CN106396679A - Graphite sand cold iron and preparation method thereof - Google Patents

Graphite sand cold iron and preparation method thereof Download PDF

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Publication number
CN106396679A
CN106396679A CN201610777952.3A CN201610777952A CN106396679A CN 106396679 A CN106396679 A CN 106396679A CN 201610777952 A CN201610777952 A CN 201610777952A CN 106396679 A CN106396679 A CN 106396679A
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China
Prior art keywords
graphite
sand
chill
parts
preparation
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Pending
Application number
CN201610777952.3A
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Chinese (zh)
Inventor
孙桔
方怡
吴跃彬
王宇
李昀旻
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JIANGSU FAW FOUNDRY CO Ltd
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JIANGSU FAW FOUNDRY CO Ltd
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Priority to CN201610777952.3A priority Critical patent/CN106396679A/en
Publication of CN106396679A publication Critical patent/CN106396679A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/515Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics
    • C04B35/52Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbon, e.g. graphite
    • C04B35/522Graphite
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D27/00Treating the metal in the mould while it is molten or ductile ; Pressure or vacuum casting
    • B22D27/04Influencing the temperature of the metal, e.g. by heating or cooling the mould
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/62204Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products using waste materials or refuse
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3418Silicon oxide, silicic acids or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/349Clays, e.g. bentonites, smectites such as montmorillonite, vermiculites or kaolines, e.g. illite, talc or sepiolite

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Mold Materials And Core Materials (AREA)

Abstract

The invention relates to graphite sand cold iron and a preparation method thereof. The graphite sand cold iron comprises the following components in parts by weight: 15-20 parts of silica sand, 80-85 parts of graphite particles, 9-11 parts of argil, 13-17 parts of a synthetic fat bonding agent and 2-3 parts of water. The preparation method comprises the following steps: firstly, before preparation, crushing, sieving and preparing waste graphite cold iron into the graphite particles; respectively adding the graphite particles, the silica sand, the argil and the water in a sand mixer; slowly adding the synthetic fat bonding agent into the sand mixer at a uniform speed; putting raw materials in the sand mixer in a core box for molding and taking out from the core box after molding and putting into a resistance furnace for drying treatment, wherein the heating temperature is 300-350 DEG C, and the heating time is 3-4 hours; cooling to prepare the graphite sand cold iron. The preparation method provided by the invention is simple, the steps are easy to operate, the prepared graphite sand cold iron can be taken as a substitute of metal cold iron on the surface of a complex casting and can effectively solve the problems of shrinkage cavity and shrinkage porosity.

