CN106396211A - Electrocoagulation and ceramic micro-filtration membrane coupling device for purifying micro-polluted source water as well as process - Google Patents

Electrocoagulation and ceramic micro-filtration membrane coupling device for purifying micro-polluted source water as well as process Download PDF

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Publication number
CN106396211A
CN106396211A CN201611166481.9A CN201611166481A CN106396211A CN 106396211 A CN106396211 A CN 106396211A CN 201611166481 A CN201611166481 A CN 201611166481A CN 106396211 A CN106396211 A CN 106396211A
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China
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water
ceramic micro
electric flocculation
micro filter
pipe
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Inventor
周振
姚吉伦
丁昭霞
左梅梅
张星
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Logistical Engineering University of PLA
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Logistical Engineering University of PLA
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/463Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrocoagulation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/444Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by ultrafiltration or microfiltration
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing

Abstract

The invention provides an electrocoagulation and ceramic micro-filtration membrane coupling device for purifying micro-polluted source water as well as a process. The device comprises a submersible pump, a raw water tank, an electrocoagulation reactor water feed pump, an electrocoagulation reactor, a middle water storage tank, a ceramic micro-filtration membrane assembly water feed pump, a ceramic micro-filtration membrane assembly, a backwash water tank, a clear water tank, an air compressor, a concentrated water drain pipe, a concentrated water backflow pipe, a concentrated water pipe, an osmosis water/backwash water conversion pipe, a backwash drain pipe and an air pipe. The device is simple, compact in structure, high in treatment efficiency and convenient to maintain and manage, combines advantages of an electrocoagulation technology and a ceramic micro-filtration membrane technology, improves the effluent quality of the ceramic micro-filtration membrane, delays attenuation of membrane flux and overcomes defects of high energy consumption and long solid-liquid separation time of electrocoagulation, thereby achieving the purpose of complementary advantages and being suitable for popularization and application.

Description

The coupling device of electric flocculation ceramic micro filter film purifying slightly polluted water source water and technique
Technical field
The present invention relates to a kind of coupling device of electric flocculation ceramic micro filter film purifying slightly polluted water source water and technique, belong to water Environmental capacity field.
Background technology
In Water purification industry, by coagulation, precipitation, filtration, sterilization based on conventional water purification PROCESS FOR TREATMENT right As if meeting the water body of drinking water source water quality standard, it is for the turbidity in water, colourity, colloid, particle, microorganism etc. Substantially, water quality is easier to up to standard reason effect.But the development with human society, various organic emission accelerate water source in water body Deterioration, part index number is higher than《Water environment quality standard》(GB3838-2002) will to the standard limited value of III class water body in Ask, in the face of this kind of micro-polluted source water, traditional water-purifying process is difficult to make water outlet meet《Drinking water sanitary standard》 (GB5749-2006) requirement is it is ensured that the safety of drinking water.
Membrane technology increasingly receives significant attention by its unique advantage as forth generation handling technology of water supply, particularly Ceramic micro filter film, has stable chemical nature, acid and alkali-resistance, organic solvent and microbial attack, high mechanical strength, energy consumption is low, no Easily block, long service life, the features such as anti-extreme climate.But during practical operation runs, ceramic micro filter film is used for processing pond During the higher source water of the content of organics such as water, reservoir water, not only the decline of membrane flux is rapid, Pore Blocking is serious, aquifer yield is anxious Acute decline, and low to the clearance of Organic substance in water, threaten water supply quality safety.Before existing employing film, chemical coagulation process is located in advance Reason, such as tiny flocculation, membrane filtration and air-float integral reaction unit and the method (application number with its low turbid micro-polluted water of process: 201010566493.7), but its chemical floc dosage is larger, sludge yield is larger, easily forms secondary pollution, and waterpower The time of staying is longer.
