CN106391061A - Preparation method of high-performance BiOCl/BiOBr photocatalytic material - Google Patents
Preparation method of high-performance BiOCl/BiOBr photocatalytic material Download PDFInfo
- Publication number
- CN106391061A CN106391061A CN201610834479.8A CN201610834479A CN106391061A CN 106391061 A CN106391061 A CN 106391061A CN 201610834479 A CN201610834479 A CN 201610834479A CN 106391061 A CN106391061 A CN 106391061A
- Authority
- CN
- China
- Prior art keywords
- solution
- biocl
- photocatalyst
- biobr
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- BWOROQSFKKODDR-UHFFFAOYSA-N oxobismuth;hydrochloride Chemical compound Cl.[Bi]=O BWOROQSFKKODDR-UHFFFAOYSA-N 0.000 title claims abstract description 12
- 238000002360 preparation method Methods 0.000 title abstract description 11
- 230000001699 photocatalysis Effects 0.000 title abstract description 9
- 239000000463 material Substances 0.000 title abstract description 5
- 239000011941 photocatalyst Substances 0.000 claims abstract description 15
- WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 claims abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 21
- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 claims description 4
- 229940043267 rhodamine b Drugs 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 3
- 230000015556 catabolic process Effects 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 238000006731 degradation reaction Methods 0.000 claims description 3
- 239000012153 distilled water Substances 0.000 claims description 3
- RXPAJWPEYBDXOG-UHFFFAOYSA-N hydron;methyl 4-methoxypyridine-2-carboxylate;chloride Chemical compound Cl.COC(=O)C1=CC(OC)=CC=N1 RXPAJWPEYBDXOG-UHFFFAOYSA-N 0.000 claims description 3
- 238000001291 vacuum drying Methods 0.000 claims description 3
- 238000005406 washing Methods 0.000 claims description 3
- 238000005119 centrifugation Methods 0.000 claims description 2
- 230000005855 radiation Effects 0.000 claims description 2
- DCAYPVUWAIABOU-UHFFFAOYSA-N hexadecane Chemical compound CCCCCCCCCCCCCCCC DCAYPVUWAIABOU-UHFFFAOYSA-N 0.000 claims 2
- 230000015572 biosynthetic process Effects 0.000 claims 1
- 238000003786 synthesis reaction Methods 0.000 claims 1
- AISMNBXOJRHCIA-UHFFFAOYSA-N trimethylazanium;bromide Chemical compound Br.CN(C)C AISMNBXOJRHCIA-UHFFFAOYSA-N 0.000 claims 1
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 abstract description 3
- 238000000034 method Methods 0.000 abstract description 3
- 239000002131 composite material Substances 0.000 abstract description 2
- 239000002957 persistent organic pollutant Substances 0.000 abstract 1
- 239000002994 raw material Substances 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 11
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 4
- 238000007146 photocatalysis Methods 0.000 description 4
- 238000006555 catalytic reaction Methods 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000004020 conductor Substances 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- LYCAIKOWRPUZTN-NMQOAUCRSA-N 1,2-dideuteriooxyethane Chemical compound [2H]OCCO[2H] LYCAIKOWRPUZTN-NMQOAUCRSA-N 0.000 description 1
- 230000010718 Oxidation Activity Effects 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 125000005211 alkyl trimethyl ammonium group Chemical group 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000001027 hydrothermal synthesis Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000005375 photometry Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
-
- B01J35/39—
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/30—Treatment of water, waste water, or sewage by irradiation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/725—Treatment of water, waste water, or sewage by oxidation by catalytic oxidation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
- C02F2305/10—Photocatalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/30—Wastewater or sewage treatment systems using renewable energies
- Y02W10/37—Wastewater or sewage treatment systems using renewable energies using solar energy
Abstract
The invention relates to preparation of a BiOCl/BiOBr photocatalyst, and belongs to the field of inorganic photocatalytic materials. The BiOCl/BiOBr photocatalyst is prepared with CTAC and CTAB as experimental raw materials and by a microwave method. The photocatalyst is applied in organic pollutants in water. The prepared BiOCl/BiOBr composite photocatalyst has the photocatalytic activity in a relatively wide wavelength range, and has good industrial application prospects.
Description
Technical field
The present invention relates to a kind of photocatalyst.
The invention still further relates to the preparation method of above-mentioned catalyst.
The invention still further relates to photocatalysis degradation organic contaminant technical field.
Background technology
Since in recent years, environmental problem has become as the significant problem that the mankind are faced.With titanium dioxide as representative half
Conductor catalysis material has the advantages that low cost, good stability, becomes the study hotspot of photocatalysis field, can be widely applied to
Sewage disposal.But, the energy gap of titanium dioxide is larger, only utilizes the ultraviolet light in sunlight, and the most sun
Light energy is all distributed in visible region.Therefore, how effectively to make full use of solar energy to curb environmental pollution increasingly by people
Attention.In the preparation method of conductor photocatalysis material, it is employed in this area research current using hydro-thermal method
Main method.But the method preparation time length and being easy in preparation process due to being heated inequality and producing impurity, defect etc..
