CN106397810A - Antistatic coated release paper - Google Patents
Antistatic coated release paper Download PDFInfo
- Publication number
- CN106397810A CN106397810A CN201610788226.1A CN201610788226A CN106397810A CN 106397810 A CN106397810 A CN 106397810A CN 201610788226 A CN201610788226 A CN 201610788226A CN 106397810 A CN106397810 A CN 106397810A
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- CN
- China
- Prior art keywords
- parts
- styrene
- block copolymer
- release paper
- film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
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- C—CHEMISTRY; METALLURGY
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- Wood Science & Technology (AREA)
- Manufacturing & Machinery (AREA)
- Laminated Bodies (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses an antistatic coated release paper. The surface of the embossed pattern area of the antistatic coated release paper is coated with an organosilicon release agent layer, and a coating layer comprises, by weigh, 100 parts of high density polyethylene, 120-180 parts of low density polyethylene, 10-30 arts of a styrene-isoprene-styrene block copolymer SIS, 5-15 parts of a styrene-butadiene block copolymer SBS, 1.2 parts of paraffin, 0.3 parts of glycerin, 7 parts of POE polyolefin elastomer and 0.3 parts of a coupling agent; the POE polyolefin elastomer is an ethylene and octylene polymer; and a ratio of the styrene-isoprene-styrene block copolymer to the styrene-butadiene block copolymer is 2:1. The antistatic coated release paper makes the release agent layer and a polyester film be closely bonded, and greatly improves the subsequent adhesion.
Description
Technical field
The present invention relates to a kind of antistatic film release paper, belong to separated type material technical field.
Background technology
Generally mould release membrance refers to be coated with organic silicone oil in polyester film surface, plays antiseized effect;Mould release membrance surface can
To have bright finish and mute face, but when the pressure sensitive adhesive adhesive tape of this traditional release film production and label tape, glue surface landscaping effect is not
Ideal, when common mould release membrance and pressure sensitive adhesive adhesive tape gluing, easily produces bubble between the two.Using embossing release paper although
The effect of aerofluxuss bubble can be reached, but easily absorbed water due to release paper, tearing toughness not high, be difficult to observe glue surface, cross cutting
Afterwards, there is paper scrap at edge it is impossible to be used by high-end product.
Content of the invention
It is an object of the present invention to provide a kind of antistatic film release paper, the netted stricture of vagina of its formation of this antistatic film release paper
Road embossing is clear, depth unification, distributing line uniformly, the embossing laminating release film of formation when with pressure-sensitive glue laminating between the two not
Bubble can be produced, thus not having influence on using effect.
For reaching above-mentioned purpose, the technical solution used in the present invention is:A kind of antistatic film release paper, its feature exists
In:Including laminated polyester film with and be coated on film coat, this film coat and the mylar of mylar layer surface
The opposite surface of floor has pattern of indentations area, and the surface in this pattern of indentations area is coated with a silicone release oxidant layer, and described film applies
Coating is grouped into by the group of following weight portion:
100 parts of high density polyethylene (HDPE),
120 ~ 180 parts of Low Density Polyethylene,
10 parts ~ 30 parts of styrene isoprene styrene block copolymer (SIS) SIS,
Styrene and 5 parts ~ 15 parts of the block copolymer SBS of butadiene;
1.2 parts of paraffin, 0.3 part of glycerol, 7 parts of POE polyolefin elastomer, 0.3 part of coupling agent;
Described POE polyolefin elastomer is the high polymer of ethylene and octene;
The ratio of the block copolymer of described styrene isoprene styrene block copolymer (SIS) and styrene and butadiene is
2:1.
In technique scheme, further improved scheme is as follows:
In such scheme, described coupling agent is silane coupler.
Because technique scheme is used, the present invention compared with prior art has following advantages and effect:
Antistatic film release paper of the present invention, the netted lines embossing that it forms is clear, depth unification, and distributing line uniformly, is formed
Antistatic film release paper will not produce bubble between the two when with pressure-sensitive glue laminating, thus not have influence on using effect
Really;Secondly, it adds the block of 10 parts ~ 30 parts of styrene isoprene styrene block copolymer (SIS), styrene and butadiene
5 parts ~ 15 parts of copolymer and 5 ~ 10 parts of POE polyolefin elastomer so that the cohesive force of parting agent layer and mylar interlayer more
Closely, and substantially improve remnants then rate, release layer is difficult for drop-off, and mesh further improves the antistatic performance of film.
Specific embodiment
With reference to embodiment, the invention will be further described:
Embodiment:A kind of antistatic film release paper, including laminated polyester film with and be coated on the film of mylar layer surface
Coat, this film coat surface opposite with laminated polyester film has pattern of indentations area, and the surface in this pattern of indentations area applies
Cloth one silicone release oxidant layer, described film coat is grouped into by the group of following weight portion:
Table 1
Above-mentioned POE polyolefin elastomer is the high polymer of ethylene and octene;
The ratio of the block copolymer of above-mentioned styrene isoprene styrene block copolymer (SIS) and styrene and butadiene is
2:1.
