CN106390594A - Highly tenacious nylon monofilament filter cloth modified by radiation grafting of nanocarbon sol and nanographite and preparation method thereof - Google Patents

Highly tenacious nylon monofilament filter cloth modified by radiation grafting of nanocarbon sol and nanographite and preparation method thereof Download PDF

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Publication number
CN106390594A
CN106390594A CN201610937022.XA CN201610937022A CN106390594A CN 106390594 A CN106390594 A CN 106390594A CN 201610937022 A CN201610937022 A CN 201610937022A CN 106390594 A CN106390594 A CN 106390594A
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filter cloth
nylon monofilament
monofilament filter
nano
parts
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骆华军
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D39/00Filtering material for liquid or gaseous fluids
    • B01D39/08Filter cloth, i.e. woven, knitted or interlaced material
    • B01D39/083Filter cloth, i.e. woven, knitted or interlaced material of organic material
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/68Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof
    • D06M11/70Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof with oxides of phosphorus; with hypophosphorous, phosphorous or phosphoric acids or their salts
    • D06M11/71Salts of phosphoric acids
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/73Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
    • D06M11/74Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon or graphite; with carbides; with graphitic acids or their salts
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M14/00Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials
    • D06M14/18Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation
    • D06M14/26Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation on to materials of synthetic origin
    • D06M14/30Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation on to materials of synthetic origin of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M14/34Polyamides
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/687Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing atoms other than phosphorus, silicon, sulfur, nitrogen, oxygen or carbon in the main chain
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2239/00Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/02Types of fibres, filaments or particles, self-supporting or supported materials
    • B01D2239/0208Single-component fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2239/00Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/04Additives and treatments of the filtering material
    • B01D2239/0407Additives and treatments of the filtering material comprising particulate additives, e.g. adsorbents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2239/00Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/04Additives and treatments of the filtering material
    • B01D2239/0442Antimicrobial, antibacterial, antifungal additives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2239/00Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/04Additives and treatments of the filtering material
    • B01D2239/0457Specific fire retardant or heat resistant properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2239/00Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/04Additives and treatments of the filtering material
    • B01D2239/0464Impregnants
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2239/00Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/10Filtering material manufacturing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2239/00Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/12Special parameters characterising the filtering material
    • B01D2239/1283Stability index
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16Synthetic fibres, other than mineral fibres
    • D06M2101/30Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/34Polyamides
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/01Stain or soil resistance
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/35Abrasion, pilling or fibrillation resistance

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Filtering Materials (AREA)

Abstract

The invention discloses a highly tenacious nylon monofilament filter cloth modified by radiation grafting of nanocarbon sol and nanographite. The filter cloth comprises, by weight, 100-105 parts of nylon monofilament filter cloth, 3-3.5 parts of nanocarbon sol, 2.7-3 parts of nanographite, 0.8-0.9 part of FeSO4-7H2O, 24-26 parts of Trifluoroethyl acrylate, 1.2-1.5 parts of nano-hydroxyapatite, 3-3.5 parts of polyphenylene sulfide micron powder, 2.8-3.2 parts of flexible SiO2 nanofibers, 1.8-2.1 parts of triallyl Isocyanurate, 24-26 parts of dodecafluoroheptyl methacrylate and suitable amount of water. The invention uses nanocarbon sol to soak the nylon monofilement filter cloth, enhances the density, heat-resistance and friction-resistance of the filter cloth. Through the incorporation of polyphenylene sulfide micron powder to adsorb the nano-hydroxyapatite, enhances the tenacity and filtration precision of the filter cloth. The use of SiO2 nanofiber enhances the tenacity and anti-deformation property of the filter cloth.