Therefore, urgently seek a kind of simply time-consuming few photocatalyst preparation method.
Content of the invention
Present invention aims to the band gap of BiOCl photocatalyst proposes one kind not only can more fully utilize too
Sun energy, and can solve the problem that the preparation method of problem of environmental pollution BiOCl/BiOBr composite photo-catalyst.
Meaning of the present invention is to provide a kind of efficient BiOCl/BiOBr photocatalyst, can keep good stablizing
Property and higher catalysis activity, simultaneously preparation method simple, time-consuming less, low cost.
The preparation method of the BiOCl/BiOBr photocatalyst that the present invention provides is as follows：
A certain amount of hexadecyltrimethylammonium chloride (CTAC) is dissolved in ethylene glycol (solution 1)；By a certain amount of ten
Six alkyl trimethyl ammonium bromides (CTAB) are dissolved in ethylene glycol (solution 2)；A certain amount of bismuth nitrate is dissolved in (solution in ethylene glycol
3)；Then respectively solution 1 and solution 2 are slowly dropped in solution three, after continuing stirring a period of time, put into microwave reactor
In 10 minutes power be 200W.After cooling, the pelleting centrifugation that will produce, uses distilled water and absolute ethanol washing, then successively
60 DEG C of vacuum drying obtain corresponding BiOCl/BiOBr photocatalyst.
Under visible radiation, the photocatalytic activity test concrete grammar of rhodamine B degradation and condition are as follows：
The Photocatalytic oxidation activity of catalyst is to carry out in homemade photo catalysis reactor.Reaction condition is：Room temperature is normal
Pressure, 300W xenon lamp (λ ＞ 420nm) is radiating light source, and reactant liquor is the rhodamine B aqueous solution of 200mL 20mg/L, and catalyst adds
Entering amount is 0.2g.Blast oxygen in reactor bottom.Every 10min sample analysis under violent stirring, divided with ultraviolet-visible
The conversion ratio of light photometric measurement rhodamine B.
Specific embodiments
Embodiment 1
0.32g CTAC is dissolved in 50mL ethylene glycol (solution 1)；1.82g CTAB is dissolved in (solution in 50mL ethylene glycol
2)；Cl/Br mol ratio is made to be 1: 5.Then respectively solution 1 and solution 2 are slowly dropped to the second two containing 2.91g bismuth nitrate
Alcoholic solution, continues stirring 1 hour, and being then placed in 10min power in microwave reactor is 200W.After cooling, heavy by produce
Form sediment and be centrifuged, use distilled water and absolute ethanol washing successively, then 60 DEG C of vacuum drying obtain corresponding catalyst.
Embodiment 2
It is 1: 1 that Cl/Br mol ratio in embodiment 1 is changed to Cl/Br mol ratio for 1: 5, and other conditions are constant.
Embodiment 3
It is 1: 2.5 that Cl/Br mol ratio in embodiment 1 is changed to Cl/Br mol ratio for 1: 5, and other conditions are constant.
Embodiment 4
It is 1: 7.5 that Cl/Br mol ratio in embodiment 1 is changed to Cl/Br mol ratio for 1: 5, and other conditions are constant.
Embodiment 5
It is 1: 10 that Cl/Br mol ratio in embodiment 1 is changed to Cl/Br mol ratio for 1: 5, and other conditions are constant.
It is pure that the medicine and reagent mentioned in embodiments above is analysis.
Photocatalyst obtained by the present invention can be carried on carrier, the invention is not restricted to embodiments above.
Claims (2)
1.BiOCl/BiOBr photocatalyst is it is characterised in that include following synthesis step：
A certain amount of hexadecyltrimethylammonium chloride (CTAC) is dissolved in ethylene glycol (solution 1), by a certain amount of hexadecane
Base trimethylammonium bromide (CTAB) is dissolved in ethylene glycol (solution 2), and a certain amount of bismuth nitrate is dissolved in ethylene glycol (solution 3),
Then respectively solution 1 and solution 2 are slowly dropped in solution three, after continuing stirring a period of time, put in microwave reactor
10 minutes power is 200W, after cooling, the pelleting centrifugation that will produce, use distilled water and absolute ethanol washing successively, then 60
DEG C vacuum drying obtains corresponding BiOCl/BiOBr photocatalyst.
