CN106398044A - Anti-aging high-strength fishing net thread - Google Patents

Anti-aging high-strength fishing net thread Download PDF

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Publication number
CN106398044A
CN106398044A CN201610814077.1A CN201610814077A CN106398044A CN 106398044 A CN106398044 A CN 106398044A CN 201610814077 A CN201610814077 A CN 201610814077A CN 106398044 A CN106398044 A CN 106398044A
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China
Prior art keywords
fishing net
strength
net thread
strength fishing
aging high
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Pending
Application number
CN201610814077.1A
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Chinese (zh)
Inventor
魏安松
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CHAOHU DINGSHENG FISHING TACKLE Co Ltd
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CHAOHU DINGSHENG FISHING TACKLE Co Ltd
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Application filed by CHAOHU DINGSHENG FISHING TACKLE Co Ltd filed Critical CHAOHU DINGSHENG FISHING TACKLE Co Ltd
Priority to CN201610814077.1A priority Critical patent/CN106398044A/en
Publication of CN106398044A publication Critical patent/CN106398044A/en
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06—Homopolymers or copolymers of vinyl chloride
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25—Component parts, details or accessories; Auxiliary operations
    • B29C48/92—Measuring, controlling or regulating
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/10—Other agents for modifying properties
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/06—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyolefin as constituent
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
    • D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
    • D01F8/10—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one other macromolecular compound obtained by reactions only involving carbon-to-carbon unsaturated bonds as constituent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00—Indexing scheme relating to extrusion moulding
    • B29C2948/92—Measuring, controlling or regulating
    • B29C2948/92504—Controlled parameter
    • B29C2948/9258—Velocity
    • B29C2948/9259—Angular velocity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00—Indexing scheme relating to extrusion moulding
    • B29C2948/92—Measuring, controlling or regulating
    • B29C2948/92504—Controlled parameter
    • B29C2948/92704—Temperature
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/12—Applications used for fibers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)

Abstract

The invention belongs to the technical field of fishery production, and more specifically relates to an anti-aging high-strength fishing net thread. The anti-aging high-strength fishing net thread is prepared from brominated butyl rubber, ternary carboxyl vinisol, siloxane grafting modified acrylic resin, boron carbide fiber, barite powder, rice bran wax, indium tin oxide, zirconium ethoxide, erucyl amide, pentaerythritol stearate, phenylmagnesium chloride, potassium perfluorobutanesulfonate, and eucalyptus globulus oil. The anti-aging high-strength fishing net thread possesses following advantages: a processing technology is simple; the size of raw material particles is reduced, the specific surface area of the raw material particles is increased, and the specific surface area of an agglomerate obtained via fusion is relatively large, so that fishing net thread oxidation resistance and wear resistance are increased; the obtained anti-aging high-strength fishing net thread is excellent in mechanical properties, impact resistance, and wear resistance; bending strength is increased greatly; excellent stain resistance and aging resistance are achieved; excellent mechanical properties can be maintained after a long term of using; and the anti-aging high-strength fishing net thread is suitable to be popularized and applied.

