CN106398087A - Highly-flame-retardant scratch-resistant frosting TPE sheathing material - Google Patents
Highly-flame-retardant scratch-resistant frosting TPE sheathing material Download PDFInfo
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- CN106398087A CN106398087A CN201610865342.9A CN201610865342A CN106398087A CN 106398087 A CN106398087 A CN 106398087A CN 201610865342 A CN201610865342 A CN 201610865342A CN 106398087 A CN106398087 A CN 106398087A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
- C08L53/025—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes modified
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
- H01B3/442—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from aromatic vinyl compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/04—Thermoplastic elastomer
Abstract
The invention discloses a highly-flame-retardant scratch-resistant frosting TPE sheathing material. The highly-flame-retardant scratch-resistant frosting TPE sheathing material comprises the following components in percentage by weight: 15 to 35 percent of styrene block copolymer, 6 to 15 percent of modified polyphenyl ether, 7 to 15 percent of thermoplastic dynamic vulcanized rubber, 5 to 18 percent of polyolefin, 8 to 15 percent of extending oil, 3 to 10 percent of plasticizer, 20 to 35 percent of flame retardant, 0.8 to 3 percent of lubricant and 0.2 to 0.5 percent of UV stabilizer. As compared with the prior art, reasonable proportions of components are obtained through elaborate design and repetitive tests, finally the highly-flame-retardant scratch-resistant frosting TPE sheathing material is obtained, the surface of the outer sheath produced by using the material disclosed by the invention is wear-resistant, the scratch resistance is excellent, scratches are not easily produced on the surface, the maximum oxygen index can reach to 40, the flame-retardant effect is very good, and the material further has the advantages of good frosting hand feeling, high oil resistance, low surface gloss, high tensile strength, good impact resistance and low temperature resistance, good processing performance and the like.
Description
Technical field
The present invention relates to technical field of polymer materials, particularly to a kind of high fire-retardance scratch-resistant frosted sense TPE protective cover material.
Background technology
Cable cover(ing) is cable indispensable intermediate structure part, play a part to protect cable it is ensured that cable logical
Electric safety, allows the medium such as copper wire and water, air to completely cut off, it is to avoid leaky.Cable lay with moving process in, easily
Swiped.Especially for the special optical cable of 3G communication engineering and fiber to the home engineering, mostly it is used in mobile communication base station
Or interior is it is desirable to the material that the sheath of optical cable uses has the performances such as environmental protection, fire-retardant, LSZH；Because such optical cable is used for
Interior, narrow space, mobile frequently, easily swiped it is desirable to cable surface is wear-resisting, scraping and wiping resistance performance is good.Existing optical cable shield
Jacking is difficult to meet these requirements.
Content of the invention
It is an object of the invention to, for the above-mentioned deficiency of prior art, provide a kind of high fire-retardance scratch-resistant frosted sense TPE
Protective cover material, scratch resistance is good, and oxygen index (OI) reaches as high as 40, and flame retardant effect is fine, and frosted handle effect is good, also has oil resistant
The advantages of property height, matte surface, low temperature resistant, good processability.
The present invention be employed technical scheme comprise that by reaching above-mentioned purpose：
A kind of high fire-retardance scratch-resistant frosted sense TPE protective cover material, percentage, including SBC
15-35%, Noryl 6%-15%, thermoplastic dynamic perduren 7-15%, polyolefin 5-18%, the oily 8- of filling
15%th, plasticizer 3-10%, fire retardant 20-35%, lubricant 0.8-3%, UV light stabilizer 0.2-0.5%.
Preferably, described thermoplastic dynamic perduren is counted by weight including following component：Nitrile rubber 60-70
Part, thermoplastic polyester elastomer 10-20 part, polylactic acid 25-30 part, phenolic resin vulcanization system 1-2 part, naphthenic oil softening agent
20-30 part, antioxidant 1010 1-2 part, inorganic filler 8-10 part, silane coupler KH570 3-6 part.
