CN106366853A - Anti-doodling paint special for lift - Google Patents

Anti-doodling paint special for lift Download PDF

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Publication number
CN106366853A
CN106366853A CN201610763945.8A CN201610763945A CN106366853A CN 106366853 A CN106366853 A CN 106366853A CN 201610763945 A CN201610763945 A CN 201610763945A CN 106366853 A CN106366853 A CN 106366853A
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CN
China
Prior art keywords
parts
graffiti
special coating
elevator special
epoxy resin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201610763945.8A
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Chinese (zh)
Other versions
CN106366853B (en
Inventor
陈秀和
贺德明
王青
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sumitomo Fuji Elevator Co Ltd
Original Assignee
Sumitomo Fuji Elevator Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumitomo Fuji Elevator Co Ltd filed Critical Sumitomo Fuji Elevator Co Ltd
Priority to CN201610763945.8A priority Critical patent/CN106366853B/en
Publication of CN106366853A publication Critical patent/CN106366853A/en
Application granted granted Critical
Publication of CN106366853B publication Critical patent/CN106366853B/en
Active legal-status Critical Current
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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16Antifouling paints; Underwater paints
    • C09D5/1656Antifouling paints; Underwater paints characterised by the film-forming substance
    • C09D5/1662Synthetic film-forming substance
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16Antifouling paints; Underwater paints
    • C09D5/1687Use of special additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

The invention discloses anti-doodling paint special for a lift. The anti-doodling paint comprises 10-30 parts of epoxy propoxy dimethyl diethoxy silane, 20-45 parts of epoxy resin, 15-25 pats of large-oil-length tung oil alkyd resin, 5-10 parts of nano-silica, 15-30 parts of silane coupling agent, 10-15 parts of glycerol, 1-5 parts of propylene glycol monomethyl ether acetate, 10-15 parts of butanone, 20-40 parts of deionized water, 1-5 parts of dispersing agent, 10-15 parts of curing agent and 1-5 parts of catalyst. By the adoption of the paint, doodling can be prevented, adhesive tape can be prevented from being pasted into a lift car, and cleanliness and attractiveness in the lift car can be easily maintained.