2. three kinds of photocatalysts according to claim 1 are it is characterised in that being capable of rhodamine B degradation solution under the radiation of light.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610834479.8A CN106391061A (en) | 2016-09-13 | 2016-09-13 | Preparation method of high-performance BiOCl/BiOBr photocatalytic material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610834479.8A CN106391061A (en) | 2016-09-13 | 2016-09-13 | Preparation method of high-performance BiOCl/BiOBr photocatalytic material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106391061A true CN106391061A (en) | 2017-02-15 |
Family
ID=57997090
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610834479.8A Pending CN106391061A (en) | 2016-09-13 | 2016-09-13 | Preparation method of high-performance BiOCl/BiOBr photocatalytic material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106391061A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106966429A (en) * | 2017-03-24 | 2017-07-21 | 许昌学院 | A kind of preparation method of n-type optoelectronic thin film material |
| CN107021458A (en) * | 2017-04-01 | 2017-08-08 | 河南师范大学 | A kind of preparation method of black BiOBr dusty materials |
| CN109158116A (en) * | 2018-07-24 | 2019-01-08 | 南昌航空大学 | The method and its application in degradation antibiotic that one kettle way in-situ reducing prepares Bi/BiOBr/rGO photochemical catalyst |
| CN114870873A (en) * | 2022-04-20 | 2022-08-09 | 南昌航空大学 | Method for constructing surface defect photocatalytic material by ion exchange |
-
2016
- 2016-09-13 CN CN201610834479.8A patent/CN106391061A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106966429A (en) * | 2017-03-24 | 2017-07-21 | 许昌学院 | A kind of preparation method of n-type optoelectronic thin film material |
| CN107021458A (en) * | 2017-04-01 | 2017-08-08 | 河南师范大学 | A kind of preparation method of black BiOBr dusty materials |
| CN107021458B (en) * | 2017-04-01 | 2019-03-12 | 河南师范大学 | A kind of preparation method of black BiOBr dusty material |
| CN109158116A (en) * | 2018-07-24 | 2019-01-08 | 南昌航空大学 | The method and its application in degradation antibiotic that one kettle way in-situ reducing prepares Bi/BiOBr/rGO photochemical catalyst |
| CN114870873A (en) * | 2022-04-20 | 2022-08-09 | 南昌航空大学 | Method for constructing surface defect photocatalytic material by ion exchange |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103071513B (en) | Hydrogen-production photocatalyst MoS2/ZnIn2S4 and preparation method thereof | |
| CN106582765B (en) | A kind of the natrium doping graphite phase carbon nitride and its application of one-step synthesis preparation | |
| CN100551831C (en) | Visible light-responded Bi 2WO 6The photocatalyst fused salt preparation method | |
| CN106391061A (en) | Preparation method of high-performance BiOCl/BiOBr photocatalytic material | |
| CN105032468A (en) | Cu2O-TiO2/g-C3N4 ternary complex and preparation and application method thereof | |
| Qiu et al. | Synthesis of salicylic acid-modified graphite carbon nitride for enhancing photocatalytic nitrogen fixation | |
| CN101816943B (en) | High-efficiency nano silver/silver bromide sunshine photocatalytic material and preparation method thereof | |
| CN103657686B (en) | A kind of low-temperature co-precipitation method prepares the method for indium sulfide tin photochemical catalyst | |
| CN109590005A (en) | A kind of high electron-transporting type nucleocapsid ZnIn2S4Nanometer sheet/Ta3N5The preparation method and application of composite photo-catalyst | |
| CN102389788B (en) | Preparation method for porous titanium dioxide-carbon combined nano hollow microsphere | |
| CN109289872B (en) | Full-spectrum response carbon dioxide reduction composite photocatalyst and preparation method thereof | |
| CN104844423A (en) | Application of MIL-100 (Fe) in preparation of phenol through photocatalytic hydroxylation of benzene | |
| CN105771962A (en) | Near-infrared response carbon quantum dots/Bi2MoO6 photocatalyst and preparing method thereof | |
| CN105833860A (en) | CQDs/Bi2WO6 composite photocatalyst and preparation method thereof | |
| CN101462073B (en) | Heteronuclear cobalt-zinc metallophthalocyanine/nano titanic oxide composite film and preparation method | |
| CN103721699A (en) | NaInO2 photocatalyst and preparation method thereof | |
| CN104096530B (en) | A kind of SnS2Nanometer sheet, preparation method and application thereof | |
| CN102553619A (en) | Visible-light catalyst Bi3O4Br and preparation method thereof | |
| CN103819672A (en) | Method for preparing polyimide by utilizing ionic liquid and application of polyimide prepared by method | |
| CN107362792A (en) | A kind of preparation method of strontium titanates/niobic acid tin composite nano materials | |
| CN103447033B (en) | Method for preparing mesoporous AgGaO2 photocatalytic material | |
| CN115121241A (en) | Indium oxide and lanthanum titanate heterojunction photocatalyst and preparation method thereof | |
| CN103962158B (en) | A kind of ternary heterojunction light degradation catalytic organism agent WS 2-Bi 2wO 6/ Bi 3.84w 0.16o 6.24and preparation method thereof | |
| CN102794188A (en) | PtC14/Bi2WO6 photocatalyst, and preparation and application thereof | |
| CN103785425A (en) | Preparation method and application of flower-like Bi2O(OH)2SO4 photocatalyst |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20170215 |
|
| WD01 | Invention patent application deemed withdrawn after publication |