Preferably, the preparation method of described thermoplastic dynamic perduren comprises the steps：
Weigh raw material by setting ratio, high speed blender adds nitrile rubber, thermoplastic polyester elastomer, poly- breast
Acid, silane coupler KH570, inorganic filler and antioxidant 1010, after mix homogeneously, through the double spiral shell of main drawing-in device feeding two steps type
The screw rod of bar extruder, extruder temperature controls at 175-185 DEG C, treats that rubber and plastics melt in two steps type double screw extruder
Afterwards, the liquid injection port in the first rank screw rod injects part naphthenic oil softening agent, continuous in the liquid injection port of second-order screw rod
The remaining naphthenic oil softening agent of injection and the mixture of phenolic resin vulcanization system, through dynamic vulcanization, obtain thermoplastic dynamic vulcanized
Rubber.
Preferably, described Noryl is allyl-polyphenylene ether, is to be catalyzed 2,6- dimethyl benzene by copper-amine system
Phenol polyreaction is obtained low-molecular polyphenylene ether, then alkene obtained from being reacted with allylmgcl after polyphenylene oxide bromination
Propyl group polyphenylene oxide.
Preferably, described polyolefin is any one in ethylene-- olefin copolymer or ethylene-octene copolymer.
Preferably, described SBC is hydrogenated styrene-butadiene-styrene block copolymers
SEBS.
Preferably, described plasticizer be epoxy plasticizer, at least one in phosphate plasticizer.
Preferably, described fire retardant percentage is by phosphorus flame retardant 11-24%, silicone flame retardant 6-
15% composition.
Preferably, described filling oil is paraffin oil or/and naphthenic oil；Described lubricant is stearic acid or stearic acid
Sodium.
Compared with prior art, the high fire-retardance scratch-resistant frosted sense TPE protective cover material that the present invention provides, by by rational proportion
SBC, Noryl, thermoplastic dynamic perduren, polyolefin carry out composite, obtain comprehensive
Close the elastomer of excellent performance, the surface of outer sheath making using the present invention is wear-resisting, scraping and wiping resistance performance is excellent, in construction and use
During surface do not allow to be also easy to produce scratch, good presentation quality can be kept, its oxygen index (OI) reaches as high as 40, flame retardant effect is very
Good, and have frosted good hand touch, oil resistivity height, matte surface, tensile strength height, shock resistance and resistance to low temperature good,
Good processability, not halogen-containing, environmentally friendly the advantages of.
Above-mentioned be inventive technique scheme general introduction, below in conjunction with specific embodiment, the present invention will be further described.
Specific embodiment：
In order that the purpose of the present invention and technical scheme and advantage become more apparent, make specifically with reference to embodiments
Bright.It should be appreciated that specific embodiment described herein, only in order to explain the present invention, is not intended to limit the present invention.
Embodiment 1：The high fire-retardance scratch-resistant frosted sense TPE protective cover material that the present embodiment provides, percentage includes
Following component：SBC 15%, Noryl 6%, thermoplastic dynamic perduren 15%, polyolefin
13%th, oil 13%, plasticizer 10%, fire retardant 25%, lubricant 2.5%, UV light stabilizer 0.5% are filled；Its preparation method
Using conventional extruding-out process, twin-screw extrusion condition is 200 DEG C of temperature.Wherein, thermoplastic dynamic perduren is by weight
Number meter includes following component：60 parts of nitrile rubber, 20 parts of thermoplastic polyester elastomer, 25 parts of polylactic acid, phenolic resin curative
2 parts of system, 20 parts of naphthenic oil softening agent, 1 part of antioxidant 1010,8 parts of inorganic filler, 3 parts of silane coupler KH570.This heat
The preparation method of plasticity dynamic perduren comprises the steps：
Weigh raw material by setting ratio, high speed blender adds nitrile rubber, thermoplastic polyester elastomer, poly- breast
Acid, silane coupler KH570, inorganic filler and antioxidant 1010, after mix homogeneously, through the double spiral shell of main drawing-in device feeding two steps type
The screw rod of bar extruder, extruder temperature controls at 175-185 DEG C, treats that rubber and plastics melt in two steps type double screw extruder
Afterwards, the liquid injection port in the first rank screw rod injects part naphthenic oil softening agent, continuous in the liquid injection port of second-order screw rod
The remaining naphthenic oil softening agent of injection and the mixture of phenolic resin vulcanization system, through dynamic vulcanization, obtain thermoplastic dynamic vulcanized
Rubber.Obtained by by rational proportions such as nitrile rubber, thermoplastic polyester elastomer, polylactic acid, taking suitable preparation method
Thermoplastic dynamic perduren, has the advantages that higher oil resistivity, tensile strength be good, resistance to low temperature, elastic good, and prepares
Method is easy, and properties of product are stable.
