CN106380637A - Colorful vamp leather material - Google Patents
Colorful vamp leather material Download PDFInfo
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- CN106380637A CN106380637A CN201610763124.4A CN201610763124A CN106380637A CN 106380637 A CN106380637 A CN 106380637A CN 201610763124 A CN201610763124 A CN 201610763124A CN 106380637 A CN106380637 A CN 106380637A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention provides a colorful vamp leather material. The colorful vamp leather material is prepared from 20-30 parts by weight of natural rubber, 3-5 parts by weight of a stabilizing agent, 1-2 parts by weight of a lubricant, 4-6 parts by weight of a promoter, 15-18 parts by weight of a filler, 5-30 parts by weight of polyvinyl chloride, 3-4 parts by weight of polydimethylsiloxane, 1-3 parts by weight of stearic acid, 4-7 parts by weight of triethanolamine, 2-3 parts by weight of zinc oxide, 6-9 parts by weight of dilauryl thiodipropionate, 2-4 parts by weight of epoxidized linseed oil, 1-2 parts by weight of CPE and 5-10 parts by weight of a dye. Compared with the existing vamp leather material, the colorful vamp leather material has the advantages that natural rubber with good elasticity, mouldability, recovery, ventilation and hydroscopicity is used as a main raw material, produces small pollution on the environment and can be easily degraded and recycled, a direct dye diamidodiphenylethene disulfonic acid with a brilliant color and moderate fastness is used and the direct orange GGL is an eco-friendly dye with good performances.
Description
Technical field
The present invention is a kind of colorful upper leather material, belongs to fabric field.
Background technology
Polrvinyl chloride (Polyvinyl Chloride), abbreviation PVC, it is the important organic synthesiss material of China, belong to three
Synthetic resin in big synthetic material (synthetic resin, synthetic fibers, synthetic rubber).Polyvinyl chloride is passed through by Vinyl Chloride Monomer
Radical polymerization forms, and polymerization degree n, typically in the range of 500～20000, is a kind of nontoxic, odorless white powder.Chemistry is steady
Qualitative very high, there is good plasticity.In addition to minority organic solvent, be resistant under room temperature any concentration hydrochloric acid, less than 90%
Sulphuric acid, 50～60% nitric acid and less than 20% Caustic soda, for salt also quite stable；The heat stability of PVC and fast light
Property is poor, can start to decompose and release hydrogen chloride (HCl) gas, cause PVC variable color more than 140 DEG C.Electrical insulating property is excellent,
Typically will not burn, flame can burn and release HCl, but leaving flame is self-extinguishment, be a kind of " self-extinguishment ", " flame retardancy "
Material.
Polrvinyl chloride is mainly for the production of slide, pipe fitting, gold card, blood transfusion equipment, soft, hard tube, sheet material, door and window, abnormal shape
Material, thin film, electrically insulating material, cable cover(ing), blood transfusion material, vamp material for sole of shoe etc..During for vamp material, polrvinyl chloride excellent
Point is that price is less expensive, and yield is big, and color is more consistent, and production quality is easily controlled, and its shortcoming does not absorb dampness for airtight, meets
Transforming into cold is crisp to be easily deformed, and resistance to bend(ing) is poor, and range of extension is few compared with natural skin, but is more than PU skin, and black skin easily absorbs heat, intolerant to height
Temperature.
Publication No. CN103352376B, publication date are 2015.12.23, the application uncommon leatherware of artificial six peace three is limited
The Chinese patent of company discloses " vamp PVC synthetic leather of high-grade sport shoess and preparation method thereof " it is characterised in that by three
Layer is compound to be constituted, and base material is cloth, and middle level is foamed PVC layer, and upper strata is polyvinyl chloride resin layer, and middle level is by the raw material system of following weight portion
Become：SG-1 type polyvinyl chloride resin 40-50, SG-5 type polyvinyl chloride resin 70-80, red phosphorus 4-5, isooctylthioglycolate 3-4, polyisobutylene 4-
5th, 2.4.6- tri- (dimethylamino methyl) phenol 1-2, zinc oxide 1-2, ABS high glue powder 4-5, attapulgite 13-15, sepiolite powder
6-9, Di(dioctylpyrophosphato) ethylene titanate 2-3, ethyl acrylate 4-6, double isooctyl mercaptoacetate two are just pungent
Base stannum 1-2, phthalic acid ester 8-9, triethyl citrate 3-4, hexamethylenetetramine 1-2, azodicarbonamide 0.3-0.5,
Modified clay powders 3-4；Formula and process modification are passed through in this invention, increased the pliability of synthetic leather, have similar to natural
The naturally comfortable feel that leather has；3-5 does not allow cracky or tear to damage, and is adapted as Fabric Used for Sport Shoes.This is special
Although profit effectively increases the resist bending performance of material, anti-wear performance is general and color is single.