Electric flocculation technique is used for water treatment field, and advantage has:Equipment is simple, compact conformation, and floor space is little, Operation and Maintenance Conveniently it is easy to couple with other techniques;The metal ion free from admixture that reaction generates, composition is pure, and sludge yield is little, electrode metal Consumption is low;Wide accommodation to raw water, is not required to add chemical agent in course of reaction, there is not the preservation problem of medicament, There is not the risk of secondary pollution;The metal ion activity that electrode dissolution is generated is high, and flocculating property is strong, the micro-bubble of formation Play the flotation that can also complete particulate matter while stirring, treatment effeciency is high.But energy consumption is too high, process time is long lacks Fall into the popularization and application that govern electric flocculation technique always.
Using electric flocculation as ceramic micro filter film pretreatment, the impurity in water first passes through electric flocculation reactor, partial impurities Oxidized removal, partly takes off and surely forms small flco, then is removed by ceramic micro filter film interception filtration.Different from more existing with Electric flocculation-ultrafiltration membrane technique is the water purification installation of core, and such as a kind of group technology processing micro-polluted water and device (are applied for Number:201410342465.5), adopt organic hollow fiber ultrafilter membrane intermittent duty in this patent, operating pressure is big, high energy consumption, And fenestra little Yi blocking, inner pressed hollow-fibre membrane not easy cleaning simultaneously, flux recovery is poor, in addition organic hollow fiber film Easily enriched microorganism, aging fracture and be difficult to discover, pollute water outlet.By contrast, using tubular ceramic micro-filtration membrane, operating pressure Relatively low, energy efficient, fenestra is larger to be difficult to block, and is readily cleaned after fouling membrane, and anti-physics and chemistry cracking and microbial degradation. Therefore, in conjunction with the coupling technique of electric flocculation technique and ceramic micro filter film technical advantage, both improve ceramic micro filter film effluent quality, Delay the decay of membrane flux, overcome electric flocculation high energy consumption, the defect of solid-liquid separation time length again, reached mutual supplement with each other's advantages Purpose.
Content of the invention
For above-mentioned weak point of the prior art, the present invention provides a kind of compact conformation, stable performance, technique letter The coupling device of the electric flocculation ceramic micro filter film purifying slightly polluted water source water single, treatment effeciency is high.
To achieve these goals, the present invention provides technical scheme below:A kind of electric flocculation ceramic micro filter film purifies micro- dirt The coupling device of dye source water, including immersible pump, raw water box, electric flocculation reactor intake pump, electric flocculation reactor, DC voltage-stabilizing Power supply, intermediate water storage case, ceramic micro filter membrane module intake pump, ceramic micro filter membrane module, backwash tank, filtered water tank, air compressor machine, Condensed water drain, condensed water return duct, concentration water pipe, infiltration water/backwash water conversion tube, backwash drain pipe and air hose, The water inlet of described raw water box is connected with immersible pump by pipeline, and outlet is reacted with electric flocculation through electric flocculation reactor intake pump Device connects, and described electric flocculation reactor is connected with D.C. regulated power supply by wire, the outlet of this electric flocculation reactor and in Between the water inlet of storage tank communicate, the outlet of intermediate water storage case is through ceramic micro filter membrane module intake pump and ceramic micro filter membrane module Connect, the bottom of described ceramic micro filter membrane module is provided with the backwash drain pipe being attached thereto, described ceramic micro filter film group The condensed water Gutron on part top is crossed threeway and is connected with condensed water drain and condensed water return duct, this condensed water return duct with middle Storage tank connects, and ceramic micro filter membrane module outlet is communicated with backwash tank via infiltration water/backwash water conversion tube, described anti- The outlet rinsing water pot connects filtered water tank, upper end is connected with air compressor machine by air hose.
Preferably, described electric flocculation reactor includes battery lead plate, conductive copper rod, lucite shell and is used for placing electricity The bracket of pole plate, this battery lead plate is connected by contact rod and parallel is staggered in lucite inside the shell.
Preferably, being provided with base and blow-off pipe in described electric flocculation reactor bottom.
Preferably, described ceramic micro filter membrane module adopts the intrinsic pressure ceramic micro filter film of tubular type.