Wherein, Noryl is allyl-polyphenylene ether, is to be catalyzed the polymerization of 2,6- xylenol instead by copper-amine system
Low-molecular polyphenylene ether should be obtained, then pi-allyl polyphenyl obtained from being reacted with allylmgcl after polyphenylene oxide bromination
Ether.Its concrete preparation process is referred to yellow bright grade East China University of Science's Master's thesis in 2007《The synthesis of polyphenylene oxide, modified and
The research of its composite》29-33 page of content.Polyphenylene oxide is a kind of thermoplastic engineering plastic of function admirable, has excellent
Electrical insulation capability, proof stress relaxes and that impact strength is good, wearability is good, resistance to water is very good, anti-flammability is good etc. is prominent excellent
Gesture, and pass through Noryl while keeping original performance, can overcome polyphenylene oxide resin processing difficulties, easily cracking,
The problems such as solvent resistance is not enough.
Preferably, SBC is hydrogenated styrene-butadiene-styrene block copolymers SEBS,
SEBS has saturation molecular structure, and it is ageing-resistant, color inhibition, heatproof, excellent anti-corrosion performance；Have excellent tensile strength,
Elasticity and electrical property, it is good with resilience to subdue, and mantle friction is big, the advantages of breathability is excellent；Polyolefin is that ethylene-- alkene is common
Polymers；Plasticizer is epoxy plasticizer, at least one in phosphate plasticizer, epoxy plasticizer be conventional plasticizer such as
Epoxidised soybean oil, epoxidised linseed oil, unsaturated fatty acid epoxidised ester for example epoxyoleic acid butyl ester, epoxyoleic acid monooctyl ester,
Epoxyoleic acid last of the ten Heavenly stems ester etc., it may be preferred to epoxidised soybean oil or epoxidised linseed oil, has good, good the resisting of thermostable effect
Extractibility and resistance to migration；Phosphate plasticizer is conventional plasticizer it may be preferred to polyphosphoric acid class flame-retardant plasticizer such as three
Aryl phosphate ester, alkyl diaryl phosphate, are specifically as follows tricresyl phosphate (TCP), triphenyl phosphate (TPP), phosphoric acid
Hexichol one monooctyl ester (DPOP), has the advantages that higher oxygen index (OI) and elastic modelling quantity, anti-flammability and antibiotic property are strong.Filling oil is stone
Wax oil or/and naphthenic oil；Described lubricant is stearic acid or sodium stearate, can also be other conventional lubricants；UV light
Stabilizer is conventional light stabilizer.Inorganic filler is customary filler, such as Calcium Carbonate, Pulvis Talci, potter's clay, white carbon black, white carbon, silicon
Diatomaceous earth etc..Fire retardant percentage is made up of phosphorus flame retardant 15%, silicone flame retardant 10%.
The present invention obtains the rational proportion of each component by well-designed and repetition test, using suitable preparation method,
Finally give high fire-retardance scratch-resistant frosted sense TPE protective cover material, not halogen-containing, environmentally friendly, its oxygen index (OI) reaches as high as 40, resistance
Fuel efficiency fruit very well, for the protective cover material of electric wire, has frosted good hand touch, scratch-resistant, oil resistivity height, matte surface, stretching
Intensity is high, shock resistance and resistance to low temperature is good, good processability the advantages of.