Description

A kind of anti-graffiti elevator special coating
Technical field
The present invention relates to elevators field, more particularly, to a kind of anti-graffiti elevator special coating.
Background technology
With the propulsion of urbanization process, increasing high buildings and large mansions stand in people at one's side.Elevator is that high level is built Build requisite take instrument, advertisement businessman then using passenger wait and take elevator door time, by sticking in elevator Advertising individual or poster are thus promote product or service to potential user.However, advertising individual or poster all pass through Glue is pasted onto elevator side wall, not only affects attractive in appearance, and is difficult to clean.
Content of the invention
The technical problem to be solved is, provides a kind of anti-graffiti elevator special coating, can be anti-graffiti, also may be used Prevent glue to be pasted onto in car, easily keep neat and artistic in car.
In order to solve above-mentioned technical problem, the invention provides a kind of anti-graffiti elevator special coating, press weight including following The raw material of amount part meter is obtained:
Glycidoxy dimethyldiethoxysilane 10-30 part;
Epoxy resin 20-45 part;
Long oil Oleum Verniciae fordii alkyd resin 15-25 part;
Nano silicon 5-10 part;
Silane coupler 15-30 part;
Glycerol 10-15 part;
Propylene glycol methyl ether acetate 1-5 part;
Butanone 10-15 part;
Deionized water 20-45 part;
Dispersant 1-5 part;
Firming agent 10-15 part;
Catalyst 1-5 part.
As the improvement of such scheme, silane coupler is aminomethylsilanes, aminoethylaminopropyl silane, aminoethyl ammonia One of hydroxypropyl methyl silane or combination.
As the improvement of such scheme, dispersant is PEG 20000.
As the improvement of such scheme, also include bentonite, described bentonite is calculated as 5-10 part by weight.
As the improvement of such scheme, also comprise selected from wetting agent, UV absorbent, pigment, fluidity regulator, in The composition of one or more of mediating recipe and defoamer.
As the improvement of such scheme, the particle diameter of described nano silicon is 10-100nm.
As the improvement of such scheme, described epoxy resin is Bisphenol-a Epoxy Resin.
As the improvement of such scheme, described catalyst is mineral acid.
Implement the embodiment of the present invention, have the advantages that
Nanometer silicon dioxide particle is contained so that nano level rough surface knot is formed on coating microcosmic in inventive formulation Structure, from macroscopically showing as anti-graffiti, hydrophobic oleophobic performance, is pasted onto in car prevented also from glue, can easily maintain Neat and artistic in car.And the material such as silane coupler, epoxy resin can strengthen coating to the adhesion of metal so as to coating has Have the advantages that corrosion-resistant, high strength, electrical insulating property are good.Additionally, not containing the functional group of phenyl ring in composition of raw materials of the present invention, can Avoid producing the noxious substance of acute and chronic poisoning, harmless to health of human body.And the present invention is water paint, overcomes molten The pollution to environment for the dosage form coating, is a kind of environmental protection and safety type coating.
Specific embodiment
For making the object, technical solutions and advantages of the present invention clearer, the present invention will be made further detailed below Description.
The present invention provides a kind of anti-graffiti elevator special coating, and described coating can not only be perfectly adhered in lift car Metallic plate on, coating is difficult to peel off, and adds nano silicon in coating so that being formed coarse on coating microcosmic Surface texture, from macroscopically showing as anti-graffiti, hydrophobic oleophobic performance, be pasted onto in car prevented also from glue so that Car neat and artistic.
Anti-graffiti elevator special coating of the present invention, is obtained including following raw material by weight:
Glycidoxy dimethyldiethoxysilane 10-30 part;
Epoxy resin 20-45 part;
Long oil Oleum Verniciae fordii alkyd resin 15-25 part;
Nano silicon 5-10 part;
Silane coupler 15-30 part;
Glycerol 10-15 part;
Propylene glycol methyl ether acetate 1-5 part;
Butanone 10-15 part;
Deionized water 20-45 part;
Dispersant 1-5 part;
Firming agent 10-15 part;
Catalyst 1-5 part.
Preferably, anti-graffiti elevator special coating of the present invention, is obtained including following raw material by weight:
Glycidoxy dimethyldiethoxysilane 15-25 part;
Epoxy resin 23-40 part;
Long oil Oleum Verniciae fordii alkyd resin 18-23 part;
Nano silicon 6-8 part;
Silane coupler 20-28 part;
Glycerol 12-14 part;
Propylene glycol methyl ether acetate 2-3 part;
Butanone 12-15 part;
Deionized water 30-40 part;
Dispersant 1-3 part;
Firming agent 12-15 part;
Catalyst 2-4 part.
It should be noted that including nanometer titanium dioxide between 10-100nm for the particle size range in coating of the present invention Silicon grain, is evenly dispersed in coating in the presence of dispersant, forms one layer on lift car surface after paint solidification Coating, and due to nano level silica dioxide granule so that nano level rough surface structure is formed on coating microcosmic, from grand Anti-graffiti, hydrophobic oleophobic performance is shown as on sight, is pasted onto in car prevented also from glue, can easily maintain whole in car Clean attractive in appearance.
In addition, in formula glycidoxy dimethyldiethoxysilane and silane coupler cooperation so that coating with The car panel caking property of metal material strengthens, and adhesive force is strong.In addition, silane coupler can also improve nanometer silicon dioxide particle Dispersibility in the epoxy and bonding force, improve the compatibility between nano silicon and epoxy resin.As silane It is aminomethylsilanes that the preferred version of coupling agent has silane coupler, aminoethylaminopropyl silane, aminoethylaminopropyl methyl One of silane or combination.
Epoxy resin of the present invention is water miscible Bisphenol-a Epoxy Resin, and Bisphenol-a Epoxy Resin is cured There are many prominent excellent properties afterwards, such as particularly very strong to the adhesion of metal to various materials, have very strong chemically-resistant rotten Corrosion, mechanical strength are very high, electrical insulating property is good, corrosion-resistant etc..