A kind of technique with above-mentioned coupling device, comprises the steps:
1) source water injects raw water box through immersible pump, then is pumped into electric flocculation reactor by the water inlet of electric flocculation reactor, Electric flocculation reactor intake pump discharge equipped with valve and effusion meter be used for adjusting electric flocculation reactor flow of inlet water constant for 4L/ In min, and then control electric flocculation reactor, the time of staying of water body is 150s, and be arranged in parallel in electric flocculation reactor 8 pieces of 3mm thickness Pure aluminum plate as battery lead plate, the through hole that Φ 10 is opened in pole plate upper end passes through conductive copper rod single stage type and connects, and pole plate lower end is placed in support On frame, polar plate spacing 10mm;
2) start D.C. regulated power supply, adjusting output current according to raw water quality makes electric current density in 0.5-3.0mA/cm2 Between float;
3) water processing through electric flocculation enters intermediate water storage case under gravity, stops 300s to form small wadding Body;
4) through step 3) reacted water body squeezes into ceramic micro filter membrane module by ceramic micro filter membrane module intake pump, pottery Micro-filtration membrane module adopts cross flow filter pattern, wherein the intrinsic pressure ceramic micro filter film of two duct tubular types of filling, the long 500mm of every film, It is connected in series, Al2O3Material, membrane aperture 200nm, concentrate the exclusion of water section concentrated water drain, partly flowed back by condensed water Pipe is back to intermediate water storage case, and to make full use of unreacted metal ion, infiltration water enters backwash tank and filtered water tank, It is 0.1MPa by Valve controlling transmembrane pressure on ceramic film component water inlet pipe, adjust the valve control concentrating on water pipe two branched pipe Reflux ratio processed is 20%;
5) when the decay of this device aquifer yield is rapid, the outlet of ceramic micro filter membrane module intake pump and filtered water tank water inlet pipe are closed On valve, open the valve on backwash drain pipe and air hose, start air compressor machine backwash ceramic micro filter film, open simultaneously The mud of electric flocculation reactor bottom excluded by blow-off pipe, and exchanges the both positive and negative polarity of battery lead plate.
The present invention be can be seen that compared with existing other technologies by above technical scheme, there is advantages below:
(1) employing of electric flocculation technique, the nascent state hydroxo complex absorption that can be formed by anode, net are caught miscellaneous in water Matter;And by redox in electric flocculation, can degrade, remove partial organic substances;What in addition negative electrode produced is small in a large number The floating loading capability of flco absorption that bubble size is little, specific surface area is evacuated to float, colloid and structure greatly is strong, can improve film skill The clearance to Organic substance for the art, lessening membrane fouling, increase the Membrane cleaning cycle.
(2) utilization of tubular ceramic micro-filtration membrane, can significantly improve the separation efficiency of solid-liquid after electric flocculation is processed, and saving accounts for Ground area, reducing energy consumption;Tubular ceramic micro-filtration membrane physics and chemistry gives birth to stable in properties, high mechanical strength, long service life, preservation side simultaneously Just, backwash is easy.
(3) combine electric flocculation and the advantage of ceramic micro filter film, both improve ceramic micro filter film effluent quality, and delayed film The decay of flux, overcomes electric flocculation high energy consumption, the defect of solid-liquid separation time length again.Apparatus structure is compact, water source adaptability Extensively, treatment effeciency is high, it is easy to accomplish Automated condtrol.
Brief description
In order to be illustrated more clearly that the embodiment of the present invention or technical scheme of the prior art, below will be to embodiment or existing Have technology description in required use accompanying drawing be briefly described it should be apparent that, drawings in the following description be only this Some embodiments of invention, for those of ordinary skill in the art, without having to pay creative labor, also may be used So that other accompanying drawings are obtained according to these accompanying drawings.
Fig. 1 is the structural representation of the present invention;
Fig. 2 is the structural representation of electric flocculation reactor in the present invention.
Specific embodiment
To further describe the present invention with reference to specific embodiment and accompanying drawing.
