CN106380633A - High-conductivity degradable 3D printing consumable material - Google Patents

High-conductivity degradable 3D printing consumable material Download PDF

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Publication number
CN106380633A
CN106380633A CN201610796239.3A CN201610796239A CN106380633A CN 106380633 A CN106380633 A CN 106380633A CN 201610796239 A CN201610796239 A CN 201610796239A CN 106380633 A CN106380633 A CN 106380633A
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CN
China
Prior art keywords
parts
weight
consumptive material
high conductivity
following component
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610796239.3A
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Chinese (zh)
Inventor
段月强
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anhui Aosibo Medical Instrument And Equipment Co Ltd
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Anhui Aosibo Medical Instrument And Equipment Co Ltd
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Publication date
Application filed by Anhui Aosibo Medical Instrument And Equipment Co Ltd filed Critical Anhui Aosibo Medical Instrument And Equipment Co Ltd
Priority to CN201610796239.3A priority Critical patent/CN106380633A/en
Publication of CN106380633A publication Critical patent/CN106380633A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L3/00Compositions of starch, amylose or amylopectin or of their derivatives or degradation products
    • C08L3/02Starch; Degradation products thereof, e.g. dextrin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B33ADDITIVE MANUFACTURING TECHNOLOGY
    • B33YADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y70/00Materials specially adapted for additive manufacturing
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12NMICROORGANISMS OR ENZYMES; COMPOSITIONS THEREOF; PROPAGATING, PRESERVING, OR MAINTAINING MICROORGANISMS; MUTATION OR GENETIC ENGINEERING; CULTURE MEDIA
    • C12N1/00Microorganisms, e.g. protozoa; Compositions thereof; Processes of propagating, maintaining or preserving microorganisms or compositions thereof; Processes of preparing or isolating a composition containing a microorganism; Culture media therefor
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/001Conductive additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/06Biodegradable
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16Fibres; Fibrils

Abstract

The invention discloses a high-conductivity degradable 3D printing consumable material. The high-conductivity degradable 3D printing consumable material comprises, by weight, 1-10 parts of silver fibers, 1-3 parts of cotton fibers, 1-5 parts of starch, 1-3 parts of gelatin, 0.05-0.1 parts of potassium chloride crystals, 0.04-0.05 parts of calcium carbonate, 0.01-0.1 parts of salicin, 0.01-0.1 parts of sodium, iron and ammonium citrate, 0.01-0.1 parts of cholate, 0.01-0.1 parts of potassium dihydrogen phosphate and 0.01-0.05 parts of propylene glycol. The 3D printing consumable material is creatively used for printing a medium, and is used for screening specific microorganisms.