Content of the invention
In view of the shortcomings of the prior art, it is an object of the present invention to provide a kind of colorful upper leather material, above-mentioned to solve
The problem proposing in background technology.
To achieve these goals, the present invention is to realize by the following technical solutions：A kind of colorful upper leather material,
It is made up of the raw material of following parts by weight：Natural rubber 20-30 weight portion, stabilizer 3-5 weight portion, lubricant 1-2 weight portion,
Accelerator 4-6 weight portion, filler 15-18 weight portion, polrvinyl chloride 5-30 weight portion, polydimethylsiloxane 3-4 weight portion,
Stearic acid 1-3 weight portion, triethanolamine 4-7 weight portion, zinc oxide 2-3 weight portion, dilauryl thiodipropionate 6-9 weight
Part, epoxy Semen Lini oil 2-4 weight portion, CPE1-2 weight portion, dyestuff 5-10 weight portion.
Further, described stabilizer is a kind of plastics used additives, the colourity of described plastics used additives：≤ 100, stannum contains
Amount：>=19.0% relative density：1.175-1.192, index of refraction：1.507-1.511nD.
Further, described lubricant is one of silicone oil, esters of silicon acis, phosphate ester, fluorocarbon oil, Esters oil and synthetic hydrocarbon oil
Or it is multiple.
Further, described accelerator is cobalt naphthenate, cobalt iso-octoate, zinc Isoocatanoate, DMA, N, N- bis-
One or more of MEA, vanadium phosphate.
Further, described dyestuff is a kind of diaminobenzil disulfonic acid class direct dyess.
Further, contain natural rubber 30 weight portion in the raw material of every 100 weight portions, in the raw material of every 100 weight portions
Containing stabilizer 3 weight portion, contain lubricant 2 weight portion in the raw material of every 100 weight portions, contain in the raw material of every 100 weight portions
There is accelerator 4 weight portion, contain filler 15 weight portion in the raw material of every 100 weight portions, contain in the raw material of every 100 weight portions
Polrvinyl chloride 18 weight portion, in the raw material of every 100 weight portions contain polydimethylsiloxane 4 weight portion, every 100 weight portions former
In material contain stearic acid 3 weight portion, in the raw material of every 100 weight portions contain triethanolamine 4 weight portion, every 100 weight portions former
Zinc oxide 2 weight portion is contained in material, containing dilauryl thiodipropionate 6 weight portion in the raw material of every 100 weight portions, every 100
Epoxy Semen Lini oil 2 weight portion is contained in the raw material of weight portion, containing CPE2 weight portion in the raw material of every 100 weight portions, every 100
Dyestuff 5 weight portion is contained in the raw material of weight portion.
Further, contain natural rubber 20 weight portion in the raw material of every 100 weight portions, in the raw material of every 100 weight portions
Containing stabilizer 5 weight portion, contain lubricant 2 weight portion in the raw material of every 100 weight portions, contain in the raw material of every 100 weight portions
There is accelerator 6 weight portion, contain filler 15 weight portion in the raw material of every 100 weight portions, contain in the raw material of every 100 weight portions
Polrvinyl chloride 18 weight portion, in the raw material of every 100 weight portions contain polydimethylsiloxane 3 weight portion, every 100 weight portions former
In material contain stearic acid 3 weight portion, in the raw material of every 100 weight portions contain triethanolamine 7 weight portion, every 100 weight portions former
Zinc oxide 3 weight portion is contained in material, containing dilauryl thiodipropionate 9 weight portion in the raw material of every 100 weight portions, every 100
Epoxy Semen Lini oil 2 weight portion is contained in the raw material of weight portion, containing CPE2 weight portion in the raw material of every 100 weight portions, every 100
Dyestuff 5 weight portion is contained in the raw material of weight portion.