A kind of coupling device of electric flocculation ceramic micro filter film purifying slightly polluted water source water as shown in Figures 1 and 2, including latent Water pump 1, raw water box 2, electric flocculation reactor intake pump 3, electric flocculation reactor 4, D.C. regulated power supply 5, intermediate water storage case 7, pottery Porcelain micro-filtration membrane module intake pump 8, ceramic micro filter membrane module 9, backwash tank 10, filtered water tank 11, air compressor machine 12, condensed water exclusion Pipe 15, condensed water return duct 16, concentration water pipe 17, infiltration water/backwash water conversion tube 18, backwash drain pipe 19 and air hose 20, the water inlet of described raw water box 2 is connected with immersible pump 1 by pipeline, and outlet is through electric flocculation reactor intake pump 3 and electricity wadding Solidifying reactor 4 connects, and described electric flocculation reactor 4 is connected with D.C. regulated power supply 5 by wire 13, this electric flocculation reactor 4 Outlet communicate with the water inlet of intermediate water storage case 7, described electric flocculation reactor 4 includes battery lead plate 21, conductive copper rod 22, has Machine glass shell 23 and the bracket 24 for placing battery lead plate 21, this battery lead plate 21 is connected and parallel staggered row by contact rod 22 It is listed in lucite shell 23, according to the block number processing water yield changeable battery lead plate 21, the length-width ratio of adjustment battery lead plate 21;Root Can be selected for Fe, Al, Mg or alloy material as battery lead plate 21, the employing of electric flocculation technique according to raw water quality, anode can be passed through The impurity in water caught by the nascent state hydroxo complex absorption being formed, net;And by redox in electric flocculation, can drop Solution, removal partial organic substances;In addition a large amount of micro-bubble sizes that negative electrode produces are little, specific surface area greatly to float, colloid and The floating loading capability of flco absorption that structure is evacuated is strong, can improve the clearance to Organic substance for the membrane technology, lessening membrane fouling, increase film Cleaning frequency, the outlet of intermediate water storage case 7 is connected with ceramic micro filter membrane module 9 through ceramic micro filter membrane module intake pump 8, described Ceramic micro filter membrane module 9 adopts the intrinsic pressure ceramic micro filter film of tubular type, and material is Al2O3, cross flow filter pattern, produce water when needing to increase During amount can branched ceramic micro filter film in parallel, or select multi-pore channel number ceramic micro filter film;Can adopt when needing to heighten effluent quality Series multistage filters, or filling small-bore ceramic micro filter film, the utilization of tubular ceramic micro-filtration membrane, can significantly improve electric flocculation and process The separation efficiency of solid-liquid, saves floor occupying area afterwards, reducing energy consumption;Tubular ceramic micro-filtration membrane physics and chemistry gives birth to stable in properties, machine simultaneously Tool intensity is high, long service life, and it is convenient to preserve, and backwash is easy, is provided with the bottom of described ceramic micro filter membrane module 9 and connects therewith The backwash drain pipe 19 connecing, the concentration water pipe 17 on described ceramic micro filter membrane module 9 top passes through threeway and condensed water drain 15 are connected with condensed water return duct 16, and this condensed water return duct 16 is connected with intermediate water storage case 7, ceramic micro filter membrane module 9 water outlet Mouth is communicated with backwash tank 10 via infiltration water/backwash water conversion tube 18, and the outlet of described backwash tank 10 connects clear water Case 11, upper end are connected with air compressor machine 12 by air hose 20.