Description

A kind of high tenacity nano carbon sol, the filter of nano-graphite irradiation grafting modified nylon monofilament Cloth and preparation method thereof
Technical field
The present invention relates to chinlon technical field of filter cloth, more particularly, to a kind of high tenacity nano carbon sol, nano-graphite irradiation Graft modification nylon monofilament filter cloth and preparation method thereof.
Background technology
《Monofilament filter cloth and its progress of performance》One literary composition describes terylene, chinlon, polypropylene, polyethylene monofilament filter cloth Performance.Monofilament filter cloth refers to the filter cloth being made into using single fiber, and conventional monofilament filter cloth typically by chinlon, terylene, polypropylene and gathers The braiding of the monfil such as ethylene forms.Compared with multifilament filter cloth, the fibre strength of monofilament filter cloth is big, good toughness, in use not Have the situation of fracture of wire;After using calendaring technology, stability is high, be unlikely to deform, aperture dense uniform;Filter cloth surface is smooth, It is difficult to block, ventilative, water permeability is good, and filter cake is easily peeled off regeneration.So, the filter efficiency of monofilament filter cloth is higher, and clearly Wash infrequently, long service life.The filtration resistance of monofilament filter cloth is relatively small, contamination resistance strong, and meeting in filtering accuracy will On the premise of asking, its combination property is better than multifilament filter cloth.
Chinlon all has very high intensity under dry, wet condition, up to 5.3cN/dtex during dry state, when wet strength is dry state 80%~90%;High abrasion resistance, is more than 10 times of cotton fiber;The percentage elongation of chinlon and elasticity are all fine, percentage elongation up to 18%~45%, when percentage elongation is 10%, elastic recovery rate is more than 90%;Alkali resistance and other medicine performances resistance to are good, molten at other More stable in agent, but acid resistance is a bit weaker;Fiber surface is smooth and hygroscopicity is strong, so easy cake discharge;Can using temperature Reach 120 DEG C, be the ideal material as filter cloth.But there is also water absorption rate larger the problems such as, influence whether the steady of filter cloth size Qualitative energy, limits the application in the industry of fine solid-liquid separation and development.The performance of nylon monofilament filter cloth also needs to further Improve.
Polyster fibre in synthetic fibers has excellent physical and chemical performance, using extensive, quickly grows, and becomes current The most chemical fibre of yield in the world, but existing ordinary polyester is hydrophobic fibre, the hygroscopicity of its fabric, hydrophilic Difference, regain is only 0.4%, and this becomes the principal element of impact terylene wearability.With the lifting of people's quality of life, take Decorations have been not only the change of color, style, it is also proposed new requirement to the quality and function of fabric.Improve dacron Hydrophilicity, so that the increasingly demand to meet people for the wearability of raising dacron, energy saving simultaneously, reduces environment Pollution, is also must concern in textile process technology.
The modified method of dacron hydrophilic has a lot, and such as corona treatment is modified, ultraviolet irradiates modification, alkali subtracts Modified method of amount, ferment treatment etc., but dacron all can not be made to reach the effect like cotton.
In recent years, the modification technology of electron beam irradiation grafting raising dacron hydrophilic performance has the glamour of uniqueness, Gradually it is valued by the people.The main thought of this technology be polymer surfaces or body phase grafting have hydrophile function monomer or Functional group, thus improve the hydrophilicity of dacron.Electron beam irradiation belongs to one of high-energy irradiation method, when having reaction Between short, little to fibre damage, percent grafting is high, the advantages of good endurance.Its principle is exactly using the ionization of radiation-initiated polymerization thing With excite, thus producing some free radicals, cause chemical reaction further, related research is a lot.This research is conventional Research foundation on by the high-power electron beam of electron accelerator, AA monomer is grafted to the surface of dacron, increase hydrophilic group Group, improves the hydrophilic of dacron, is allowed to really possess hydrophilicity specific to natural fiber.
《The hydrophilicity of irradiation grafting modified dacron fabric》Give irradiation grafting modified polyester monofilament filter cloth, equally may be used With irradiation grafting modified nylon monofilament filter cloth, to improve the problem that water absorption rate is larger, filter cloth size stability is poor.Also need to change Enter chinlon filter cloth loosely organized, elasticity is bad, resistant and resistance to elevated temperatures are poor, the problem that filter cake is not easily stripped.Also need to improve The thermostability of filter cloth, UV resistance, antistatic, intensity, toughness, wearability, antifouling, antibacterial, adsorptivity and graft modification film strong The performances such as degree.
Content of the invention
The object of the invention is exactly the defect in order to make up prior art, provides a kind of high tenacity nano carbon sol, nanometer stone Black irradiation grafting modified nylon monofilament filter cloth and preparation method thereof.
The present invention is achieved by the following technical solutions:
A kind of high tenacity nano carbon sol, nano-graphite irradiation grafting modified nylon monofilament filter cloth, by the raw material of following weight portion Make:Nylon monofilament filter cloth 100-105, nano carbon sol 3-3.5, nano-graphite 2.7-3, FeSO4∙7H2O 0.8-0.9, propylene Sour trifluoro ethyl ester 24-26, nanometer hydroxyapatite 1.2-1.5, polyphenylene sulfide micron powder 3-3.5, flexible SiO2Nanowire Dimension 2.8-3.2, Triallyl isocyanurate 1.8-2.1, dodecafluoroheptyl methacrylate 24-26, appropriate amount of water.
Described high tenacity nano carbon sol, the preparation method of nano-graphite irradiation grafting modified nylon monofilament filter cloth, including Following steps:
(1)Nano carbon sol is mixed with water, is configured to the dispersion liquid of 1-1.5% mass concentration, nylon monofilament filter cloth is put into point Dispersion liquid, soaks 20-25 minute, and period does not stop to stir nylon monofilament filter cloth, takes out and dries, puts into valve bag, carry out pre-irradiation, inhales Receipts dosage is 42-44kGy, obtains modified nylon monofilament filter cloth;
(2)Polyphenylene sulfide micron powder is heated to softening, sprays into nanometer hydroxyapatite while stirring, continue to grind 10- 15 minutes, obtain mixed material;Acrylic acid trifluoro ethyl ester, dodecafluoroheptyl methacrylate are added to the water, are configured to 50- The dispersion liquid of 55% mass concentration, adds described mixed material and other residual componentss, stirs, then by modified nylon Monofilament filter cloth puts into dispersion liquid, soaks 20-25 minute, and period does not stop to stir nylon monofilament filter cloth, takes out and dries, puts into self-styled Bag, carries out positive and negative each mutual radiation, and absorbed dose are 190-195kGy;
(3)By step(2)The nylon monofilament filter cloth obtaining is carried out, dries, and obtains final product.
Described heat-resisting nano carbon sol, nano-graphite irradiation grafting modified nylon monofilament filter cloth, described nylon monofilament filter cloth Thickness is 1.85-1.90mm, and filter cloth organizational structure is 14 comprehensive double-layered structures, weaves 68/cm of end count, 30/cm of filling density.
It is an advantage of the invention that:The present invention is impregnated to nylon monofilament filter cloth using nano carbon sol, inhales in the fibre Attached nano-sized carbon, improves compactness, thermostability and the wearability of filter cloth, improves filtering accuracy.Reuse acrylic acid trifluoro second It is modified that ester, dodecafluoroheptyl methacrylate, nano-graphite carry out cross-linked graft, improves the dimensional stability of filter cloth, smooth Property, resistant and heat-resisting quantity, filtrate is easily passed through, and reduces filter cloth water absorption, and filter cake moisture content reduces, and is easily peeled, and has at 140 DEG C There is good elasticity, indeformable, uniformly, filter effect keeps constant so that the service life of chinlon filter cloth extends for hole.Pass through Be heated to softening using polyphenylene sulfide micron powder, then adhere to nanometer hydroxyapatite, improve polyphenylene sulfide toughness and Adsorptivity, improves toughness and the filtering accuracy of filter cloth, by using flexible SiO2Nanofiber, improve filter cloth toughness and Anti-deformation performance.
Specific embodiment
A kind of high tenacity nano carbon sol, nano-graphite irradiation grafting modified nylon monofilament filter cloth, by following weight portion(Public Jin)Raw material make:Nylon monofilament filter cloth 100, nano carbon sol 3, nano-graphite 2.7, FeSO4∙7H2O 0.8, acrylic acid three Fluorine ethyl ester 24, nanometer hydroxyapatite 1.2, polyphenylene sulfide micron powder 3, flexible SiO2Nanofiber 2.8, triallyl are different Cyanurate 1.8, dodecafluoroheptyl methacrylate 24, appropriate amount of water.
Described high tenacity nano carbon sol, the preparation method of nano-graphite irradiation grafting modified nylon monofilament filter cloth, including Following steps:
(1)Nano carbon sol is mixed with water, is configured to the dispersion liquid of 1% mass concentration, nylon monofilament filter cloth is put into dispersion Liquid, soaks 20 minutes, and period does not stop to stir nylon monofilament filter cloth, takes out and dries, puts into valve bag, carry out pre-irradiation, absorbent Measure as 42kGy, obtain modified nylon monofilament filter cloth;
(2)Polyphenylene sulfide micron powder is heated to softening, sprays into nanometer hydroxyapatite while stirring, continue to grind 10 points Clock, obtains mixed material;Acrylic acid trifluoro ethyl ester, dodecafluoroheptyl methacrylate are added to the water, are configured to 50% mass dense The dispersion liquid of degree, adds described mixed material and other residual componentss, stirs, then modified nylon monofilament filter cloth is put Enter dispersion liquid, soak 20 minutes, period does not stop to stir nylon monofilament filter cloth, takes out and dries, puts into valve bag, carry out positive and negative each one Secondary mutual radiation, absorbed dose are 190kGy;
(3)By step(2)The nylon monofilament filter cloth obtaining is carried out, dries, and obtains final product.
Described heat-resisting nano carbon sol, nano-graphite irradiation grafting modified nylon monofilament filter cloth, described nylon monofilament filter cloth Thickness is 1.85mm, and filter cloth organizational structure is 14 comprehensive double-layered structures, weaves 68/cm of end count, 30/cm of filling density.
Experimental data:
This embodiment filter cloth thickness is 1.85mm, and filter cloth tensile strength is 2682N/cm, and determining power percentage elongation is 0.20%(50N/ cm), filter cloth Air permenbility is 228L/m2/ S, permeability rate is 0.48m3/m2/S.