Beneficial effects of the present invention：A kind of colorful upper leather material of the present invention, using natural rubber, has good bullet
Property, formability, restoration, air permeability and water absorption, easily degraded and less with natural components for primary raw material environmental pollution
Using by increasing diaminobenzil disulfonic acid class direct dyess, this kind of dyestuff is bright in colour, and fastness is moderate, directly resistance to
Shine the environmental protection type dye that orange GGL (C.I. direct orange 39) is better performances.Direct fast yellow 3BLL (C.I. directly Huang 106) is three
Nitrogen azoles direct dyess, sunlight fastness reaches 6～7 grades.Directly the green IRC of sun-proof (C.I. direct green 34) dye-uptake is high, has excellent
Dyefastness, sunlight fastness reaches 6～7 grades, and washing fastness reaches 3～4 grades.
Specific embodiment
Technological means, creation characteristic, reached purpose and effect for making the present invention realize are easy to understand, with reference to
Specific embodiment, is expanded on further the present invention.
The present invention provides a kind of technical scheme：A kind of colorful upper leather material, is made up of the raw material of following parts by weight：My god
So rubber 20-30 weight portion, stabilizer 3-5 weight portion, lubricant 1-2 weight portion, accelerator 4-6 weight portion, filler 15-18
Weight portion, polrvinyl chloride 5-30 weight portion, polydimethylsiloxane 3-4 weight portion, stearic acid 1-3 weight portion, triethanolamine 4-7
Weight portion, zinc oxide 2-3 weight portion, dilauryl thiodipropionate 6-9 weight portion, epoxy Semen Lini oil 2-4 weight portion,
CPE1-2 weight portion, dyestuff 5-10 weight portion.
Stabilizer is a kind of plastics used additives, the colourity of described plastics used additives：≤ 100, Theil indices：>=19.0% relatively
Density：1.175-1.192, index of refraction：1.507-1.511nD, lubricant is silicone oil, esters of silicon acis, phosphate ester, fluorocarbon oil, Esters oil
One or more of with synthetic hydrocarbon oil, accelerator is cobalt naphthenate, cobalt iso-octoate, zinc Isoocatanoate, DMA, N,
One or more of N- diethylaniline, vanadium phosphate, dyestuff is a kind of diaminobenzil disulfonic acid class direct dyess.
As one embodiment of the present of invention：Containing natural rubber 30 weight portion in the raw material of every 100 weight portions, every 100
Contain stabilizer 3 weight portion in the raw material of weight portion, in the raw material of every 100 weight portions, contain lubricant 2 weight portion, every 100 weights
Contain accelerator 4 weight portion in the raw material of amount part, in the raw material of every 100 weight portions, contain filler 15 weight portion, every 100 weight
Contain polrvinyl chloride 18 weight portion in the raw material of part, in the raw material of every 100 weight portions, contain polydimethylsiloxane 4 weight portion,
Contain stearic acid 3 weight portion in the raw material of every 100 weight portions, in the raw material of every 100 weight portions, contain triethanolamine 4 weight portion,
Contain zinc oxide 2 weight portion in the raw material of every 100 weight portions, in the raw material of every 100 weight portions, contain thiodipropionic acid dilauryl osmanthus
Ester 6 weight portion, contains epoxy Semen Lini oil 2 weight portion in the raw material of every 100 weight portions, contains in the raw material of every 100 weight portions
CPE2 weight portion, contains dyestuff 5 weight portion in the raw material of every 100 weight portions.
As one embodiment of the present of invention：Containing natural rubber 20 weight portion in the raw material of every 100 weight portions, every 100
Contain stabilizer 5 weight portion in the raw material of weight portion, in the raw material of every 100 weight portions, contain lubricant 2 weight portion, every 100 weights
Contain accelerator 6 weight portion in the raw material of amount part, in the raw material of every 100 weight portions, contain filler 15 weight portion, every 100 weight
Contain polrvinyl chloride 18 weight portion in the raw material of part, in the raw material of every 100 weight portions, contain polydimethylsiloxane 3 weight portion,
Contain stearic acid 3 weight portion in the raw material of every 100 weight portions, in the raw material of every 100 weight portions, contain triethanolamine 7 weight portion,
Contain zinc oxide 3 weight portion in the raw material of every 100 weight portions, in the raw material of every 100 weight portions, contain thiodipropionic acid dilauryl osmanthus
Ester 9 weight portion, contains epoxy Semen Lini oil 2 weight portion in the raw material of every 100 weight portions, contains in the raw material of every 100 weight portions
CPE2 weight portion, contains dyestuff 5 weight portion in the raw material of every 100 weight portions.