A kind of technique with above-mentioned coupling device, comprises the steps:
1) source water injects raw water box 2 through immersible pump 1, then is pressed into electric flocculation reaction by electric flocculation reactor intake pump 3 Device 4, electric flocculation reactor intake pump 3 exports the flow of inlet water perseverance being used for adjusting electric flocculation reactor 4 equipped with valve and effusion meter The time of staying being set to water body in 4L/min, and then control electric flocculation reactor 4 is 150s, as shown in Fig. 2 electric flocculation reactor The thick pure aluminum plate of 8 pieces of 3mm be arranged in parallel as battery lead plate 21, the through hole that Φ 10 is opened in pole plate upper end passes through conductive copper rod 22 list in 4 Level formula connects, and pole plate lower end is placed on bracket 24, polar plate spacing 10mm;
2) start D.C. regulated power supply 5, adjusting output current according to raw water quality makes electric current density in 0.5-3.0mA/cm2 Between float;
3) water processing through electric flocculation enters intermediate water storage case 7 under gravity, stops 300s to form small wadding Body;
4) through step 3) reacted water body squeezes into ceramic micro filter membrane module 9 by ceramic micro filter membrane module intake pump 8, pottery Porcelain micro-filtration membrane module 9 adopts cross flow filter pattern, wherein the intrinsic pressure ceramic micro filter film of two 19 duct tubular types of filling, and every film is long 500mm, is connected in series, Al2O3Material, membrane aperture 200nm, concentrate water section concentrated water drain 15 and exclude, partly pass through dense Shrink return duct 16 is back to intermediate water storage case 7, and to make full use of unreacted metal ion, infiltration water enters backwashing water Tank 10 and filtered water tank 11, are 0.1MPa by Valve controlling transmembrane pressure on ceramic film component 9 water inlet pipe, adjust and concentrate water pipe two Valve controlling reflux ratio on branched pipe is 20%;
5) when the decay of this device aquifer yield is rapid, close ceramic micro filter membrane module intake pump 8 outlet and filtered water tank 11 enters Valve on water pipe, opens the valve on backwash drain pipe 19 and air hose 20, starts air compressor machine 12 backwash ceramic micro filter Film, opens the mud that electric flocculation reactor 4 bottom excluded by blow-off pipe 14 simultaneously, and exchanges the both positive and negative polarity of battery lead plate 21.
Using coupling device and the PROCESS FOR TREATMENT somewhere lake water of above-mentioned electric flocculation ceramic micro filter film purifying slightly polluted water source water, Raw water quality is after testing:23 DEG C of temperature, pH is 8.2, and turbidity is 9.61NTU, CODMnFor 6.29mg/L, UV254For 0.169cm-1, as shown in table 1, as shown in Table 1 under other conditions same case, electric current density is 2.0mA/cm to effluent quality2When water outlet Get well and reach《Drinking water sanitary standard》(GB5749-2006) limit value requires.
Effluent quality after the process of table 1 electric flocculation ceramic micro filter film coupling technique
The present invention constructs a kind of dynamically continuous group technology running, and combines the excellent of electric flocculation and ceramic micro filter film Point, had both improve ceramic micro filter film effluent quality, had delayed the decay of membrane flux, overcame electric flocculation high energy consumption again, and solid-liquid divides Defect from time length.Apparatus structure is compact, water source wide adaptability, and treatment effeciency is high, it is easy to accomplish Automated condtrol, electric flocculation The employing of technology, the impurity in water caught by the nascent state hydroxo complex absorption that can be formed by anode, net;And pass through electric flocculation Middle redox, can degrade, remove partial organic substances;In addition a large amount of micro-bubble sizes that negative electrode produces are little, specific surface The long-pending big floating loading capability of flco absorption that float, colloid and structure are evacuated is strong, can improve the removal to Organic substance for the membrane technology Rate, lessening membrane fouling, increase the Membrane cleaning cycle;The utilization of tubular ceramic micro-filtration membrane, can significantly improve solid-liquid after electric flocculation is processed The separation efficiency of body, saves floor occupying area, reducing energy consumption;Tubular ceramic micro-filtration membrane physics and chemistry gives birth to stable in properties, mechanical strength simultaneously Height, long service life, it is convenient to preserve, and backwash is easy;Group technology can pass through to increase and decrease battery lead plate block number and ceramic micro filter film radical, Adjustment water purification scale and effluent quality, realize engineer applied.
The technical scheme above embodiment of the present invention being provided is described in detail, specific case used herein The principle and embodiment of the embodiment of the present invention is set forth, the explanation of above example is only applicable to help understand this The principle of inventive embodiments;Simultaneously for one of ordinary skill in the art, according to the embodiment of the present invention, in specific embodiment party All will change in formula and range of application, in sum, this specification content should not be construed as limitation of the present invention.

