CN106380803A - Novel environment-friendly degradable corn fiber leisure shoe material - Google Patents

Novel environment-friendly degradable corn fiber leisure shoe material Download PDF

Info

Publication number
CN106380803A
CN106380803A CN201610782246.8A CN201610782246A CN106380803A CN 106380803 A CN106380803 A CN 106380803A CN 201610782246 A CN201610782246 A CN 201610782246A CN 106380803 A CN106380803 A CN 106380803A
Authority
CN
China
Prior art keywords
fiber
parts
corn fiber
pulverized
shoe material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610782246.8A
Other languages
Chinese (zh)
Inventor
马汝霖
段永杰
段晓辉
赵冰冰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JIESHOU MOUTAINTOP LEISURE GOODS CO Ltd
Original Assignee
JIESHOU MOUTAINTOP LEISURE GOODS CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by JIESHOU MOUTAINTOP LEISURE GOODS CO Ltd filed Critical JIESHOU MOUTAINTOP LEISURE GOODS CO Ltd
Priority to CN201610782246.8A priority Critical patent/CN106380803A/en
Publication of CN106380803A publication Critical patent/CN106380803A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/04Polyesters derived from hydroxycarboxylic acids, e.g. lactones
    • AHUMAN NECESSITIES
    • A43FOOTWEAR
    • A43BCHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B1/00Footwear characterised by the material
    • A43B1/14Footwear characterised by the material made of plastics
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/06Biodegradable
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16Fibres; Fibrils

Abstract

The invention discloses a novel environment-friendly degradable corn fiber leisure shoe material. The shoe material is prepared from the following raw materials (by weight): 36.8-42.5 parts of corn fiber, 18.5-20.7 parts of carbon fiber, 8.8-10.2 parts of fibrilia, 12.5-14.5 parts of hydroxypropyl methyl cellulose, 8.5-10.5 parts of gelatin, 6.3-7.8 parts of glycerin, 10.5-13.2 parts of poly3-hydroxybutyrate, 22.4-24.8 parts of starch, 5.5-7.5 parts of an ethylene-carbon monoxide copolymer and 9.5-11.5 parts of polyvinyl alcohol. The leisure shoe material containing corn fiber and prepared from degradable fiber is biodegradable, has rich sources of raw materials and is environment friendly. The prepared leisure shoe material of the invention has high strength and is biodegradable. The problem of pollution caused by waste leisure shoe products which cannot be effectively treated can be effectively alleviated.