Embodiment 2：The high fire-retardance scratch-resistant frosted sense TPE protective cover material that the present embodiment provides, its basic phase with embodiment 1
With difference is：
A kind of high fire-retardance scratch-resistant frosted sense TPE protective cover material, percentage includes following component：Phenylethylene is embedding
Section copolymer 35%, Noryl 10%, thermoplastic dynamic perduren 7%, polyolefin 5%, filling oil 15%, plasticizer
7%th, fire retardant 20%, lubricant 0.8%, UV light stabilizer 0.2%；Polyolefin is ethylene-octene copolymer, and weight pressed by fire retardant
Amount percent meter is made up of phosphorus flame retardant 11%, silicone flame retardant 9%.
Wherein, thermoplastic dynamic perduren is counted by weight including following component：70 parts of nitrile rubber, thermoplastic poly
10 parts of ester elastomer, 30 parts of polylactic acid, 1 part of phenolic resin vulcanization system, 30 parts of naphthenic oil softening agent, 2 parts of antioxidant 1010,
10 parts of inorganic filler, 6 parts of silane coupler KH570.
Other are same as Example 1, and here is no longer burdensome.
Embodiment 3：The high fire-retardance scratch-resistant frosted sense TPE protective cover material that the present embodiment provides, its basic phase with embodiment 1
With difference is：
A kind of high fire-retardance scratch-resistant frosted sense TPE protective cover material, percentage includes following component：Phenylethylene is embedding
Section copolymer 20%, Noryl 15%, thermoplastic dynamic perduren 10%, polyolefin 7%, filling oil 8%, plasticizer
3%th, fire retardant 35%, lubricant 1.7%, UV light stabilizer 0.3%；Polyolefin is ethylene-octene copolymer；Weight pressed by fire retardant
Amount percent meter is made up of phosphorus flame retardant 20%, silicone flame retardant 15%.
Wherein, thermoplastic dynamic perduren is counted by weight including following component：66 parts of nitrile rubber, thermoplastic poly
11 parts of ester elastomer, 27 parts of polylactic acid, 1.5 parts of phenolic resin vulcanization system, 26 parts of naphthenic oil softening agent, antioxidant 1010 1.8
Part, 9 parts of inorganic filler, 5 parts of silane coupler KH570.
Other are same as Example 1, and here is no longer burdensome.
Embodiment 4：The high fire-retardance scratch-resistant frosted sense TPE protective cover material that the present embodiment provides, its basic phase with embodiment 1
With difference is：
A kind of high fire-retardance scratch-resistant frosted sense TPE protective cover material, percentage includes following component：Phenylethylene is embedding
Section copolymer 25%, Noryl 7%, thermoplastic dynamic perduren 8%, polyolefin 18%, filling oil 10%, plasticizer
5%th, fire retardant 24%, lubricant 2.6%, UV light stabilizer 0.4%；Polyolefin is ethylene-- olefin copolymer；Fire retardant is pressed
Percent by weight is made up of phosphorus flame retardant 18%, silicone flame retardant 6%.
Wherein, thermoplastic dynamic perduren is counted by weight including following component：69 parts of nitrile rubber, thermoplastic poly
18 parts of ester elastomer, 26 parts of polylactic acid, 2 parts of phenolic resin vulcanization system, 28 parts of naphthenic oil softening agent, antioxidant 1010 1.4
Part, 9.5 parts of inorganic filler, 4.6 parts of silane coupler KH570.
Other are same as Example 1, and here is no longer burdensome.
The announcement of book and teaching according to the above description, those skilled in the art in the invention can also be to above-mentioned embodiment party
Formula is changed and is changed.Therefore, the invention is not limited in specific embodiment disclosed and described above, to invention
In the scope of the claims that a little modifications and changes should also be as fall into the present invention.
Claims (9)
1. a kind of high fire-retardance scratch-resistant frosted sense TPE protective cover material is it is characterised in that percentage, including phenylethylene
Block copolymer 15-35%, Noryl 6%-15%, thermoplastic dynamic perduren 7-15%, polyolefin 5-18%, fill out
Oil-filled 8-15%, plasticizer 3-10%, fire retardant 20-35%, lubricant 0.8-3%, UV light stabilizer 0.2-0.5%.