Above-mentioned laminated polyester film is one of PP, PET, PBT, PEN and PBN.
Comparative example 1:A kind of antistatic film release paper, including laminated polyester film and and be coated on mylar layer surface
Film coat, this film coat surface opposite with laminated polyester film has pattern of indentations area, the table in this pattern of indentations area
Face is coated with a silicone release oxidant layer, and described film coat is grouped into by the group of following weight portion:High density polyethylene (HDPE) 100
Part, 125 parts of Low Density Polyethylene.
Comparative example 2:A kind of antistatic film release paper, including laminated polyester film and and be coated on mylar layer surface
Film coat, this film coat surface opposite with laminated polyester film has pattern of indentations area, the table in this pattern of indentations area
Face is coated with a silicone release oxidant layer, and described film coat is grouped into by the group of following weight portion:High density polyethylene (HDPE) 100
Part, 150 parts of Low Density Polyethylene.
The antistatic film release paper of embodiment and comparative example gained is tested, as shown in table 2:
Table 2
During using above-mentioned antistatic film release paper, the netted lines embossing that it forms is clear, depth unification, and distributing line is uniform,
The embossing laminating release film being formed will not produce bubble when with pressure-sensitive glue laminating between the two, thus not having influence on using effect
Really;Secondly, it adds the block of 10 parts ~ 30 parts of styrene isoprene styrene block copolymer (SIS), styrene and butadiene
5 parts ~ 15 parts of copolymer and 5 ~ 10 parts of POE polyolefin elastomer, coupling agent 0.3-0.8 part is so that film coat and polyester
Cohesive force between film layer is even closer, and substantially improves remnants then rate, and release layer is difficult for drop-off, and mesh further improves film
Antistatic performance.
Above-described embodiment only technology design to illustrate the invention and feature, its object is to allow person skilled in the art
Scholar will appreciate that present disclosure and implements according to this, can not be limited the scope of the invention with this.All according to the present invention
Equivalence changes or modification that spirit is made, all should be included within the scope of the present invention.
Claims (2)
1. a kind of antistatic film release paper it is characterised in that:Including laminated polyester film and and be coated on mylar layer surface
Film coat, this film coat surface opposite with laminated polyester film have pattern of indentations area, this pattern of indentations area
Surface is coated with a silicone release oxidant layer, and described film coat is grouped into by the group of following weight portion:
100 parts of high density polyethylene (HDPE),
120 ~ 180 parts of Low Density Polyethylene,
10 parts ~ 30 parts of styrene isoprene styrene block copolymer (SIS) SIS,
Styrene and 5 parts ~ 15 parts of the block copolymer SBS of butadiene;
1.2 parts of paraffin, 0.3 part of glycerol, 7 parts of POE polyolefin elastomer, 0.3 part of coupling agent;
Described POE polyolefin elastomer is the high polymer of ethylene and octene;
The ratio of the block copolymer of described styrene isoprene styrene block copolymer (SIS) and styrene and butadiene is
2:1.
2. antistatic film release paper according to claim 1 it is characterised in that:Described coupling agent is silane coupler.
Priority Applications (1)
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CN201610788226.1A CN106397810A (en) | 2015-04-27 | 2015-04-27 | Antistatic coated release paper |
Applications Claiming Priority (2)
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CN201610788226.1A CN106397810A (en) | 2015-04-27 | 2015-04-27 | Antistatic coated release paper |
CN201510204411.7A CN104999751B (en) | 2015-04-27 | 2015-04-27 | Embossing release film |
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CN201510204411.7A Division CN104999751B (en) | 2015-04-27 | 2015-04-27 | Embossing release film |
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Family Applications (15)
Application Number | Title | Priority Date | Filing Date |
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CN201610718684.8A Pending CN106279741A (en) | 2015-04-27 | 2015-04-27 | Silicone release film |
CN201610697582.2A Pending CN106279907A (en) | 2015-04-27 | 2015-04-27 | Antistatic embossing type mould release membrance |
CN201610696814.2A Pending CN106317437A (en) | 2015-04-27 | 2015-04-27 | Anti-foam embossed release film |
CN201610788143.2A Pending CN106397809A (en) | 2015-04-27 | 2015-04-27 | Anti-adherent film which is provided with embossing and is used for adhesive tape |