Description

A kind of ageing-resistant high-strength fishing netting twine
Technical field
The invention belongs to fish production technical field is and in particular to a kind of ageing-resistant high-strength fishing netting twine.
Background technology
Fishing lines is the important net materials of fish production, no matter being in the various fishing gears of seawater or fresh water fishing, culturing net Fence mesh in case, cylinder mould, or lake, reservoir is required for using fishing lines, with the development of China's fishery, multiple high-performance Also gradually promote the use of, the feature that fishing net line strength is high, lightweight, cost performance is high makes fishing lines achieve in fish production field Good using effect, and cage culture, enclose lake cultivation and deep-sea fishing development, to the hired height being chronically exposed in air Strength filaments are ageing-resistant to put forward higher requirement, and fishing lines is in use, comprehensive due to factors such as light, oxygen, heat, water Cooperation is used, and so that performance is gradually degenerated, therefore, it is necessary to study to the resistance to ag(e)ing of high-strength fishing netting twine.
Content of the invention
The purpose of the present invention is for existing problem, there is provided a kind of ageing-resistant high-strength fishing netting twine.
The present invention is achieved by the following technical solutions：A kind of ageing-resistant high-strength fishing netting twine, by following weight portion Raw material make：Brombutyl 16-20 part, ternary carboxyl vinyl chloride-vinyl acetate resin 25-30 part, polysiloxane grafted modified acroleic acid tree Fat 25-30 part, boron carbide fibre 6-10 part, blanc fixe 4-8 part, rice bran wax 2-3 part, tin indium oxide 0.5-0.8 part, ethanol zirconium 0.1-0.2 part, erucyl amide 0.3-0.5 part, pentaerythritol stearate 0.7-1.2 part, phenyl-magnesium-chloride 2.4-3 part, perfluor Butyl sulfonic acid potassium 0.2-0.6 part, Eucalyptus Globulus oil 2-3 part；
Its preparation method comprises the following steps：
（1）By brombutyl, ternary vinyl chloride-vinyl acetate resin, polysiloxane modified acrylic resin, boron carbide fibre, oxygen in one's power After change indium tin, ethanol zirconium and phenyl-magnesium-chloride mix in proportion, process 1-1.5 hour under conditions of 120-150 DEG C, with grinding Machine grinds to form fine powder, as mixed powder；
（2）To be divided with high-speed mixer stirring 30-40 under conditions of 65-80 DEG C after above-mentioned mixed powder and surplus stock mixing Clock, obtains mixed material；
（3）Above-mentioned gained mixed material is added in double screw extruder and melt extrudes, melt stream is become by spinning nozzle, so Solidified by cooler afterwards, cooler passes through 10-12 DEG C of the side-blown cooling and solidifying of cross air blasting low temperature, the speed of blowing of cross air blasting is 1800-2000m³/h；
（4）Tow after above-mentioned cooling and solidifying, by 5 pairs of hot-rolling drawing-offs and sizing, drafting multiple is 6-8 times, the temperature of 5 pairs of hot-rollings Degree is followed successively by：95℃、100℃、130℃、180℃、160℃；
（5）Through high-speed winder coiling and molding, winding speed is 2200-2400m/min to fiber after sizing.
As further improvement of these options, the fineness of described mixed powder is 600-800 mesh.
As further improvement of these options, the described condition that melt extrudes is：Melt distribution pipe temperature 220-240 DEG C, 215-235 DEG C of spinning body temperature, 165-185 rev/min of engine speed, feeding power 26-28Hz.
The present invention has advantages below compared to existing technology：By the brombutyl of difference in functionality, ternary in the present invention Vinyl chloride-vinyl acetate resin, polysiloxane modified acrylic resin are applied in combination in one's power, and carry out pre- place to its collaborative auxiliary agent before processing Reason, vinyl chloride-vinyl acetate resin difficulty of processing is big in one's power to solve the problems, such as brombutyl, ternary；The reduction of raw particles, increased The size of its specific surface area is so as to the agglomerate specific surface area obtaining after merging is larger, thus increasing fishing lines oxidation resistance And wearability；Obtained fishing lines better mechanical property, anti-impact force are strong, wearability is good, and bending strength is improved largely, There is preferable antifouling capacity and ageing-resistant performance, Long-Time Service can keep stronger mechanical performance, be suitable to promote the use of.