Preferably, dispersant of the present invention is PEG 20000.
Preferably, also include bentonite in raw material of the present invention, described bentonite is calculated as 5-10 part by weight.
Preferably, also comprise in raw material of the present invention to adjust selected from wetting agent, UV absorbent, pigment, mobility The composition of one or more of agent, nertralizer and defoamer.
Do not contain the functional group of phenyl ring in composition of raw materials of the present invention, can avoid producing the noxious substance of acute and chronic poisoning, Harmless to health of human body.And the present invention is water paint, overcomes the pollution to environment for the solvent based coating, it is a kind of environmental protection peace Holotype coating.
Further illustrate below by way of specific embodiment
Embodiment 1
Anti-graffiti elevator special coating described in the present embodiment, is obtained including following raw material by weight:
15 parts of glycidoxy dimethyldiethoxysilanes;25 parts of epoxy resin;18 parts of long oil Oleum Verniciae fordii alkyd resin;6 parts Nano silicon;20 parts of silane couplers;12 parts of glycerol;2 parts of propylene glycol methyl ether acetates;12 parts of butanone;38 parts of deionizations Water;3 parts of dispersants;12 parts of firming agent;3 parts of catalyst.
Nano silicon is distributed in deionized water under stirring, then sequentially adds glycidoxy diformazan Base diethoxy silane, epoxy resin, propylene glycol methyl ether acetate, glycerol, dispersant, silane coupler, under the conditions of 60 DEG C Heated and stirred 2 hours, finally pours in mixed liquor firming agent and catalyst at a temperature of 55 DEG C heated and stirred 1.5 hours again, Anti-graffiti elevator special coating of the present invention is obtained after cooling.
Embodiment 2
Anti-graffiti elevator special coating described in the present embodiment, is obtained including following raw material by weight:
20 parts of glycidoxy dimethyldiethoxysilanes;35 parts of epoxy resin;20 parts of long oil Oleum Verniciae fordii alkyd resin;7 parts Nano silicon;22 parts of silane couplers;13 parts of glycerol;3 parts of propylene glycol methyl ether acetates;13 parts of butanone;26 parts of deionizations Water;1 part of dispersant;14 parts of firming agent;4 parts of catalyst.
Nano silicon is distributed in deionized water under stirring, then sequentially adds glycidoxy diformazan Base diethoxy silane, epoxy resin, propylene glycol methyl ether acetate, glycerol, dispersant, silane coupler, under the conditions of 60 DEG C Heated and stirred 2 hours, finally pours in mixed liquor firming agent and catalyst at a temperature of 55 DEG C heated and stirred 1.5 hours again, Anti-graffiti elevator special coating of the present invention is obtained after cooling.
Embodiment 3
Anti-graffiti elevator special coating described in the present embodiment, is obtained including following raw material by weight:
22 parts of glycidoxy dimethyldiethoxysilanes;28 parts of epoxy resin;23 parts of long oil Oleum Verniciae fordii alkyd resin;8 parts Nano silicon;26 parts of silane couplers;14 parts of glycerol;5 parts of propylene glycol methyl ether acetates;14 parts of butanone;35 parts of deionizations Water;3 parts of dispersants;12 parts of firming agent;2 parts of catalyst.
Nano silicon is distributed in deionized water under stirring, then sequentially adds glycidoxy diformazan Base diethoxy silane, epoxy resin, propylene glycol methyl ether acetate, glycerol, dispersant, silane coupler, under the conditions of 60 DEG C Heated and stirred 2 hours, finally pours in mixed liquor firming agent and catalyst at a temperature of 55 DEG C heated and stirred 1.5 hours again, Anti-graffiti elevator special coating of the present invention is obtained after cooling.
Embodiment 4
Anti-graffiti elevator special coating described in the present embodiment, is obtained including following raw material by weight:
25 parts of glycidoxy dimethyldiethoxysilanes;33 parts of epoxy resin;22 parts of long oil Oleum Verniciae fordii alkyd resin;8 parts Nano silicon;27 parts of silane couplers;12 parts of glycerol;5 parts of propylene glycol methyl ether acetates;15 parts of butanone;40 parts of deionizations Water;5 parts of dispersants;11 parts of firming agent;2 parts of catalyst.
Nano silicon is distributed in deionized water under stirring, then sequentially adds glycidoxy diformazan Base diethoxy silane, epoxy resin, propylene glycol methyl ether acetate, glycerol, dispersant, silane coupler, under the conditions of 60 DEG C Heated and stirred 2 hours, finally pours in mixed liquor firming agent and catalyst at a temperature of 55 DEG C heated and stirred 1.5 hours again, Anti-graffiti elevator special coating of the present invention is obtained after cooling.
Embodiment 5
Anti-graffiti elevator special coating described in the present embodiment, is obtained including following raw material by weight:
12 parts of glycidoxy dimethyldiethoxysilanes;42 parts of epoxy resin;20 parts of long oil Oleum Verniciae fordii alkyd resin;5 parts Nano silicon;15 parts of silane couplers;12 parts of glycerol;3 parts of propylene glycol methyl ether acetates;15 parts of butanone;32 parts of deionizations Water;4 parts of dispersants;12 parts of firming agent;2 parts of catalyst.
Nano silicon is distributed in deionized water under stirring, then sequentially adds glycidoxy diformazan Base diethoxy silane, epoxy resin, propylene glycol methyl ether acetate, glycerol, dispersant, silane coupler, under the conditions of 60 DEG C Heated and stirred 2 hours, finally pours in mixed liquor firming agent and catalyst at a temperature of 55 DEG C heated and stirred 1.5 hours again, Anti-graffiti elevator special coating of the present invention is obtained after cooling.
Last should be noted that above example is only in order to illustrate technical scheme rather than to present invention guarantor The restriction of shield scope, although being explained in detail to the present invention with reference to preferred embodiment, those of ordinary skill in the art should Understand, technical scheme can be modified or equivalent, without deviating from the essence of technical solution of the present invention And scope.