Description

A kind of 3D printing consumptive material of degradable high conductivity
Technical field
The present invention relates to 3D printing technique field, more particularly, to a kind of 3D printing consumptive material of degradable high conductivity.
Background technology
3D printing is one kind of rapid shaping technique, it be a kind of based on mathematical model file, with powdered gold Belong to or plastics etc. can jointing material, carry out the technology of constructed object by way of successively printing.3D printing is typically with numeral Technologic material printer is realizing.Often be used for modeling in fields such as Making mold, industrial designs, after be gradually available for one The direct manufacture of a little products, has had the parts printing using this technology.This technology sets in jewelry, footwear, industry Meter, building, engineering and construction, automobile, Aero-Space, dentistry and medical industries, education, GIS-Geographic Information System, civil engineering, rifle Prop up and other field has all been applied.
However, existing 3D printing consumptive material, the consumptive material of degradable and high conductivity not yet occurs, this problems demand solution Certainly.
Content of the invention
It is an object of the invention to overcoming the deficiency of above-mentioned prior art and providing a kind of 3D of degradable high conductivity to beat Print consumptive material.
For achieving the above object, the present invention provides a kind of 3D printing consumptive material of degradable high conductivity, by weight, including Following component:
Silver fiber, 1 to 10 part;
Cotton fiber, 1 to 3 part;
Starch, 1 to 5 part;
Gelatin, 1 to 3 part;
Potassium chloride, 0.05 to 0.1 part;
Calcium Carbonate, 0.04 to 0.05 part;
Salicin, 0.01 to 0.1 part;
Sodium citrate ferrum ammonium, 0.01 to 0.1 part;
Cholate, 0.01 to 0.1 part;
Potassium dihydrogen phosphate, 0.01 to 0.1 part;
Propylene glycol, 0.01 to 0.05 part.
Preferably, by weight, including following component:
Silver fiber, 5 parts;
Cotton fiber, 1.5 parts;
Starch, 2 parts;
Gelatin, 1.5 parts;
Potassium chloride, 0.08 part;
Calcium Carbonate, 0.04 part;
Salicin, 0.05 part;
Sodium citrate ferrum ammonium, 0.05 part;
Cholate, 0.05 part;
Potassium dihydrogen phosphate, 0.05 part;
Propylene glycol, 0.02 part.
Preferably, by weight, also comprise the following components:
Rhamnose, 0.5 to 0.1 part.
Preferably, by weight, also comprise the following components:
Fluorescent material, 0.1 to 0.5 part.
Preferably, by weight, also comprise the following components:
Quartz sand, 0.1 to 0.5 part.
Preferably, by weight, also comprise the following components:
Butanediol, 0.03 to 0.05 part.
Preferably, by weight, also comprise the following components:
Described carbon nano-tube fibre, 0.5 to 1 part.
Preferably, by weight, also comprise the following components:
Carnis Bovis seu Bubali cream, 3 to 5 parts.
The invention has the beneficial effects as follows:The 3D printing consumptive material of the present invention, is mainly used in 3D printing solid medium, is using When, after each component is weighed by weight, mix, add water, each component is 100 parts with the weight sum of water.In order to protect Card viscosity, is easy to for material to be prepared into paste, can add 1 part to 3 parts of binding agent or firming agent.Will by 3D printer Material is printed as pie, and in order to be prepared into solid medium, the diameter of this solid medium and culture dish match.The present invention's Culture medium is used for the microorganism that selectivity culture is resistant to weak current, by being passed through unidirectional current in the medium, thus filtering out It is resistant to the microorganism of electric current.The portion of material of the present invention can be degraded, in incubation, by microbial consumption part battalion Foster material, then some of which material can pass through biodegradation, and silver fiber can reclaim.Silver fiber in the present invention increases Strong electric conductivity, when after prepared by consumptive material, silver fiber is inter-adhesive in three dimensions, thus spatially building small leading Line.Starch is used for providing carbon source.Gelatin is used for solidifying consumptive material.Potassium chloride provides inorganic salt.And Calcium Carbonate can be used for Adjust acid-base value.Propylene glycol provide carbon source, can using propylene glycol for carbon source microorganism can obtain in this consumptive material bigger Enrichment.Potassium dihydrogen phosphate can provide phosphate.And in order to provide the nutrition of more horn of plenty, Carnis Bovis seu Bubali cream etc. can be added, in order to Guarantee to form full culture medium.The invention 3D printing consumptive material is printed culture medium, and be used for screening specifically micro- life Thing.The culture medium of this high conductivity cannot be prepared using conventional experiment maneuver, and current 3D printing also not used for Print the example of this solid medium, and the selectivity culture for microorganism, screening.
Specific embodiment
Embodiment one
The present invention provides a kind of 3D printing consumptive material of degradable high conductivity, by weight, including following component:Silver is fine Dimension, 1 to 10 part;Cotton fiber, 1 to 3 part;Starch, 1 to 5 part;Gelatin, 1 to 3 part;Potassium chloride, 0.05 to 0.1 part;Carbonic acid Calcium, 0.04 to 0.05 part;Salicin, 0.01 to 0.1 part;Sodium citrate ferrum ammonium, 0.01 to 0.1 part;Cholate, 0.01 to 0.1 part; Potassium dihydrogen phosphate, 0.01 to 0.1 part;Propylene glycol, 0.01 to 0.05 part.
Embodiment two