Description

A kind of graphite sand chill and preparation method thereof
Technical field
The present invention relates to a kind of graphite sand chill and preparation method thereof, belong to graphite sand preparing technical field.
Background technology
Casting heat energy-saving position easily produces shrinkage cavity or shrinkage defect, in order to eliminate shrinkage cavity or shrinkage porosite, technique typically can be adopted With chill or rising head.
Chill mostly adopts metal chill, material selection HT200 or HT250 etc., and a small amount of enterprise selects graphite chilling block.Metal Chill is larger due to its deadweight, and density is molding sand more than 4 times, so limited by its position of putting, be placed in foundry goods side or Top surface may drop and cause to subside, thus causing scrapping of foundry goods;Have simultaneously access times limit, in addition using before to clear up beat Mill weldering is dry, rustless no greasy dirt no dampness.This increased difficulty to production management.
Graphite chilling block does not then have the disadvantages mentioned above of metal chill.But the low intensity of graphite chilling block, cracky during knockout, from And reduce service life, increase use cost.That generally the abrasion of big graphite chilling block is severe and that major part cannot use Little graphite chilling block can only be discarded, and causes to waste.In order that these damaged graphite chilling blocks can recycle, we trial-produce successfully Graphite sand chill.
Graphite sand chill is these discarded graphite chilling blocks to be processed into graphite particle mix with silica sand.Graphite sand chill is easy In molding, various complicated shapes can be made;For some cast(ing) surfaces need place chill and execute-in-place is inconvenient to use gold Belong to the place of chill, directly made using graphite sand and use as chill.Having of graphite can fully be inherited by graphite sand chill Light specific gravity, refractoriness is high, the advantages of heat conductivity is big, can play chill effect and solve transportation problem.
Content of the invention
The invention aims to solving the above problems, there is provided a kind of graphite sand chill and preparation method thereof, preparation Method is simple, and the graphite sand chill preparing can effectively solve the problem that the problem of shrinkage porosite.
The present invention adopts the following technical scheme that:A kind of graphite sand chill, each component is calculated by weight as:Silica sand 15-20 Part, graphite granule 80-85 part, potter's clay 9-11 part, synthetic fat binder 13-17 part, water 2-3 part.
Further, the mesh number of described silica sand is 30-70 mesh, ash≤0.5% of silica sand.
Further, described graphite granule be discarded graphite chilling block through broken sieve prepared.
The preparation method of graphite sand chill, comprises the steps:
(1)Graphite chilling block is carried out broken sieving and makes graphite granule, remove powder and bulk, choose the graphite of 30-70 mesh Grain;
(2)The water taking the silica sand of 15-20 part, the graphite granule of 80-85 part, the potter's clay of 9-11 part and 2 parts by weight adds It is sufficiently stirred for 5-8min to puddle mixer;
(3)Slow addition synthetic fat binder at the uniform velocity in puddle mixer, continues stirring 8-12min and obtains graphite sand chill raw material;
(4)Raw material in puddle mixer is placed in core box and carries out molding, take out to put in resistance furnace from core box after molding and dry Process, heating-up temperature is 300-350 DEG C, heat time heating time is 3-4h;
(5)Graphite sand chill after molding is cooled to the furnace room temperature.
Further, described step(3)Middle synthetic fat binder adds in 30-60s.
Further, described step(4)Middle raw material takes out after placing 2-10min molding in core box.
Further, described step(4)Middle raw material stirs while adding during putting into core box, makes raw material in core box It is compacted layer by layer, add and after finishing, stop stirring.
Preparation method of the present invention is simple, and step is easily operated, and the graphite sand chill preparing can be used as intricate casting The replacement of the metal chill on surface, can effectively solve the problem that the problem of shrinkage cavity shrinkage porosity.
Brief description
Fig. 1 is the schematic diagram of the T word footpath experiment in embodiment one in the present invention.
Fig. 2 is the schematic diagram of the experiment in embodiment two in the present invention.
Fig. 3 is the schematic diagram of the experiment in embodiment three in the present invention.
Brief description:Graphite sand chill 1, graphite chilling block 2.
Specific embodiment
Below in conjunction with specific embodiment, the present invention is further illustrated.
It is purchased from Dong Yu synthetic fat binder factory of Donggang City outside synthetic fat binder in the present invention.
Embodiment one:A kind of graphite sand chill, each component is calculated by weight as:15 parts of silica sand, 85 parts of graphite granule, 9 parts of potter's clay, 14 parts of synthetic fat binder, 2 parts of water.
Preparation method is:
(1)Graphite chilling block is carried out broken sieving and makes graphite granule, remove powder and bulk, choose the graphite granule of 50 mesh;
(2)15 parts of silica sand, 85 parts of graphite granule, the water of 9 parts of potter's clay and 2 parts is taken to add to puddle mixer by weight It is sufficiently stirred for 5min;
(3)Slow addition synthetic fat binder at the uniform velocity in puddle mixer, synthetic fat binder adds in 30s, continues stirring 8min and obtains To graphite sand chill raw material;