By adopting natural rubber, there is good elasticity, formability, restoration, air permeability and water absorption, with natural one-tenth
Part is little for primary raw material environmental pollution, easily degrades and recycles, direct by increase diaminobenzil disulfonic acid class
Dyestuff, this kind of dyestuff is bright in colour, and fastness is moderate, and direct Fast Orange GGL (C.I. direct orange 39) is the environment-friendly type of better performances
Dyestuff.Direct fast yellow 3BLL (C.I. directly Huang 106) is triazole direct dyess, and sunlight fastness reaches 6～7 grades.Directly resistance to
Shine green IRC (C.I. direct green 34) dye-uptake high, have excellent dyefastness, sunlight fastness reaches 6～7 grades, washing fastness
Reach 3～4 grades.
Ultimate principle and principal character and the advantages of the present invention of the present invention have been shown and described above, for this area skill
It is clear that the invention is not restricted to the details of above-mentioned one exemplary embodiment for art personnel, and in the spirit without departing substantially from the present invention or
In the case of basic feature, the present invention can be realized in other specific forms.Therefore, no matter from the point of view of which point, all should be by
Embodiment regards exemplary as, and is nonrestrictive, the scope of the present invention by claims rather than on state
Bright restriction, it is intended that all changes in the implication and scope of the equivalency of claim that fall are included in the present invention
Interior.
Moreover, it will be appreciated that although this specification is been described by according to embodiment, not each embodiment only wraps
Containing an independent technical scheme, only for clarity, those skilled in the art should for this narrating mode of description
Using description as an entirety, the technical scheme in each embodiment can also form those skilled in the art through appropriately combined
Understandable other embodiment.
Claims (7)
1. a kind of colorful upper leather material it is characterised in that：It is made up of the raw material of following parts by weight：Natural rubber 20-30 weight
Amount part, stabilizer 3-5 weight portion, lubricant 1-2 weight portion, accelerator 4-6 weight portion, filler 15-18 weight portion, polychlorostyrene second
Alkene 5-30 weight portion, polydimethylsiloxane 3-4 weight portion, stearic acid 1-3 weight portion, triethanolamine 4-7 weight portion, zinc oxide
2-3 weight portion, dilauryl thiodipropionate 6-9 weight portion, epoxy Semen Lini oil 2-4 weight portion, CPE1-2 weight portion, dyestuff
5-10 weight portion.
2. a kind of colorful upper leather material according to claim 1 it is characterised in that：Described stabilizer is that a kind of plastics are used
Auxiliary agent, the colourity of described plastics used additives：≤ 100, Theil indices：>=19.0% relative density：1.175-1.192, index of refraction：
1.507-1.511nD.
3. a kind of colorful upper leather material according to claim 1 it is characterised in that：Described lubricant is silicone oil, silicic acid
One or more of ester, phosphate ester, fluorocarbon oil, Esters oil and synthetic hydrocarbon oil.
4. a kind of colorful upper leather material according to claim 1 it is characterised in that：Described accelerator be cobalt naphthenate,
Cobalt iso-octoate, zinc Isoocatanoate, DMA, N, one or more of N- diethylaniline, vanadium phosphate.
5. a kind of colorful upper leather material according to claim 1 it is characterised in that：Described dyestuff is a kind of diaminourea two
Styrene disulfonic acid class direct dyess.
6. a kind of colorful upper leather material according to claim 1 it is characterised in that：Contain in the raw material of every 100 weight portions
There is natural rubber 30 weight portion, contain stabilizer 3 weight portion in the raw material of every 100 weight portions, contain in the raw material of every 100 weight portions
There is lubricant 2 weight portion, contain accelerator 4 weight portion in the raw material of every 100 weight portions, contain in the raw material of every 100 weight portions
Filler 15 weight portion, contains polrvinyl chloride 18 weight portion in the raw material of every 100 weight portions, contains in the raw material of every 100 weight portions
Have polydimethylsiloxane 4 weight portion, in the raw material of every 100 weight portions contain stearic acid 3 weight portion, every 100 weight portions former
In material contain triethanolamine 4 weight portion, in the raw material of every 100 weight portions contain zinc oxide 2 weight portion, every 100 weight portions former
Contain dilauryl thiodipropionate 6 weight portion in material, in the raw material of every 100 weight portions, contain epoxy Semen Lini oil 2 weight portion,
Contain CPE2 weight portion in the raw material of every 100 weight portions, in the raw material of every 100 weight portions, contain dyestuff 5 weight portion.