CN201610788142.8A Pending CN106279742A (en) | 2015-04-27 | 2015-04-27 | Can discharge type embossing release film |
CN201610696877.8A Pending CN106318043A (en) | 2015-04-27 | 2015-04-27 | Organosilicon release film for label adhesive tape |
CN201610788195.XA Pending CN106279743A (en) | 2015-04-27 | 2015-04-27 | Mute antistatic embossing release film |
CN201610788226.1A Pending CN106397810A (en) | 2015-04-27 | 2015-04-27 | Antistatic coated release paper |
CN201610696878.2A Pending CN106279738A (en) | 2015-04-27 | 2015-04-27 | Embossing laminating release paper |
CN201610718683.3A Pending CN106317439A (en) | 2015-04-27 | 2015-04-27 | Low residual rate embossed release paper |
CN201610786795.2A Pending CN106318258A (en) | 2015-04-27 | 2015-04-27 | Release film with net-shaped patterns |
CN201610788227.6A Active CN106368068B (en) | 2015-04-27 | 2015-04-27 | Silicone oil isolation film for pressure sensitive adhesive tape |
CN201610697021.2A Pending CN106279739A (en) | 2015-04-27 | 2015-04-27 | There is the mould release membrance of netted lines |
CN201610697583.7A Pending CN106280731A (en) | 2015-04-27 | 2015-04-27 | Pressure sensitive adhesive tape silicon oil membrane |
CN201510204411.7A Active CN104999751B (en) | 2015-04-27 | 2015-04-27 | Embossing release film |
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Application Number | Title | Priority Date | Filing Date |
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CN201610718684.8A Pending CN106279741A (en) | 2015-04-27 | 2015-04-27 | Silicone release film |
CN201610697582.2A Pending CN106279907A (en) | 2015-04-27 | 2015-04-27 | Antistatic embossing type mould release membrance |
CN201610696814.2A Pending CN106317437A (en) | 2015-04-27 | 2015-04-27 | Anti-foam embossed release film |
CN201610788143.2A Pending CN106397809A (en) | 2015-04-27 | 2015-04-27 | Anti-adherent film which is provided with embossing and is used for adhesive tape |
CN201610788142.8A Pending CN106279742A (en) | 2015-04-27 | 2015-04-27 | Can discharge type embossing release film |
CN201610696877.8A Pending CN106318043A (en) | 2015-04-27 | 2015-04-27 | Organosilicon release film for label adhesive tape |
CN201610788195.XA Pending CN106279743A (en) | 2015-04-27 | 2015-04-27 | Mute antistatic embossing release film |
Family Applications After (7)
Application Number | Title | Priority Date | Filing Date |
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CN201610696878.2A Pending CN106279738A (en) | 2015-04-27 | 2015-04-27 | Embossing laminating release paper |
CN201610718683.3A Pending CN106317439A (en) | 2015-04-27 | 2015-04-27 | Low residual rate embossed release paper |
CN201610786795.2A Pending CN106318258A (en) | 2015-04-27 | 2015-04-27 | Release film with net-shaped patterns |
CN201610788227.6A Active CN106368068B (en) | 2015-04-27 | 2015-04-27 | Silicone oil isolation film for pressure sensitive adhesive tape |
CN201610697021.2A Pending CN106279739A (en) | 2015-04-27 | 2015-04-27 | There is the mould release membrance of netted lines |
CN201610697583.7A Pending CN106280731A (en) | 2015-04-27 | 2015-04-27 | Pressure sensitive adhesive tape silicon oil membrane |
CN201510204411.7A Active CN104999751B (en) | 2015-04-27 | 2015-04-27 | Embossing release film |
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CN105936169A (en) * | 2016-06-07 | 2016-09-14 | 无锡市新久科技有限公司 | PET embossed release film for rubber isolation |
TWI706853B (en) * | 2018-01-17 | 2020-10-11 | 南亞塑膠工業股份有限公司 | Polyolefin releasing film and method for manufacturing the same, and thermoplastic polyurethane composite structure |
CN109575804A (en) * | 2018-11-30 | 2019-04-05 | 上海盈实纸塑材料有限公司 | It is a kind of to be heat-shrinked separated type material small, that adhesive force is strong |
CN109609051A (en) * | 2018-12-19 | 2019-04-12 | 四川东材科技集团股份有限公司 | A kind of preparation method of high temperature resistant grid acrylic pressure sensitive adhesive tape |
CN110303741B (en) * | 2019-07-22 | 2021-02-12 | 广东安德力新材料有限公司 | Easy-to-wash label film and preparation method thereof |
CN114774008B (en) * | 2022-06-17 | 2022-09-13 | 宁波长阳科技股份有限公司 | High-low-density POE (polyolefin elastomer) co-extrusion packaging adhesive film and preparation method thereof |
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Also Published As
Publication number | Publication date |
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CN106279741A (en) | 2017-01-04 |
CN106317439A (en) | 2017-01-11 |
CN106368068A (en) | 2017-02-01 |
CN104999751B (en) | 2017-04-19 |
CN106279742A (en) | 2017-01-04 |
CN106279743A (en) | 2017-01-04 |
CN106397809A (en) | 2017-02-15 |
CN106317437A (en) | 2017-01-11 |
CN104999751A (en) | 2015-10-28 |
CN106368068B (en) | 2018-09-18 |
CN106318258A (en) | 2017-01-11 |
CN106279738A (en) | 2017-01-04 |
CN106318043A (en) | 2017-01-11 |
CN106279907A (en) | 2017-01-04 |
CN106279739A (en) | 2017-01-04 |
CN106280731A (en) | 2017-01-04 |
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