The present invention provides a kind of 3D printing consumptive material of degradable high conductivity, by weight, including following component:Silver is fine Dimension, 5 parts;Cotton fiber, 1.5 parts;Starch, 2 parts;Gelatin, 1.5 parts;Potassium chloride, 0.08 part;Calcium Carbonate, 0.04 part;Bigcatkin willow Element, 0.05 part;Sodium citrate ferrum ammonium, 0.05 part;Cholate, 0.05 part;Potassium dihydrogen phosphate, 0.05 part;Propylene glycol, 0.02 part.
Embodiment three
The present invention provides a kind of 3D printing consumptive material of degradable high conductivity, by weight, including following component:Silver is fine Dimension, 5 parts;Cotton fiber, 1.5 parts;Starch, 2 parts;Gelatin, 1.5 parts;Potassium chloride, 0.08 part;Calcium Carbonate, 0.04 part;Bigcatkin willow Element, 0.05 part;Sodium citrate ferrum ammonium, 0.05 part;Cholate, 0.05 part;Potassium dihydrogen phosphate, 0.05 part;Propylene glycol, 0.02 part;Mus Lee's sugar, 0.5 to 0.1 part.
Preferably, by weight, also comprise the following components:
Fluorescent material, 0.1 to 0.5 part.
Example IV
The present invention provides a kind of 3D printing consumptive material of degradable high conductivity, by weight, including following component:Silver is fine Dimension, 5 parts;Cotton fiber, 1.5 parts;Starch, 2 parts;Gelatin, 1.5 parts;Potassium chloride, 0.08 part;Calcium Carbonate, 0.04 part;Bigcatkin willow Element, 0.05 part;Sodium citrate ferrum ammonium, 0.05 part;Cholate, 0.05 part;Potassium dihydrogen phosphate, 0.05 part;Propylene glycol, 0.02 part;Stone Sand, 0.1 to 0.5 part.
Embodiment five
The present invention provides a kind of 3D printing consumptive material of degradable high conductivity, by weight, including following component:Silver is fine Dimension, 5 parts;Cotton fiber, 1.5 parts;Starch, 2 parts;Gelatin, 1.5 parts;Potassium chloride, 0.08 part;Calcium Carbonate, 0.04 part;Bigcatkin willow Element, 0.05 part;Sodium citrate ferrum ammonium, 0.05 part;Cholate, 0.05 part;Potassium dihydrogen phosphate, 0.05 part;Propylene glycol, 0.02 part;Fourth Glycol, 0.03 to 0.05 part.
Embodiment six
The present invention provides a kind of 3D printing consumptive material of degradable high conductivity, by weight, including following component:Silver is fine Dimension, 5 parts;Cotton fiber, 1.5 parts;Starch, 2 parts;Gelatin, 1.5 parts;Potassium chloride, 0.08 part;Calcium Carbonate, 0.04 part;Bigcatkin willow Element, 0.05 part;Sodium citrate ferrum ammonium, 0.05 part;Cholate, 0.05 part;Potassium dihydrogen phosphate, 0.05 part;Propylene glycol, 0.02 part;Institute State carbon nano-tube fibre, 0.5 to 1 part.
Embodiment six
The present invention provides a kind of 3D printing consumptive material of degradable high conductivity, by weight, including following component:Silver is fine Dimension, 5 parts;Cotton fiber, 1.5 parts;Starch, 2 parts;Gelatin, 1.5 parts;Potassium chloride, 0.08 part;Calcium Carbonate, 0.04 part;Bigcatkin willow Element, 0.05 part;Sodium citrate ferrum ammonium, 0.05 part;Cholate, 0.05 part;Potassium dihydrogen phosphate, 0.05 part;Propylene glycol, 0.02 part;Cattle Meat extract, 3 to 5 parts.
In sum, the 3D printing consumptive material of the present invention, is mainly used in 3D printing solid medium, when in use, will After each component weighs by weight, mix, add water, each component is 100 parts with the weight sum of water.In order to ensure viscosity, just 1 part to 3 parts of binding agent or firming agent in material is prepared into paste, can be added.By 3D printer, material is printed Become pie, in order to be prepared into solid medium, the diameter of this solid medium and culture dish match.The culture medium of the present invention is used It is resistant to the microorganism of weak current in selectivity culture, by being passed through unidirectional current in the medium, thus filter out being resistant to electricity The microorganism of stream.The portion of material of the present invention can be degraded, in incubation, by a part of nutrient substance of microbial consumption, Then some of which material can pass through biodegradation, and silver fiber can reclaim.Silver fiber in the present invention enhances to be led Electrically, when after prepared by consumptive material, silver fiber is inter-adhesive in three dimensions, thus spatially building small wire.Form sediment Powder is used for providing carbon source.Gelatin is used for solidifying consumptive material.Potassium chloride provides inorganic salt.And Calcium Carbonate can be used for adjusting acid Basicity.Propylene glycol provides carbon source, can obtain bigger enrichment using propylene glycol for the microorganism of carbon source in this consumptive material.Phosphorus Acid dihydride potassium can provide phosphate.And in order to provide the nutrition of more horn of plenty, Carnis Bovis seu Bubali cream etc. can be added, in order to guarantee to be formed Full culture medium.The invention 3D printing consumptive material is printed culture medium, and be used for screening specific microorganism.Using normal The experiment maneuver of rule cannot prepare the culture medium of this high conductivity, and current 3D printing is also this solid not used for printing The example of body culture medium, and the selectivity culture for microorganism, screening.
Although embodiments of the invention have been shown and described above it is to be understood that above-described embodiment is example Property it is impossible to be interpreted as limitation of the present invention, those of ordinary skill in the art is in the principle without departing from the present invention and objective In the case of above-described embodiment can be changed within the scope of the invention, change, replace and modification.