2. high fire-retardance scratch-resistant frosted sense TPE protective cover material according to claim 1 is it is characterised in that described thermoplasticity
Dynamic perduren is counted by weight including following component：Nitrile rubber 60-70 part, thermoplastic polyester elastomer 10-20 part,
Polylactic acid 25-30 part, phenolic resin vulcanization system 1-2 part, naphthenic oil softening agent 20-30 part, antioxidant 1010 1-2 part, inorganic
Filler 8-10 part, silane coupler KH570 3-6 part.
3. high fire-retardance scratch-resistant frosted sense TPE protective cover material according to claim 2 is it is characterised in that described thermoplasticity
The preparation method of dynamic perduren comprises the steps：
Weigh raw material by setting ratio, high speed blender adds nitrile rubber, thermoplastic polyester elastomer, polylactic acid, silicon
Alkane coupling agent KH570, inorganic filler and antioxidant 1010, after mix homogeneously, squeeze through main drawing-in device feeding two steps type twin screw
Go out the screw rod of machine, extruder temperature controls at 175-185 DEG C, after rubber and plastics melt in two steps type double screw extruder,
Liquid injection port injection part naphthenic oil softening agent in the first rank screw rod, the liquid injection port in second-order screw rod are continuously injected into
Remaining naphthenic oil softening agent and the mixture of phenolic resin vulcanization system, through dynamic vulcanization, obtain thermoplastic dynamic perduren.
4. high fire-retardance scratch-resistant frosted sense TPE protective cover material according to claim 1 is it is characterised in that described modification gathers
Phenylate is allyl-polyphenylene ether, is to be catalyzed 2,6- xylenol polyreaction by copper-amine system low molecular weight polyphenylene is obtained
Ether, then allyl-polyphenylene ether obtained from being reacted with allylmgcl after polyphenylene oxide bromination.
5. high fire-retardance scratch-resistant frosted sense TPE protective cover material according to claim 1 is it is characterised in that described polyolefin
For any one in ethylene-- olefin copolymer or ethylene-octene copolymer.
6. high fire-retardance scratch-resistant frosted sense TPE protective cover material according to claim 1 is it is characterised in that described styrene
Based block copolymer is hydrogenated styrene-butadiene-styrene block copolymers SEBS.
7. high fire-retardance scratch-resistant frosted sense TPE protective cover material according to claim 1 is it is characterised in that described plasticizer
For at least one in epoxy plasticizer, phosphate plasticizer.
8. high fire-retardance scratch-resistant frosted sense TPE protective cover material according to claim 1 is it is characterised in that described fire retardant
Percentage is made up of phosphorus flame retardant 11-24%, silicone flame retardant 6-15%.
9. high fire-retardance scratch-resistant frosted sense TPE protective cover material according to claim 1 is it is characterised in that described filling is oily
For paraffin oil or/and naphthenic oil；Described lubricant is stearic acid or sodium stearate.
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| CN108912479A (en) * | 2018-05-17 | 2018-11-30 | 合肥民众亿兴软件开发有限公司 | A kind of data line protective cover material of bend-resistance crack resistence |
| CN109735087A (en) * | 2018-12-15 | 2019-05-10 | 安徽伊法拉电力科技有限公司 | A kind of high-strength corrosion-resistant erosion modified silicon rubber ABB fuse protective cover material |
| CN114276575A (en) * | 2021-12-09 | 2022-04-05 | 东莞市诚宝塑胶实业有限公司 | Plate layer frosted PVC sheet and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN109735087A (en) * | 2018-12-15 | 2019-05-10 | 安徽伊法拉电力科技有限公司 | A kind of high-strength corrosion-resistant erosion modified silicon rubber ABB fuse protective cover material |
| CN114276575A (en) * | 2021-12-09 | 2022-04-05 | 东莞市诚宝塑胶实业有限公司 | Plate layer frosted PVC sheet and preparation method thereof |
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Application publication date: 20170215 |