(4)Raw material in puddle mixer is placed in the graphite sand chill carrying out in core box that 75mm × 75mm × 80mm is prepared in molding, former Material stirs while adding during putting into core box, so that raw material is laminated in core box middle level real, adds and stops stirring, raw material after finishing Take out from core box after placing 2min molding in core box and put into drying and processing in resistance furnace, heating-up temperature is 300 DEG C, during heating Between be 3h;
(5)Graphite sand chill after molding is cooled to the furnace room temperature.
The graphite sand chill being prepared using embodiment one carries out the experiment of T word muscle:
In experimentation left side placing graphite sand cooling ferrum 1 for T word muscle A, it is T word muscle B that any chill is not placed in centre, and right side is put Putting graphite chilling block 2 is T word muscle C, and graphite chilling block is identical with the size of graphite chilling block.Pouring temperature is 1350-1360 DEG C;Material is QT400-18ULT.Carry out ultrasonic examination UT detection after foundry goods is unpacking, and carry out dissection to three block casting parts seeing whether deposit inside it In shrinkage porosite.Experiment schematic diagram such as Fig. 1.
Experimental result shows, T word muscle B anatomy experiment and UT detection all have shrinkage defect, and T word muscle A and C does not all find to contract Pine.Illustrate that the shrinkproof loose ability of the graphite sand chill 1 that the present invention prepares is identical with graphite chilling block 2 effect.
Embodiment two:A kind of graphite sand chill, each component is calculated by weight as:17 parts of silica sand, 83 parts of graphite granule, 10 parts of potter's clay, 15 parts of synthetic fat binder, 2 parts of water.
Preparation method is:
(1)Graphite chilling block is carried out broken sieving and makes graphite granule, remove powder and bulk, choose the graphite granule of 60 mesh;
(2)17 parts of silica sand, 83 parts of graphite granule, the water of 10 parts of potter's clay and 2 parts is taken to add to puddle mixer by weight In be sufficiently stirred for 8min;
(3)Slow addition synthetic fat binder at the uniform velocity in puddle mixer, synthetic fat binder adds in 45s, continues stirring 9min and obtains To graphite sand chill raw material;
(4)Raw material in puddle mixer is placed in the graphite sand chill carrying out in core box that 200mm × 175mm × 70mm is prepared in molding, Raw material stirs while adding during putting into core box, so that raw material is laminated in core box middle level real, adds and stops stirring after finishing, former Material takes out from core box after placing 8min molding in core box and puts into drying and processing in resistance furnace, and heating-up temperature is 350 DEG C, heating Time is 3.5h;
(5)Graphite sand chill after molding is cooled to the furnace room temperature.
As shown in Fig. 2 testing inspection, process of the test are carried out to the graphite sand chill that embodiment 2 prepares:Certain 2.5MW At rear bearing block one, wall thickness is thicker, reaches 200mm, be herein with base faying face it is desirable to very high it is impossible to there be Shrinkage cavity, for this Need in technique to place chill.
Herein, the graphite sand chill 1 of the 200mmX175mmX70mm making is placed, and can be together with sand mold Brushing zircon flour coating is it is ensured that the surface quality of foundry goods.
When before this not using graphite sand chill, the foundry goods scrappage that this foundry goods therefore position occurs that shrinkage porosite problem causes is 5%, scrapped using the foundry goods that after graphite sand chill, therefore position shrinkage porosite causes and be reduced to 1%.
Embodiment three:A kind of graphite sand chill, each component is calculated by weight as:20 parts of silica sand, 80 parts of graphite granule, 11 parts of potter's clay, 17 parts of synthetic fat binder, 3 parts of water.
Preparation method is:
(1)Graphite chilling block is carried out broken sieving and makes graphite granule, remove powder and bulk, choose the graphite granule of 70 mesh;
(2)20 parts of silica sand, 80 parts of graphite granule, the water of 11 parts of potter's clay and 3 parts is taken to add to puddle mixer by weight In be sufficiently stirred for 7min;
(3)Slow addition synthetic fat binder at the uniform velocity in puddle mixer, continues stirring 12min and obtains graphite sand chill raw material;
(4)Raw material in puddle mixer is placed in and carries out molding in core box and prepare small-sized graphite sand chill, core box put into by raw material During stir while adding, so that raw material is laminated in core box middle level real, add and after finishing, stop stirring, raw material is placed in core box Take out from core box after 2-10min molding and put into drying and processing in resistance furnace, heating-up temperature is 330 DEG C, heat time heating time is 4h;
(5)Graphite sand chill after molding is cooled to the furnace room temperature.
As shown in figure 3, testing to the graphite sand chill that embodiment three prepares, process of the test:Certain stator frame At one, joint hinge is whole foundry goods and the follow-up boom hoisting assembling after finishing, and customer requirement shrinkage porosite can not herein, and And need to carry out x-ray inspection(RT detects).Shrinkage porosite is had to scrap due to not placing chill UT detection when initial workpiece produces, for this Determine to adopt graphite sand chill.
According to said method do not produced, RT detection duration finds shrinkage defect.According to said method produce 10 foundry goods to examine through UT Survey and RT detection does not find to where there is shrinkage defect.