Description

A kind of novel environment friendly degradable corn fiber leisure shoes materials
Technical field
The invention belongs to leisure goods technical field, it is related to a kind of playshoes and in particular to a kind of novel environment friendly degradable Corn fiber leisure shoes materials.
Background technology
Advocate nature, the continuous enhancing of the demand of back to nature and environmental protection consciousness with people, green health is weaved Product are increasingly subject to the favor of people.Fiber, as a kind of natural high polymer, because of the special construction of its macromole, and has good suppression The only health care such as bacterial growth, absorption abnormal flavour, and hygroscopic vapor transmission, biodegradable, it is described as the green fiber of new century.By The product that fiber is made has excellent anti-bacterial anti-foul function and snugness of fit, no electrostatic and Nantural non-toxic, biodegradable, Meet the development trend of new century green health textile.
With the enhancing to earth protective awareness, lack of energy consciousness, safety consciousness and clothing health consciousness for the mankind, pure sky So environmentally-friefabric fabric is paid attention to by everybody, is a kind of ecological fiber of great development potentiality.
China is populous nation, and the demand of clothes and various fabric is also got more and more and extensive.The home textile face in past As long as material wins the desire to purchase of consumer with durable and outward appearance, with the continuous improvement of people's living standard, health and when It is still a kind of consumption pattern that people pursue, and the clothes demand of various patterns is also got more and more, therefore given up using complete Some clothes process problem need bring into schedule.Reduce the pollution of environment, develop new fabrics for industrial use or garment surface Reproducible Biodegradable fiber used by material, is one of important topic of following textile development research, some are conducive to improving people The textile of class quality of life has also just obtained extensive research, and for the process of environmental conservation and solid waste, market needs Seek Biodegradable polymeric, this kind of polymer energy degradable one-tenth carbon dioxide and water under microbial action, to reach The environmental requirement of increasingly raising.Also there is certain research to the fabric lining of environment-friendly type at present, but composition is more single, simultaneously existing Fabric lining be used for producing playshoes and be not met by needing it is impossible to solve comfortable simultaneously, the problems such as absorbing sweat, good permeability; Meanwhile, existing leisure shoes materials also do not have degradability, lead to discarded playshoes difficult treatment, and have shadow to environment Ring.
Content of the invention
The shoes materials it is an object of the invention to provide a kind of novel environment friendly degradable corn fiber lies fallow.
The purpose of the present invention can be achieved through the following technical solutions:
A kind of novel environment friendly degradable corn fiber leisure shoes materials, this shoes materials is obtained by following weight parts raw material:Beautiful Rice fiber 36.8-42.5 part, carbon fiber 18.5-20.7 part, flaxen fiber 8.8-10.2 part, hydroxypropyl methyl cellulose 12.5- 14.5 parts, gelatin 8.5-10.5 part, glycerol 6.3-7.8 part, poly 3-hydroxy butyrate 10.5-13.2 part, starch 22.4-24.8 Part, ethylene/carbon monoxide multipolymer 5.5-7.5 part, polyvinyl alcohol 9.5-11.5 part;
This shoes materials is obtained by following steps:
After described corn fiber, carbon fiber, flaxen fiber and ethylene/carbon monoxide multipolymer raw material are pulverized, cross 60 Mesh sieve, obtains being pulverized and mixed material;Material will be pulverized and mixed mix with starch, hydroxypropyl methyl cellulose, and add compound gross weight The water stirring of amount 7-9%, continuously adds gelatin, glycerol, poly 3-hydroxy butyrate, polyvinyl alcohol stir, is led Material;Major ingredient is injected in 240-250 DEG C of mould and pressurizes, control pressure is 35-45T, after pushing 10-12s, prepared shoes materials.
Corn fiber is with starch such as Semen Maydiss, Semen Tritici aestivis as raw material, and the fermented lactic acid that changes into is aggregated again, spinning and make Synthetic fibers.This fiber has softly smooth, and intensity is big, the feature that moisture absorption is breathed freely, and the product of processing has the gloss as silk And comfortable skin sense of touch and feel, drapability is good, good thermostability and anti-ultraviolet function, and wearability is good, and has The faintly acid having natural bacteriostatic and making skin trust.Press close to the smooth feeling of skin, good shape keeping property, preferable gloss As degree, silk, splendid feel, good hygroscopicity and quick-drying effect, make corn fiber in underskirt, sportswear, shoes and hats On be widely used in a variety of applications
Beneficial effects of the present invention:The present invention is adopted the playshoes that the biodegradable fiber including corn fiber is obtained Material, can be biodegradable, abundant raw material source, environmentally friendly;Binding agent and plasticizer are used as by polyvinyl alcohol, have Effect promotes the uniform mixing between each fiber, improves the mechanical property of fabric;The addition of G & W can improve phase between raw material The mutually performance of mixing;The playshoes strength of materials that the present invention is obtained is high and biodegradable, can effectively alleviate discarded playshoes and produce Product cannot the pollution problem that brings of effective process.
Specific embodiment
With reference to embodiment, technical scheme is clearly and completely described with the enforcement it is clear that described Example is only a part of embodiment of the present invention, rather than whole embodiments.Based on the embodiment in the present invention, this area is common All other embodiment that technical staff is obtained under the premise of not making creative work, broadly falls into the model of present invention protection Enclose.
Embodiment 1