Claims (5)

1. a kind of coupling device of electric flocculation ceramic micro filter film purifying slightly polluted water source water, including immersible pump (1), raw water box (2), Electric flocculation reactor intake pump (3), electric flocculation reactor (4), D.C. regulated power supply (5), intermediate water storage case (7), ceramic micro filter Membrane module intake pump (8), ceramic micro filter membrane module (9), backwash tank (10), filtered water tank (11), air compressor machine (12), condensed water Drain (15), condensed water return duct (16), concentration water pipe (17), infiltration water/backwash water conversion tube (18), backwash drain pipe (19) and air hose (20) it is characterised in that:The water inlet of described raw water box (2) is connected with immersible pump (1) by pipeline, water outlet Mouth is connected with electric flocculation reactor (4) through electric flocculation reactor intake pump (3), and described electric flocculation reactor (4) passes through wire (13) it is connected with D.C. regulated power supply (5), the water inlet phase of the outlet of this electric flocculation reactor (4) and intermediate water storage case (7) Logical, the outlet of intermediate water storage case (7) is connected with ceramic micro filter membrane module (9) through ceramic micro filter membrane module intake pump (8), in institute The bottom stating ceramic micro filter membrane module (9) is provided with the backwash drain pipe (19) being attached thereto, described ceramic micro filter membrane module (9) the concentration water pipe (17) on top is connected with condensed water drain (15) and condensed water return duct (16) by threeway, this concentration Water return duct (16) is connected with intermediate water storage case (7), and ceramic micro filter membrane module (9) outlet is via infiltration water/backwash water conversion Pipe (18) is communicated with backwash tank (10), and the outlet of described backwash tank (10) connects filtered water tank (11), sky is passed through in upper end Trachea (20) is connected with air compressor machine (12).
2. the coupling device of electric flocculation ceramic micro filter film purifying slightly polluted water source water according to claim 1, its feature exists In:Described electric flocculation reactor (4) includes battery lead plate (21), conductive copper rod (22), lucite shell (23) and is used for placing The bracket (24) of battery lead plate (21), this battery lead plate (21) passes through contact rod (22) and connects and parallel be staggered outside lucite In shell (23).
3. the coupling device of electric flocculation ceramic micro filter film purifying slightly polluted water source water according to claim 1 and 2, its feature It is:Described electric flocculation reactor (4) bottom is provided with base (6) and blow-off pipe (14).
4. the coupling device of electric flocculation ceramic micro filter film purifying slightly polluted water source water according to claim 1, its feature exists In:Described ceramic micro filter membrane module (9) adopts the intrinsic pressure ceramic micro filter film of tubular type.
5. a kind of technique with above-mentioned coupling device, is characterized in that, comprise the steps:
1) source water is through immersible pump (1) injection raw water box (2) more anti-by electric flocculation reactor intake pump (3) press-in electric flocculation Answer device (4), electric flocculation reactor intake pump (3) outlet is used for adjusting entering of electric flocculation reactor (4) equipped with valve and effusion meter The discharge constant time of staying for water body in 4L/min, and then control electric flocculation reactor (4) is 150s, electric flocculation reactor (4) it be arranged the thick pure aluminum plate of 8 pieces of 3mm in parallel as battery lead plate (21), the through hole that Φ 10 is opened in pole plate upper end passes through conductive copper rod (22) single stage type connects, and pole plate lower end is placed on bracket (24), polar plate spacing 10mm;
2) start D.C. regulated power supply (5), adjusting output current according to raw water quality makes electric current density in 0.5-3.0mA/cm2It Between float;
3) water processing through electric flocculation enters intermediate water storage case (7) under gravity, stops 300s to form small flco;
4) through step 3) reacted water body squeezes into ceramic micro filter membrane module (9) by ceramic micro filter membrane module intake pump (8), pottery Porcelain micro-filtration membrane module (9) adopts cross flow filter pattern, wherein the intrinsic pressure ceramic micro filter film of two (19) duct tubular types of filling, every film Long 500mm, is connected in series, Al2O3Material, membrane aperture 200nm, concentrate water section concentrated water drain (15) exclusion, partly lead to Cross condensed water return duct (16) and be back to intermediate water storage case (7), to make full use of unreacted metal ion, infiltration water enters Backwash tank (10) and filtered water tank (11), are 0.1MPa by Valve controlling transmembrane pressure on ceramic film component (9) water inlet pipe, Adjusting the Valve controlling reflux ratio concentrating on water pipe two branched pipe is 20%;
5) when the decay of this device aquifer yield is rapid, close ceramic micro filter membrane module intake pump (8) outlet and filtered water tank (11) enters Valve on water pipe, opens the valve on backwash drain pipe (19) and air hose (20), starts air compressor machine (12) backwash pottery Porcelain micro-filtration membrane, opens the mud that electric flocculation reactor (4) bottom excluded by blow-off pipe (14) simultaneously, and just exchanges battery lead plate (21) Negative pole.