Claims (7)

1. a kind of graphite sand chill it is characterised in that:Each component is calculated by weight as:Silica sand 15-20 part, graphite granule 80- 85 parts, potter's clay 9-11 part, synthetic fat binder 13-17 part, water 2-3 part.
2. graphite sand chill as claimed in claim 1 it is characterised in that:The mesh number of described silica sand is 30-70 mesh, the ash of silica sand Part≤0.5%.
3. graphite sand chill as claimed in claim 1 it is characterised in that:Described graphite granule is discarded graphite chilling block through broken Sieve prepared.
4. the graphite sand chill described in claim 1 preparation method it is characterised in that:Comprise the steps:
(1)Graphite chilling block is carried out broken sieving and makes graphite granule, remove powder and bulk, choose the graphite of 30-70 mesh Grain;
(2)The water taking the silica sand of 15-20 part, the graphite granule of 80-85 part, the potter's clay of 9-11 part and 2 parts by weight adds It is sufficiently stirred for 5-8min to puddle mixer;
(3)Slow addition synthetic fat binder at the uniform velocity in puddle mixer, continues stirring 8-12min and obtains graphite sand chill raw material;
(4)Raw material in puddle mixer is placed in core box and carries out molding, take out to put in resistance furnace from core box after molding and dry Process, heating-up temperature is 300-350 DEG C, heat time heating time is 3-4h;
(5)Graphite sand chill after molding is cooled to the furnace room temperature.
5. graphite sand chill as claimed in claim 4 preparation method it is characterised in that:Described step(3)Middle conjunction fat bonding Agent adds in 30-60s.
6. graphite sand chill as claimed in claim 4 preparation method it is characterised in that:Described step(4)Middle raw material is in core Take out after placing 2-10min molding in box.
7. graphite sand chill as claimed in claim 4 preparation method it is characterised in that:Described step(4)Middle raw material is being put Stir while adding during entering core box, so that raw material is laminated in core box middle level real, add and after finishing, stop stirring.
CN201610777952.3A 2016-08-30 2016-08-30 Graphite sand cold iron and preparation method thereof Pending CN106396679A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107604237A (en) * 2017-09-27 2018-01-19 安徽海立精密铸造有限公司 A kind of A type graphite casting and its preparation technology
CN108262449A (en) * 2018-03-06 2018-07-10 溧阳市联华机械制造有限公司 A kind of method that hot box makes forming graphite chill
CN108326264A (en) * 2018-03-06 2018-07-27 溧阳市联华机械制造有限公司 A kind of method that cold-box makes forming graphite chill
CN108705027A (en) * 2018-04-19 2018-10-26 南通冠峰铸造有限公司 A kind of technique of the anti-shrinkage cavity shrinkage porosity of graphite carburant control casting condensation sequence
CN109774130A (en) * 2017-11-13 2019-05-21 科华控股股份有限公司 A kind of 3D printing forming graphite chill and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0225261A (en) * 1988-07-13 1990-01-26 Kitagawa Iron Works Co Ltd Internal chill body
CN102847907A (en) * 2012-09-28 2013-01-02 贵州安吉航空精密铸造有限责任公司 Disposable chilling block and manufacturing method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0225261A (en) * 1988-07-13 1990-01-26 Kitagawa Iron Works Co Ltd Internal chill body
CN102847907A (en) * 2012-09-28 2013-01-02 贵州安吉航空精密铸造有限责任公司 Disposable chilling block and manufacturing method thereof

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107604237A (en) * 2017-09-27 2018-01-19 安徽海立精密铸造有限公司 A kind of A type graphite casting and its preparation technology
CN109774130A (en) * 2017-11-13 2019-05-21 科华控股股份有限公司 A kind of 3D printing forming graphite chill and preparation method thereof
CN108262449A (en) * 2018-03-06 2018-07-10 溧阳市联华机械制造有限公司 A kind of method that hot box makes forming graphite chill
CN108326264A (en) * 2018-03-06 2018-07-27 溧阳市联华机械制造有限公司 A kind of method that cold-box makes forming graphite chill
CN108705027A (en) * 2018-04-19 2018-10-26 南通冠峰铸造有限公司 A kind of technique of the anti-shrinkage cavity shrinkage porosity of graphite carburant control casting condensation sequence

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