A kind of novel environment friendly degradable corn fiber leisure shoes materials, this shoes materials is obtained by following weight parts raw material:Beautiful 40.5 parts of fiber of rice, 19.5 parts of carbon fiber, 9.6 parts of flaxen fiber, 13.6 parts of hydroxypropyl methyl cellulose, 9.3 parts of gelatin, glycerol 7.1 parts, 11.8 parts of poly 3-hydroxy butyrate, 23.5 parts of starch, 6.8 parts of ethylene/carbon monoxide multipolymer, polyvinyl alcohol 10.2 Part;
This shoes materials is obtained by following steps:
After described corn fiber, carbon fiber, flaxen fiber and ethylene/carbon monoxide multipolymer raw material are pulverized, cross 60 Mesh sieve, obtains being pulverized and mixed material;Material will be pulverized and mixed mix with starch, hydroxypropyl methyl cellulose, and add compound gross weight The water stirring of amount 8%, continuously adds gelatin, glycerol, poly 3-hydroxy butyrate, polyvinyl alcohol stir, and obtain major ingredient; Major ingredient is injected in 245 DEG C of moulds and pressurizes, control pressure is 40T, after pushing 11s, prepared shoes materials.
The present invention is adopted the leisure shoes materials that the biodegradable fiber including corn fiber is obtained, and can be dropped by biology Solution, abundant raw material source, environmentally friendly;The leisure shoes materials that the technical program provides have biodegradability, softly slide Suitable, intensity is big, and moisture absorption is breathed freely, and product has the gloss and comfortable skin sense of touch and feel as silk, and drapability is good, has concurrently good Thermostability and anti-ultraviolet function.Binding agent and plasticizer are used as by polyvinyl alcohol, effectively facilitate equal between each fiber Even mixing, improves the mechanical property of material;The addition of G & W can improve the performance being mutually mixed between raw material, and fiber is risen To plasticization;The playshoes strength of materials that the present invention is obtained is high and biodegradable, can effectively alleviate and be produced by discarded playshoes Product cannot the pollution problem that brings of effective process.
Embodiment 2
A kind of novel environment friendly degradable corn fiber leisure shoes materials, this shoes materials is obtained by following weight parts raw material:Beautiful 42.5 parts of fiber of rice, 18.5 parts of carbon fiber, 8.8 parts of flaxen fiber, 14.5 parts of hydroxypropyl methyl cellulose, 8.5 parts of gelatin, glycerol 7.8 parts, 10.5 parts of poly 3-hydroxy butyrate, 24.8 parts of starch, 5.5 parts of ethylene/carbon monoxide multipolymer, polyvinyl alcohol 11.5 Part;
This shoes materials is obtained by following steps:
After described corn fiber, carbon fiber, flaxen fiber and ethylene/carbon monoxide multipolymer raw material are pulverized, cross 60 Mesh sieve, obtains being pulverized and mixed material;Material will be pulverized and mixed mix with starch, hydroxypropyl methyl cellulose, and add compound gross weight The water stirring of amount 7%, continuously adds gelatin, glycerol, poly 3-hydroxy butyrate, polyvinyl alcohol stir, and obtain major ingredient; Major ingredient is injected in 250 DEG C of moulds and pressurizes, control pressure is 35T, after pushing 12s, prepared shoes materials.
Embodiment 3
A kind of novel environment friendly degradable corn fiber leisure shoes materials, this shoes materials is obtained by following weight parts raw material:Beautiful 36.8 parts of fiber of rice, 20.7 parts of carbon fiber, 10.2 parts of flaxen fiber, 12.5 parts of hydroxypropyl methyl cellulose, 10.5 parts of gelatin, glycerol 6.3 parts, 13.2 parts of poly 3-hydroxy butyrate, 22.4 parts of starch, 7.5 parts of ethylene/carbon monoxide multipolymer, 9.5 parts of polyvinyl alcohol;
This shoes materials is obtained by following steps:
After described corn fiber, carbon fiber, flaxen fiber and ethylene/carbon monoxide multipolymer raw material are pulverized, cross 60 Mesh sieve, obtains being pulverized and mixed material;Material will be pulverized and mixed mix with starch, hydroxypropyl methyl cellulose, and add compound gross weight The water stirring of amount 9%, continuously adds gelatin, glycerol, poly 3-hydroxy butyrate, polyvinyl alcohol stir, and obtain major ingredient; Major ingredient is injected in 240 DEG C of moulds and pressurizes, control pressure is 45T, after pushing 10s, prepared shoes materials.
It is raw material that corn fiber adopts the plant resourceses of natural reproducible, decreases the dependence to conventional petroleum resource, symbol Close the requirement of international community's sustainable development, it has the advantage of synthetic fibers and natural fiber concurrently, tool follows completely naturally again simultaneously Ring-like feature biolytic with energy, compared with conventional fibrous material, corn fiber also has many unique performances, so obtaining Extensive attention to World Textile circle.It is recommended as " the enviromental cycle material of 21 century " by numerous experts, be a kind of great The ecological fiber of exhibition potential quality.
In the description of this specification, the description of reference term " embodiment ", " example ", " specific example " etc. means It is contained at least one enforcement of the present invention in conjunction with the specific features of this embodiment or example description, structure, material or feature In example or example.In this manual, identical embodiment or example are not necessarily referring to the schematic representation of above-mentioned term. And, the specific features of description, structure, material or feature can be to close in any one or more embodiments or example Suitable mode combines.
Present invention disclosed above preferred embodiment is only intended to help illustrate the present invention.Preferred embodiment is not detailed Describe all of details, also do not limit the specific embodiment that this invention is only described.Obviously, the content according to this specification, Can make many modifications and variations.This specification is chosen and is specifically described these embodiments, is to preferably explain the present invention Principle and practical application so that skilled artisan can be best understood by and utilize the present invention.The present invention is only Limited by claims and its four corner and equivalent.