Claims (3)

1. a kind of high tenacity nano carbon sol, nano-graphite irradiation grafting modified nylon monofilament filter cloth it is characterised in that:By following The raw material of weight portion is made:Nylon monofilament filter cloth 100-105, nano carbon sol 3-3.5, nano-graphite 2.7-3, FeSO4∙7H2O 0.8-0.9, acrylic acid trifluoro ethyl ester 24-26, nanometer hydroxyapatite 1.2-1.5, polyphenylene sulfide micron powder 3-3.5, soft Property SiO2Nanofiber 2.8-3.2, Triallyl isocyanurate 1.8-2.1, dodecafluoroheptyl methacrylate 24-26, water In right amount.
2. high tenacity nano carbon sol, the system of nano-graphite irradiation grafting modified nylon monofilament filter cloth according to claim 1 Preparation Method is it is characterised in that comprise the following steps:
(1)Nano carbon sol is mixed with water, is configured to the dispersion liquid of 1-1.5% mass concentration, nylon monofilament filter cloth is put into point Dispersion liquid, soaks 20-25 minute, and period does not stop to stir nylon monofilament filter cloth, takes out and dries, puts into valve bag, carry out pre-irradiation, inhales Receipts dosage is 42-44kGy, obtains modified nylon monofilament filter cloth;
(2)Polyphenylene sulfide micron powder is heated to softening, sprays into nanometer hydroxyapatite while stirring, continue to grind 10- 15 minutes, obtain mixed material;Acrylic acid trifluoro ethyl ester, dodecafluoroheptyl methacrylate are added to the water, are configured to 50- The dispersion liquid of 55% mass concentration, adds described mixed material and other residual componentss, stirs, then by modified nylon Monofilament filter cloth puts into dispersion liquid, soaks 20-25 minute, and period does not stop to stir nylon monofilament filter cloth, takes out and dries, puts into self-styled Bag, carries out positive and negative each mutual radiation, and absorbed dose are 190-195kGy;
(3)By step(2)The nylon monofilament filter cloth obtaining is carried out, dries, and obtains final product.
3. heat-resisting nano carbon sol, nano-graphite irradiation grafting modified nylon monofilament filter cloth according to claim 1, its feature It is that described nylon monofilament filter cloth thickness is 1.85-1.90mm, filter cloth organizational structure is 14 comprehensive double-layered structures, weaves end count 68 Root/cm, 30/cm of filling density.
CN201610937022.XA 2016-10-25 2016-10-25 Highly tenacious nylon monofilament filter cloth modified by radiation grafting of nanocarbon sol and nanographite and preparation method thereof Withdrawn CN106390594A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111346431A (en) * 2018-12-24 2020-06-30 上海钱丰纺织品有限公司 Heat-resistant filter felt, preparation method thereof and composite filter felt prepared from heat-resistant filter felt

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103255619A (en) * 2013-05-04 2013-08-21 广东职业技术学院 Electron beam irradiation finishing method capable of endowing textile fabric with functions of durability and easiness in cleaning as well as low discoloration

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103255619A (en) * 2013-05-04 2013-08-21 广东职业技术学院 Electron beam irradiation finishing method capable of endowing textile fabric with functions of durability and easiness in cleaning as well as low discoloration

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111346431A (en) * 2018-12-24 2020-06-30 上海钱丰纺织品有限公司 Heat-resistant filter felt, preparation method thereof and composite filter felt prepared from heat-resistant filter felt
CN111346431B (en) * 2018-12-24 2021-08-24 上海钱丰纺织品有限公司 Heat-resistant filter felt, preparation method thereof and composite filter felt prepared from heat-resistant filter felt

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Application publication date: 20170215