CN201611166481.9A 2016-12-16 2016-12-16 Electrocoagulation and ceramic micro-filtration membrane coupling device for purifying micro-polluted source water as well as process Pending CN106396211A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107352704A (en) * 2017-08-18 2017-11-17 沈瑞忠 A kind of printing ink wastewater recycling device
CN109502841A (en) * 2018-12-04 2019-03-22 广东工业大学 A kind of the advanced treating coupling device and its coupling technique of landfill leachate

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1842831A2 (en) * 2006-04-05 2007-10-10 L'Oceane des Plastics Method and station for treating effluent, in particular urban, industrial or animal effluent, and sanitary installation capable of being associated with such a treatment station.
CN101269863A (en) * 2008-04-18 2008-09-24 清华大学 Apparatus and method for removing phosphor and organic matter in sewage water with electric flocculation membrane bioreactor
CN201240964Y (en) * 2008-05-08 2009-05-20 中国人民解放军后勤工程学院 Ultrasonic electrocoagulation-film filtering combined water treating device
JP2011083727A (en) * 2009-10-16 2011-04-28 Miura Co Ltd Water treatment system
CN103951129A (en) * 2014-05-16 2014-07-30 东莞市珠江海咸水淡化研究所 Emergency water treatment process and movable emergency water treatment equipment
CN206308183U (en) * 2016-12-16 2017-07-07 中国人民解放军后勤工程学院 The coupling device of electric flocculation ceramic micro filter film purifying slightly polluted water source water

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1842831A2 (en) * 2006-04-05 2007-10-10 L'Oceane des Plastics Method and station for treating effluent, in particular urban, industrial or animal effluent, and sanitary installation capable of being associated with such a treatment station.
CN101269863A (en) * 2008-04-18 2008-09-24 清华大学 Apparatus and method for removing phosphor and organic matter in sewage water with electric flocculation membrane bioreactor
CN201240964Y (en) * 2008-05-08 2009-05-20 中国人民解放军后勤工程学院 Ultrasonic electrocoagulation-film filtering combined water treating device
JP2011083727A (en) * 2009-10-16 2011-04-28 Miura Co Ltd Water treatment system
CN103951129A (en) * 2014-05-16 2014-07-30 东莞市珠江海咸水淡化研究所 Emergency water treatment process and movable emergency water treatment equipment
CN206308183U (en) * 2016-12-16 2017-07-07 中国人民解放军后勤工程学院 The coupling device of electric flocculation ceramic micro filter film purifying slightly polluted water source water

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
周振等: "电絮凝强化陶瓷微滤膜出水水质研究", 《科学技术与工程》 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107352704A (en) * 2017-08-18 2017-11-17 沈瑞忠 A kind of printing ink wastewater recycling device
CN109502841A (en) * 2018-12-04 2019-03-22 广东工业大学 A kind of the advanced treating coupling device and its coupling technique of landfill leachate

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Application publication date: 20170215