Claims (1)

1. a kind of novel environment friendly degradable corn fiber leisure shoes materials are it is characterised in that this shoes materials is former by following weight parts Material is obtained:Corn fiber 36.8-42.5 part, carbon fiber 18.5-20.7 part, flaxen fiber 8.8-10.2 part, hydroxypropyl methyl fiber Plain 12.5-14.5 part, gelatin 8.5-10.5 part, glycerol 6.3-7.8 part, poly 3-hydroxy butyrate 10.5-13.2 part, starch 22.4-24.8 part, ethylene/carbon monoxide multipolymer 5.5-7.5 part, polyvinyl alcohol 9.5-11.5 part;
This shoes materials is obtained by following steps:
After described corn fiber, carbon fiber, flaxen fiber and ethylene/carbon monoxide multipolymer raw material are pulverized, cross 60 mesh sieves, Obtain being pulverized and mixed material;Material will be pulverized and mixed mix with starch, hydroxypropyl methyl cellulose, and add compound gross weight 7- 9% water stirring, continuously adds gelatin, glycerol, poly 3-hydroxy butyrate, polyvinyl alcohol stir, and obtain major ingredient;Will Major ingredient injects pressurization in 240-250 DEG C of mould, and control pressure is 35-45T, after pushing 10-12s, prepared shoes materials.
CN201610782246.8A 2016-08-30 2016-08-30 Novel environment-friendly degradable corn fiber leisure shoe material Pending CN106380803A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610782246.8A CN106380803A (en) 2016-08-30 2016-08-30 Novel environment-friendly degradable corn fiber leisure shoe material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610782246.8A CN106380803A (en) 2016-08-30 2016-08-30 Novel environment-friendly degradable corn fiber leisure shoe material

Publications (1)

Publication Number Publication Date
CN106380803A true CN106380803A (en) 2017-02-08

Family

ID=57939377

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610782246.8A Pending CN106380803A (en) 2016-08-30 2016-08-30 Novel environment-friendly degradable corn fiber leisure shoe material

Country Status (1)