Claims (8)

1. a kind of anti-graffiti elevator special coating is obtained it is characterised in that including following raw material by weight:
Glycidoxy dimethyldiethoxysilane 10-30 part;
Epoxy resin 20-45 part;
Long oil Oleum Verniciae fordii alkyd resin 15-25 part;
Nano silicon 5-10 part;
Silane coupler 15-30 part;
Glycerol 10-15 part;
Propylene glycol methyl ether acetate 1-5 part;
Butanone 10-15 part;
Deionized water 20-45 part;
Dispersant 1-5 part;
Firming agent 10-15 part;
Catalyst 1-5 part.
2. as claimed in claim 1 anti-graffiti elevator special coating it is characterised in that silane coupler be aminomethylsilanes, One of aminoethylaminopropyl silane, aminoethylaminopropyl methyl-monosilane or combination.
3. as claimed in claim 1 anti-graffiti elevator special coating it is characterised in that dispersant be PEG 20000.
4. as claimed in claim 1 anti-graffiti elevator special coating it is characterised in that also including bentonite, described bentonite is pressed Weight portion is calculated as 5-10 part.
5. as claimed in claim 1 anti-graffiti elevator special coating it is characterised in that also comprise selected from wetting agent, ultraviolet inhale Receive the composition of one or more of agent, pigment, fluidity regulator, nertralizer and defoamer.
6. as claimed in claim 1 anti-graffiti elevator special coating it is characterised in that the particle diameter of described nano silicon is 10-100nm.
7. as claimed in claim 1 anti-graffiti elevator special coating it is characterised in that described epoxy resin be Bisphenol A Type epoxy Resin.
8. as claimed in claim 1 anti-graffiti elevator special coating it is characterised in that described catalyst be mineral acid.
CN201610763945.8A 2016-08-31 2016-08-31 A kind of anti-graffiti elevator special coating Active CN106366853B (en)

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Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
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CN106366853A true CN106366853A (en) 2017-02-01
CN106366853B CN106366853B (en) 2019-01-04

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107312453A (en) * 2017-08-07 2017-11-03 袁洪 A kind of anti-coating and preparation method thereof of keeping a public place clean for scrawling disorderly patch
CN115403988A (en) * 2022-09-01 2022-11-29 林德(广东)新材料有限公司 Formaldehyde-removing negative ion coating and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101585990A (en) * 2009-07-08 2009-11-25 兰州迅美漆业科技有限公司 Aqueous anti-graffiti adhesion resistant paint and preparation method thereof
CN101698770A (en) * 2009-10-30 2010-04-28 广东嘉宝莉化工有限公司 Aqueous anti-doodling paint and preparation method thereof
CN102911584A (en) * 2012-11-21 2013-02-06 戚城 Anti-graffiti anti-sticking nano coating and preparation method thereof
CN104087104A (en) * 2014-07-18 2014-10-08 关锦池 Waterborne anti-doodling coating
CN105400398A (en) * 2015-12-25 2016-03-16 青岛佰众化工技术有限公司 Contamination resistant vehicle nano paint

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101585990A (en) * 2009-07-08 2009-11-25 兰州迅美漆业科技有限公司 Aqueous anti-graffiti adhesion resistant paint and preparation method thereof
CN101698770A (en) * 2009-10-30 2010-04-28 广东嘉宝莉化工有限公司 Aqueous anti-doodling paint and preparation method thereof
CN102911584A (en) * 2012-11-21 2013-02-06 戚城 Anti-graffiti anti-sticking nano coating and preparation method thereof
CN104087104A (en) * 2014-07-18 2014-10-08 关锦池 Waterborne anti-doodling coating
CN105400398A (en) * 2015-12-25 2016-03-16 青岛佰众化工技术有限公司 Contamination resistant vehicle nano paint

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107312453A (en) * 2017-08-07 2017-11-03 袁洪 A kind of anti-coating and preparation method thereof of keeping a public place clean for scrawling disorderly patch
CN115403988A (en) * 2022-09-01 2022-11-29 林德(广东)新材料有限公司 Formaldehyde-removing negative ion coating and preparation method thereof

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