Specific embodiment
Embodiment 1
A kind of ageing-resistant high-strength fishing netting twine, is made up of the raw material of following weight portion：18 parts of brombutyl, ternary carboxyl 28 parts of vinyl chloride-vinyl acetate resin, 26 parts of polysiloxane modified acrylic resin, 10 parts of boron carbide fibre, 8 parts of blanc fixe, rice bran wax 2 Part, 0.6 part of tin indium oxide, 0.2 part of ethanol zirconium, 0.4 part of erucyl amide, 1.2 parts of pentaerythritol stearate, phenyl-magnesium-chloride 3 Part, 0.6 part of perfluorobutyl potassium sulfonate, 2 parts of Eucalyptus Globulus oil；
Its preparation method comprises the following steps：
（1）By brombutyl, ternary vinyl chloride-vinyl acetate resin, polysiloxane modified acrylic resin, boron carbide fibre, oxygen in one's power After change indium tin, ethanol zirconium and phenyl-magnesium-chloride mix in proportion, process 1-1.5 hour under conditions of 120-150 DEG C, with grinding Machine grinds to form the fine powder that fineness is 600-800 mesh, as mixed powder；
（2）To be divided with high-speed mixer stirring 30-40 under conditions of 65-80 DEG C after above-mentioned mixed powder and surplus stock mixing Clock, obtains mixed material；
（3）Above-mentioned gained mixed material is added in double screw extruder and melt extrudes, melt stream is become by spinning nozzle, so Solidified by cooler afterwards, cooler passes through 10-12 DEG C of the side-blown cooling and solidifying of cross air blasting low temperature, the speed of blowing of cross air blasting is 1800-2000m³/h；
（4）Tow after above-mentioned cooling and solidifying, by 5 pairs of hot-rolling drawing-offs and sizing, drafting multiple is 6-8 times, the temperature of 5 pairs of hot-rollings Degree is followed successively by：95℃、100℃、130℃、180℃、160℃；
（5）Through high-speed winder coiling and molding, winding speed is 2200-2400m/min to fiber after sizing.
Wherein, the described condition that melt extrudes is：Melt distribution pipe temperature 220-240 DEG C, spinning body temperature 215-235 DEG C, 165-185 rev/min of engine speed, feeding power 26-28Hz.
Embodiment 2
A kind of ageing-resistant high-strength fishing netting twine, is made up of the raw material of following weight portion：16 parts of brombutyl, ternary carboxyl 30 parts of vinyl chloride-vinyl acetate resin, 28 parts of polysiloxane modified acrylic resin, 8 parts of boron carbide fibre, 8 parts of blanc fixe, rice bran wax 3 Part, 0.8 part of tin indium oxide, 0.1 part of ethanol zirconium, 0.5 part of erucyl amide, 0.8 part of pentaerythritol stearate, phenyl-magnesium-chloride 2.4 parts, 0.4 part of perfluorobutyl potassium sulfonate, 2 parts of Eucalyptus Globulus oil；
Its preparation method is same as Example 1.
Embodiment 3
A kind of ageing-resistant high-strength fishing netting twine, is made up of the raw material of following weight portion：20 parts of brombutyl, ternary carboxyl 26 parts of vinyl chloride-vinyl acetate resin, 30 parts of polysiloxane modified acrylic resin, 7 parts of boron carbide fibre, 7 parts of blanc fixe, rice bran wax 2 Part, 0.5 part of tin indium oxide, 0.2 part of ethanol zirconium, 0.3 part of erucyl amide, 1.1 parts of pentaerythritol stearate, phenyl-magnesium-chloride 2.6 parts, 0.3 part of perfluorobutyl potassium sulfonate, 3 parts of Eucalyptus Globulus oil；
Its preparation method is same as Example 1.
Design anti-aging test, by made fishing lines temperature be 50 DEG C, humidity be 65% under conditions of, use irradiation power Light source for 0.65W/mm, is irradiating to it at fishing lines 30cm 12 hours, is then condensing 6 hours under dark condition； Repeatedly process 5 times.
Select a diameter of 3mm, the fishing lines for more than 6.5cN/dtex for the single wire fracture intensity as a control group, says control group Carry out respectively after anti-aging test with embodiment 1-3, obtain following result：
Table 1 anti-aging test fishing lines the performance test results
It is seen from the above data that the fishing lines of preparation, after anti-aging test, remains to keep higher machinery in the present invention Performance, in cage culture, encloses in lake cultivation and deep-sea fishing use, service life can reach more than 6 years, and fishing in fresh water makes Can reach more than 10 years with the life-span.