Claims (8)

1. a kind of 3D printing consumptive material of degradable high conductivity it is characterised in that by weight, including following component:
Silver fiber, 1 to 10 part;
Cotton fiber, 1 to 3 part;
Starch, 1 to 5 part;
Gelatin, 1 to 3 part;
Potassium chloride, 0.05 to 0.1 part;
Calcium Carbonate, 0.04 to 0.05 part;
Salicin, 0.01 to 0.1 part;
Sodium citrate ferrum ammonium, 0.01 to 0.1 part;
Cholate, 0.01 to 0.1 part;
Potassium dihydrogen phosphate, 0.01 to 0.1 part;
Propylene glycol, 0.01 to 0.05 part.
2. the 3D printing consumptive material of degradable high conductivity according to claim 1 is it is characterised in that by weight, including Following component:
Silver fiber, 5 parts;
Cotton fiber, 1.5 parts;
Starch, 2 parts;
Gelatin, 1.5 parts;
Potassium chloride, 0.08 part;
Calcium Carbonate, 0.04 part;
Salicin, 0.05 part;
Sodium citrate ferrum ammonium, 0.05 part;
Cholate, 0.05 part;
Potassium dihydrogen phosphate, 0.05 part;
Propylene glycol, 0.02 part.
3. the 3D printing consumptive material of degradable high conductivity according to claim 2 it is characterised in that by weight, also wraps Include following component:
Rhamnose, 0.5 to 0.1 part.
4. the 3D printing consumptive material of degradable high conductivity according to claim 2 it is characterised in that by weight, also wraps Include following component:
Fluorescent material, 0.1 to 0.5 part.
5. the 3D printing consumptive material of degradable high conductivity according to claim 2 it is characterised in that by weight, also wraps Include following component:
Quartz sand, 0.1 to 0.5 part.
6. the 3D printing consumptive material of degradable high conductivity according to claim 2 it is characterised in that by weight, also wraps Include following component:
Butanediol, 0.03 to 0.05 part.
7. the 3D printing consumptive material of degradable high conductivity according to claim 2 it is characterised in that by weight, also wraps Include following component:
Described carbon nano-tube fibre, 0.5 to 1 part.
8. the 3D printing consumptive material of degradable high conductivity according to claim 2 it is characterised in that by weight, also wraps Include following component:
Carnis Bovis seu Bubali cream, 3 to 5 parts.
CN201610796239.3A 2016-08-31 2016-08-31 High-conductivity degradable 3D printing consumable material Pending CN106380633A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610796239.3A CN106380633A (en) 2016-08-31 2016-08-31 High-conductivity degradable 3D printing consumable material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610796239.3A CN106380633A (en) 2016-08-31 2016-08-31 High-conductivity degradable 3D printing consumable material

Publications (1)

Publication Number Publication Date
CN106380633A true CN106380633A (en) 2017-02-08

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Country Status (1)

Country Link
CN (1) CN106380633A (en)

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105482394A (en) * 2015-12-24 2016-04-13 江苏道勤新材料科技有限公司 High-conductivity 3D printing consumable capable of being degraded and preparation method thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105482394A (en) * 2015-12-24 2016-04-13 江苏道勤新材料科技有限公司 High-conductivity 3D printing consumable capable of being degraded and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
郭成金编著: "《实用覃菌生物学》", 30 November 2014, 天津科学技术出版社 *

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Application publication date: 20170208

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