；
Step 2：According to formula by polycaprolactone, phenolic resin, sodium alginate, modified starch, pregnancy urotropine, nanometer
Nanometer in barium sulfate, zinc stearate, aluminate coupling agent F-1, antioxidant 1010, phosphite ester, UV-531 and step one
Titanium dioxide mixes 20min in high-speed mixer；Pour into after taking-up in double screw extruder, melt blending, extruding pelletization.
Embodiment 2
A kind of high modified plastics of wearability of degradable, is prepared by the raw materials in：
Polycaprolactone 17, phenolic resin 43, modified starch 8, nanometer titanium dioxide 3, sodium alginate 4, pregnancy urotropine 4, hard
Fat acid zinc 2.5, nano barium sulfate 9, aluminate coupling agent F-1 6, antioxidant 1010 1, phosphite ester 2, UV-531 0.5.
The manufacture method of the high modified plastics of the wearability of above-mentioned degradable, comprises the following steps：
Step one：It is placed in nanometer titanium dioxide in the ultrasonic cleaning instrument of 40KHz, using the ultrasonic 30min of dehydrated alcohol；Super
After sound finishes, with absolute ethanol washing 3 times, 60 DEG C of dryings are to constant weight, stand-by；
Step 2：According to formula by polycaprolactone, phenolic resin, sodium alginate, modified starch, pregnancy urotropine, nanometer
Nanometer in barium sulfate, zinc stearate, aluminate coupling agent F-1, antioxidant 1010, phosphite ester, UV-531 and step one
Titanium dioxide mixes 25min in high-speed mixer；Pour into after taking-up in double screw extruder, melt blending, extruding pelletization.
The technical parameter of the plastic sheeting of modified plastics blowing being produced using the present invention is as follows：
Claims (2)
1. a kind of high modified plastics of wearability of degradable is it is characterised in that be prepared by the raw materials in：
Polycaprolactone 15-30, phenolic resin 40-60, modified starch 4-10, nanometer titanium dioxide 2-4, sodium alginate 1-4, hexamethyl
Tetramine 2-5, zinc stearate 2-3, nano barium sulfate 2-10, aluminate coupling agent F-1 5-10, antioxidant 1010 0.5-1, Asia
Phosphate ester 1-2, UV-531 0.1-0.5.
2. a kind of high modified plastics of the wearability of degradable according to claim 1 manufacture method it is characterised in that
Comprise the following steps：
Step one：It is placed in nanometer titanium dioxide in the ultrasonic cleaning instrument of 30-50KHz, using the ultrasonic 20-50min of dehydrated alcohol；
Ultrasonic finish after, with absolute ethanol washing 2-3 time, 60-90 DEG C of drying is to constant weight, stand-by；
Step 2：According to formula by polycaprolactone, phenolic resin, sodium alginate, modified starch, pregnancy urotropine, nanometer sulphuric acid
Nanometer Titanium Dioxide in barium, zinc stearate, aluminate coupling agent F-1, antioxidant 1010, phosphite ester, UV-531 and step one
Powder mixes 20-30min in high-speed mixer；Pour into after taking-up in double screw extruder, melt blending, extruding pelletization.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610751702.2A CN106398107A (en) | 2016-08-29 | 2016-08-29 | High-wear resistance degradable modified plastic and making method thereof |
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| CN201610751702.2A CN106398107A (en) | 2016-08-29 | 2016-08-29 | High-wear resistance degradable modified plastic and making method thereof |
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| CN106398107A true CN106398107A (en) | 2017-02-15 |
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| CN201610751702.2A Pending CN106398107A (en) | 2016-08-29 | 2016-08-29 | High-wear resistance degradable modified plastic and making method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113214571A (en) * | 2021-04-01 | 2021-08-06 | 浙江理工大学 | Alkali-corrosion-resistant high-strength flexible polyvinyl chloride film material and preparation method thereof |
| CN115160654A (en) * | 2022-07-13 | 2022-10-11 | 集美大学 | Modified cellulose acetate fiber capable of being degraded by microorganisms and preparation method thereof |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1454925A (en) * | 2002-12-13 | 2003-11-12 | 张沛生 | Fully-biodegradable plastic and its product preparing method |
| CN101284922A (en) * | 2008-05-20 | 2008-10-15 | 安徽德琳环保发展（集团）有限公司 | Biological degradation plastic with high starch content for blowing molding and method for preparing same |
| CN101525494A (en) * | 2008-03-04 | 2009-09-09 | 艾唐贸易(深圳)有限公司 | Completely degradable vegetable fiber product and manufacturing method thereof |
| US20100119417A1 (en) * | 2008-11-10 | 2010-05-13 | Biotix, Inc. | Degradable fluid handling devices |
| CN101760037A (en) * | 2008-12-23 | 2010-06-30 | 金发科技股份有限公司 | Completely degraded plant powder modified thermoplastics composite material and preparation method thereof |
| CN103265730A (en) * | 2013-05-23 | 2013-08-28 | 苏州富通高新材料科技股份有限公司 | Degradable film containing starch and preparation method of degradable film |
| CN104292718A (en) * | 2014-09-24 | 2015-01-21 | 铜陵市新泰电容电器有限责任公司 | Degradable capacitor plastic shell and preparation method thereof |
| CN105199412A (en) * | 2015-09-09 | 2015-12-30 | 青岛鑫铁成汽车配件有限公司 | Interpenetrating polymer network enhanced fully-degradable biomass matrix composite material and preparation method thereof |
-
2016
- 2016-08-29 CN CN201610751702.2A patent/CN106398107A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1454925A (en) * | 2002-12-13 | 2003-11-12 | 张沛生 | Fully-biodegradable plastic and its product preparing method |
| CN101525494A (en) * | 2008-03-04 | 2009-09-09 | 艾唐贸易(深圳)有限公司 | Completely degradable vegetable fiber product and manufacturing method thereof |
| CN101284922A (en) * | 2008-05-20 | 2008-10-15 | 安徽德琳环保发展（集团）有限公司 | Biological degradation plastic with high starch content for blowing molding and method for preparing same |
| US20100119417A1 (en) * | 2008-11-10 | 2010-05-13 | Biotix, Inc. | Degradable fluid handling devices |
| CN101760037A (en) * | 2008-12-23 | 2010-06-30 | 金发科技股份有限公司 | Completely degraded plant powder modified thermoplastics composite material and preparation method thereof |
| CN103265730A (en) * | 2013-05-23 | 2013-08-28 | 苏州富通高新材料科技股份有限公司 | Degradable film containing starch and preparation method of degradable film |
| CN104292718A (en) * | 2014-09-24 | 2015-01-21 | 铜陵市新泰电容电器有限责任公司 | Degradable capacitor plastic shell and preparation method thereof |
| CN105199412A (en) * | 2015-09-09 | 2015-12-30 | 青岛鑫铁成汽车配件有限公司 | Interpenetrating polymer network enhanced fully-degradable biomass matrix composite material and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 余绍火等: "《中国粉体工业通鉴（2005版）》", 31 May 2005, 西安地图出版社 * |
| 郑德等: "《热稳定剂的生产应用及进展》", 30 June 2011, 国防工业出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113214571A (en) * | 2021-04-01 | 2021-08-06 | 浙江理工大学 | Alkali-corrosion-resistant high-strength flexible polyvinyl chloride film material and preparation method thereof |
| CN115160654A (en) * | 2022-07-13 | 2022-10-11 | 集美大学 | Modified cellulose acetate fiber capable of being degraded by microorganisms and preparation method thereof |
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Application publication date: 20170215 |