Claims (3)

1. a kind of ageing-resistant high-strength fishing netting twine is it is characterised in that be made up of the raw material of following weight portion：Brombutyl 16-20 part, ternary carboxyl vinyl chloride-vinyl acetate resin 25-30 part, polysiloxane modified acrylic resin 25-30 part, boron carbide fibre 6- 10 parts, blanc fixe 4-8 part, rice bran wax 2-3 part, tin indium oxide 0.5-0.8 part, ethanol zirconium 0.1-0.2 part, erucyl amide 0.3- 0.5 part, pentaerythritol stearate 0.7-1.2 part, phenyl-magnesium-chloride 2.4-3 part, perfluorobutyl potassium sulfonate 0.2-0.6 part, indigo plant Volatile oil extracted from eucalyptus' leaves or twigs 2-3 part；
Its preparation method comprises the following steps：
By vinyl chloride-vinyl acetate resin, polysiloxane modified acrylic resin, boron carbide fibre, the oxidation in one's power of brombutyl, ternary After indium tin, ethanol zirconium and phenyl-magnesium-chloride mix in proportion, process 1-1.5 hour under conditions of 120-150 DEG C, use grinder Grind to form fine powder, as mixed powder；
Stir 30-40 minute with high-speed mixer by after above-mentioned mixed powder and surplus stock mixing under conditions of 65-80 DEG C, obtain To mixed material；
Above-mentioned gained mixed material is added in double screw extruder and melt extrudes, melt stream is become by spinning nozzle, then Solidified by cooler, cooler passes through 10-12 DEG C of the side-blown cooling and solidifying of cross air blasting low temperature, the speed of blowing of cross air blasting is 1800-2000m³/h；
Tow after above-mentioned cooling and solidifying, by 5 pairs of hot-rolling drawing-offs and sizing, drafting multiple is 6-8 times, the temperature of 5 pairs of hot-rollings It is followed successively by：95℃、100℃、130℃、180℃、160℃；
Through high-speed winder coiling and molding, winding speed is 2200-2400m/min to fiber after sizing.
2. as claimed in claim 1 a kind of ageing-resistant high-strength fishing netting twine it is characterised in that the fineness of described mixed powder is 600-800 mesh.
3. as claimed in claim 2 a kind of ageing-resistant high-strength fishing netting twine it is characterised in that the described condition melt extruding For：Melt distribution pipe temperature 220-240 DEG C, 215-235 DEG C of spinning body temperature, 165-185 rev/min of engine speed, feeding work( Rate 26-28Hz.
CN201610814077.1A 2016-09-10 2016-09-10 Anti-aging high-strength fishing net thread Pending CN106398044A (en)

Priority Applications (1)

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Application Number Priority Date Filing Date Title
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108060470A (en) * 2017-12-29 2018-05-22 付主枝 A kind of preparation method and applications of hard special type textile material
CN113215681A (en) * 2021-04-29 2021-08-06 江苏普乐菲新材料有限公司 Wear-resistant and aging-resistant fishing net thread

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103724769A (en) * 2013-12-11 2014-04-16 巢湖亚塑网具制造有限公司 Nylon-reinforced fishing net
CN105385076A (en) * 2015-11-14 2016-03-09 巢湖市荷花渔网有限公司 Sunscreen fishing net and preparation method thereof
CN105754264A (en) * 2016-04-14 2016-07-13 巢湖市荷花渔网有限公司 High-strength tensile-resistant fishing net

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103724769A (en) * 2013-12-11 2014-04-16 巢湖亚塑网具制造有限公司 Nylon-reinforced fishing net
CN105385076A (en) * 2015-11-14 2016-03-09 巢湖市荷花渔网有限公司 Sunscreen fishing net and preparation method thereof
CN105754264A (en) * 2016-04-14 2016-07-13 巢湖市荷花渔网有限公司 High-strength tensile-resistant fishing net

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108060470A (en) * 2017-12-29 2018-05-22 付主枝 A kind of preparation method and applications of hard special type textile material
CN113215681A (en) * 2021-04-29 2021-08-06 江苏普乐菲新材料有限公司 Wear-resistant and aging-resistant fishing net thread

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