7. a kind of colorful upper leather material according to claim 1 it is characterised in that：Contain in the raw material of every 100 weight portions
There is natural rubber 20 weight portion, contain stabilizer 5 weight portion in the raw material of every 100 weight portions, contain in the raw material of every 100 weight portions
There is lubricant 2 weight portion, contain accelerator 6 weight portion in the raw material of every 100 weight portions, contain in the raw material of every 100 weight portions
Filler 15 weight portion, contains polrvinyl chloride 18 weight portion in the raw material of every 100 weight portions, contains in the raw material of every 100 weight portions
Have polydimethylsiloxane 3 weight portion, in the raw material of every 100 weight portions contain stearic acid 3 weight portion, every 100 weight portions former
In material contain triethanolamine 7 weight portion, in the raw material of every 100 weight portions contain zinc oxide 3 weight portion, every 100 weight portions former
Contain dilauryl thiodipropionate 9 weight portion in material, in the raw material of every 100 weight portions, contain epoxy Semen Lini oil 2 weight portion,
Contain CPE2 weight portion in the raw material of every 100 weight portions, in the raw material of every 100 weight portions, contain dyestuff 5 weight portion.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610763124.4A CN106380637A (en) | 2016-08-29 | 2016-08-29 | Colorful vamp leather material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610763124.4A CN106380637A (en) | 2016-08-29 | 2016-08-29 | Colorful vamp leather material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106380637A true CN106380637A (en) | 2017-02-08 |
Family
ID=57938459
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610763124.4A Pending CN106380637A (en) | 2016-08-29 | 2016-08-29 | Colorful vamp leather material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106380637A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107142746A (en) * | 2017-06-13 | 2017-09-08 | 合肥远科服装设计有限公司 | A kind of nontoxic textile dyestuff and preparation method thereof |
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|---|---|---|---|---|
| CN102020793A (en) * | 2011-01-14 | 2011-04-20 | 尚盟运动用品(惠阳)有限公司 | Heat-preservation folding-resistance vamp material and preparation method thereof |
| CN105218881A (en) * | 2015-11-05 | 2016-01-06 | 常州卓源橡胶制品有限公司 | A kind of rubber overshoes vamp compounded rubber and preparation method thereof |
| CN105237824A (en) * | 2015-11-05 | 2016-01-13 | 常州卓源橡胶制品有限公司 | Lightweight rain boot and making method thereof |
| CN105542344A (en) * | 2016-01-21 | 2016-05-04 | 苏州市景荣科技有限公司 | Bending-resistant air-permeable polyvinyl chloride vamp material and preparation method thereof |
-
2016
- 2016-08-29 CN CN201610763124.4A patent/CN106380637A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102020793A (en) * | 2011-01-14 | 2011-04-20 | 尚盟运动用品(惠阳)有限公司 | Heat-preservation folding-resistance vamp material and preparation method thereof |
| CN105218881A (en) * | 2015-11-05 | 2016-01-06 | 常州卓源橡胶制品有限公司 | A kind of rubber overshoes vamp compounded rubber and preparation method thereof |
| CN105237824A (en) * | 2015-11-05 | 2016-01-13 | 常州卓源橡胶制品有限公司 | Lightweight rain boot and making method thereof |
| CN105542344A (en) * | 2016-01-21 | 2016-05-04 | 苏州市景荣科技有限公司 | Bending-resistant air-permeable polyvinyl chloride vamp material and preparation method thereof |
Non-Patent Citations (1)
| Title |
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| 张世源编: "《生态纺织工程》", 31 May 2004, 中国纺织出版社出版发行 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107142746A (en) * | 2017-06-13 | 2017-09-08 | 合肥远科服装设计有限公司 | A kind of nontoxic textile dyestuff and preparation method thereof |
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