Country Link
CN (1) CN106380803A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107163302A (en) * 2017-07-03 2017-09-15 山东大农药业有限公司 Degradable pesticide slow-release capsule housing
CN110074509A (en) * 2019-05-20 2019-08-02 扬州金露日用品有限公司 A kind of preparation method of degradable slippers
CN112321902A (en) * 2020-09-14 2021-02-05 惠州市环美盛新材料有限公司 Biodegradable functional material and preparation method thereof
CN114196222A (en) * 2022-01-07 2022-03-18 云南猫哆哩集团食品有限责任公司 Biodegradable material prepared from tamarind fruit shell and fiber, and preparation and application thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104098792A (en) * 2014-06-30 2014-10-15 安徽巢湖南方膜业有限责任公司 Corn starch degradable plastic film and preparation method thereof
CN104448743A (en) * 2014-12-02 2015-03-25 福州友星生物科技有限公司 Biodegradable material and preparation method thereof
CN105778372A (en) * 2016-03-22 2016-07-20 苏州市湘园特种精细化工有限公司 High-performance completely-biodegradable plastic

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104098792A (en) * 2014-06-30 2014-10-15 安徽巢湖南方膜业有限责任公司 Corn starch degradable plastic film and preparation method thereof
CN104448743A (en) * 2014-12-02 2015-03-25 福州友星生物科技有限公司 Biodegradable material and preparation method thereof
CN105778372A (en) * 2016-03-22 2016-07-20 苏州市湘园特种精细化工有限公司 High-performance completely-biodegradable plastic

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107163302A (en) * 2017-07-03 2017-09-15 山东大农药业有限公司 Degradable pesticide slow-release capsule housing
CN110074509A (en) * 2019-05-20 2019-08-02 扬州金露日用品有限公司 A kind of preparation method of degradable slippers
CN112321902A (en) * 2020-09-14 2021-02-05 惠州市环美盛新材料有限公司 Biodegradable functional material and preparation method thereof
CN114196222A (en) * 2022-01-07 2022-03-18 云南猫哆哩集团食品有限责任公司 Biodegradable material prepared from tamarind fruit shell and fiber, and preparation and application thereof

Similar Documents

Publication Publication Date Title
CN106380803A (en) Novel environment-friendly degradable corn fiber leisure shoe material
CN100491630C (en) Preparation method and application of ceiba fiber in non-woven fabrics field
CN100999846A (en) Compounding process of bamboo fibre fabric
CN102352551A (en) Anti-bacterial anti-mite wool textile and production method thereof
CN102293555A (en) Chitosan fiber health-care pillow
CN207449279U (en) A kind of cool feeling, the bamboo fibre of antibacterial and mint fibers sofa fabric
CN102443923A (en) Polylactic acid and tencel interwoven fabric
CN201864881U (en) Down knitted thermal underwear fabric
CN106003896B (en) Heat-preservation antibacterial textile material
CN202293464U (en) Glue-sprayed non-woven fabric with breathable film
CN102041579A (en) Nano boron nitride PP (Polypropylene) fiber and preparation method thereof
CN103526569A (en) Multifunctional corn fiber fabric
CN105167479B (en) Composite blanket
CN108060483A (en) A kind of environment-friendly degradable scribbled
CN104338171A (en) Corn polylactic acid fiber infant paper diaper
CN102501445A (en) Composite thermal-insulation breathable shell fabric
CN202466057U (en) Functional fabric formed by interweaving Parster fiber and Viloft fiber
CN202144541U (en) Composite bamboo fiber knitted fabric
CN105266240A (en) Moisture-permeable antibiosis fabric
CN205695725U (en) A kind of can the two-sided outer polylactic acid fiber fabric underwear worn
CN111041714A (en) Antibacterial hot melt cotton
CN105029973B (en) A kind of health care woolen blanket
CN204245773U (en) A kind of yakwool relaxes dormancy quilt
CN202175796U (en) Knitted fabric containing silver fibers
CN206266788U (en) A kind of environment-friendly degradable scribbled

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20170208

RJ01 Rejection of invention patent application after publication